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1.
Mertens, K. N., Dale, B., Ellegaard, M., Jansson, I.‐M., Godhe, A., Kremp, A. & Louwye, S. 2010: Process length variation in cysts of the dinoflagellate Protoceratium reticulatum, from surface sediments of the Baltic–Kattegat–Skagerrak estuarine system: a regional salinity proxy. Boreas, 10.1111/j.1502‐3885.2010.00193.x. ISSN 0300‐9483. Results are presented from a regional comparison of average process length variation in cysts of Protoceratium reticulatum and Lingulodinium polyedrum, extracted from surface sediments in the Skagerrak–Kattegat–Baltic estuarine system, with the environmental variables of seawater temperature and salinity. Although too few cysts of Lingulodinium polyedrum were recovered from the sediments to make reliable correlations, cysts of Protoceratium reticulatum were well represented, and average process length was correlated significantly with both salinity and temperature. Owing to dominant summer surface production, and regional covariation between salinity and density, we propose the use of the significant correlation with summer sea surface salinity (SSSsummer) by the equation SSSsummer=3.16 × average process length ?0.84 (R2=0.8). Application of this equation down‐core in Limfjord (northern Denmark) shows its usefulness as a regional palaeosalinity proxy.  相似文献   

2.
The detection of pulsed radio emission from the X-ray pulsar AXP 4U 0142+61 with a period of P = 8.68832935(6) s and a period derivative of $ \dot P $ \dot P = 18.713(4) × 10−13 s/s is reported. The observations were carried out on two high-sensitivity radio telescopes of the Pushchino Radio Astronomy Observatory: the Large Phased Array at 111MHz and the DKR-1000 at 40MHz.Mean pulse profiles are presented; the measured flux density is S 111 = 30 ± 20 mJy. The estimated distance derived from the dispersion measure, 27 pc/cm3, is 1.4 kpc, and the integrated radio luminosity is L R = 1.5 × 1027 erg/cm. Comparison with X-ray data shows an appreciable difference in the pulse duration (the radio pulse is about a factor of 20 more narrow) and strong variations in the flux density.  相似文献   

3.
The Mazhuangshan area is located in the east of the Aqikekuduke Island Arc, where there are distributed intermediate-acid magmatic rocks emplaced during the Middle-Late Carboniferous. There are more than 20 orebodies in the area with an average gold grade 6.4 × 10−6 at present. The dominant metallic minerals are natural gold, auriferous silver, natural silver, pyrite and galena. Pyrite is the key gold carrier, high in Fe and low in S. Wall-rock alterations mainly include pyritization, silicification, and sericitization. Carbonation alteration was extensive at the late stage, often resulting in a high-grade orebody. Three mineralization stages may be distinguished. The peak homogenization temperatures of primary fluid inclusions range from 240 to 260°C. Mineralization pressures and depths are 47.2–68.8 MPa and 1.6–2.3 km respectively, showing the ore-forming features of hypergene gold deposit. The average salinity is 15 wt% NaCl equivalent. Fluid inclusion geochemistry data show that Ca2+ is far higher than Mg2+, and mK +/mNa +, mNa2 +/mCa 2+ (0.001∼0.338), mΣCl/mΣS and mΣC/mΣS ratios change with the reduction parameter [R = (CO + CH4)/CO2] and temperature. And the gold contents of ores and gangues are positively correlated withR.  相似文献   

4.
The process of evaporation from the lake surface is one of the main mechanisms in the energy and water budgets of the lake hydrologic cycle, and an essential component of the water balance especially for inland lakes. In this study, using routine meteorological data as input, a one-layer potential evaporation model was employed to simulate evaporation and energy fluxes over Lake Yamdrok Yumco, the largest high-elevation inland lake in the mountain area of the Tibet-Himalaya in China. Then, the calculation results were compared with the measured values from a big pan evaporator of 20 m2 near the lake. The results show that the average annual input radiation flux R ↓ is 128.2 W m−2, the lake storage heat flux G is 19.4 W m−2, the sensible heat flux H is 20.4 W m−2 and the latent heat flux lE is 107.8 W m−2. The R ↓ and G exhibit similar seasonal variations. The lE reaches a maximum in October, lagging nearly 4 months behind the R ↓ and the G, which indicates the large heat capacity of the lake. The simulated annual evaporation ranges from 1,113.2 to 1,429.1 mm and its mean value is 1,252.5 mm during 1961–2005. The simulated annual evaporation is in good agreement with the measured value, and the measured average lake temperature is as expected when compared with the measured lake surface temperature.  相似文献   

