Unquenchable high-pressure perovskite polymorphs of MnSnO3 and FeTiO3     

Kurt Leinenweber  Wataru Utsumi  Yoshihiko Tsuchida  Takehiko Yagi  Kei Kurita 《Physics and Chemistry of Minerals》1991,18(4):244-250

New high-pressure orthorhombic (GdFeO₃-type) perovskite polymorphs of MnSnO₃ and FeTiO₃ have been observed using in situ powder X-ray diffraction in a diamond-anvil cell with synchrotron radiation. The materials are produced by the compression of the lithium niobate polymorphs of MnSnO₃ and FeTiO₃ at room temperature. The lithium niobate to perovskite transition occurs reversibly at 7 GPa in MnSnO₃, with a volume change of -1.5%, and at 16 GPa in FeTiO₃, with a volume change of -2.8%. Both transitions show hysteresis at room temperature. For MnSnO₃ perovskite at 7.35 (8) GPa, the orthorhombic cell parameters are a=5.301 (2) A, b=5.445 (2) Å, c=7.690 (8) Å and V= 221.99 (15) ų. Volume compression data were collected between 7 and 20 GPa. The bulk modulus calculated from the compression data is 257 (18) GPa in this pressure region. For FeTiO₃ perovskite at 18.0 (5) GPa, cell parameters are a=5.022 (6) Å, b=5.169 (5) Å, c=7.239 (9) Å and V= 187.94 (36) ų. Based on published data on the quench phases, the FeTiO₃ perovskite breaks down to a rocksalt + baddelyite mixture of FeO and TiO₂ at 23 GPa. This is the first experimental verification of the pressure-induced breakdown of a perovskite to simple oxides.  相似文献   

BSRs and Associated Reflections as an Indicator of Gas Hydrate and Free Gas Accumulation: An Example of Accretionary Prism and Forearc Basin System along the Nankai Trough, off Central Japan   总被引：1，自引：0，他引：1  

Kei Baba  Yasuhiro Yamada 《Resource Geology》2004,54(1):11-24

Abstract. Multi-channel seismic data obtained from the Nankai accretionary prism and forearc basin system has been studied to elucidate the migration and accumulation process of gas to the BGHS and examine the distribution pattern of BSRs and characteristic reflections associated with them.
BSRs are distributed widely in the Nankai accretionary prism and associated forearc basins (33,000 km²) and 90 % of them have migration and recycling origins. The widest distribution of the BSRs can be seen at the prism. A correlation between the BSR distributions and prism size shows that the BSRs tend to be more well-developed in a prism of large size. This suggests that a large prism may produce much amount of gas-bearing fluids that migrate to the BGHS and form the BSRs (tectonic control), hi the forearc basins, the BSRs are identified at topographic highs, anticlines and basin margins (structural control).
The upward migration of gas-bearing fluids is carried out through permeable sand layers and as a result, the distribution of BSRs is confined to alternating beds of sand and mud facies (sedimentary control). However, if there is enough time for upward migration and accumulation of gas to the BGHS, the BSRs can be generated widely in low-permeable mud facies (time control).
Those results imply that structural, tectonic, sedimentary and time controls are primary factors to decide the distribution of BSRs in the Nankai Trough area.  相似文献   

Experimental Study of Fe-Mg Exchange Reaction Between Orthopyroxene and Sapphirine and its Calibration as a Geothermometer     

Toshisuke Kawasaki  Kei Sato 《Gondwana Research》2002,5(4):741-747

The exchange of Fe²⁺ and Mg²⁺ between orthopyroxene and sapphirine has been investigated at pressures 7-16 kbar and temperatures 850-1300°C using a piston cylinder apparatus for the synthetic and natural systems. This reaction is temperature-dependent and would be a good geothermometer. The equilibration temperature T is approximately expressed by the distribution coefficient as follows: T(°C)=1515/(ln K_D+0.943)-273.

