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31.
Determination of reaction kinetics using grain size: An application for metamorphic zircon growth 
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下载免费PDF全文 The reaction kinetics of metamorphic minerals can be subdivided into interface‐ and diffusion‐controlled kinetics. The discrimination of reaction kinetics is crucial for estimating reaction rates. Here, we propose a new and simple method for discriminating reaction kinetics. This method requires measuring only the initial and final grain sizes during growth. The reaction kinetics is inferred from different plotted arrays of initial vs. final grain sizes after the mineral growth. Using metamorphic zircon, we take detrital core sizes as the initial sizes and post‐metamorphic grain sizes as the final sizes. The application of the method to the subduction‐related high‐pressure Nagasaki metamorphic complex in Japan shows that this metamorphic zircon grew under interface‐controlled kinetics even at the relatively low temperature of 440°C. This method is potentially applicable to other minerals that have time‐markers, such as chemical zoning or internal structures that are captured at a given point in time during growth. 相似文献
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Tetsuo Kawakami Isao Yamaguchi Akira Miyake Tomoyuki Shibata Kenshi Maki Takaomi D. Yokoyama Takafumi Hirata 《Contributions to Mineralogy and Petrology》2013,165(3):575-591
Behavior of zircon at the schist/migmatite transition is investigated. Syn-metamorphic overgrowth is rare in zircon in schists, whereas zircon in migmatites has rims with low Th/U that give 90.3 ± 2.2 Ma U–Pb concordia age. Between inherited core and the metamorphic rim, a thin, dark-CL annulus containing melt inclusion is commonly developed, suggesting that it formed contemporaneous with the rim in the presence of melt. In diatexites, the annulus is further truncated by the brighter-CL overgrowth, suggesting the resorption and regrowth of the zircon after near-peak metamorphism. Part of the zircon rim crystallized during the solidification of the melt in migmatites. Preservation of angular-shaped inherited core of 5–10 μm in zircon included in garnet suggests that zircon of this size did not experience resorption but developed overgrowths during near-peak metamorphism. The Ostwald ripening process consuming zircon less than 5–10 μm is required to form new overgrowths. Curved crystal size distribution pattern for fine-grained zircons in a diatexite sample may indicate the contribution of this process. Zircon less than 20 μm is confirmed to be an important sink of Zr in metatexites, and ca. 35-μm zircon without detrital core are common in diatexites, supporting new nucleation of zircon in migmatites. In the Ryoke metamorphic belt at the Aoyama area, monazite from migmatites records the prograde growth age of 96.5 ± 1.9 Ma. Using the difference of growth timing of monazite and zircon, the duration of metamorphism higher than the amphibolite facies grade is estimated to be ca. 6 Myr. 相似文献
34.
Biogeochemical responses associated with the passage of a cyclonic eddy based on shipboard observations in the western North Pacific 总被引：1，自引：0，他引：1
A shipboard high-resolution hydrographic survey in the subtropical region of the western North Pacific conducted from October to November 2008 detected part of a cyclonic eddy around 30°N, 145°E. This eddy had propagated westward in the region south of the Kuroshio extension for at least 6 months as a wavelike disturbance. Within this eddy, isopycnals shallowed between a depth of 600 m and just below the surface mixed layer. In addition, maximal dissolved oxygen concentrations were observed in the subsurface layer between depths of 50 and 100 m. Nitrate was depleted within this subsurface maximal oxygen layer. These results suggest that nutrients in the deeper layers were supplied into the euphotic layer as a result of the uplift of isopycnals in the eddy, fueling the photosynthesis of phytoplankton in the subsurface and emitting an excess of oxygen due to new production. Compared with the outside of the eddy, the enhancement of oxygen and the decrease of nitrate in the center of the eddy were estimated to be 2.7 mol O2 m?2 and 0.22 mol N m?2, respectively. The primary productivity calculated using the eddy transition speed of 5.1 km day?1 was 548 mg C m?2 day?1 at the center of the eddy. The enhanced primary productivity due to the passage of the eddy is likely to have an important role in the ecosystem and on material cycling in the subtropical region. 相似文献
35.
Sachihiko Itoh Ichiro Yasuda Hiromichi Ueno Toshio Suga Shigeho Kakehi 《Journal of Oceanography》2014,70(3):211-223
Regeneration of a warm anticyclonic ring as a result of interaction with cold water masses was observed within the western subarctic gyre of the North Pacific. Satellite, profiling float, and shipboard observations revealed that a warm-core ring originated from the Kuroshio Extension, propagating northeastwards, entrained cold and fresh water masses from the coastal area of Hokkaido, which are typically recognized within the ring as water that is colder than 2.5 °C. The potential temperature and planetary contribution of potential vorticity of the cold water in the coastal area of Hokkaido were <2 °C and 15 × 10?11 m?1s?1, respectively, suggesting that it originated from the Sea of Okhotsk. After the intrusion, the warm core of the ring cooled, freshened, and contracted, while the outer and lower parts became occupied by the cold and fresh water; however, even after the cooling, the positive surface elevation and downward depression of the main pycnocline, typical of an anticyclonic ring, were still evident. The ring continued to propagate northeastwards, with the main part of its structure occupied by the cold water, but changed its direction of travel from northwest to west-southwest 8 months after the cold-water event, and was finally absorbed into another warm-core ring. It is suggested that these anticyclonic rings, which transported and mixed warm and cold water masses, play important roles in the cross-gyre exchange of subtropical and subarctic waters in the North Pacific. 相似文献
36.