5.
High temperature creep of single crystal gadolinium gallium garnet (GGG) was studied in the temperature range of 1723–1853 K (0.86–0.94 Tm, Tm: melting temperature) and strain rate from 9 · 10?7 s?1 to 2 · 10?5 s?1. The compression tests were made along the 〈100〉 and 〈111〉 orientations. We have performed both constant strain-rate and stress-dip tests. For the 〈100〉 orientation, deformation occurs via the 〈111〉 slip systems. For the 〈111〉 orientation, both the 〈100〉 {010} and the 〈111〉 slip systems can be activated. GGG garnet is very strong under these conditions: σ/μ=(1–3)×10?3 (σ: creep strength, μ: shear modulus). The creep behavior is characterized by a power law with stress exponent n=2.9–3.3 and high activation energies E*=612–743 kJ/mol (E*～45×RTm, at zero stress which decrease with the increase of stress). Stress-dip tests suggest a small internal stress (σi/σ～0.62; σi: internal stress, σ: applied stress) compared to other materials. These results suggest that the high creep strength of GGG is mainly due to difficulty of dislocation glide rather than dislocation climb.  相似文献   

6.
The Khor Arbaat basin is the main source of potable water supply for the more than 750,000 inhabitants of Port Sudan, eastern Sudan. The variation in hydraulic conductivity and storage capacity is due to the heterogeneity of the sediments, which range from clay and silt to gravely sand and boulders. The water table rises during the summer and winter rainy seasons; it reaches its lowest level in the dry season. The storage capacity of the Khor Arbaat aquifer is estimated to be 21.75?×?106 m3. The annual recharge through the infiltration of flood water is about 1.93?×?106 m3. The groundwater recharge, calculated as underground inflow at the ‘upper gate’, is 1.33?×?105 m3/year. The total annual groundwater recharge is 2.06?×?106 m3. The annual discharge through underground outflow at the ‘lower gate’ (through which groundwater flows onto the coastal plain) is 3.29?×?105 m3/year. Groundwater discharge due to pumping from Khor Arbaat basin is 4.38?×?106 m3/year on average. The total annual groundwater discharge is about 4.7?×?106 m3. A deficit of 2.6?×?106 m3/year is calculated. Although the total annual discharge is twice the estimated annual recharge, additional groundwater flow from the fractured basement probably balances the annual groundwater budget since no decline is observed in the piezometric levels.  相似文献   

7.
Using data of spectroscopic measurements in Moscow and Moscow region and data of ecological monitoring from Ostankino TV Tower, it has been found that, in the period of intense smoke blanketing of the atmosphere in summer 2010 due to large-scale forest-peat fires on the territory of the European part of the Russian Federation, the carbon monoxide content in the boundary layer and in the atmospheric depth of Moscow region reached the extremely high level of 8 g/m2, or 17 ×1018 mol/cm2, and the carbon monoxide concentration in the near-ground atmospheric layer increased to 37.5 mg/m3, i.e., an unprecedentedly large value for Moscow and more than a factor of 7 larger than the one-time maximum permissible concentration for carbon monoxide MPCot = 5 mg/m3. In the first decade of August, when intense smoke blanketing of the Moscow region was observed, the average carbon monoxide concentrations varied in the range from approximately 3 to 7 m/g3, i.e., an order of magnitude larger than the annual average concentrations calculated according to data of measurements in 2009. The probabilities of exceeding MPCot and multiples of MPCot are calculated. Analysis of data of thermal sensing showed that an important feature of the atmospheric boundary layer over the city was a high stability of the lower atmospheric layer with the thickness of 150–200 m, and also long-term nighttime and morning inversions of the air temperature in this layer.  相似文献   

