Erratum to: The impact of climate change on California’s ecosystem services     

M. Rebecca Shaw  Linwood Pendleton  D. Richard Cameron  Belinda Morris  Dominique Bachelet  Kirk Klausmeyer  Jason MacKenzie  David R. Conklin  Gregory N. Bratman  James Lenihan  Erik Haunreiter  Christopher Daly  Patrick R. Roehrdanz 《Climatic change》2012,110(3-4):1067-1067

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Macroscopic and spectroscopic analysis of lanthanide adsorption to bacterial cells     

Bryne T. Ngwenya  J. Fred W. Mosselmans  Kirk D. Atkinson  Janette Tourney  Valerie Olive 《Geochimica et cosmochimica acta》2009,73(11):3134-6719

This study was designed to combine surface complexation modelling of macroscopic adsorption data with X-ray Absorption Spectroscopic (XAS) measurements to identify lanthanide sorption sites on the bacterial surface. The adsorption of selected representatives for light (La and Nd), middle (Sm and Gd) and heavy (Er and Yb) lanthanides was measured as a function of pH, and biomass samples exposed to 4 mg/L lanthanide at pH 3.5 and 6 were analysed using XAS. Surface complexation modelling was consistent with the light lanthanides adsorbing to phosphate sites, whereas the adsorption of middle and heavy lanthanides could be modelled equally well by carboxyl and phosphate sites. The existence of such mixed mode coordination was confirmed by Extended X-ray Absorption Fine Structure (EXAFS) analysis, which was also consistent with adsorption to phosphate sites at low pH, with secondary involvement of carboxyl sites at high adsorption density (high pH). Thus, the two approaches yield broadly consistent information with regard to surface site identity and lanthanide coordination environment. Furthermore, spectroscopic analysis suggests that coordination to phosphate sites is monodentate at the metal/biomass ratios used. Based on the best-fitting pK_a site, we infer that the phosphate sites are located on N-acetylglucosamine phosphate, the most likely polymer on gram-negative cells with potential phosphate sites that deprotonate around neutral pH.  相似文献   

A late Holocene paleo-productivity record in the western Gulf of Maine,USA, inferred from growth histories of the long-lived ocean quahog (<Emphasis Type="Italic">Arctica islandica</Emphasis>)     

Alan D. WanamakerJr.  Karl J. Kreutz  Bernd R. Schöne  Kirk A. Maasch  Andrew J. Pershing  Harold W. Borns  Douglas S. Introne  Scott Feindel 《International Journal of Earth Sciences》2009,98(1):19-29

To investigate environmental variability during the late Holocene in the western Gulf of Maine, USA, we collected a 142-year-old living bivalve (Arctica islandica) in 2004, and three fossil A. islandica shells of the Medieval Warm Period (MWP) and late MWP / Little Ice Age (LIA) period (corrected ¹⁴C_AMS = 1030 ± 78 ad; 1320 ± 45 ad; 1357 ± 40 ad) in 1996. We compared the growth record of the modern shell with continuous plankton recorder (CPR) time-series (1961–2003) from the Gulf of Maine. A significant correlation (r ² = 0.55; p < 0.0001) exists between the standardized annual growth index (SGI) of the modern shell and the relative abundance of zooplankton species Calanus finmarchicus. We therefore propose that SGI data from A. islandica is a valid proxy for paleo-productivity of at least one major zooplankton taxa. SGIs from these shells reveal significant periods of 2–6 years (NAO-like) based on wavelet analysis, multitaper method (MTM) analysis and singular spectrum analysis (SSA) during the late Holocene. Based on established physical oceanographic observation in the Gulf of Maine, we suggest that slope water variability coupled with North Atlantic Oscillation (NAO) dynamics is primarily responsible for the observed SGI variability. Special Issue: AGU OS06 special issue “Ocean’s role in climate change—a paleo perspective”.  相似文献   