A new type of pycnostad has been identified in the western subtropical-subarctic transition region of the North Pacific, based
on the intensive hydrographic survey carried out in July, 2002. The potential density, temperature and salinity of the pycnostad
were found to be 26.5–26.7 σ
θ
, 5°–7°C and 33.5–33.9 psu respectively. The pycnostad is denser, colder and fresher than those of the North Pacific Central
Mode Water and different from those of other known mode waters in the North Pacific. The thickness of the pycnostad is comparable
to that of other mode waters, spreading over an area of at least 650 × 500 km around 43°N and 160°E in the western transition
region. Hence, we refer to the pycnostad as Transition Region Mode Water (TRMW). Oxygen data, geostrophic current speed and
climatology of mixed layer depth in the winter suggest that the TRMW is formed regularly in the deep winter mixed layer near
the region where it was observed. Analysis of surface heat flux also supports the idea and suggests that there is significant
interannual variability in the property of the TRMW. The TRMW is consistently distributed between the Subarctic Boundary and
the Subarctic Front. It is also characterized by a wide T-S range with similar density, which is the characteristic of such
a transition region between subtropical and subarctic water masses, which forms a density-compensating temperature and salinity
front. The frontal nature also tends to cause isopycnal intrusions within the pycnostad of the TRMW. 相似文献
37.
Insight into nitrous oxide production processes in the western North Pacific based on a marine ecosystem isotopomer model 总被引：2，自引：0，他引：2
38.
Atsushi Noda Hajime Katayama Tsumoru Sagayama Kazuya Suga Yasuhito Uchida Kenji Satake Kohei Abe Yukinobu Okamura 《Sedimentary Geology》2007,200(3-4):314-327
A combined approach of field geology and numerical simulation was conducted for evaluating the tsunami impacts on the shelf sediments. The 2003 Tokachi-oki earthquake, M 8.0, that occurred on 25 September 2003 off southeastern Hokkaido, northern Japan, generated a locally destructive tsunami. Maximum run-up height of the tsunami waves reached 4 m above sea level. In order to estimate the tsunami impacts on shallow marine sediments, we compared pre- and post-tsunami marine sediments in water depths of 38–112 m in terms of grain size, sedimentary structure, and microfossil content. Decreases of fine fractions, especially finer than very fine sand, which led to coarsen the mean grain size, were detected in the inner shelf of the northern part of the study area. Foraminiferal assemblages also changed in the coarsened sediments. On the other hand, the other shelf sediments largely unchanged or slightly fined. We also simulated the tsunami wave velocity and direction, and grain size entrained by the modeled tsunami. The numerical simulation resulted in that the 2003 tsunami could transport very fine sand in water depths shallower than 45–95 m at the northern part of the study area. This is comparable with the actual grain-size changes after the tsunami had passed. However, some storms and tidal currents might also be possible to stir the surface sediments after the pre-tsunami survey, so we could not conclude that the grain-size changes had been caused only by the tsunami. Nevertheless, a combined approach of sampling and modeling was powerful for estimating the tsunami impacts under the sea. 相似文献
39.
Variations of water properties in surface and intermediate layers along 32°S in the southern Indian Ocean were examined using
a 50-year (1960–2010) time series reproduced from historical hydrographic and Argo data by using optimum interpolation. Salinity
in the 26.7–27.3σθ density layer decreased significantly over the whole section, at a maximum rate of 0.02 decade−1 at 26.8–26.9σθ, for the 50-year average. Three deoxygenating cores were identified east of 75°E, and the increasing rate of apparent oxygen
utilization in the most prominent core (26.9–27.0σθ) exceeded 0.05 ml l−1 decade−1. The pycnostad core of Subantarctic Mode Water (SAMW) and the salinity minimum of Antarctic Intermediate Water shifted slightly
toward the lighter layers. Comparisons with trans-Indian Ocean survey data from 1936 suggest that the tendencies found in
the time series began before 1960. Interestingly, cores of many prominent trends were located just offshore of Australia at
26.7–27.0σθ, which is in the SAMW density range. Spectrum analysis revealed that two oscillation components with time scales of about
40 and 10 years were dominant in the subsurface layers. Our results are fairly consistent with, and thus support, the oceanic
responses in the southern Indian Ocean to anthropogenic climate change predicted by model studies. 相似文献
40.
This study describes the three-dimensional distributions of the Turner angle (Tu) and the potential vorticity (PV) of the
main pycnocline water in the subtropical North Pacific (10–50°N, 120°E–120°W) using a large in situ CTD data set taken by
the Argo profiling floats during June to October of 2001–2009 to clarify the detailed distribution of the central water and
the mode waters as well as the relationship between these water masses. The ventilated part of the main pycnocline water (σ
θ < 26.7 kg m−3) in the subtropical gyre generally displays a sharp peak in Tu value of 59° in the histogram. The Tu histograms for 10° × 10°
geographical boxes mostly show that the mode for the Tu value is 59° too, but they also show some regional differences, suggesting
some types of relations with the North Pacific mode waters. To further investigate this relationship, the appearance probability
density function of the central water (defined as the main pycnocline water with Tu = 56°–63°) and those of the mode waters
with PVs lower than the critical value on each isopycnal surface were analyzed. The distribution area of the central mode
water (CMW) corresponds so well with that of the central water that a direct contribution of the CMW to the formation and
maintenance of the central water is suggested. On the other hand, the distribution areas of subtropical mode water (STMW),
Eastern STMW, and transition region mode water do not correspond to that of the central water. Nevertheless, indirect contributions
of these mode waters to the formation and maintenance of the central water through salt finger type convection or diapycnal
mixing are suggested. 相似文献