Determination of reaction kinetics using grain size: An application for metamorphic zircon growth          下载免费PDF全文

Kazuhiro Miyazaki  Yasushi Mori  Tadao Nishiyama  Kenshi Suga  Miki Shigeno 《地学学报》2018,30(2):162-168

The reaction kinetics of metamorphic minerals can be subdivided into interface‐ and diffusion‐controlled kinetics. The discrimination of reaction kinetics is crucial for estimating reaction rates. Here, we propose a new and simple method for discriminating reaction kinetics. This method requires measuring only the initial and final grain sizes during growth. The reaction kinetics is inferred from different plotted arrays of initial vs. final grain sizes after the mineral growth. Using metamorphic zircon, we take detrital core sizes as the initial sizes and post‐metamorphic grain sizes as the final sizes. The application of the method to the subduction‐related high‐pressure Nagasaki metamorphic complex in Japan shows that this metamorphic zircon grew under interface‐controlled kinetics even at the relatively low temperature of 440°C. This method is potentially applicable to other minerals that have time‐markers, such as chemical zoning or internal structures that are captured at a given point in time during growth.  相似文献   

Radio imaging of the Subaru/XMM–Newton Deep Field – I. The 100-μJy catalogue, optical identifications, and the nature of the faint radio source population     

Chris Simpson  Alejo Martínez-Sansigre  Steve Rawlings  Rob Ivison  Masayuki Akiyama  Kazuhiro Sekiguchi  Tadafumi Takata  Yoshihiro Ueda  Mike Watson 《Monthly notices of the Royal Astronomical Society》2006,372(2):741-757

We describe deep radio imaging at 1.4 GHz of the 1.3-deg² Subaru/ XMM–Newton Deep Field (SXDF), made with the Very Large Array in B and C configurations. We present a radio map of the entire field, and a catalogue of 505 sources covering 0.8 deg² to a peak flux density limit of 100 μJy. Robust optical identifications are provided for 90 per cent of the sources, and suggested identifications are presented for all but 14 (of which seven are optically blank, and seven are close to bright contaminating objects). We show that the optical properties of the radio sources do not change with flux density, suggesting that active galactic nuclei (AGN) continue to contribute significantly at faint flux densities. We test this assertion by cross-correlating our radio catalogue with the X-ray source catalogue and conclude that radio-quiet AGN become a significant population at flux densities below 300 μJy, and may dominate the population responsible for the flattening of the radio source counts if a significant fraction of them are Compton-thick.  相似文献   

Field measurement and modeling of near-bed sediment transport processes with fluid mud layer in Tokyo Bay     

Nakagawa  Yasuyuki  Nadaoka  Kazuo  Yagi  Hiroshi  Ariji  Ryuichi  Yoneyama  Haruo  Shirai  Kazuhiro 《Ocean Dynamics》2012,62(10):1535-1544

Tokyo Bay is one of the estuaries in Japan with a high population of almost 26 million people in the basin area. One of the major concerns for the environment in this water area is the decreasing ecosystem functions including the deterioration of water and sediment qualities caused by various anthropogenic activities. Since the bottom sediments around almost the entire area of the inner bay consist of fine materials with a high organic content, which cause the deterioration of water quality through processes such as hypoxia, an understanding of the fine sediment dynamics in the Bay is crucial for an environmental assessment of the water area. This paper proposes a model for the key processes of fine sediment dynamics, which reflects field data about muddy bed structures and their dynamics obtained during the monitoring campaign in 2007. One of the specific features of the sediment in the Bay at present is the persistent existence of fluid mud layers (water content over 300 %) with a thickness of around a few decimeters, which might be caused by deposition of abundant organic particles due to eutrophication. The present study shows that diffusion flux model delivers quite reliable results for estimating erosion flux from the top of fluid mud layers after calibrating the model parameter against the time series data of vertical flux measured by an acoustic Doppler velocimeter system. This study also derives analytical solutions, based on the Bingham fluid concept, of advection flux in the fluid mud layer on which external shear stress force is applied.