8.
The River Gash Basin is filled by the Quaternary alluvial deposits, unconformably overlying the basement rocks. The alluvial deposits are composed mainly of unconsolidated layers of gravel, sand, silt, and clays. The aquifer is unconfined and is laterally bounded by the impermeable Neogene clays. The methods used in this study include the carry out of pumping tests and the analysis of well inventory data in addition to the river discharge rates and other meteorological data. The average annual discharge of the River Gash is estimated to be 1,056?×?106 m3 at El Gera gage station (upstream) and 587?×?106 m3 at Salam-Alikum gage station (downstream). The annual loss mounts up to 40% of the total discharge. The water loss is attributed to infiltration and evapotranspiration. The present study proofs that the hydraulic conductivity ranges from 36 to 105 m/day, whereas the transmissivity ranges from 328 to 1,677 m2/day. The monitoring of groundwater level measurements indicates that the water table rises during the rainy season by 9 m in the upstream and 6 m in the midstream areas. The storage capacity of the upper and middle parts of the River Gash Basin is calculated as 502?×?106 m3. The groundwater input reach 386.11?×?106 m3/year, while the groundwater output is calculated as 365.98?×?106 m3/year. The estimated difference between the input and output water quantities in the upper and middle parts of the River Gash Basin demonstrates a positive groundwater budget by about 20?×?106 m3/year  相似文献   

9.
Frontier exploration in the Kuqa Depression, western China, has identified the continuous tight-sand gas accumulation in the Lower Cretaceous and Lower Jurassic as a major unconventional gas pool. However, assessment of the shale gas resource in the Kuqa Depression is new. The shale succession in the Middle–Upper Triassic comprises the Taliqike Formation (T3t), the Huangshanjie Formation (T3h) and the middle–upper Karamay Formation (T2–3k), with an average accumulated thickness of 260 m. The high-quality shale is dominated by type III kerogen with high maturity and an average original total organic carbon (TOC) of about 2.68 wt%. An improved hydrocarbon generation and expulsion model was applied to this self-contained source–reservoir system to reveal the gas generation and expulsion (intensity, efficiency and volume) characteristics of Middle–Upper Triassic source rocks. The maximum volume of shale gas in the source rocks was obtained by determining the difference between generation and expulsion volumes. The results indicate that source rocks reached the hydrocarbon expulsion threshold of 1.1% VR and the hydrocarbon generation and expulsion reached their peak at 1.0% VR and 1.28% VR, with the maximum rate of 56 mg HC/0.1% TOC and 62.8 mg HC/0.1% TOC, respectively. The volumes of gas generation and expulsion from Middle–Upper Triassic source rocks were 12.02 × 1012 m3 and 5.98 × 1012 m3, respectively, with the residual volume of 6.04 × 1012 m3, giving an average gas expulsion efficiency of 44.38% and retention efficiency of 55.62%. Based on the gas generation and expulsion characteristics, the predicted shale gas potential volume is 6.04 × 1012 m3, indicating a significant shale gas resource in the Middle–Upper Triassic in the eastern Kuqa Depression.  相似文献   

10.
The carbonate aquifers of Lora and Mingo form part of the hydrogeological unit of Sierra de Estepa (SE Spain). By means of time series analysis and a 1D numerical groundwater model, groundwater exploitation was quantified and the mean annual recharge in both systems was estimated (2001–2004). During this period, the Lora and Mingo aquifers received an average groundwater recharge of 0.29 × 106 m3/year and 0.14 × 106 m3/year, respectively, whereas an average of 0.34 × 106 m3/year and 0.21 × 106 m3/year, respectively, was extracted. These conditions led to a conspicuous lowering of the water table in both systems. In addition, the analysis of the evolution of the main hydrogeochemical parameters of the groundwater showed that the increased pumping rates produced an increase in total dissolved solids, and chloride and sodium ions in both aquifers. In the case of the Lora aquifer, the only ion that presented decreased levels was nitrate. The results show that groundwater pumping in both aquifers should not exceed the mean annual recharge of 0.29 × 106 m3/year and 0.14 × 106 m3/year in the Lora and Mingo aquifers, respectively. Nevertheless, it would be advisable to reduce pumping rates to below these values in order to restore piezometric levels and improve groundwater quality for different uses in the future.  相似文献   

