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11.
Labradorite was altered artificially by HC1 solution ranging from M = 1 to M = 0.003 at 245 and 230°C. The products of alteration were examined by X-ray diffraction, electron microscopy, electron diffraction, infrared spectroscopy and the electron microprobe and the solution was analyzed chemically.Amorphous silica only was formed in solutions with MHCl = 1 and MHCl = 0.3. In a solution with MHCl = 0.2, amorphous silica was initially formed, later dissolved and replaced by kaolinite. A mixture of microcrystalline boehmite and amorphous aluminosilicate was formed, altering to kaolinite in solutions with MHCl = 0.1 and 0.3. Small amounts of kaolinite were initially formed but the alteration soon stopped in solution with MHCl = 0.003. Relationships between the alteration processes and pH of the solutions can be roughly explained by using solubility diagrams assuming the congruent dissolution of labradorite and precipitation of the products in partial equilibrium. However, these assumptions are not valid with strongly acid solutions.The rate of dissolution of labradorite is controlled not only by its surface area, but also by the diffusion of matter through the layer of alteration products. 相似文献
12.
An unusual association of chromite and hornblende was found in the spessartites of andesite composition, occurring as a dike
swarm associated with a Cretaceous granite batholith. The spessartites are largely porphyritic with phenocrysts of either
hornblende or augite. One dike, comprising a finegrained spessartite, exhibits distinct chilled selvages of aphanitic facies.
The chromites in the fine-grained and augite-spessartites are significantly higher in Cr/ (Cr+Al) than those occurring rarely
as inclusions in the phenocrystic hornblendes in the hornblende spessartite, although both are similar in Mg/ (Mg+Fe), Fe2O3, and TiO2. The phenocrystic hornblendes are titaniferous pargasite with high Mg/ (Mg+Fe), and differ in their higher octahedral Al
from the groundmass hornblendes including those in the fine-grained spessartite. The crystallization sequence in the phenocrystic
hornblende-bearing spessartites is Al-rich chromite, phenocrystic hornblende, and plagioclase without pyroxene, suggesting
a high water content in the magma and the start of the crystallization at relatively high pressures. The finegrained spessartite
from which the porphyritic spessartites have been derived by fractionation of dominant mafic minerals, has the high Mg-value
and Cr content equivalent to those in primitive, undifferentiated basalts, although still andesitic in SiO2 content. Chemically similar magnesian andesites, although uncommon, found in some orogenic calc-alkalic suites may represent
a magma composition in equilibrium with mantle peridotite under the condition of high water pressures. 相似文献
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Yoshida A Nomura H Toyoda K Nishino T Seo Y Yamada M Nishimura M Wada M Okamoto K Shibata A Takada H Kogure K Ohwada K 《Marine pollution bulletin》2006,52(1):89-95
Microbial responses to the addition of oil with or without a chemical dispersant were examined in mesocosm and microcosm experiments by using denaturing gradient gel electrophoresis of bacterial ribosomal DNA and direct cell counting. When a water-soluble fraction of oil was added to seawater, increases in cell density were observed in the first 24h, followed by a decrease in abundance and a change in bacterial species composition. After addition of an oil-dispersant mixture, increases in cell density and changes in community structure coincided, and the amount of bacteria remained high. These phenomena also occurred in response to addition of only dispersant. Our results suggest that the chemical dispersant may be used as a nutrient source by some bacterial groups and may directly or indirectly prevent the growth of other bacterial groups. 相似文献
16.
Composite analysis was conducted using high-frequency radar data obtained during 2006–2015 in order to gain a better understanding of the current field in the Ariake Sea. The seasonally averaged surface current in the Ariake Sea was directed southward in all seasons, except around river mouths during summer. Heavy rainfall enhanced the outflow along the eastern coast of the Shimabara Peninsula from Isahaya Bay to the southern area 2–5 days after heavy rainfall. Spring–neap differences were clearly seen in the southward current along the Shimabara Peninsula. Interannual variation in the M2 tidal current amplitude was synchronized with the lunar nodal cycle. 相似文献
17.