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Long-term (36-year) observations on the dynamics of the fish-killing raphidophyte Chattonella in Harima-Nada,eastern Seto Inland Sea,Japan     

Tetsuya Nishikawa  Yutaka Hori  Satoshi Nagai  Kazutaka Miyahara  Yukinobu Nakamura  Kazuhiro Harada  Kuninao Tada  Ichiro Imai 《Journal of Oceanography》2014,70(2):153-164

Long-term changes of the fish-killing raphidophyte Chattonella spp. (Chattonella antiqua, Chattonella marina and Chattonella ovata) were examined in relation to environmental factors at 19 sampling stations in Harima-Nada, eastern Seto Inland Sea, Japan, for 36 years from 1973 to 2008. Long-term trends in the dynamics of Chattonella populations were considered to relate to environmental factors such as nutrient concentrations and water temperature. High nutrient levels during the period from the 1970s to the early 1980s have contributed to the high cell density and large-scale red tides of Chattonella spp. in Harima-Nada. However, nutrient levels exhibited a decreasing trend thereafter, and it is thought that Chattonella spp. cannot form large-scale blooms under the present conditions. After the mid-1990s, the occurrence period of vegetative cells of Chattonella spp. has been several weeks or 1 month earlier than that of the 1970s and early 1980s, and the appearance frequency of Chattonella spp. has increased in the northern coastal area, although the cell density and the spatial scale of the distribution have become lower and smaller than those in the previous decades. It is suggested that the timing of germination of Chattonella cysts has become earlier as a result of the increase in water temperature, and the chances of vegetative growth have also increased, especially at the northern coast where most of large rivers discharge into the Harima-Nada. In addition, the present results revealed that fewer diatoms were also one of the significant factors for the high abundance of Chattonella spp. in Harima-Nada.  相似文献   

Geological setting of basaltic rocks in an accretionary complex,Khangai–Khentei Belt,Mongolia     

Kazuhiro Tsukada  Yuki Nakane  Koshi Yamamoto  Toshiyuki Kurihara  Shigeru Otoh  Kenji Kashiwagi  Minjin Chuluun  Sersmaa Gonchigdorj  Manchuk Nuramkhaan  Masakazu Niwa  Tetsuya Tokiwa 《Island Arc》2013,22(2):227-241

We describe the mode of occurrence and geochemical characteristics of basalts, in the Khangai–Khentei belt in Mongolia, overlain by Middle Paleozoic radiolarian chert in an extensive accretionary complex. These basalts are greatly enriched in K, Ti, Fe, P, Rb, Ba, Th, and Nb in comparison to the composition of the mid‐ocean ridge basalts, indicative of within‐plate alkaline type. Ti/Y vs Nb/Y and MnO/TiO₂/P₂O₅ ratios of the basalts also suggest within‐plate affinities. Considering the geochemical characteristics as well as the conformable relationship with the overlying radiolarian chert, the alkaline basalts were clearly not continental but formed a pelagic oceanic island. The mode of occurrence and geochemistry of the basalts show that the alkaline basaltic volcanic activity had taken place to form an oceanic island in the Paleozoic pelagic region sufficiently far from continents to allow radiolarian ooze accumulation.  相似文献   

Another sea area separated from the Panthalassic Ocean in the Norian,the Late Triassic: The lowest Sr isotopic composition of the Ishimaki limestone in central Japan     

Kazuhiro Suzuki  Yoshihiro Asahara  Koichi Mimura  Tsuyoshi Tanaka 《Chemie der Erde / Geochemistry》2012,72(1):77-84

Mt. Ishimaki is the Jurassic accretionary complex of the Chichibu Belt in Toyohashi City, near Nagoya in central Japan. The Ishimaki limestone is thought to be seamount-type limestone. The P₁ elements of the conodonts Norigondolella navicula and Ancyrogondolella quadrata found in the limestone indicate it is of Norian age. The Sr isotopic compositions of 45 Ishimaki limestone samples ranged from 0.7055 to 0.7077. Eighteen of these samples had lower Sr isotopic compositions than the lowest Sr isotopic composition (0.7068) of seawater throughout the Phanerozoic. The Sr isotopic compositions in the limestone block are generally lower at the base of the block and higher at the top. The present Sr isotopic compositions of the Ishimaki limestone are unlikely to have been reduced by post-depositional alteration because most of the limestone samples had a low amount of Mn (<300 ppm) or high Sr/Mn ratios (>2) and the conodont elements had low (1–2) CAI (conodont alteration index) values. Additionally, there was little acid-insoluble residue. Thus, the low Sr isotopic compositions are thought to represent the strontium of the past ambient seawater. The low Sr isotopic compositions are in complete disagreement with the generally recognised range of seawater Sr isotopic compositions in the Norian stage of the Late Triassic (0.7075–0.7078) because the depositional environment of the Ishimaki limestone was closed or semi-closed from the Panthalassic Ocean. Therefore, the Sr isotopic composition of the limestone differs from that of the Panthalassic seawater. The low Sr isotopic compositions were probably affected by Sr inflows from mafic oceanic crust by hydrothermal fluid circulation or from hinterlands surrounded by mafic rocks by river water circulation.  相似文献   

