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31.
Katsumi Hirose 《Marine Chemistry》1990,28(4)
Chemical speciation of particulate metals in seawater was examined theoretically. Mass balance considerations showed that the apparent conditional stability constant, defined for organically binding metals in suspended particles, coincides with the conditional stability constant determined for the corresponding metal-organic complexes dissolved in seawater. This hypothesis suggests that some metals, which are present as organic complexes (e.g. copper), are directly associated with particulate organic matter. Metals, whose free ion is buffered by organic and/or inorganic ligands, may be used as indicators of the presence of particulate organic matter in the marine environment. 相似文献
32.
Kurt Leinenweber Wataru Utsumi Yoshihiko Tsuchida Takehiko Yagi Kei Kurita 《Physics and Chemistry of Minerals》1991,18(4):244-250
New high-pressure orthorhombic (GdFeO3-type) perovskite polymorphs of MnSnO3 and FeTiO3 have been observed using in situ powder X-ray diffraction in a diamond-anvil cell with synchrotron radiation. The materials are produced by the compression of the lithium niobate polymorphs of MnSnO3 and FeTiO3 at room temperature. The lithium niobate to perovskite transition occurs reversibly at 7 GPa in MnSnO3, with a volume change of -1.5%, and at 16 GPa in FeTiO3, with a volume change of -2.8%. Both transitions show hysteresis at room temperature. For MnSnO3 perovskite at 7.35 (8) GPa, the orthorhombic cell parameters are a=5.301 (2) A, b=5.445 (2) Å, c=7.690 (8) Å and V= 221.99 (15) Å3. Volume compression data were collected between 7 and 20 GPa. The bulk modulus calculated from the compression data is 257 (18) GPa in this pressure region. For FeTiO3 perovskite at 18.0 (5) GPa, cell parameters are a=5.022 (6) Å, b=5.169 (5) Å, c=7.239 (9) Å and V= 187.94 (36) Å3. Based on published data on the quench phases, the FeTiO3 perovskite breaks down to a rocksalt + baddelyite mixture of FeO and TiO2 at 23 GPa. This is the first experimental verification of the pressure-induced breakdown of a perovskite to simple oxides. 相似文献
33.
Abstract. Multi-channel seismic data obtained from the Nankai accretionary prism and forearc basin system has been studied to elucidate the migration and accumulation process of gas to the BGHS and examine the distribution pattern of BSRs and characteristic reflections associated with them.
BSRs are distributed widely in the Nankai accretionary prism and associated forearc basins (33,000 km2 ) and 90 % of them have migration and recycling origins. The widest distribution of the BSRs can be seen at the prism. A correlation between the BSR distributions and prism size shows that the BSRs tend to be more well-developed in a prism of large size. This suggests that a large prism may produce much amount of gas-bearing fluids that migrate to the BGHS and form the BSRs (tectonic control), hi the forearc basins, the BSRs are identified at topographic highs, anticlines and basin margins (structural control).
The upward migration of gas-bearing fluids is carried out through permeable sand layers and as a result, the distribution of BSRs is confined to alternating beds of sand and mud facies (sedimentary control). However, if there is enough time for upward migration and accumulation of gas to the BGHS, the BSRs can be generated widely in low-permeable mud facies (time control).
Those results imply that structural, tectonic, sedimentary and time controls are primary factors to decide the distribution of BSRs in the Nankai Trough area. 相似文献
BSRs are distributed widely in the Nankai accretionary prism and associated forearc basins (33,000 km
The upward migration of gas-bearing fluids is carried out through permeable sand layers and as a result, the distribution of BSRs is confined to alternating beds of sand and mud facies (sedimentary control). However, if there is enough time for upward migration and accumulation of gas to the BGHS, the BSRs can be generated widely in low-permeable mud facies (time control).
Those results imply that structural, tectonic, sedimentary and time controls are primary factors to decide the distribution of BSRs in the Nankai Trough area. 相似文献
34.
