Global land mapping of satellite-observed CO2 total columns using spatio-temporal geostatistics     

Zhao-Cheng Zeng  Liping Lei  Kimberly Strong  Dylan B. A. Jones  Lijie Guo  Min Liu 《International Journal of Digital Earth》2017,10(4):426-456

ABSTRACT

This study presents an approach for generating a global land mapping dataset of the satellite measurements of CO₂ total column (XCO₂) using spatio-temporal geostatistics, which makes full use of the joint spatial and temporal dependencies between observations. The mapping approach considers the latitude-zonal seasonal cycles and spatio-temporal correlation structure of XCO₂, and obtains global land maps of XCO₂, with a spatial grid resolution of 1° latitude by 1° longitude and temporal resolution of 3 days. We evaluate the accuracy and uncertainty of the mapping dataset in the following three ways: (1) in cross-validation, the mapping approach results in a high correlation coefficient of 0.94 between the predictions and observations, (2) in comparison with ground truth provided by the Total Carbon Column Observing Network (TCCON), the predicted XCO₂ time series and those from TCCON sites are in good agreement, with an overall bias of 0.01?ppm and a standard deviation of the difference of 1.22?ppm and (3) in comparison with model simulations, the spatio-temporal variability of XCO₂ between the mapping dataset and simulations from the CT2013 and GEOS-Chem are generally consistent. The generated mapping XCO₂ data in this study provides a new global geospatial dataset in global understanding of greenhouse gases dynamics and global warming.  相似文献   

Infidelity and the Internet: The Geography of Ashley Madison Usership in the United States          下载免费PDF全文

Michael L. Chohaney  Kimberly A. Panozzo 《Geographical review》2018,108(1):69-91

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A sample preparation guide for clay-rich carbonaceous chondrites     

Bennett J. K. Wilson  Veronica E. Di Cecco  Laurence A. J. Garvie  Kimberly T. Tait  Michael G. Daly 《Meteoritics & planetary science》2024,59(3):560-567

The matrix of the C2-ungrouped Tarda meteorite contains abundant smectite minerals that swell and crumble when exposed to polar liquids, causing the sample to rapidly slake. This phenomenon presents a serious challenge when polishing the meteorite, as common polishing liquids used on carbonaceous chondrites, such as water, ethanol, ethylene glycol, and isopropyl alcohol, are polar and will cause the sample to swell, making it unsuitable for some analyses. Hexane and mineral oil are nonpolar liquids that were found to not induce swelling on highly expansive montmorillonite-clay analog material and were effectively integrated into a polishing procedure for Tarda. Here, we detail a procedure for mounting, cutting, and polishing the Tarda meteorite to prepare a surface that is suitable for a variety of sensitive techniques, such as electron microprobe analysis. This work offers a practical methodology for the preparation of other clay-rich samples, which may include the recently returned Ryugu and Bennu materials.  相似文献   

Entanglement of Steller sea lions (Eumetopias jubatus) in marine debris: Identifying causes and finding solutions     

Kimberly L. Raum-Suryan  Lauri A. Jemison 《Marine pollution bulletin》2009,58(10):1487-1495

Entanglement in marine debris is a contributing factor in Steller sea lion (SSL; Eumetopias jubatus) injury and mortality. We quantified SSL entanglement by debris type, sex and age class, entanglement incidence, and estimated population level effects. Surveys of SSL haul-outs were conducted from 2000-2007 in Southeast Alaska and northern British Columbia. We recorded 386 individuals of all age classes as being either entangled in marine debris or having ingested fishing gear. Packing bands were the most common neck entangling material (54%), followed by rubber bands (30%), net (7%), rope (7%), and monofilament line (2%). Ingested fishing gear included salmon fishery flashers (lures: 80%), longline gear (12%), hook and line (4%), spinners/spoons (2%), and bait hooks (2%). Entanglement incidence was 0.26% (SD = 0.0064, n = 69 sites). “Lose the Loop!” Simple procedures such as cutting entangling loops of synthetic material and eliminating the use of packing bands can prevent entanglements.  相似文献   

