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111.
We report on the detection of H2 as seen in our analysis of twilight observations of the lunar atmosphere observed by the LAMP instrument aboard NASA’s Lunar Reconnaissance Orbiter. Using a large amount of data collected on the lunar atmosphere between September 2009 and March 2013, we have detected and identified, the presence of H2 in the native lunar atmosphere, for the first time. We derive a surface density for H2 of 1.2 ± 0.4 × 103 cm−3 at 120 K. This is about 10 times smaller than originally predicted, and several times smaller than previous upper limits from the Apollo era data.  相似文献   
112.
We investigated rutile needles with a clear shape preferred orientation in garnet from (ultra) high-pressure metapelites from the Kimi Complex of the Greek Rhodope by electron microprobe, electron backscatter diffraction and TEM techniques. A definite though complex crystallographic orientation relationship between the garnet host and rutile was identified in that Rt[001] is either parallel to Grt<111> or describes cones with opening angle 27.6° around Grt<111>. Each Rt[001] small circle representing a cone on the pole figure displays six maxima in the density plots. This evidence together with microchemical observations in TEM, when compared to various possible mechanisms of formation, corroborates a precipitate origin. A review of exchange vectors for Ti substitution in garnet indicates that rutile formation from garnet cannot occur in a closed system. It requires that components are exchanged between the garnet interior and the rock matrix by solid-state diffusion, a process we refer to as “open-system precipitation” (OSP). The kinetically most feasible reaction of this type will dominate the overall process. The perhaps most efficient reaction involves internal oxidation of Fe2+ to Fe3+ and transfer from the dodecahedral to the octahedral site just vacated by $ {\text{Ti}}^{ 4+ }: 6\,{\text{M}}^{ 2+ }_{ 3} {\text{TiAl}}\left[ {{\text{AlSi}}_{ 2} } \right]{\text{O}}_{ 1 2} + 6\,{\text{M}}^{ 2+ }_{ 2, 5} {\text{TiAlSi}}_{ 3} {\text{O}}_{ 1 2} = 10\,{\text{M}}^{ 2+ }_{ 3.0} {\text{Al}}_{ 1. 8} {\text{Fe}}_{0. 2} {\text{Si}}_{ 3} {\text{O}}_{ 1 2} + {\text{M}}^{2+} + 2 {\text{e}}^{-} + 1 2\,{\text{TiO}}_{ 2} . $ OSP is likely to occur at conditions where the transition of natural systems to open-system behaviour becomes apparent, as in the granulite and high-temperature eclogite facies.  相似文献   
113.
Stilbite is locally present as a very late mineral on fractures and fissures of granitic basement in the Central Swiss Alps. Stilbite samples from the Gotthard rail base tunnel provide evidence that they originally formed as a K-absent variety at depth. However, all stilbite samples from surface outcrops above the tunnel display significant potassium concentrations. Interestingly, water from fractures in the tunnel (at 50 °C) is oversaturated with respect to stilbite and essentially potassium-free whereas waters from high-Alpine brooks above the tunnel (and at other high-Alpine areas) have unusually high K/Na ratios. The data suggest that stilbite that may actively form on fissures at tunnel level as a K-absent variety by precipitation from water. Older stilbite that originally formed as coatings on fracture walls was gradually exhumed and uplifted and finally reached the today’s erosion surface about 2,000 m above the tunnel. However, the stilbite reaches the erosion surface as a K-rich variety as a result of interaction of the original low-K stilbite with surface water and near-surface groundwater. This leads to the conclusion that minerals once formed at depth may significantly change their composition once they reach the ground water zone on their way to the erosion surface. In the case of the stilbite, if surface outcrops would have been the only source of samples and data, the K-rich composition could have been mistaken for the composition of the mineral when it formed, which is not the case. Late-stage compositional readjustments may be difficult to discern in samples from surface outcrops. The provided data show that original mineral compositions may be adjusted by late-stage water–rock interaction in a highly selective way.  相似文献   
114.
Representatives of the Antarctic food web (krill, cephalopod, fish, penguin, seal) of the area around Elephant Island and from the Weddell Sea were analysed for the most recalcitrant organochlorine compounds. Due to sorption of the compounds to sinking particles and accumulation in sediments, two benthic fish species (Gobionotothen gibberifrons, Chaenocephalus aceratus) feeding on benthos invertebrates and fish reflected significantly increasing concentrations within a decade (1987-1996), while a benthopelagic species (Champsocephalus gunnari) feeding on krill did not. In the pelagic food chain, lipid normalised concentrations of all compounds increased from Antarctic krill to fish proving that biomagnification of highly lipophilic pollutants (log octanol-water partition coefficient>5) occurs in water-breathing animals. As top predators Weddell and southern elephant seals (Leptonychotes weddellii, Mirounga leonina) biomagnified the persistent organic pollutants relative to krill 30-160 fold with the exception of hexachlorobenzene, the levels of which were lower than in fish indicating its intense specific elimination.  相似文献   
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118.
This work examines circulatory patterns of airpollutants in the area of Barcelona (Spain), a regionwith strong coastal and orographic influences. Thiswas achieved through exploitation ofelastic-backscatter lidar data and by numericalsimulation of the atmosphere with a meteorologicalmesoscale model (MEMO). Lidar data were acquired inJuly 1992 during a collaborative campaign between LosAlamos National Laboratory (LANL) and the PolytechnicUniversity of Catalonia (UPC). The lidar providedinformation about the distribution of aerosols and theprevailing winds, determined by application of amaximum cross-correlation algorithm toelastic-backscatter lidar data. Lidar winds are usedto evaluate high altitude winds simulated by themodel. This study showed that circulatory patterns inBarcelona are correlated with daytime convectivevertical mixing, sea-breeze circulations, and verticalforcing caused by mountain thermal and mechanicaleffects.  相似文献   
119.
BVR data for the middle-aged radio pulsar PSR 0656+14 obtained on January 20-21, 1996 at the 6-m telescope of the Special Astrophysical Observatory are presented. The brightness of a star-like object coincident with the position of the VLA radio source in the Cousins B filter is B 25.1, with eff = 4448Å, adjacent to the HST F130LP long-pass filter. The relatively large V and R fluxes (3 or > 10-30 ergs cm-2 s-2 Hz-1) provide evidence that the optical emission of this pulsar is non-thermal up to 6600 Å. Most probably, in the UV-optical (BVR) spectral range, a power-law spectrum is super-imposed on the thermal-like emission of the neutron star surface, which could be related to the mechanism of the pulsar activity itself.  相似文献   
120.
Measurements from the 1225 to 1340 Å region by the ultraviolet detectors on Mars-3 are presented. Model calculations of the intensity of the OI triplet lines at 1304 Å are compared with the measurements made on December 27, 1971, and February 17, 1972. Agreement is found between experimental data and a model in which the neutral oxygen density at 100 km is 2–8 × 109 cm?3.  相似文献   
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