Synchrotron self-Compton models of high brightness temperature radio sources     

Olivia Tsang  J. G. Kirk 《Astrophysics and Space Science》2008,314(1-3):193-197

We re-examine the maximum brightness temperature that a synchrotron source can sustain by adapting standard synchrotron theory to an electron distribution that exhibits a deficit at low energy. The absence of low energy electrons reduces the absorption of synchrotron photons, allowing the source to reach a higher brightness temperature without the onset of catastrophic cooling. We find that a temperature of ∼10¹⁴ K is possible at GHz frequencies. In addition, a high degree of intrinsic circular polarisation is produced. We compute the stationary, synchrotron and self-Compton spectrum arising from the continuous injection of such a distribution (modelled as a double power-law) balanced by radiative losses and escape, and compare it with the simultaneously observed multi-wavelength spectrum of the BL Lac object S5 0716+714. This framework may provide an explanation of other high brightness-temperature sources without the need for mechanisms such as coherent emission or proton synchrotron radiation.  相似文献   

Titan's surface from the Cassini RADAR radiometry data during SAR mode     

F. Paganelli  M.A. Janssen  E. Stofan  R.D. Lorenz  R.L. Kirk  C. Elachi  The Cassini Radar Team 《Planetary and Space Science》2008,56(1):100-108

We present initial results on the calibration and interpretation of the high-resolution radiometry data acquired during the Synthetic Aperture Radar (SAR) mode (SAR-radiometry) of the Cassini Radar Mapper during its first five flybys of Saturn's moon Titan.We construct maps of the brightness temperature at the 2-cm wavelength coincident with SAR swath imaging. A preliminary radiometry calibration shows that brightness temperature in these maps varies from 64 to 89 K. Surface features and physical properties derived from the SAR-radiometry maps and SAR imaging are strongly correlated; in general, we find that surface features with high radar reflectivity are associated with radiometrically cold regions, while surface features with low radar reflectivity correlate with radiometrically warm regions. We examined scatterplots of the normalized radar cross-section σ⁰ versus brightness temperature, outlining signatures that characterize various terrains and surface features. The results indicate that volume scattering is important in many areas of Titan's surface, particularly Xanadu, while other areas exhibit complex brightness temperature variations consistent with variable slopes or surface material and compositional properties.  相似文献   

Particle acceleration by ultrarelativistic shocks: theory and simulations   总被引：1，自引：0，他引：1  

Abraham Achterberg  Yves A. Gallant  John G. Kirk  Axel W. Guthmann 《Monthly notices of the Royal Astronomical Society》2001,328(2):393-408

We consider the acceleration of charged particles near ultrarelativistic shocks, with Lorentz factor     . We present simulations of the acceleration process and compare these with results from semi-analytical calculations. We show that the spectrum that results from acceleration near ultrarelativistic shocks is a power law,     , with a nearly universal value     for the slope of this power law.
We confirm that the ultrarelativistic equivalent of the Fermi acceleration at a shock differs from its non-relativistic counterpart by the occurrence of large anisotropies in the distribution of the accelerated particles near the shock. In the rest frame of the upstream fluid, particles can only outrun the shock when their direction of motion lies within a small loss cone of opening angle     around the shock normal.
We also show that all physically plausible deflection or scattering mechanisms can change the upstream flight direction of relativistic particles originating from downstream by only a small amount:     . This limits the energy change per shock crossing cycle to     , except for the first cycle where particles originate upstream. In that case the upstream energy is boosted by a factor     for those particles that are scattered back across the shock into the upstream region.  相似文献   

Structure of the Venus mesosphere and lower thermosphere from measurements during entry of the pioneer Venus probes     

A. Seiff  Donn B. Kirk 《Icarus》1982,49(1):49-70

Data on the thermal structure of the nightside middle atmosphere of Venus, from 84 to 137 km altitude, have been obtained from analysis of deceleration measurements from the third Pioneer Venus small probe, the night probe, which entered the atmosphere near the midnight meridian at 27°S latitude. Comparison of the midnight sounding with the morning sounding at 31°S latitude indicates that the temperature structure is essentially diurnally invariant up to 100 km, above which the nightside structure diverges sharply from the dayside toward lower temperatures. Very large diurnal pressure differences develop above 100 km with dayside pressure ten times that on the nightside at 126 km altitude. This has major implications for upper atmospheric dynamics. The data are compared with the measurements of G. M. Keating, J. Y. Nicholson, and L. R. Lake (1980, J. Geophys. Res., 85, 7941–7956) above 140 km with theoretical thermal structure models of Dickinson, and with data obtained by Russian Venera spacecraft below 100 km. Midnight temperatures are ～ 130°K, somewhat warmer than those reported by Keating et al.  相似文献   