Principal fault zone width and permeability of the active Neodani fault, Nobi fault system, Southwest Japan 总被引:2,自引:0,他引:2
A. Tsutsumi S. Nishino K. Mizoguchi T. Hirose S. Uehara K. Sato W. Tanikawa T. Shimamoto 《Tectonophysics》2004,379(1-4):93-108
The internal structure and permeability of the Neodani fault, which was last activated at the time of the 1891 Nobi earthquake (M8.0), were examined through field survey and experiments. A new exposure of the fault at a road construction site reveals a highly localized feature of the past fault deformation within a narrow fault core zone. The fault of the area consists of three zone units towards the fault core: (a) protolith rocks; (b) 15 to 30 m of fault breccia, and (c) 200 mm green to black fault gouge. Within the fault breccia zone, cataclastic foliation oblique to the fault has developed in a fine-grained 2-m-wide zone adjacent to the fault. Foliation is defined by subparallel alignment of intact lozenge shaped clasts, or by elongated aggregates of fine-grained chert fragments. The mean angle of 20°, between the foliation and the fault plane suggests that the foliated breccia accommodated a shear strain of γ<5 assuming simple shear for the rotation of the cataclastic foliation. Previous trench surveys have revealed that the fault has undergone at least 70 m of fault displacement within the last 20,000 years in this locality. The observed fault geometry suggests that past fault displacements have been localized into the 200-mm-wide gouge zone. Gas permeability analysis of the gouges gives low values of the order of 10−20 m2. Water permeability as low as 10−20 m2 is therefore expected for the fault gouge zone, which is two orders of magnitude lower than the critical permeability suggested for a fault to cause thermal pressurization during a fault slip. 相似文献
35.
— Earthquake faultings have a wide variety of slip behaviors, such as, a log-linear frequency-magnitude relation, characteristic earthquakes, slow slip events, and so on. We report a model which can reproduce a certain variety of observed complex slip behaviors on a fault. Our 3-D model simulates the seismic cycle on a shallow dipping subduction fault in a homogeneous elastic half-space, on which frictional sliding is controlled by a rate- and state-dependent friction law. We find that the behaviors of reproduced seismic cycles depend on a lateral dimension of a seismogenic zone (H) with respect to a constant seismogenic width in dip direction (W). The following three domains appear in the seismic cycle behaviors: (1) Regular, periodic behaviors when H is comparable to W; (2) transitional, quasi-periodic behaviors when H/W~ 3; and (3) complex behaviors when H/W is larger than about 4. The slip behavior in the domain (1) is characterized by a periodical recurrence of a characteristic earthquake, which is centered in strike direction. In the domain (2), although earthquakes are still centered, these recurrence intervals and the sizes are modulated within a certain range. Also, in the domain (3), earthquakes occur not only at the center but at various lateral positions on the seismogenic zone. In this domain, the log-linear frequency-magnitude relations, like the Gutenberg-Richter relation, are produced. Slow slip events also occur at source areas of the earthquakes. It is suggested that a heterogeneous stress distribution at a source region is important, as well as heterogeneities in friction properties on the fault, for understanding the wide variety of slip behaviors in faultings. 相似文献
36.
The exchange of Fe2+ and Mg2+ between orthopyroxene and sapphirine has been investigated at pressures 7-16 kbar and temperatures 850-1300°C using a piston cylinder apparatus for the synthetic and natural systems. This reaction is temperature-dependent and would be a good geothermometer. The equilibration temperature T is approximately expressed by the distribution coefficient as follows: T(°C)=1515/(ln KD+0.943)-273.
This empirical equation was applied to some Antarctic granulites and associated rocks. The new orthopyroxene-sapphirine geothermometer gives consistent results with those estimated from the Fe-Mg orthopyroxene-garnet geothermometer. 相似文献
37.