Cation field strength effects on high pressure aluminosilicate glass structure: Multinuclear NMR and La XAFS results     

Kimberly E. Kelsey  Jonathan F. Stebbins  Gordon E. Brown Jr.  Jed L. Mosenfelder 《Geochimica et cosmochimica acta》2009,73(13):3914-2191

We examined aluminosilicate glasses containing a variety of network modifying to intermediate cations (Li, La, Sc, and Fe), quenched from melts at 1 atm to 8 GPa, to further investigate the role of cation field strength in Al coordination changes and densification. ²⁷Al Nuclear Magnetic Resonance Spectroscopy (NMR) reveals that the mean Al coordination increases with increasing pressure in the Li-containing glasses, which can be explained by a linear dependence of fractional change in Al coordination number on cation field strengths in similar K-, Na-, and Ca-containing aluminosilicate glasses (K < Na < Li < Ca). Measured recovered densities follow a similar linear trend. In contrast, the La-containing glasses have significantly lower mean Al coordination numbers at given pressures than the cation field strength of La and glass density would predict. La L₃ X-ray absorption fine structure (XAFS) spectroscopy results indicate a significant increase with pressure in average La-O bond distances, suggesting that La and Al may be “competing” for higher coordinated sites and hence that both play a significant role in the densification of these glasses, especially in the lower pressure range. However, in Na aluminosilicate glasses with small amounts of Sc, ⁴⁵Sc NMR reveals only modest Sc coordination changes, which do not seem to significantly affect the mean Al coordination values. For a Li aluminosilicate glass, ¹⁷O MAS and multiple quantum magic angle spinning (3QMAS) NMR data are consistent with generation of more highly coordinated Al at the expense of non-bridging oxygen (NBO), whereas La aluminosilicate glasses have roughly constant O environments, even up to 8 GPa. Finally, we demonstrate that useful ²³Na and ²⁷Al MAS NMR spectra can be collected for Ca-Na aluminosilicate glasses containing up to 5 wt.% Fe oxide. We discuss the types of structural changes that may accompany density increases with pressure and how these structural changes are affected by the presence of different cations.  相似文献   

Quantifying household social resilience: a place-based approach in a rapidly transforming community     

Sarah Henly-Shepard  Cheryl Anderson  Kimberly Burnett  Linda J. Cox  John N. Kittinger  Maka‘ala Ka‘aumoana 《Natural Hazards》2015,75(1):343-363

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Research Note: Overpressure prediction from C‐wave seismic data     

Robert J. Ferguson  Daniel A. Ebrom  Kimberly M. Kumar 《Geophysical Prospecting》2011,59(4):787-792

Recently, mode converted shear waves (C‐waves) have been shown to enable overpressure prediction in media where primary wave acquisition is inhibited by gas and fluid effects – C‐wave moveout is analysed and a long standing relationship between differential stress and primary‐wave (P‐wave) velocity is modified and employed. Though pore‐pressure prediction based on C‐waves is supported by empirical evidence from laboratory and field experiments, a theoretical justification has yet to be developed. In this research note, we provide a supporting algebra for the original relationship between pore pressure and C‐wave velocity.  相似文献   

Microbial sources of intact polar diacylglycerolipids in the Western North Atlantic Ocean     

Kimberly J. PopendorfMichael W. Lomas  Benjamin A.S. Van Mooy 《Organic Geochemistry》2011,42(7):803-811