NUMERICAL ANALYSIS IN GEOMORPHOLOGY: AN INTRODUCTION     

Bob  Kirk 《New Zealand geographer》1973,29(1):97-97

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Submarine groundwater discharge to Great South Bay, NY, estimated using Ra isotopes   总被引：1，自引：0，他引：1  

Aaron J. Beck  John P. Rapaglia  J. Kirk Cochran  Henry J. Bokuniewicz  Suhui Yang 《Marine Chemistry》2008,109(3-4):279

There is increasing evidence that submarine groundwater discharge (SGD) in many areas represents a major source of dissolved chemical constituents to the coastal ocean. In Great South Bay, NY, previous studies have shown that the discharge of nutrients with SGD may cause harmful algal blooms. This study estimates SGD to Great South Bay during August 2006 by performing a mass balance for each of the dissolved Ra isotopes (²²⁴Ra, ²²³Ra, ²²⁸Ra, ²²⁶Ra). The budget indicates a major unknown source (between 30 and 60% of the total input) of Ra to the bay. This imbalance can be resolved by a flux of Ra-enriched groundwater on the order of 3.5–4.5 × 10⁹ L d^− 1, depending on the Ra isotope. The Ra-estimated SGD rates compare well with those previously estimated by models of flow that decreases exponentially away from shore. Compared to previous reports of fresh groundwater discharge to the bay, the Ra-estimated discharge must comprise approximately 90% recirculated seawater. The good agreement between Ra- and model-estimated flow rates indicates that the primary SGD endmember may be best sampled at shallow depths in the sediments a short distance bayward of the low tide line.  相似文献   

Time-series measurements of Th in water column and sediment trap samples from the northwestern Mediterranean Sea     

J. Kirk Cochran  Juan Carlos Miquel  Robert Armstrong  Scott W. Fowler  Pere Masqu  Beat Gasser  David Hirschberg  Jennifer Szlosek  Alessia M. Rodriguez y Baena  Elisabet Verdeny  Gillian M. Stewart 《Deep Sea Research Part II: Topical Studies in Oceanography》2009,56(18):1487-1501

Disequilibrium between ²³⁴Th and ²³⁸U in water column profiles has been used to estimate the settling flux of Th (and, by proxy, of particulate organic carbon); yet potentially major non-steady-state influences on ²³⁴Th profiles are often not able to be considered in estimations of flux. We have compared temporal series of ²³⁴Th distributions in the upper water column at both coastal and deep-water sites in the northwestern Mediterranean Sea to coeval sediment trap records at the same sites. We have used sediment trap records of ²³⁴Th fluxes to predict temporal changes in water column ²³⁴Th deficits and have compared the predicted deficits to those measured to determine whether the time-evolution of the two coincide. At the coastal site (327 m water depth), trends in the two estimates of water column ²³⁴Th deficits are in fairly close agreement over the 1-month deployment during the spring bloom in 1999. In contrast, the pattern of water column ²³⁴Th deficits is poorly predicted by sediment trap records at the deep-water site (DYFAMED, 2300 m water depth) in both 2003 and 2005. In particular, the transition from a mesotrophic to an oligotrophic system, clearly seen in trap fluxes, is not evident in water column ²³⁴Th profiles, which show high-frequency variability. Allowing trapping efficiencies to vary from 100% does not reconcile the differences between trap and water column deficit observations; we conclude that substantial lateral and vertical advective influences must be invoked to account for the differences.Advective influences are potentially greater on ²³⁴Th fluxes derived from water column deficits relative to those obtained from traps because the calculation of deficits in open-ocean settings is dominated by the magnitude of the “dissolved” ²³⁴Th fraction. For observed current velocities of 5–20 cm s⁻¹, in one radioactive mean-life of ²³⁴Th, the water column at the DYFAMED site can reflect ²³⁴Th scavenging produced tens to hundreds of kilometers away. In contrast, most of the ²³⁴Th flux collected in shallow sediment traps at the DFYFAMED site was in the fraction settling >200 m d⁻¹; in effect the sediment trap can integrate the ²³⁴Th flux over distances 40-fold less than water column ²³⁴Th distributions. In some sense, sediment trap and water column sampling for ²³⁴Th provide complementary pictures of ²³⁴Th export. However, because the two methods can be dominated by different processes and are subject to different biases, their comparison must be treated with caution.  相似文献