11.
In order to examine the fluxes of methane (CH4) from the Indian estuaries, measurements were carried out by collecting samples from 26 estuaries along the Indian coast during high discharge (wet) and low water discharge (dry) periods. The CH4 concentrations in the estuaries located along the west coast of India were significantly higher (113?±?40 nM) compared to the east coast of India (27?±?6 nM) during wet and dry periods (88?±?15 and 63?±?12 nM, respectively). Supersaturation of CH4 was observed in the Indian estuaries during both periods ((0.18 to 22.3?×?103 %). The concentrations of CH4 showed inverse relation with salinity indicating that freshwater is a significant source. Spatial variations in CH4 saturation were associated with the organic matter load suggesting that its decomposition may be another source in the Indian estuaries. Fluxes of CH4 ranged from 0.01 to 298 μmol m?2 day?1 (mean 13.4?±?5 μmol m?2 day?1) which is ~30 times lower compared to European estuaries (414 μmol m?2 day?1). The annual emission from Indian estuaries, including Pulicat and Adyar, amounted to 0.39?×?1010 g CH4?year?1 with the surface area of 0.027?×?106 km2 which is significantly lower than that in European estuaries (2.7?±?6.8?×?1010 g CH4?year?1 with the surface area of 0.03?×?106 km2). This study suggests that Indian estuaries are a weak source for atmospheric CH4 than European estuaries and such low fluxes were attributed to low residence time of water and low decomposition of organic matter within the estuary. The CH4 fluxes from the Indian estuaries are higher than those from Indian mangroves (0.01?×?1010 g CH4?year?1) but lower than those from Indian inland waters (210?×?1010 g CH4?year?1).  相似文献   

12.
This study was undertaken to evaluate land use change impact and management scenarios on annual average surface runoff (SR) and sediment yield (SY) using the GeoWEPP tool in the Lighvanchai watershed (located in northwestern Iran). Following a sensitivity analysis, the WEPP model was calibrated (2005–2007) and validated (2008–2010) against monthly observed SY and SR. The coefficient of determination (R 2), Nash–Sutcliffe efficiency (NSE), mean bias error (MBE), and root-mean-square error (RMSE) were applied to quantitatively evaluate the WEPP model. The results indicate a satisfactory model performance with R 2 > 0.80 and NSE > 0.60. Therefore, the model for current land use (scenario 1) was run for a 30-year time period (1982–2011). The annual average of SR and sediment load were predicted as 93,584 m3/year and 4340 ton/year, respectively. To reduce the annual average surface runoff and sediment yield at the watershed scale, the second scenario (alfalfa cultivation with suitable tillage) and the third scenario (grassland development) as two management scenarios of land use changes were defined by identifying the critical hillslopes. The rate of SR and sediment load in the second scenario were 42,096 m3/year and 429 ton/year, respectively. For the third scenario, the model predictions were 30,239 m3/year and 226 ton/year, respectively. Compared to the first scenario, the reduction rates in annual average of sediment load were about 90 and 94%, respectively. Moreover, for the second and third management scenarios, the reduction rates in annual average of SR were about 55 and 67%, respectively.  相似文献   

