A preliminary study of the carbon-isotopic content of ambient formic acid and two selected sources: Automobile exhaust and formicine ants   总被引：2，自引：0，他引：2  

Bryan J. Johnson  George A. Dawson 《Journal of Atmospheric Chemistry》1993,17(2):123-140

Relatively large quantities (1 mg) of formic acid have been collected from the atmosphere and subjected to carbon-isotopic analysis, as a means of source discrimination. Ambient formic acid was captured on Ca(OH)₂-treated filters using a high-volume sampler. The collection method was not only efficient (>96%), but also appears to have low artifact production.Most of the samples (36 out of 52) were collected over a two-year period at the summit of Mount Lemmon, Arizona, where a strong seasonality in HCOOH mixing ratio was observed (0.2 ppb during winter months to 1.5 ppb in the summer). Other collection sites included the Oregon coast, Colorado Rockies, urban Tucson, and the North Dakota prairie. The carbon-13 content of atmospheric HCOOH was found to be have little variation (–18 to –25), regardless of location or season. This is consistent with a single dominant source of formic acid. The carbon-14 measurements of 6 Mount Lemmon samples showed high levels of modern carbon (93–113% modern).The emissions from formicine ants and automobile combustion were selected as two other potential sources for isotopic analysis. The HCOOH collected from auto exhaust was much more depleted in¹³C than the atmospheric samples, with a ¹³C of –28.0 and –48.6 from a leaded and unleaded automobile, respectively. Formicine ants, on the other hand, ranged from –17.2 to –20.6.  相似文献   

Seismic response of self‐centring hysteretic SDOF systems     

Constantin Christopoulos  Andr Filiatrault  Bryan Folz 《地震工程与结构动力学》2002,31(5):1131-1150

The seismic response of single‐degree‐of‐freedom (SDOF) systems incorporating flag‐shaped hysteretic structural behaviour, with self‐centring capability, is investigated numerically. For a SDOF system with a given initial period and strength level, the flag‐shaped hysteretic behaviour is fully defined by a post‐yielding stiffness parameter and an energy‐dissipation parameter. A comprehensive parametric study was conducted to determine the influence of these parameters on SDOF structural response, in terms of displacement ductility, absolute acceleration and absorbed energy. This parametric study was conducted using an ensemble of 20 historical earthquake records corresponding to ordinary ground motions having a probability of exceedence of 10% in 50 years, in California. The responses of the flag‐shaped hysteretic SDOF systems are compared against the responses of similar bilinear elasto‐plastic hysteretic SDOF systems. In this study the elasto‐plastic hysteretic SDOF systems are assigned parameters representative of steel moment resisting frames (MRFs) with post‐Northridge welded beam‐to‐column connections. In turn, the flag‐shaped hysteretic SDOF systems are representative of steel MRFs with newly proposed post‐tensioned energy‐dissipating connections. Building structures with initial periods ranging from 0.1 to 2.0s and having various strength levels are considered. It is shown that a flag‐shaped hysteretic SDOF system of equal or lesser strength can always be found to match or better the response of an elasto‐plastic hysteretic SDOF system in terms of displacement ductility and without incurring any residual drift from the seismic event. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

Rates of Deglaciation during the Last Glaciation and Holocene in the Cordillera Vilcanota-Quelccaya Ice Cap Region, Southeastern Perú     

Bryan G. Mark  Geoffrey O. Seltzer  Donald T. Rodbell  Adam Y. Goodman 《Quaternary Research》2002,57(3):287

Moraine chronology is combined with digital topography to model deglacial rates of paleoglacier volumes in both the Huancané Valley on the west side of the Quelccaya Ice Cap and the Upismayo Valley on the northwest side of the Cordillera Vilcanota. The fastest rates of deglaciation (39×10⁻⁵ to 114×10⁻⁵ km³ yr⁻¹ and 112×10⁻⁵ to 247×10⁻⁵ km³ yr⁻¹ for each valley, respectively) were calculated for the most recent paleoglaciers, corresponding to the last few centuries. These results are consistent with observations in the Venezuelan Andes showing high rates of deglaciation since the Little Ice Age. These rates also fall within the range of 20th century rates of deglaciation measured on the Quelccaya Ice Cap (29×10⁻⁵ to 220×10⁻⁵ km³ yr⁻¹, Brecher and Thompson, 1993; Thompson, 2000). These results imply that rates of deglaciation may fluctuate significantly over time and that high rates of deglaciation may not be exclusive to the late 20th century. Equilibrium line altitude (ELA) depressions for the ice volumes of the last glaciation modeled here were computed as 230 m for the Quelccaya Ice Cap and 170 m for the Cordillera Vilcanota. Maximum ELA depressions are lower than previously published: <500 m for the Cordillera Vilcanota and <400 m for the Quelccaya Ice Cap. These lower values could imply a topographic control over paleoglacier extent.  相似文献   