Bhaskar Preethi Milind Mujumdar Amita Prabhu Ramesh Kripalani 《Asia-Pacific Journal of Atmospheric Sciences》2017,53(2):305-325
Coupled Model Inter-comparison Project Phase 5 (CMIP5) model outputs of the South and East Asian summer monsoon variability and their tele-connections are investigated using historical simulations (1861-2005) and future projections under the RCP4.5 scenario (2006-2100). Detailed analyses are performed using nine models having better representation of the recent monsoon teleconnections for the interactive Asian monsoon sub-systems. However, these models underestimate rainfall mainly over South Asia and Korea-Japan sector, the regions of heavy rainfall, along with a bias in location of rainfall maxima. Indeed, the simulation biases, underestimations of monsoon variability and teleconnections suggest further improvements for better representation of Asian monsoon in the climate models. Interestingly, the performance of Australian Community Climate and Earth System Simulator version 1.0 (ACCESS1.0) in simulating the annual cycle, spatial pattern of rainfall and multi-decadal variations of summer monsoon rainfall over South and East Asia appears to more realistic. In spite of large spread among the CMIP5 models, historical simulations as well as future projections of summer monsoon rainfall indicate multi-decadal variability. These rainfall variations, displaying certain epochs of more rainfall over South Asia than over East Asia and vice versa, suggest an oscillatory behaviour. Teleconnections between South and East Asian monsoon rainfall also exhibit a multi-decadal variation with alternate epochs of strengthening and weakening relationship. Furthermore, large-scale circulation features such as South Asian monsoon trough and north Pacific subtropical high depict zonal oscillatory behaviour with east-west-east shifts. Periods with eastward or westward extension of the Mascarene High, intensification and expansion of the upper tropospheric South Asian High are also projected by the CMIP5 models. 相似文献
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Metamorphic condition of a regional metamorphic complex in the Omuta district in northern Kyushu,southwest Japan 下载免费PDF全文
A high‐temperature (T) metamorphic complex occurs in the Omuta district, northern Kyushu, Japan. Three metamorphic zones are defined based on pelitic mineral assemblage, i.e. chlorite–biotite zone, muscovite–andalusite zone and sillimanite–K‐feldspar zone with ascending metamorphic grade from north to south. Two isograds trend approximately east–west, which is oblique to the boundary between the metamorphic complex and the Tamana Granodiorite located on the southeast. The metamorphic condition of two pelitic rocks that occur in the muscovite–andalusite zone and sillimanite–K‐feldspar zone are estimated as 510 ±30 °C, 300 ±60 MPa and 720 ±30 °C, 620 ±60 MPa, respectively. Thermodynamic consideration reveals that use of the same geothermobarometer enables precise determination of the difference in pressure between the samples as 320 ±10 MPa. This indicates that the pelitic samples were metamorphosed at different depth by 11–12 km that is significantly larger than the geographic distance of 6.8 km between the sample localities. This also suggests that crustal thinning took place after the high‐T metamorphism. The high‐T metamorphic complex is, therefore, not of static contact metamorphism but of dynamic regional metamorphism. The present result combined with petrological and chronological similarities implies that this complex suffered the regional Ryoke metamorphism. 相似文献
20.
Progressive changes in lithological association of the Sanbagawa metamorphic complex,Southwest Japan: Relict clinopyroxene and detrital zircon perspectives 下载免费PDF全文
The main tectono‐stratigraphic unit (Shirataki unit) of the Sanbagawa metamorphic complex in central Shikoku is characterized by abundant mafic schist layers that show the mid‐ocean ridge basalt (MORB) affinity. These MORB‐derived schist layers are absent in a southern (structurally lower) domain within the unit. Instead, sporadic occurrences of small metabasite lenses that contain relict igneous minerals (Ti‐rich augite and kaersutite) indicative of alkali basalt magmatism are newly recognized in the southern domain. Compositions of relict clinopyroxene in metabasalt are useful to identify the tectonic setting and origin of the protolith basalt, and those in each unit of the Sanbagawa metamorphic complex are presented. The metamorphic grade of the Shirataki unit generally increases structurally upwards in the southern side of the highest‐grade zone, and metamorphic zonation is subparallel to lithostratigraphic succession. The protolith assemblage of the Shirataki unit shows a distinct change from the southern low‐grade domain (lower Shirataki subunit) composed of terrigenous sedimentary rocks (mudstone and sandstone) with minor alkali basalt to the northern higher‐grade domain (upper Shirataki subunit) consisting of terrigenous and pelagic sedimentary rocks with abundant MORB. The youngest detrital zircon U–Pb ages (ca 95–90 Ma) suggest that both domains have Late Cretaceous depositional ages at the trench. Progressive peeling of oceanic plate stratigraphy during subduction can account for the observed change of lithological association in the Shirataki unit. 相似文献