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171.
Abundant cone sheets form one of the last magmatic stages in the Tertiary central complex on the Scottish peninsula of Ardnamurchan and can be grouped into a younger inner and an older outer suite relative to a gabbro intrusion. Most of the cone-sheets consist of tholeiitic to transitional basalt with MgO contents between 7.5% and 4%, although more evolved rocks also occur (to 0.5% MgO). The mafic samples are slightly enriched in the light rare earth elements (Chondrite-normalized La/Sm ∼1.1), the enrichment increases in the more evolved rocks. The compositional variation of the basaltic rocks is mainly due to crystal fractionation of olivine and clinopyroxene at depths of ∼10 km but trace elements show simultaneous assimilation of Archean Lewisian granulite crust. The andesitic to rhyolitic lavas formed by fractional crystallization from the contaminated basaltic magma coupled with assimilation of Proterozoic Moine metasediments at uppermost crustal levels. The occurrence of composite cone-sheets with basaltic and rhyolitic parts and mixtures between these magmas implies that the melts ascended successively but within a short period of time. The parental magmas of the Ardnamurchan cone-sheets must have formed at relatively shallow depths in the mantle and are comparable to the youngest tholeiitic lavas from the neighbouring island of Mull. Received: 5 June 1997 / Accepted: 12 November 1997  相似文献   
172.
The aim of this study is to intervalidate observations and numerical simulation results for the turbulent dissipation rate under strong wind conditions in the Northern North Sea during one week in October 1998. The observations were obtained by spatially and temporally averaging measurements of small-scale shear with a free-falling shear probe. The 1D numerical model used for this study is based on a state-of-the-art two-equation k− turbulence model with an algebraic second-moment closure scheme. It is discussed by means of annual and seasonal model simulations how the influence of heat and salt advection and internal waves can be accounted for. After these precautions, the agreement between observations and simulations of the turbulent dissipation rate are fairly good. Remaining differences cannot only be explained by problems such as undersampling and noise level, but also by idealising model assumptions.  相似文献   
173.
Micro-organisms must be included in any hydrogeochemical modelling efforts in the ongoing Swedish programme to characterize potential sites for the geological disposal of spent nuclear fuel. This paper presents the development and testing of several methods for estimating the total numbers of micro-organism groups and amounts of their biomass in groundwater, their diversity, and the rates of microbial processes. The enumeration and cultivation methods were tested and evaluated on groundwater from boreholes at 450 m depth in the Äspö Hard Rock Laboratory (HRL), Sweden, and from two potential sites for a final repository of spent nuclear fuel, Forsmark and Laxemar. The reproducibility of the methods between parallel samples and over time was investigated and found to be excellent. Nitrate-, iron-, manganese- and sulphate-reducing bacteria and acetogens and methanogens were found in numbers up to approximately 87,000 cells L−1 groundwater from the studied sites. A methodology that analysed microbial process rates was developed and tested under open and closed controlled in situ conditions in a circulation system situated 447 m underground in the MICROBE laboratory at the Äspö HRL. The sulphide and acetate production rates were determined to be 0.08 and 0.14 mg L−1 day−1, respectively. The numbers of sulphide- and acetate-producing micro-organisms increased concomitantly in the analysed circulating groundwater. Flushing the sampled circulation aquifer created an artefact, as it lowered the sulphide concentration. Microbial and inorganic processes involved in sulphur transformations are summarized in a conceptual model, based on the observations and results presented here. The model outlines how dissolved sulphide may react with Fe(III) and Fe(II) to form solid phases of iron sulphide and pyrite. Sulphide will, consequently, continuously be removed from the aqeous phase via these reactions, at a rate approximately equalling the rate of production by microbial sulphate reduction.  相似文献   
174.
Naturally occurring stable and radioactive isotopes were used as environmental tracers to investigate contaminant metal mobilization processes in a metal smelter dump mainly consisting of slag. Water emerging from the dump at a spring is heavily contaminated by metals. The smelter dump contains minor amounts of flue dust, a material which shows a high potential for metal mobilization. Nearby dumps mainly consist of low-grade ore. Concentration patterns of 238U, 226Ra and 210Pb determined in sediment deposited close to the contaminated spring reveal the flue dust to be the major local metal source rather than the slag or the low-grade ore. Contamination pathways inside the dump were investigated using hydrological, chemical and isotopic data. Strong negative correlation between water discharge and metal concentration in the spring water suggests, besides short-term dilution of the metal concentration by direct rainwater runoff, distinct long-term dilution of the spring water by groundwater being discharged at a significantly increased rate as a result of heavy rains. δ18O and δD signatures of rain, local groundwater and spring water confirm the importance of groundwater derived from the local aquifer. Another hydrological component with importance for metal mobilization was found to be water that is recharged in the dump itself. Tritium analysis allowed an assessment of the probable residence time of that water component in the smelter dump. Since that water component seems to represent a major local contamination pathway the findings of the study are of substantial importance for site remediation planning. As a primary result it could be stated that covering the dump would not result in any noteworthy short-term improvement of the spring water quality. First significant effects would only be visible after 2–3 decades at the earliest.  相似文献   
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177.
