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81.
Variationally consistent homogenization is exploited for the analysis of transient uncoupled consolidation in micro‐heterogeneous porous solids, whereby the classical approach of first‐order homogenization for stationary problems is extended to transient problems. Homogenization is then carried out in the spatial domain on representative volume elements (RVE), which are introduced in quadrature points in standard fashion. Along with the classical averages, a higher‐order conservation quantity is obtained. An iterative FE2‐algorithm is devised for the case of nonlinear permeability and storage coefficients, and it is applied to pore pressure changes in asphalt‐concrete (particle composite). Various parametric studies are carried out, in particular, with respect to the influence of the ‘substructure length scale’ that is represented by the size of the RVE's. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   
82.
Process length variation of cysts of the dinoflagellate Protoceratium reticulatum (Claparède et Lachmann) Bütschli in surface sediments from the North Pacific was investigated. The average process length showed a significant inverse relation to annual seawater density: σt annual = ?0.8674 × average process length + 1029.3 (R2 = 0.84), with a standard error of 0.78 kg m?3. A sediment trap study from Effingham Inlet in British Columbia revealed the same relationship between average process length and local seawater density variations. In the Baltic–Skagerrak region, the average process length variation was related significantly to annual seawater density: σt annual = 3.5457 × average process length ? 993.28 (R2 = 0.86), with a standard error of 3.09 kg m?3. These calibrations cannot be reconciled, which accentuates the regional character of the calibrations. This can be related to variations in molecular data (small subunit, long subunit and internal transcribed spacer sequences), which show the presence of several genotypes and the occurrence of pseudo‐cryptic speciation within this species. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
83.
The maximum limits of the assemblage albiteforsterite have been determined experimentally at high pressures and temperatures. At subsolidus temperatures, albite plus forsterite is replaced at high pressures by jadeitic clinopyroxene and enstatitic orthopyroxene. The boundary for this reaction lies within experimental uncertainity of that for jadeite=albite+nepheline. Melting of albite+forsterite at high pressures produces enstatite+liquid, which is different from the low-pressure eutectic behavior. Melting rates are very slow and several hundred hours are required to establish equilibrium near the solidus. The subsolidus boundary for albite plus forsterite lies near that for sanidine plus forsterite, but with a shallower slope which more closely matches that of anorthite plus forsterite. Both albite plus forsterite and anorthite plus forsterite are replaced at high pressures by an assemblage containing clinopyroxene plus orthopyroxene, unlike sanidine plus forsterite, which is replaced by a feldspathoid plus orthopyroxene. The presence of sodium enlarges the depth region over which plagioclase lherzolite can stably exist; it may also stabilize alkali feldspar plus olivine in crustal rocks.  相似文献   
84.
Project organization problems are not uncommon in ground water monitoring projects, particularly those which occur at sites remote from the office. Successful project management depends on coordination of the personnel, supplies, and equipment necessary to carry out each phase of the project. Procedures for planning and organizing field projects involving well installation, ground water sampling, and aquifer testing are outlined. Methods are suggested that will aid the Project Manager in planning and scheduling field work to make efficient use of personnel and material resources. Cautions are given regarding common pitfalls of projects involving operations at remote sites, and means of avoidance are enumerated. A checklist of commonly used field equipment and supplies is provided.  相似文献   
85.
Cavernous weathering (tafoni development) occurs on coastal slopes in greenschist bedrock at elevations up to 40 m above sea level. The freshly weathered surfaces of the cavern interiors are irregular in morphology, discordant to major rock structure, formed by substantially weakened rock and associated with granular weathering debris. The weathering debris contains soluble elements in proportions similar to those present in seawater, and the penetration of elements associated with sea salts into the weathering surface to estimated depths of at least 0·1–0·2 m is indicated by the presence of chlorine. Scanning electron microscopy and microprobe analyses suggest that rock breakdown occurs principally through limited chemical weathering at grain boundaries. The mechanism for the emplacement of marine salts within sheltered rock surfaces in the tafoni is postulated to be a combination of dry deposition under turbulent atmospheric conditions and wetting by coastal fog.  相似文献   
86.