13.
Daily and annual integrated rates of primary productivity and community respiration were calculated using physiological parameters measured in oxygen-based photosynthesis-irradiance (P-I) incubations at 8 stations throughout central and western Long Island Sound (cwLIS) during the summer and autumn of 2002 and 2003 and the late spring of 2003. Each calculation takes into account actual variations in incident irradiance over the day and underwater irradiance and standing stock with depth. Annual peak rates, ±95% confidence interval of propagated uncertainty in each measurement, of gross primary production (GPP, 1,730±610 mmol O2 m−2 d−1), community respiration (Rc, 1,660±270 mmol O2 m−2 d−1), and net community production (NCP, 1,160±1,100 mmol O2 m−2 d−1) occurred during summer at the western end of the Sound. Lowest rates of GPP (4±11 mmol O2 m−2 d−1), Rc (−50±300 mmol O2 m−2 d−1), and NCP (−1,250±270 mmol O2 m−2 d−1) occurred during late autumn-early winter at the outer sampled stations. These large ranges in rates of GPP, Rc, and NCP throughout the photic zone of cwLIS are attributed to seasonal and spatial variability. Algal respiration (Ra) was estimated to consume an average of 5% to 52% of GPP, using a literature-based ratio of Ra:Rc. From this range, we established that the estimated Ra accounts for approximately half of GPP, and was used to estimate daily net primary production (NPP), which ranged from 2 to 870 mmol O2 m−2 d−1 throughout cwLIS during the study. Annual NPP averaged 40±8 mol O2 m−2 yr−1 for all sampled stations, which more than doubled along the main axis of the Sound, from 32±14 mol O2 m−2 yr−1 at an eastern station to 82±25 mol O2 m−2 yr−1 at the western-most station. These spatial gradients in productivity parallel nitrogen loads along the main axis of the Sound. Daily integrals of productivity were used to test and formulate a simple, robust biomass-light model for the prediction of phytoplankton production in Long Island Sound, and the slope of the relationship was consistent with reports for other systems.  相似文献   

14.
The Service d’Observation de la Rade de Villefranche-sur-Mer is designed to study the temporal variability of hydrological conditions as well as the abundance and composition of holo- and meroplankton at a fixed station in this bay of the northwest Mediterranean. The weekly data collected at this site, designated as “Point B” since 1957, represent a long-term time series of hydrological conditions in a coastal environment. Since 2007, the historical measurements of hydrological and biological conditions have been complemented by measurements of the CO2–carbonic acid system parameters. In this contribution, CO2–carbonic acid system parameters and ancillary data are presented for the period 2007–2011. The data are evaluated in the context of the physical and biogeochemical processes that contribute to variations in CO2 in the water column and exchange of this gas between the ocean and atmosphere. Seasonal cycles of the partial pressure of CO2 in seawater (pCO2) are controlled principally by variations in temperature, showing maxima in the summer and minima during the winter. Normalization of pCO2 to the mean seawater temperature (18.5 °C), however, reveals an apparent reversal of the seasonal cycle with maxima observed in the winter and minima in the summer, consistent with a biogeochemical control of pCO2 by primary production. Calculations of fluxes of CO2 show this area to be a weak source of CO2 to the atmosphere during the summer and a weak sink during the winter but near neutral overall (range ?0.3 to +0.3 mmol CO2 m?2 h?1, average 0.02 mmol CO2 m?2 h?1). We also provide an assessment of errors incurred from the estimation of annual fluxes of CO2 as a function of sampling frequency (3-hourly, daily, weekly), using data obtained at the Hawaii Kilo Nalu coastal time-series station, which shows similar behavior to the Point B location despite significant differences in climate and hydrological conditions and the proximity of a coral reef ecosystem.  相似文献   

15.
The present study examines the temporal variability of air–water CO2 fluxes (FCO2) and seawater carbonate chemistry in a Baja California coastal lagoon during an exceptionally warm anomaly that was developed in Northeast Pacific coasts during 2014. This oceanographic condition led to a summer-like season (weak upwelling condition) during the study period, which reached a maximum surface temperature anomaly of 2 °C in September 2014. San Quintín Bay acts as a source of CO2 to the atmosphere in 2014 (3.3 ± 4.8 mmol C m?2 day?1) with the higher positive fluxes mainly observed in summer months (9.0 ± 5.3 mmol C m?2 day?1). Net ecosystem production (NEP) switched seasonally between net heterotrophy and net autotrophy during the study period, with an annual average of 2.2 ± 7.1 mmol C m?2 day?1, which indicates that San Quintín Bay was a net autotrophic system during the atypical warm oceanographic condition in 2014. This pattern of seasonal variations in the carbon balance at San Quintín Bay appears to be linked to the life cycle of benthic communities, which play an important role in the whole-ecosystem metabolism. Under the limited input from external sources coupled with an increase in seawater temperatures, the recycled benthic carbon and nutrient fluxes play a major role to sustain water-column processes within the bay. Since the upwelling condition may influence the magnitude of the air–water CO2 fluxes, our results clearly indicated that San Quintín Bay is a net source of carbon to the atmosphere regardless of the adjacent oceanic conditions. Our study sheds light on the carbon dynamics and its metabolic implications in a shallow coastal ecosystem under a regional warm anomaly and contributes potentially relevant information in view of the likely future scenario of global climate change.  相似文献   