Surveying Stonehenge By Photogrammetry     

P. G. Bryan  M. Clowes 《The Photogrammetric Record》1997,15(89):739-751

For centuries the ruins of Stonehenge have proved to be both a source of fascination and mystery for the many visitors to this World Heritage Site. The monument itself sets a puzzle that even to this day has not been solved, although there have been numerous theories suggested as to its construction. There is little accurate survey data currently available on the stones themselves, against which these many theories could be tested. The Photogrammetric Unit of English Heritage was therefore requested, in 1993, to commence a project to digitally map all the external faces of all the stones that form the visible remains of this internationally important monument. Photogrammetry was the chosen survey technique and this paper outlines the work of the Unit in using the latest digital photogrammetric equipment to generate a basic three dimensional model of Stonehenge.  相似文献   

A predictability study of simulated North Atlantic multidecadal variability   总被引：1，自引：1，他引：1  

S. M. Griffies  K. Bryan 《Climate Dynamics》1997,13(7-8):459-487

 The North Atlantic is one of the few places on the globe where the atmosphere is linked to the deep ocean through air–sea interaction. While the internal variability of the atmosphere by itself is only predictable over a period of one to two weeks, climate variations are potentially predictable for much longer periods of months or even years because of coupling with the ocean. This work presents details from the first study to quantify the predictability for simulated multidecadal climate variability over the North Atlantic. The model used for this purpose is the GFDL coupled ocean-atmosphere climate model used extensively for studies of global warming and natural climate variability. This model contains fluctuations of the North Atlantic and high-latitude oceanic circulation with variability concentrated in the 40–60 year range. Oceanic predictability is quantified through analysis of the time-dependent behavior of large-scale empirical orthogonal function (EOF) patterns for the meridional stream function, dynamic topography, 170 m temperature, surface temperature and surface salinity. The results indicate that predictability in the North Atlantic depends on three main physical mechanisms. The first involves the oceanic deep convection in the subpolar region which acts to integrate atmospheric fluctuations, thus providing for a red noise oceanic response as elaborated by Hasselmann. The second involves the large-scale dynamics of the thermohaline circulation, which can cause the oceanic variations to have an oscillatory character on the multidecadal time scale. The third involves nonlocal effects on the North Atlantic arising from periodic anomalous fresh water transport advecting southward from the polar regions in the East Greenland Current. When the multidecadal oscillatory variations of the thermohaline circulation are active, the first and second EOF patterns for the North Atlantic dynamic topography have predictability time scales on the order of 10–20 y, whereas EOF-1 of SST has predictability time scales of 5–7 y. When the thermohaline variability has weak multidecadal power, the Hasselmann mechanism is dominant and the predictability is reduced by at least a factor of two. When the third mechanism is in an extreme phase, the North Atlantic dynamic topography patterns realize a 10–20 year predictability time scale. Additional analysis of SST in the Greenland Sea, in a region associated with the southward propagating fresh water anomalies, indicates the potential for decadal scale predictability for this high latitude region as well. The model calculations also allow insight into regional variations of predictability, which might be useful information for the design of a monitoring system for the North Atlantic. Predictability appears to break down most rapidly in regions of active convection in the high-latitude regions of the North Atlantic. Received: 28 October 1996 / Accepted: 21 March 1997  相似文献   

Viruses as potential regulators of regional brown tide blooms caused by the alga,Aureococcus anophagefferens     

Mary Downes Gastrich  Justine A. Leigh-Bell  Christopher J. Gobler  O. Roger Anderson  Steven W. Wilhelm  Martha Bryan 《Estuaries and Coasts》2004,27(1):112-119

Blooms of the brown tide organismAureccoccus anophagefferens have recurred in the coastal bays in New Jersey since 1995 and in the coastal bays of Long Island since 1985. Intracellular viral-like particles (VLPs) were documented during 1999–2000 brown tide blooms in Little Egg Harbor, New Jersey, but it was not determined whether cells were infected during the termination of the bloom. The objective of this study was to determine if VLPs infected and lysed natural populations ofA. anophagefferens in coastal bays of New Jersey and New York in 2002 with the same frequency as in 1999–2000 and especially at the termination of the bloom. Our results confirmed that the highest percentage (37.5%) of VLP-infected cells occurred at the termination of the brown tide bloom in New Jersey in 2002. Intracellular VLPs were present throughout the bloom event. The percentage of visibly infected cells was higher at the beginning of the bloom than during the peak of the bloom. The intracellular VLPs in natural populations ofA. anophagefferens were consistent in size and shape (approximately 140 nm in diameter) and comparable to those in previous studies. Concentrated viral isolates, prepared from waters during brown tide blooms in New York and New Jersey in 2002, infected healthy laboratoryA. anophagefferens cultures in vitro. The viral isolates associated with the highest laboratory viral activity (lysis positive) were concentrated from water samples having the highest viral and bacteria concentrations. The intracellular viruses in these virally infected laboratory cultures ofA. anophagefferens were similar in size and shape to those found in natural populations. The successful isolation of a virus specific toA. anophagefferens from a brown tide bloom in the field, the similarity of ultrastructure of VLPs infecting both natural populations and laboratory infected cultures, and the pattern of VLP infection during bloom activity in combination with the observed high percentage of VLP-infected cells during bloom termination, supports, the hypothesis that viruses may be a major source of mortality for brown tide blooms in regional coastal bays of New Jersey and New York.  相似文献   