A new olivine reference material – MongOL Sh11‐2 – for in situ analysis has been prepared from the central portion of a large (20 × 20 × 10 cm) mantle peridotite xenolith from a ~ 0.5 My old basaltic breccia at Shavaryn‐Tsaram, Tariat region, central Mongolia. The xenolith is a fertile mantle lherzolite with minimal signs of alteration. Approximately 10 g of 0.5–2 mm gem quality olivine fragments were separated under binocular microscope and analysed by EPMA, LA‐ICP‐MS, SIMS and bulk analytical methods (ID‐ICP‐MS for Mg and Fe, XRF, ICP‐MS) for major, minor and trace elements at six institutions world‐wide. The results show that the olivine fragments are sufficiently homogeneous with respect to major (Mg, Fe, Si), minor and trace elements. Significant inhomogeneity was revealed only for phosphorus (homogeneity index of 12.4), whereas Li, Na, Al, Sc, Ti and Cr show minor inhomogeneity (homogeneity index of 1–2). The presence of some mineral and fluid‐melt micro‐inclusions may be responsible for the inconsistency in mass fractions obtained by in situ and bulk analytical methods for Al, Cu, Sr, Zr, Ga, Dy and Ho. Here we report reference and information values for twenty‐seven major, minor and trace elements.  相似文献   
178.
Suspended particulate matter (SPM) fluxes and dynamics are investigated in the East Frisian Wadden Sea using a coupled modeling system based on a hydrodynamical model [the General Estuarine Transport Model (GETM)], a third-generation wave model [Simulating Waves Nearshore (SWAN)], and a SPM module attached to GETM. Sedimentological observations document that, over longer time periods, finer sediment fractions disappear from the Wadden Sea Region. In order to understand this phenomenon, a series of numerical scenarios were formulated to discriminate possible influences such as tidal currents, wind-enhanced currents, and wind-generated surface waves. Starting with a simple tidal forcing, the considered scenarios are designed to increase the realism step by step to include moderate and strong winds and waves and, finally, to encompass the full effects of one of the strongest storm surges affecting the region in the last hundred years (Storm Britta in November 2006). The results presented here indicate that moderate weather conditions with wind speeds up to 7.5 m/s and small waves lead to a net import of SPM into the East Frisian Wadden Sea. Waves play only a negligible role during these conditions. However, for stronger wind conditions with speeds above 13 m/s, wind-generated surface waves have a significant impact on SPM dynamics. Under storm conditions, the numerical results demonstrate that sediments are eroded in front of the barrier islands by enhanced wave action and are transported into the back-barrier basins by the currents. Furthermore, sediment erosion due to waves is significantly enhanced on the tidal flats. Finally, fine sediments are flushed out of the tidal basins due to the combined effect of strong erosion by wind-generated waves and a longer residence time in the water column because of their smaller settling velocities compared to coarser sediments.
Karsten A. LettmannEmail:
  相似文献   
179.
Stationarity has traditionally been a requirement of geostatistical simulations. A common way to deal with non-stationarity is to divide the system into stationary sub-regions and subsequently merge the realizations for each region. Recently, the so-called partition approach that has the flexibility to model non-stationary systems directly was developed for multiple-point statistics simulation (MPS). The objective of this study is to apply the MPS partition method with conventional borehole logs and high-resolution airborne electromagnetic (AEM) data, for simulation of a real-world non-stationary geological system characterized by a network of connected buried valleys that incise deeply into layered Miocene sediments (case study in Denmark). The results show that, based on fragmented information of the formation boundaries, the MPS partition method is able to simulate a non-stationary system including valley structures embedded in a layered Miocene sequence in a single run. Besides, statistical information retrieved from the AEM data improved the simulation of the geology significantly, especially for the deep-seated buried valley sediments where borehole information is sparse.  相似文献   
180.
Here we present results of a 1-year realistic North Sea simulation from the new model GETM (general estuarine transport model) and assess the capabilities of this model by comparing them to model results from the well-known HAMSOM (Hamburg shelf sea and ocean model) model, in situ data from the North Sea project and satellite-derived sea-surface temperature data. The annual cycle and the spatial variability of stratification and mixing in the North Sea is simulated. It is shown that the new model is successful in reproducing the general temporal and spatial dynamics of the North Sea. The major advantages of GETM for achieving improved results in this simulation are the implementation of general vertical coordinates, of a state-of-the-art turbulence model and of higher-order advection schemes. By exploiting the full capabilities of these features a more realistic simulation could be achieved. We found that the greatest differences in the model results are produced by applying advection schemes of different complexity. Here we are able to demonstrate that better advection schemes lead to stronger horizontal gradients and stronger vertical stratification during summer. When comparing these results to measurements from the North Sea project and to satellite data, we find that these stronger gradients are more realistic. Therefore, we consider it as essential to use such high-order advection schemes if the spatial variability of estuarine or shelf seas like the North Sea is to be resolved adequately. The advanced turbulence closure scheme also contributed to more realistic simulation of the vertical stratification. Finally, general vertical coordinates better resolve the shallow regions, but are also useful for the deeper regions, as they allow a better estimation of sea-surface temperature compared to traditional coordinates.Responsible Editor: Phil Dyke  相似文献   
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