16.
As the most important source rocks in the eastern Junggar Basin, the middle Permian Pingdiquan (P2p) source rocks have attracted increasing attention after the discovery of tight oil in the Shazhang uplift. The P2p source rocks are widely distributed (up to 7546 km2) and have an elevated thickness in the eastern Junggar Basin. To explore the P2p tight oil resource in the eastern Junggar Basin, 113 core samples from 34 exploration wells were analysed geochemically and re-examined for their organic matter abundance, type and thermal maturity, hydrocarbon potential and sedimentary environment. Geochemical analysis results indicate that the P2p source rocks are fair to good source rocks dominated by Type II kerogen, presently in a low mature–mature stage, and biomarkers and trace elements indicate deposition in a terrestrial to coastal environment under oxic to dysoxic, and fresh to brackish conditions, with possible intermittent seawater influence, implying proximity to the open sea. Based on hydrocarbon expulsion modelling, hydrocarbon expulsion began at 0.87% Ro, and the peak expulsion occurred at 1.1% Ro. Hydrocarbon generation intensities in the Shazhang uplift and the Wucaiwan sag are relatively large, with values centred at 4–6.5 million t/km2 and 4–6 million t/km2, respectively, with total hydrocarbon generation and expulsion from the P2p source rocks approximately 4.56 × 109 t and 1.44 × 109 t, respectively, indicating significant tight oil exploration potential in the eastern Junggar Basin. The Shazhang uplift and the Wucaiwan sag are two hydrocarbon expulsion centres in the study area with the largest hydrocarbon expulsion intensity centred around the Shazhang uplift, exceeding 3 × 106 t/km2. We suggest that the area with high hydrocarbon expulsion intensities is a favourable target for tight oil accumulation and exploration.  相似文献   

17.
This study was conducted in six plots along an elevation gradient in the Qinghai spruce (Picea crassifolia Kom.) forest ecosystem of the Qilian Mountains, northwest China. Soil CO2 efflux over bare soil (R s) and moss covered soil (R s+m) were investigated from June to September in 2010 and 2011 by means of an automated soil CO2 flux system (LI-8100). The results showed that R s ranged from 1.51 to 3.96 (mean 2.64 ± 0.72) μmol m?2 s?1 for 2010, and from 1.41 to 4.09 (mean 2.55 ± 0.70) μmol m?2 s?1 for 2011. The daily change trend of R s resembled that of air temperature (T a), and there was a hysteresis between R s and soil temperature (T s). The seasonal variations of R s at lowlands (i.e., Plot 1, Plot 2 and Plot 3) were driven by soil moisture and temperature (T a and T s), while that at highlands (i.e., Plot 4, Plot 5 and Plot 6) were obviously affected by temperature. There were higher values at Plot 2 and Plot 6, which were caused by the interaction between soil moisture and temperature. In addition, soil CO2 efflux over moss covered soil (R s+m) was 8.83 % less than that over bare soil (R s), indicating that moss was another factor affecting R s. It was concluded that R s had temporal and spatial variations and was mainly controlled by temperature and soil moisture; the main determinants differed at different elevations; moss could reduce R s.  相似文献   