Oxygen‐18 dynamics in precipitation and streamflow in a semi‐arid agricultural watershed,Eastern Washington,USA     

Bryan G. Moravec  C. Kent Keller  Jeffrey L. Smith  Richelle M. Allen‐King  Angela J. Goodwin  Jerry P. Fairley  Peter B. Larson 《水文研究》2010,24(4):446-460

Understanding flow pathways and mechanisms that generate streamflow is important to understanding agrochemical contamination in surface waters in agricultural watersheds. Two environmental tracers, δ¹⁸O and electrical conductivity (EC), were monitored in tile drainage (draining 12 ha) and stream water (draining nested catchments of 6‐5700 ha) from 2000 to 2008 in the semi‐arid agricultural Missouri Flat Creek (MFC) watershed, near Pullman Washington, USA. Tile drainage and streamflow generated in the watershed were found to have baseline δ¹⁸O value of ?14·7‰ (VSMOW) year round. Winter precipitation accounted for 67% of total annual precipitation and was found to dominate streamflow, tile drainage, and groundwater recharge. ‘Old’ and ‘new’ water partitioning in streamflow were not identifiable using δ¹⁸O, but seasonal shifts of nitrate‐corrected EC suggest that deep soil pathways primarily generated summer streamflow (mean EC 250 µS/cm) while shallow soil pathways dominated streamflow generation during winter (EC declining as low as 100 µS/cm). Using summer isotopic and EC excursions from tile drainage in larger catchment (4700‐5700 ha) stream waters, summer in‐stream evaporation fractions were estimated to be from 20% to 40%, with the greatest evaporation occurring from August to October. Seasonal watershed and environmental tracer dynamics in the MFC watershed appeared to be similar to those at larger watershed scales in the Palouse River basin. A 0·9‰ enrichment, in shallow groundwater drained to streams (tile drainage and soil seepage), of δ¹⁸O values from 2000 to 2008 may be evidence of altered precipitation conditions due to the Pacific Decadal Oscillation (PDO) in the Inland Northwest. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Differing controls on river‐ and lake‐water hydrogen and oxygen isotopic values in the western United States     

Anna King Henderson  Bryan Nolan Shuman 《水文研究》2010,24(26):3894-3906

Surface water oxygen and hydrogen isotopic values are commonly used as proxies of precipitation isotopic values to track modern hydrologic processes while proxies of water isotopic values preserved in lake and river sediments are used for paleoclimate and paleoaltimetry studies. Previous work has been able to explain variability in USA river‐water and meteoric‐precipitation oxygen isotope variability with geographic variables. These studies show that in the western United States, river‐water isotopic values are depleted relative to precipitation values. In comparison, the controls on lake‐water isotopic values are not well constrained. It has been documented that western United States lake‐water input values, unlike river water, reflect the monthly weighted mean isotopic value of precipitation. To understand the differing controls on lake‐ and river‐water isotopic values in the western United States, we examine the seasonal distribution of precipitation, evaporation and snowmelt across a range of seasonality regimes. We generate new predictive equations based on easily measured factors for western United States lake‐water, which are able to explain 69–63% of the variability in lake‐water hydrogen and oxygen isotopic values. In addition to the geographic factors that can explain river and precipitation values, lake‐water isotopic values need factors related to local hydrologic and climatic characteristics to explain variability. Study results suggest that the spring snowmelt runs off the landscape via rivers and streams, depleting river and stream‐water isotopic values. By contrast, lakes receive seasonal contributions of precipitation in proportion to the seasonal fraction of total annual precipitation within their watershed. Climate change may alter the ratio of snow to rain fall, affecting water resource partitioning between rivers and lakes and by implication of groundwater. Paleolimnological studies must account for the multiple drivers of water isotopic values; likewise, studies based on the isotopic composition of fossil material need to distinguish between species that are associated with rivers versus lakes. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

A review of observations of the effect of bathymetry on ocean circulation in recent decades     

Kirk Bryan 《Izvestiya Atmospheric and Oceanic Physics》2016,52(4):341-347

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On aerosol production and enrichment by breaking wind waves     

Bryan R. Kerman 《大气与海洋》2013,51(4):329-345

Abstract

A model is presented for the production and enrichment of aerosols. Bubbles distributed in size by fragmentation scavenge particles and transport them to the surface. In the collapse process at the surface the bubble's skin is enveloped into the ejected aerosol leading to significant enrichment. For no mass accumulation at the surface in foam the flux due to scavenging equals that for resuspension leading to an estimate of the enrichment. The model results compare favourably with observations of artificial and wind‐generated enrichment if it is assumed that during the scavenging the bubble's clean and mobile surface during the initial stages collects most of its particle load. Further scavenging by the encrusted bubble surface, while significant, is not as dramatic. Other observations of the wind dependency of the process support the model.  相似文献