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61.
We present an experimental investigation on the dissolution of uniaxially stressed crystals of NaClO3 in contact with brine. The crystals are immersed in a saturated fluid, stressed vertically by a piston and monitored constantly in situ with a CCD camera. The experiments are temperature-controlled and uniaxial shortening of the sample is measured with a high-resolution capacitance analyzer. Once the crystal is stressed it develops dissolution grooves on its free surface. The grooves are oriented with their long axis perpendicular to the direction of compressive stress and the initial distance between the parallel grooves is in accordance with the Asaro-Tiller-Grinfeld instability. We observe a novel, transient evolution of this roughness: The grooves on the crystal surface migrate upwards (against gravity), grow in size and the inter-groove distance increases linearly with time. During the coarsening of the pattern this switches from a one-dimensional geometry of parallel grooves to a two-dimensional geometry with horizontal and vertical grooves. At the end of the experiment one large groove travels across the crystal and the surface becomes smooth again. Uniaxial shortening of the crystal by pressure solution creep decays exponentially with time and shows no long term creep within the range of the resolution of the capacitance analyzer (accuracy of 100nm over a period of 14 days). This indicates that, while active, the fast transient processes on the free surface increase the solution concentration and thereby significantly slow down or stop pressure solution at the top of the crystal. This novel feedback mechanism can explain earlier results of cyclic pressure solution creep and demands development of a more complex theory of pressure-solution creep including processes that act on free surfaces. 相似文献
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Achim Aretz Kristian Bär Annette E. Götz Ingo Sass 《International Journal of Earth Sciences》2016,105(5):1431-1452
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Basin and petroleum system modelling of the East Coast Basin,New Zealand: a test of overpressure scenarios in a convergent margin 
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下载免费PDF全文 In the East Coast Basin (ECB), an active convergent margin of the North Island, New Zealand, the smectite‐rich Eocene Wanstead Formation forms an effective regional seal, creating high overpressure in the underlying Cretaceous through Palaeocene units due to disequilibrium compaction. This study examines the evolution of pore pressure and porosity in Hawke Bay of the ECB based on stepwise structural reconstruction of a stratigraphic and structural framework derived from interpretation of a regional two‐dimensional seismic line. This framework is incorporated into a basin and petroleum system model to predict the generation, distribution, and dissipation of overpressure, and examine the influence of faults, erosion, structural thickening, and seal effectiveness of the Wanstead Formation on pore pressure evolution. We find that natural hydraulic fracturing is likely occurring in sub‐Wanstead source rocks, which makes it a favourable setting for potential shale gas plays. We use poroelastic modelling to investigate the impact of horizontal bulk shortening due to tectonic compression on pore pressure and the relative order of principal stresses. We find that shortening modestly increases pore pressure. When 5% or greater shortening occurs, the horizontal stress may approach and exceed vertical stress in the last 4 Myr of the basin's history. Shortening impacts both the magnitude and relative order of principal stresses through geological time. Due to the overpressured nature of the basin, we suggest that subtle changes in stress regime are responsible for the significant changes in structural deformational styles observed, enabling compressional, extensional, and strike‐slip fault regimes to all occur during the tectonic history and, at times, simultaneously. 相似文献
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The point of departure for this article is the contemporary tendency towards localisation of politics in the context of neo-liberal globalisation. Mediated through institutional reforms, political discourses and localised struggles, this localisation of politics produce new and transformed local political spaces. The purpose of the article is to examine the capacity of popular movements to use and transform such political spaces within the South African housing sector. This analysis is done through a combination of conceptual examination of political space and actor capacity and a concrete case study of the political strategies and capacities of The South African Homeless People’s Federation. The article argues that the Federation has utilised political relations at different scales to mobilise resources such as land and subsidies for housing for its members. It has also influenced the formulation of housing policies through its discourses and practical experiences with people-driven housing processes. In consequence the Federation’s ability to function as a civil/political movement has granted them a certain capacity to participate in the complicated process of turning de jure rights to adequate shelter into de facto rights for the urban poor as citizens of a democratic South Africa. 相似文献
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Acta Geochimica - Goethite (α-FeOOH) is one of the most abundant minerals on the Earth surface, occurring in temperate, tropical and equatorial climates. Fe in goethite can be substituted by... 相似文献