Hideyuki Kawamura Toshimichi Ito Naoki Hirose Tetsutaro Takikawa Jong-Hwan Yoon 《Journal of Oceanography》2009,65(4):439-454
The branches of the Tsushima Warm Current (TWC) are realistically reproduced using a three-dimensional ocean general circulation
model (OGCM). Simulated structures of the First Branch and the Second Branch of the TWC (FBTWC and SBTWC) in the eastern Japan
Sea are mainly addressed in this study, being compared with measurement in the period September–October 2000. This is the
first numerical experiment so far in which the OGCM is laterally exerted by real volume transports measured by acoustic Doppler
current profiler (ADCP) through the Tsushima Straits and the Tsugaru Strait. In addition, sea level variation measured by
tide-stations along the Japanese coast as well as satellite altimeters is assimilated into the OGCM through a sequential data
assimilation method. It is demonstrated that the assimilation of sea level variation at the coastal tide-stations is useful
in reproducing oceanic conditions in the nearshore region. We also examine the seasonal variation of the branches of the TWC
in the eastern Japan Sea in 2000. It is suggested as a consequence that the FBTWC is continuous along northwestern Honshu
Island in summertime, while it degenerates along the coast between the Sado Strait and the Oga Peninsula in other seasons.
On the other hand, a mainstream of the SBTWC exists with meanders and eddies in the offshore region deeper than 1000 m to
the north of the Sado Island throughout the year. 相似文献
38.
Toshifumi Komatsu Chen Jinhua Hiroaki Ugai Koji Hirose 《Journal of Asian Earth Sciences》2007,29(5-6):795-802
Trigonioides goshourensis n. sp. and Trigonioides amakusensis Kikuchi and Tashiro occur in the late Albian Eboshi Formation of the Goshoura Group in Kyushu, Japan. These Albian species are characterized by three radial pseudocardinal teeth on the thick and wide hinge plate, and are probably ancestors of Cenomanian species of Trigonioides (Kumamotoa) with four radial pseudocardinal teeth. This chronological relation may be important for the correlation of non-marine Cretaceous strata in East Asia. In addition, the habitat of T. amakusensis is interpreted as estuarine tidal flats under brackish water conditions, although Trigonioides is generally a freshwater bivalve genus. 相似文献
39.
Tetsuya Komabayashi Kei Hirose Nagayoshi Sata Yasuo Ohishi Leonid S. Dubrovinsky 《Earth and Planetary Science Letters》2007,260(3-4):564-569
A phase transition in pure CaSiO3 perovskite was investigated at 27 to 72 GPa and 300 to 819 K by in-situ X-ray diffraction experiments in an externally-heated diamond-anvil cell. The results show that CaSiO3 perovskite takes a tetragonal form at 300 K and undergoes phase transition to a cubic structure above 490–580 K in a pressure range studied here. The transition boundary is strongly temperature-dependent with a slightly positive dT / dP slope of 1.1 (± 1.3) K/GPa. It is known that the transition temperature depends on Al2O3 content dissolved in CaSiO3 perovskite [Kurashina et al., Phys. Earth Planet. Inter. 145 (2004) 67–74]. The phase transition in CaSiO3(+ 3 wt.% Al2O3) perovskite therefore could occur in a cold subducted mid-oceanic ridge basalt (MORB) crust at about 1200 K in the upper- to mid-lower mantle. This phase transition is possibly ferroelastic-type and may cause large seismic anomalies in a wide depth range. 相似文献
40.
Shigehiko Tateno Kei Hirose Nagayoshi Sata Yasuo Ohishi 《Physics and Chemistry of Minerals》2006,32(10):721-725
The stability and high-pressure behavior of perovskite structure in MnGeO3 and CdGeO3 were examined on the basis of in situ synchrotron X-ray diffraction measurements at high pressure and temperature in a laser-heated diamond-anvil cell. Results demonstrate that the structural distortion of orthorhombic MnGeO3 perovskite is enhanced with increasing pressure and it undergoes phase transition to a CaIrO3-type post-perovskite structure above 60 GPa at 1,800 K. A molar volume of the post-perovskite phase is smaller by 1.6% than that of perovskite at equivalent pressure. In contrast, the structure of CdGeO3 perovskite becomes less distorted from the ideal cubic perovskite structure with increasing pressure, and it is stable even at 110 GPa and 2,000 K. These results suggest that the phase transition to post-perovskite is induced by a large distortion of perovskite structure with increasing pressure. 相似文献