18.
A new mineral barioferrite—a natural analogue of synthetic barium ferrite Ba Fe 12 3+ O19—has been identified in the central part of a metamorphosed barite nodule in the rock of the Haturim Formation (Mottled Zone) on the southern slope of Mount Ye’elim in Israel. The mineral is associated with barite, calcite, magnetite, and maghemite and occurs as tiny platy crystals up to 3 × 15 × 15 μm and their irregular aggregates. Barioferrite is black with streaks of brown, and its luster is submetallic. Its Calculated density is 5.31 g/cm3. The mineral is brittle; cleavage is absent. IR absorption bands (cm?1) are observed at 635 (shoulder), 582, 544, 433, and 405 (shoulder). Barioferrite is characterized by ferrimagnetic behavior. Under a microscope in reflected light, barioferrite is grayish white with brownish red internal reflections, the pleochroism is weak (from gray-white on R o to gray-white with a brown tint on R e), and the bireflectance is weak with distinct anisotropy. The reflectance values of R o/R e, % (λ, nm) are 24.51/22.80 (470), 24.17/22.25 (546), 23.65/21.68 (589), and 22.67/20.85 (650). The chemical composition (electron microprobe, wt %; the ranges are given in parentheses) is BaO 13.13 (12.5–13.8), Fe2O3 86.47 (85.5–87.5), and 99.60 in total. The empirical formula is Ba0.95Fe 12.03 3+ O19. Barioferrite is hexagonal with space group P63/mmc, a = 5.875 (3) Å, c = 23.137 (19) Å, V = 691.6 (5) Å3, and Z = 2. The strongest lines of the X-ray powder diffraction pattern [d, Å, (I, 5) (hkl)] are 2.938(46) (110), 2.770(100) (107), 2.624 (84) (114, 200), 2.420(44) (203), 2.225(40) (205), and 1.627(56) (304, 2.0.11). The holotype specimen of barioferrite is deposited at the Mineralogical Museum of St. Petersburg State University; its catalogue number is 1/19436.  相似文献   

19.
A new superstructure was found in bafertisite [(Ba0.98Na0.02)1.00(Fe1.71Mn0.26Mg0.01)1.98 TiO[(Si1.82Ti0.04Al0.03Cr0.01)1.90O7](OH1.40F0.53Cl0.03)1.96] from Donghai County, Jiangsu Province, China. The occurrence of the superstructure reflections were observed by single crystal diffraction using a SMAR APEX CCD. The a*, b*and c* axis directions revealed extra weak reflection spots of the superstructure. The apparent 2a, 2b and 2c superstructure is monoclinic with unit cell a＝10.6502(15)?, b＝13.7233(19)?, c＝21.6897(3)?, α＝90o, β＝94.698(3)o, γ＝90o,space group Cm,Z=16. If c* extra weak reflections are ignored, the secondary supercell gave a cell a＝10.6548(15)?, b＝13.7284(19)?, c＝11.6900(17)?, α＝90o, β＝112.322(28)o, γ＝90o,space group Cm,Z=8. The basic subcell was obtained by ignoring all extra weak reflection spots and gave: a＝5.3249(17)?, b＝6.8669(22)?, c＝10.8709(36)?, α＝90o, β＝94.740(62)o, γ＝90o,space P21/m,Z=2. The superstructure has been refined to R = 0.063 for 7805 [R(int) = 0.0266] unique reflections I>2δ(I). The structure consists of an octahedra (O) sheet sandwiched between two heteropolyhedral (H) sheets. These sheets consist of Ti–octahedra and twin tetrahedral disilicate groups [Si2O7]. The O sheet comprises (Fe,Mg)O4 octahedra. The large Ba cation is located in the interlayer area. The refined structure shows Fe, Mg are partly ordered. The shifting of the TiO6 octahedron and SiO4 tetrahedron sites in the sheet may be a consequence of the superstructure.  相似文献   

20.
综合钻井、大量实测剖面、样品测试分析和区域地质资料，对西昌盆地白果湾组烃源岩生烃强度、镜质体反射率、砂岩储层物性等关键指标进行了系统评价。西昌盆地上三叠统白果湾组主要油气储层类型为中-粗砂岩，有利层段主要发育在白果湾组一段、三段和四段，砂岩具有中孔低渗、区域分布广、厚度大等特征，ZD-1井揭示砂岩含油气性好。西昌盆地白果湾组烃源岩在盆地中心厚度大，盆地中心的生烃强度达（56.74~97.70）×108 m3/km2。烃源岩成熟度（RO）在1.08%~3.98%范围，具有东低西高的特征。通过综合分析西昌盆地油气形成的关键指标，优选了夹铁-四开致密砂岩油气成藏有利区和4个甜点区，该区生烃强度（10~80）×108m3/km2，RO为1.08%~3.0%，中-粗砂岩厚度为10~50m，天然气资源量为6756×108m3，可形成"改造再重建"致密砂岩油气藏。  相似文献   

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