This empirical equation was applied to some Antarctic granulites and associated rocks. The new orthopyroxene-sapphirine geothermometer gives consistent results with those estimated from the Fe-Mg orthopyroxene-garnet geothermometer.  相似文献   

Phase transition in CaSiO₃ perovskite     

Tetsuya Komabayashi  Kei Hirose  Nagayoshi Sata  Yasuo Ohishi  Leonid S. Dubrovinsky 《Earth and Planetary Science Letters》2007,260(3-4):564-569

A phase transition in pure CaSiO₃ perovskite was investigated at 27 to 72 GPa and 300 to 819 K by in-situ X-ray diffraction experiments in an externally-heated diamond-anvil cell. The results show that CaSiO₃ perovskite takes a tetragonal form at 300 K and undergoes phase transition to a cubic structure above 490–580 K in a pressure range studied here. The transition boundary is strongly temperature-dependent with a slightly positive dT / dP slope of 1.1 (± 1.3) K/GPa. It is known that the transition temperature depends on Al₂O₃ content dissolved in CaSiO₃ perovskite [Kurashina et al., Phys. Earth Planet. Inter. 145 (2004) 67–74]. The phase transition in CaSiO₃(+ 3 wt.% Al₂O₃) perovskite therefore could occur in a cold subducted mid-oceanic ridge basalt (MORB) crust at about 1200 K in the upper- to mid-lower mantle. This phase transition is possibly ferroelastic-type and may cause large seismic anomalies in a wide depth range.  相似文献   

Rainfall thresholds for shallow landsliding derived from pressure‐head monitoring: cases with permeable and impermeable bedrocks in Boso Peninsula,Japan     

Yuki Matsushi  Yukinori Matsukura 《地球表面变化过程与地形》2007,32(9):1308-1322

Rainfall thresholds for shallow landslide initiation were determined for hillslopes with two types of bedrock, permeable sandstone and impermeable mudstone, in the Boso Peninsula, Japan. The pressure‐head response to rainfall was monitored above a slip scarp due to earlier landslides. Multiple regression analysis estimated the rainfall thresholds for landsliding from the relation between the magnitude of the rainfall event and slope instability caused by the increased pressure heads. The thresholds were expressed as critical combinations of rainfall intensity and duration, incorporating the geotechnical properties of the hillslope materials and also the slope hydrological processes. The permeable sandstone hillslope has a greater critical rainfall and hence a longer recurrence interval than the impermeable mudstone hillslope. This implies a lower potential for landsliding in sandstone hillslopes, corresponding to lower landslide activity. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

High-pressure behavior of MnGeO3 and CdGeO3 perovskites and the post-perovskite phase transition     

Shigehiko Tateno  Kei Hirose  Nagayoshi Sata  Yasuo Ohishi 《Physics and Chemistry of Minerals》2006,32(10):721-725

The stability and high-pressure behavior of perovskite structure in MnGeO₃ and CdGeO₃ were examined on the basis of in situ synchrotron X-ray diffraction measurements at high pressure and temperature in a laser-heated diamond-anvil cell. Results demonstrate that the structural distortion of orthorhombic MnGeO₃ perovskite is enhanced with increasing pressure and it undergoes phase transition to a CaIrO₃-type post-perovskite structure above 60 GPa at 1,800 K. A molar volume of the post-perovskite phase is smaller by 1.6% than that of perovskite at equivalent pressure. In contrast, the structure of CdGeO₃ perovskite becomes less distorted from the ideal cubic perovskite structure with increasing pressure, and it is stable even at 110 GPa and 2,000 K. These results suggest that the phase transition to post-perovskite is induced by a large distortion of perovskite structure with increasing pressure.  相似文献   

Numerical Simulation of Accretion Discs in Close Binary Systems andDiscovery of Spiral Shocks     