Intact polar membrane lipids are essential components of microbial membranes and recent work has uncovered a diversity of them occurring in the ocean. While it has long been understood that lipid composition varies across microbial groups, the microbial origins of the intact polar lipids in the surface ocean remain to be fully explained. This study focused on identifying the microbial sources of intact polar diacylglycerolipids (IP-DAGs) in the surface waters of the western North Atlantic Ocean. We used three approaches to define these microbial sources: (i) ¹³C tracing to identify photoautotrophic and heterotrophic production of the major classes of IP-DAGs, (ii) cell sorting flow cytometry of Prochlorococcus, Synechococcus and heterotrophic bacteria to determine IP-DAG composition and (iii) regrowth incubations targeting IP-DAG production by heterotrophic bacteria. Stable isotope tracing indicated that sulfoquinovosyldiacylglycerol (SQDG) and diacylglyceryl-trimethyl-homoserine (DGTS) were produced predominantly by photoautotrophs, while phosphatidylglycerol (PG) production was dominated by heterotrophic bacteria. Of the cells sorted with flow cytometry, Prochlorococcus and Synechococcus were found to have abundant glycolipids, while heterotrophic bacteria were dominated by phospholipids. The regrowth incubations showed that the growth of heterotrophic bacteria correlated with an increase in the concentration of PG, phosphatidylethanolamine (PE) and monoglycosyldiacylglycerol (MGDG). The finding of MGDG in heterotrophic bacteria differs from previous work, which had asserted that the membranes of heterotrophic bacteria in this environment were composed entirely of phospholipids. Overall, our findings indicate that phytoplankton are the primary source of SQDG and DGTS, while heterotrophic bacteria are the dominant source of PG, making these three compounds promising biomarkers for the study of microbes in the surface ocean.  相似文献   

Knowledge gaps in tropical Southeast Asian seagrass systems     

Jillian Lean Sim Ooi  Gary A. Kendrick  Kimberly P. Van Niel  Yang Amri Affendi 《Estuarine, Coastal and Shelf Science》2011

Seagrasses are habitats with significant ecological and economic functions but we have limited knowledge of seagrasses in Southeast Asia, the hypothesized centre-of-origin for tropical seagrasses. There have been only 62 ISI-cited publications on the seagrasses of Southeast Asia in the last three decades and most work has been in few sites such as Northwest Luzon in the Philippines and South Sulawesi in Indonesia. Our understanding of the processes driving spatial and temporal distributions of seagrass species here has focussed primarily on backreef and estuarine seagrass meadows, with little work on forereef systems. We used Pulau Tinggi, an island off the southeast coast of Peninsular Malaysia, as an example of a subtidal forereef system. It is characterized by a community of small and fast growing species such as Halophila ovalis (mean shoot density 1454.6 ± 145.1 m⁻²) and Halodule uninervis (mean shoot density 861.7 ± 372.0 m⁻²) growing in relatively low light conditions (mean PAR 162.1 ± 35.0 μmol m⁻² s⁻¹ at 10 m depth to 405.8 ± 99.0 μmol m⁻² s⁻¹ at 3 m water depth) on sediment with low carbonate (mean 9.24 ± 1.74 percentage dry weight), organic matter (mean 2.56 ± 0.35 percentage dry weight) and silt-clay content (mean 2.28 ± 2.43 percentage dry weight). The literature reveals that there is a range of drivers operating in Southeast Asian seagrass systems and we suggest that this is because there are various types of seagrass habitats in this region, i.e. backreef, forereef and estuary, each of which has site characteristics and ecological drivers unique to it. Based on our case study of Pulau Tinggi, we suggest that seagrasses in forereef systems are more widespread in Southeast Asia than is reflected in the literature and that they are likely to be driven by recurring disturbance events such as monsoons, sediment burial and herbivory.  相似文献   

Tornado folk science in Alabama and Mississippi in the 27 April 2011 tornado outbreak     

Kimberly E. Klockow  Randy A. Peppler  Renee A. McPherson 《GeoJournal》2014,79(6):791-804

In this paper, we collect, categorize, and discuss the existence of numerous ways of knowing about tornado threat that largely differ from the perspective taken by the meteorological community. These alternate ways of knowing became apparent during interviews with survivors of the 27 April 2011 tornado outbreak in the US southeast, particularly in Alabama and Mississippi. Phenomena discussed herein include perceptions of safety near waterways, vulnerability near a specific highway with a recently modified landscape, the protective nature of hills, relative optimism about home sites, and local observational weather knowledge. Theoretical explanations offered for these observed phenomena include ideas from risk perception and place attachment literatures.  相似文献