Inverse methods for estimating primary input signals from time-averaged isotope profiles     

Benjamin H. Passey  Thure E. Cerling  Todd F. Robinson  Stephen K. Krueger 《Geochimica et cosmochimica acta》2005,69(16):4101-4116

Mammalian teeth are invaluable archives of ancient seasonality because they record along their growth axes an isotopic record of temporal change in environment, plant diet, and animal behavior. A major problem with the intra-tooth method is that intra-tooth isotope profiles can be extremely time-averaged compared to the actual pattern of isotopic variation experienced by the animal during tooth formation. This time-averaging is a result of the temporal and spatial characteristics of amelogenesis (tooth enamel formation), and also results from laboratory sampling. This paper develops and evaluates an inverse method for reconstructing original input signals from time-averaged intra-tooth isotope profiles. The method requires that the temporal and spatial patterns of amelogenesis are known for the specific tooth and uses a minimum length solution of the linear system Am = d, where d is the measured isotopic profile, A is a matrix describing temporal and spatial averaging during amelogenesis and sampling, and m is the input vector that is sought. Accuracy is dependent on several factors, including the total measurement error and the isotopic structure of the measured profile. The method is shown to accurately reconstruct known input signals for synthetic tooth enamel profiles and the known input signal for a rabbit that underwent controlled dietary changes. Application to carbon isotope profiles of modern hippopotamus canines reveals detailed dietary histories that are not apparent from the measured data alone. Inverse methods show promise as an effective means of dealing with the time-averaging problem in studies of intra-tooth isotopic variation.  相似文献   

A Pool-Based Model of the Spatial Distribution of Undiscovered Petroleum Resoufrces     

Haiyu Gao  Zhuoheng Chen  Kirk G. Osadetz  Peter Hannigan  Cameron Watson 《Mathematical Geology》2000,32(6):725-749

An approach is proposed to predict the spatial distributions of undiscovered petroleum resources. Each pool is parameterized as a marked-point. The independence chain of the Hastings algorithm is used to generate an appropriate structure for pool combinations in a play. Petroleum-bearing favorability estimated from geological observations is used to represent the sampling probabilities of pool locations. An objective function measuring the distance between characteristics of the realization and constraints is constructed from both the pool size distribution and entropy maximum criterion, in which the entropy criterion places all undiscovered pools in the most favorable positions. The geometrical convergence property of the proposed Hastings algorithm is presented. The method is illustrated by a case study from the Western Canada Sedimentary Basin.  相似文献   

Trade in ‘virtual carbon’: Empirical results and implications for policy     

Giles Atkinson  Kirk HamiltonGiovanni Ruta  Dominique Van Der Mensbrugghe 《Global Environmental Change》2011,21(2):563-574

The fact that developing countries do not have carbon emission caps under the Kyoto Protocol has led to the current interest in high income countries in border taxes on the ‘virtual’ carbon content of imports. We use GTAP data and input-output analysis to estimate the flows of virtual carbon implicit in domestic production technologies and the pattern of international trade. The results present striking evidence on the wide variation in the carbon-intensiveness of trade across countries, with major developing countries being large net exporters of virtual carbon. Our analysis suggests that a tax on virtual carbon could lead to very substantial effective tariff rates on the exports of the most carbon-intensive developing nations. As an illustration, we find that average tariff rates of 10%, 8% and 12% would be faced by imports from China, India and South Africa if carbon is taxed at $50/ton CO₂. Moreover, there is wide variation in intensiveness across sectors within countries with implications for the disparate effective tariff burdens on particulars parts of the economies of these countries. Such empirical findings, we argue, are useful for framing on-going discussions about the principles and practice of border taxes on virtual carbon.  相似文献   

Ammonium in thermal waters of Yellowstone National Park: Processes affecting speciation and isotope fractionation     

JoAnn M. Holloway  D. Kirk Nordstrom  R. Blaine McCleskey 《Geochimica et cosmochimica acta》2011,75(16):4611-4636