Concentration of polychlorinated biphenyls (PCBs) in beached resin pellets: variability among individual particles and regional differences   总被引：1，自引：0，他引：1  

Endo S  Takizawa R  Okuda K  Takada H  Chiba K  Kanehiro H  Ogi H  Yamashita R  Date T 《Marine pollution bulletin》2005,50(10):1103-1114

Concentrations of polychlorinated biphenyls (PCBs) in beached resin pellets were examined to reveal variability between individual particles and differences among beaches. Fifty-five resin pellets from a beach in Tokyo were individually analyzed for PCBs, and showed concentrations ranging from <28 to 2,300 ng/g. This indicates that concentrations are highly variable between particles. Among several characters, discoloration (e.g., yellowing) had a positive relationship with PCB concentration: discolored pellets contained more PCBs than others on most of the beaches sampled. Given the color-selective ingestion of food by some organisms, this may be ecotoxicologically important. Measurements of samples from 47 beaches in Japan showed regional differences in PCB concentrations in resin pellets consistent with those in mussels. Sporadic high concentrations of PCBs were also found in pellets from remote islands, suggesting that resin pellets could be the dominant route of exposure to the contaminants at remote sites. The similarity of PCB concentrations between resin pellets and mussels suggests a potential use of resin pellets to monitor pollution in seawater.  相似文献   

The infrared and ultraviolet absorptions of micro-organisms and their relation to the Hoyle-Wickramashinghe hypothesis     

Shin Yabushita  Kazuhiro Wada 《Astrophysics and Space Science》1985,110(2):405-411

Absorption of yeast andE. coli in the infrared and ultraviolet regions and that of diatomaceous soil in the infrared region have been obtained. Electron microscope photographs of aggregates ofE. coli have also been obtained. These results are discussed in relation to the Hoyle-Wickramasinghe hypothesis regarding the nature of interstellar grains.Department of Nuclear Engineering  相似文献   

Thematic Section: Fluids and metamorphism     

Toru Takeshita  Kazuhiro Miyazaki 《Island Arc》2007,16(1):4-5

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Formation of a high-temperature metamorphic complex due to pervasive melt migration in the hot crust   总被引：1，自引：0，他引：1  

Kazuhiro  Miyazaki 《Island Arc》2007,16(1):69-82

Abstract   Detailed reviews of metamorphic thermal structures and spatial distributions of granitic rocks in the high- T Higo metamorphic complex (HMC), central Kyushu, Japan, and Ryoke metamorphic complex in the Yanai district (RMC-Y), southwest Japan, reveal that the high-grade metamorphic rocks were associated with migmatites or syn-metamorphic granitoids. The close association of these rocks suggests that transport and solidification of granitic melts are appreciable heat sources. Partial melting of the pelitic host resists heating of the crust due to its endothermic reaction (i.e. absorption of latent heat). However, the effects of slower thermal evolution produced by partial melting are limited by the boundary conditions assumed for the HMC and RMC-Y. New thermal numerical modeling reveals that the volume fraction of the solidified melt products and the duration of melt migration required for crustal heating to a certain temperature decrease with increasing rates of melt migration. The model predicts that the melt migration rate during formation of the HMC is about three to 10 times higher than that of the RMC-Y, and the corresponding duration of melt migration is about one order of magnitude shorter. The model described here also explains the apparently contradictory observations made in different structural units of the RMC-Y: the metamorphic pressure–temperature ( P-T ) ratio of the southern unit is higher than those of the central and northern units, even though the volume fraction of granitic rocks in the southern unit is larger. The model suggests that the melt migration rate in the northern and central units was faster than that in the southern unit. Overall, the model implies that variations of metamorphic field P-T arrays and the spatial distributions of granitic rocks in high- T metamorphic complexes may be explained simply by variations in the rate and duration of melt migration in the hot crust.  相似文献