Takuya Matsuda  Makoto Makita  Hidekazu Fujiwara  Takizo Nagae  Kei Haraguchi  Eiji Hayashi  H.M.J. Boffin 《Astrophysics and Space Science》2000,274(1-2):259-273

The history of hydrodynamic numerical simulations for accretion disks in close binary systems is reviewed, in which emphasis is placed, in particular, on the facts that spiral shock waves were numerically found in 1986 by researchers including one of the present authors and that spiral structure was discovered in IP Pegasi in 1997 by Steeghs et al. The results of our two and three-dimensional numerical simulations in recent years are then summarized, with comparison being made with observations. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Effect of Rock Hardness and Moisture Content on Tafoni Weathering in the Granite of Mount Doeg-sung, Korea   总被引：2，自引：0，他引：2  

Yukinori Matsukura  & Yukiya Tanaka 《Geografiska Annaler: Series A, Physical Geography》2000,82(1):59-67

Many tafoni occur on the granite tors of Mount Doeg-sung, Korea. Relationships are investigated between growth processes of granite tafoni and rock properties such as rock hardness and moisture content. Field evidence shows that the rock surface of the inner backwalls and ceiling of tafoni have reduced hardness and higher moisture content compared to the outer visor of tafoni and to vertical cliff walls with no tafoni. This suggests that tafoni arise in weathered rock where conditions of low strength and high moisture content are both satisfied.  相似文献   

Projected 21st century climate change on snow conditions over Shasta Dam watershed by means of dynamical downscaling          下载免费PDF全文

Toan Trinh  M. Levent Kavvas  Kei Ishida  Kara Carr  Noriaki Ohara 《水文研究》2017,31(16):2887-2901

Snow is an important component of the Earth's climate system and is particularly vulnerable to global warming. It has been suggested that warmer temperatures may cause significant declines in snow water content and snow cover duration. In this study, snowfall and snowmelt were projected by means of a regional climate model that was coupled to a physically based snow model over Shasta Dam watershed to assess changes in snow water content and snow cover duration during the 21st century. This physically based snow model requires both physical data and future climate projections. These physical data include topography, soils, vegetation, and land use/land cover, which were collected from associated organizations. The future climate projections were dynamically downscaled by means of the regional climate model under 4 emission scenarios simulated by 2 general circulation models (fifth‐generation of the ECHAM general circulation model and the third‐generation atmospheric general circulation model). The downscaled future projections were bias corrected before projecting snowfall and snowmelt processes over Shasta Dam watershed during 2010–2099. This study's results agree with those of previous studies that projected snow water equivalent is decreasing by 50–80% whereas the fraction of precipitation falling as snowfall is decreasing by 15% to 20%. The obtained projection results show that future snow water content will change in both time and space. Furthermore, the results confirm that physical data such as topography, land cover, and atmospheric–hydrologic data are instrumental in the studies on the impact of climate change on the water resources of a region.  相似文献   

Slip Distribution of the 1963 Great Kurile Earthquake Estimated from Tsunami Waveforms     

Kei Ioki  Yuichiro Tanioka 《Pure and Applied Geophysics》2011,168(6-7):1045-1052

The 1963 great Kurile earthquake was an underthrust earthquake occurred in the Kurile?CKamchatka subduction zone. The slip distribution of the 1963 earthquake was estimated using 21 tsunami waveforms recorded at tide gauges along the Pacific and Okhotsk Sea coasts. The extended rupture area was divided into 24 subfaults, and the slip on each subfault was determined by the tsunami waveform inversion. The result shows that the largest slip amount of 2.8?m was found at the shallow part and intermediate depth of the rupture area. Large slip amounts were found at the shallow part of the rupture area. The total seismic moment was estimated to be 3.9?×?10²¹?Nm (M_w 8.3). The 2006 Kurile earthquake occurred right next to the location of the 1963 earthquake, and no seismic gap exists between the source areas of the 1963 and 2006 earthquakes.  相似文献