Dissolved inorganic nitrogen, largely in reduced form (), has been documented in thermal waters throughout Yellowstone National Park, with concentrations ranging from a few micromolar along the Firehole River to millimolar concentrations at Washburn Hot Springs. Indirect evidence from rock nitrogen analyses and previous work on organic compounds associated with Washburn Hot Springs and the Mirror Plateau indicate multiple sources for thermal water NH₄(T), including Mesozoic marine sedimentary rocks, Eocene lacustrine deposits, and glacial deposits. A positive correlation between NH₄(T) concentration and δ¹⁸O of thermal water indicates that boiling is an important mechanism for increasing concentrations of NH₄(T) and other solutes in some areas. The isotopic composition of dissolved NH₄(T) is highly variable (δ¹⁵N = −6‰ to +30‰) and is positively correlated with pH values. In comparison to likely δ¹⁵N values of nitrogen source materials (+1‰ to +7‰), high δ¹⁵N values in hot springs with pH >5 are attributed to isotope fractionation associated with loss by volatilization. NH₄(T) in springs with low pH typically is relatively unfractionated, except for some acid springs with negative δ¹⁵N values that are attributed to condensation. NH₄(T) concentration and isotopic variations were evident spatially (between springs) and temporally (in individual springs). These variations are likely to be reflected in biomass and sediments associated with the hot springs and outflows. Elevated NH₄(T) concentrations can persist for 10s to 1000s of meters in surface waters draining hot spring areas before being completely assimilated or oxidized.  相似文献   

Hydrogeochemical processes governing the origin, transport and fate of major and trace elements from mine wastes and mineralized rock to surface waters   总被引：2，自引：0，他引：2  

D. Kirk Nordstrom 《Applied Geochemistry》2011,26(11):1777-1791

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Ecosystem-based marine spatial management: Review of concepts, policies, tools, and critical issues   总被引：1，自引：0，他引：1  

Stelios Katsanevakis  Vanessa Stelzenmüller  Andy South  Thomas Kirk Sørensen  Peter J.S. Jones  Sandy Kerr  Fabio Badalamenti  Christos Anagnostou  Patricia Breen  Guillem Chust  Giovanni D’Anna  Mike Duijn  Tatiana Filatova  Fabio Fiorentino  Helena Hulsman  Kate Johnson  Aristomenis P. Karageorgis  Ingrid Kröncke  Simone Mirto  Carlo Pipitone  Susan Portelli  Wanfei Qiu  Henning Reiss  Dimitris Sakellariou  Maria Salomidi  Luc van Hoof  Vassiliki Vassilopoulou  Tomás Vega Fernández  Sandra Vöge  Anke Weber  Argyro Zenetos  Remment ter Hofstede 《Ocean & Coastal Management》2011,54(11):807-820

Conventional sectoral management and piecemeal governance are considered less and less appropriate in pursuit of sustainable development. Ecosystem based marine spatial management (EB-MSM) is an approach that recognizes the full array of interactions within an ecosystem, including human uses, rather than considering single issues, species, or ecosystem services in isolation. Marine spatial planning and ocean zoning are emerging concepts that can support EB-MSM. EB-MSM is driven by high-level goals that managers aim to achieve through the implementation of measures. High-level goals and objectives need to be translated into more operational objectives before specific targets, limits and measures can be elaborated.Monitoring, evaluation and adaptation are necessary to ensure that marine management measures are both effective and efficient. Solid monitoring frameworks are the foundation of adaptive management, as they provide the necessary information to evaluate performance and the effectiveness of management actions. Marine protected areas (MPAs) - possibly set up in networks - constitute a key component in EB-MSM policies and practises and have been applied as a cornerstone in conservation of marine biodiversity, management of fish populations, development of coastal tourism, etc. Moreover, MPA experiences have provided methods and concepts (such as zoning) to a wider EB-MSM context. The assignment of values to biophysical features of the marine environment allows the direct assessment of related management choices and may assist EB-MSM.A range of monetary valuation techniques have been proposed to reduce attributes of goods and services to a single metric. However, in the marine environment such an approach is often over simplistic, and thus less reductive techniques may be necessary. Rather than producing a single metric, the results of non-monetary assessments guide policy allowing weight to be given as necessary to potential areas of conflict and consensus.Strategies to take into account climate change effects and geohazard risks in EB-MSM have been applied or proposed worldwide. EB-MSM regimes must be alert to such risks and flexible to account for changes.  相似文献   