The structure, crystal chemistry, and microstructure of disordered and ordered Mg-cordierites synthesized in a bismuth oxide flux system have been studied by a combination of x-ray and neutron powder diffraction and quantitative x-ray microanalysis using analytical electron microscopy. Microchemical data obtained on Bi-flux cordierites using energy-dispersive x-ray analysis is interpreted through comparison with data collected on stoichiometric Mg2Al4Si5O18 glass and α- and β-cordierite samples synthesized by subsolidus crystallization of the glass. Bi-flux cordierites crystallize in both the hexagonal and orthorhombic polymorphs and contain 5 to 10 at% occupancy of bismuth on the C1 and C2 channel sites. The microstructure of Bi-flux α-cordierite is characterized by the existence of local domains of disordered cordierite solid solutions with variable composition and significant vacancy concentrations on the octahedral site. The β-cordierites have a more homogeneous microstructure but are still Al-deficient, Si-rich solid solutions.  相似文献   
87.
The Oklahoma Geological Survey has developed several maps and reports for preliminary screening of the state of Oklahoma to identify areas that are generally acceptable or unacceptable for disposal of a wide variety of waste materials. These maps and reports focus on the geologic and hydrogeologic parameters that must be evaluated in the screening process. One map (and report) shows the outcrop distribution of 35 thick shale or clay units that are generally suitable for use as host rocks for surface disposal of wastes. A second map shows the distribution of unconsolidated alluvial and terrace-deposit aquifers, and a third map shows the distribution and hydrologic character of bedrock aquifers and their recharge areas. These latter two maps show the areas in the state where special attention must be exercised in permitting storage or disposal of waste materials that could degrade the quality of groundwater. State regulatory agencies and industry are using these maps and reports in preliminary screening of the state to identify potential disposal sites. These maps in no way replace the need for site-specific investigations to prove (or disprove) the adequacy of a site to safely contain waste materials.  相似文献   
88.
The Southern Oscillation is a major component in the interannual variations of global climate. The Oregon State University global climate model, with a dynamically interactive upper ocean, reproduces in qualitatively correct fashion some of the major characteristics of the Southern Oscillation. This model simulates the observed anti-correlation of annually averaged sea-level pressure (SLP) between the eastern Pacific and the Indonesian region, the primary atmospheric signal of the Southern Oscillation. In the composite of the simulated warm events positive sea-surface temperature (SST) anomalies expand eastward towards South America from the tropical western Pacific during the first half of the calendar year. The SST anomalies develop in conjunction with eastward mixed layer current anomalies in the tropical Pacific. In the late summer and early fall anomalously warm water near South America develops and moves westward to merge with the central Pacific anomalies. This lagged development in the eastern Pacific is analogous to the evolution of the 1982/83 and 1986/87 El Ninos. The temperature of the thermocline layer also increases, with the slope of the equatorial Pacific thermocline decreasing in response to the relaxation of the surface forcing. Enhanced precipitation occurs in the mid-Pacific while in the Indian and Australian monsoon regions a deficit occurs. The peak of the warm phase occurs in late northern fall/early winter, somewhat earlier than during observed El Ninos. The cold phase of the Southern Oscillation, enhancement of the zonal circulation, evolves in a fashion similar to the warm phase with the signs of the anomalies reversed, similar to observations. Occurrence of Southern Oscillation in this coarse resolution GCM indicates that high resolution ocean waves do not play a crucial role in the generation of this phenomenon as suggested by Pacific basin models. These results also show that ocean-atmosphere global climate models are useful tools for investigation of time dependent changes on the interannual timescale in addition to their hitherto accepted use for studying equilibrium properties of climate.  相似文献   
89.
90.
A new form of equation of state is described with application to carbon dioxide from 215 K to T>2000 K and from zero pressure to more than 105 bar (10 GPa). The equation was calibrated using properties predicted by existing formulations at low to moderate PT conditions, original experimental PVT data at higher pressures, corresponding states comparisons at higher temperatures and using shock compression data at still higher PTs. Extensive comparisons illustrating the correlation of our new EOS with available phase equilibria and volumetric data are provided. Fugacities of carbon dioxide at high pressures and temperatures predicted using our EOS are in agreement with mineral equilibria calculated from internally consistent thermodynamic data for minerals.  相似文献   
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