SCUBA Polarisation Observations of the Magnetic Fields in Prestellar Cores     

D.J. Nutter  D. Ward-Thompson  R.M. Crutcher  J.M. Kirk 《Astrophysics and Space Science》2004,292(1-4):179-184

Prestellar cores represent the stage of star formation immediately prior to protostellar collapse. We present polarisation maps of three prestellar cores, L183, L1544 and L43. In each case the magnetic field lines are uniform but not parallel to the semi-minor axis of the core. This suggests that magnetic and thermal pressure support alone are inconsistent with the data. We also calculate the magnetic field strength using the Chandrasekhar-Fermi technique and find that all three cores are magnetically supercritical by a factor of ～ 2. This is consistent with the observation that the magnetic field is not dominating the evolution of these cores.  相似文献   

Quasar tomography: unification of echo mapping and photoionization models     

Keith Horne  Kirk T. Korista  Michael R. Goad 《Monthly notices of the Royal Astronomical Society》2003,339(2):367-386

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Saturn's icy satellites: Thermal and structural models     

Kirk Ellsworth  Gerald Schubert 《Icarus》1983,54(3):490-510

Thermal histories of the small icy Saturnian satellites Mimas, Tethys, Dione, Rhea, and Iapetus are constructed by assuming that they formed as homogeneous ice-silicate mixtures. The models include effects of radiogenic and accretional heating, conductive and subsolidus convective heat transfer, and lithospheric growth. Accretional heating is unlikely to have melted the water ice in the interiors of these bodies and solid state creep of the predominately ice material precludes melting by radiogenic heating. Mimas is so small that its thermal evolution is essentially purely conductive; at present it is a cold, nearly isothermal body. Any subsolidus convection or thermal activity in Mimas would have been confined to a brief period in its early history and would have been due to a warm formation. The four largest satellites are big enough and contain sufficient heat-producing silicates that solid state convection beneath a rigid lithosphere is inevitable independent of initial conditions. Dione and Rhea have convective interiors for most of their thermal histories, while Tethys and Iapetus have mainly conductive thermal histories with early periods of convective 0activity. The thermal histories of the five satellites for the last 4 by are independent of initial conditions; at present they have cold, conductive interiors. The model thermal histories are qualitatively consistent with the appearances of these satellites: Mimas has an ancient heavily cratered surface, Tethys and probably Iapetus have both heavily cratered and more lightly cratered areas, and Dione and Rhea have extensively modified surfaces. Because of their similar sizes and densities, Mimas and Enceladus are expected to have similar surfaces and thermal histories, but instead Enceladus has the most modified surface of all the small icy Saturnian satellites. Our results suggest a heat source for Enceladus, in addition to radiogenic and accretional heating; tidal dissipation is a possibility. Because the water ice in these bodies does not melt, resurfacing must be accomplished by the melting of a low-melting-temperature minor component such as ammonia hydrate.  相似文献   

GSFC optical ozonesonde results during the Gap,France, intercomparisons,June 1981     

Arlin J. Krueger  Peter Simeth  Carol A. Fry  Krishna Tewari 《Planetary and Space Science》1983,31(7):749-759

A GSFC Super Loki optical ozonesonde instrument was flown as part of the ozone sensor intercomparison balloon campaign at Gap, France, in June 1981. A primary objective was to confirm biases between external absorption techniques, such as the GSFC sonde, and in situ techniques, which include ECC, Mast-Brewer, and DASIBI sondes. Ozone distributions were obtained with the GSFC sonde on three of the four ascent-descent legs of the first flight on 19 June. Ozone densities were measured redundantly over altitudes from 22 to 32 km using filters centered at 303 and 300 nm. The three profiles obtained by averaging the data from the two channels are in close agreement with an average S.E. of 1.4%. However, small but consistent differences were found between the ozone densities measured at the two wavelengths. The average difference is 5% using Vigroux cross sections and 4% using preliminary Bass cross sections. The integral ozone amount above the first ceiling altitude of 32.85 km was determined by the Langley plot method to be 45 D.U. The total ozone derived by integrating the optical ozonesonde and ECC profiles is within 2% of the Chiran Dobson Spectrophotometer observation based on a pre-campaign calibration but is 9% greater than the amount derived using a post-campaign calibration.  相似文献