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91.
92.
Abstract— Transmission electron microscopic (TEM) and electron energy‐loss spectroscopic (EELS) study of the Ivuna and Orgueil (CI), and Tagish Lake (C2 ungrouped) carbonaceous chondrite meteorites shows two types of C‐clay assemblages. The first is coarser‐grained (to 1 μm) clay flakes that show an intense O K edge from the silicate together with a prominent C K edge, but without discrete C particles. Nitrogen is common in some clay flakes. Individual Orgueil and Tagish Lake meteorite clay flakes contain up to 6 and 8 at% C, respectively. The C K‐edge spectra from the clays show fine structure revealing aromatic, aliphatic, carboxylic, and carbonate C. The EELS data shows that this C is intercalated with the clay flakes. The second C‐clay association occurs as poorly crystalline to amorphous material occurring as nanometer aggregates of C, clay, and Fe‐O‐rich material. Some aggregates are dominated by carbonaceous particles that are structurally and chemically similar to the acid insoluble organic matter. The C K‐edge shape from this C resembles that of amorphous C, but lacking the distinct peaks corresponding to aliphatic, carboxylic, and carbonate C groups. Nanodiamonds are locally abundant in some carbonaceous particles. The abundance of C in the clays suggest that molecular speciation in the carbonaceous chondrites is partly determined by the effects of aqueous processing on the meteorite parent bodies, and that clays played an important role. This intricate C‐clay association lends credence to the proposal that minerals were important in the prebiotic chemical evolution of the early solar system.  相似文献   
93.
The phase relationship between climate parameters during terminations gives insight into deglaciation mechanisms. By combining foraminiferal Mg/Ca and alkenone thermometers with planktonic and benthic foraminiferal δ18O, we determined the phase relationship between local sea surface temperature (SST) and global seawater δ18O changes in the Coral Sea in the Southwestern Pacific over the last 360 ka. The onset of the SST warming preceded the seawater δ18O change by several ka for Termination I, II and III. During Termination I, the SST warming started at 20 ka BP, earlier than atmospheric CO2 rise suggesting that the greenhouse effect was not the main trigger of this early warming. Compilation of 14C-dated SST records from the whole Pacific during Termination I reveals that the onset of the warming is generally earlier in the Southern and the tropical Pacific than in the North Pacific. This spatio-temporal warming pattern suggests linkage between the southern ocean and tropical Pacific. The early tropical warming could provide heat and moisture to the northern high latitudes, modifying radiative balance and precipitation over ice sheets at the onset of deglaciation.  相似文献   
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A compilation of literature data on the Fe-Mg composition of coexisting chlorite and chloritoid from metapelites metamorphosed at various P - T  conditions shows that the logarithm of the Fe-Mg partitioning (ln K D) varies linearly with the inverse of temperature, from about 2.4 at 300  °C to about 1.3 at 600  °C. In contrast, no trend was observed with pressure, and the molar volumes of Mg- and Fe-chlorite end-members suggest that the pressure dependence of ln K D is not significant. Therefore, the chloritoid-chlorite Mg-Fe exchange reaction is a potential thermometer and has been empirically calibrated using the analyses of 112 chloritoid-chlorite pairs from 28 different localities. Temperatures estimated using the Chl-Cld thermometer were checked against independent estimates for 20 samples not involved in the calibration (Beni Mzala window, Morocco), and the results are in fair agreement with independent temperature estimates. However, the analytical uncertainties and errors are too large to obtain reliable temperature estimates for extremely Mg-rich or Fe-rich compositions. The Chl-Cld thermometer is unreliable at XMg-CLD<0.2 and XMg-CLD>0.8 at 700  °C, and XMg-CLD<0.1 and XMg-CLD>0.9 at 300  °C. Using the results of the empirical calibration, we calculated new thermodynamic data for daphnite. Implementing these data, it becomes possible to estimate T  and P conditions of metamorphism for the invariant chlorite-chloritoid-quartz-aluminosilicate assemblage that is widespread in low-grade metapelites. These estimates appear to be relevant only in the stability field of kyanite, whereas the uncertainties on the calculated pressure conditions are very large in the stability field of kaolinite and pyrophyllite.  相似文献   
96.
A computational fluid dynamics (CFD)‐based methodology is proposed to derive convective mass‐transfer coefficients (wind functions) that are required for estimating evaporation of water bodies with the mass‐transfer method. Three‐dimensional CFD was applied to model heat transfer in two water bodies: a Class‐A tank evaporimeter and an on‐farm artificial pond. The standard k–? model assuming isotropic turbulence was adopted to describe turbulent heat transport, whereas the heat and mass transfer analogy was assumed to derive the wind functions. The CFD‐derived wind functions were very similar to those empirically derived from the experimental water bodies. The evaporation rates calculated with the synthetic wind functions were in good agreement with hourly and daily evaporation measurements for the tank and pond, respectively. The proposed CFD‐approach is generalisable and cost effective, because it has low input data requirements. Besides, it provides additional capability of modelling the spatial distribution of the evaporation rate over the water surface. Although the application of CFD to water bodies evaporation modelling is still in development, it looks very promising. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
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Using crowdsourcing techniques, the US Geological Survey’s (USGS) Volunteered Geographic Information (VGI) project known as “The National Map Corps (TNMCorps)” encourages citizen scientists to collect and edit data about man-made structures in an effort to provide accurate and authoritative map data for the USGS National Geospatial Program’s web-based The National Map. VGI is not new to the USGS, but past efforts have been hampered by available technologies. Building on lessons learned, TNMCorps volunteers are successfully editing 10 different structure types in all 50 states as well as Puerto Rico and the US Virgin Islands.  相似文献   
100.
Rock coatings are frequent on natural rock outcrops and even more on stone surfaces of historical buildings and monuments. They are interesting as some of them have a protective effect against erosion. In the last 30 years, research on rock coatings has been performed separately on either buildings or natural outcrops. This paper studies and compares thin coatings found on granitic rock surfaces of historical buildings with coatings found on natural granite outcrops in a same climatic area (NW Spain) by analysing their surface and cross-sections. As rock surfaces of buildings have known age they can be used to assess rates of weathering and coating growth. This is the first comparative study of formation of coatings on natural and built surfaces in the same region. Both endogenous (rock characteristics) and exogenous factors (climatic conditions, air pollution) that could affect the coatings formation are considered to assess the origin and formation of coatings. X-Ray Diffraction (XRD) and X-Ray Fluorescence (XRF) analyses of the underlying rocks, XRD analyses of the coatings and Scanning Electron Microscopy (SEM) observations of surface and cross-sections of the coatings, performing Energy Dispersive Spectrometry (EDS) and X-ray maps, were carried out to establish their composition. Fieldwork and results indicate that natural outcrops are widely covered by biological coatings or coatings formed due to rock weathering, while coatings found on rock ashlars are highly variable with air pollution, other building materials, organic droppings and micro-environmental factors contributing to coatings on rock ashlars in a more significant way than substrate characteristics and exposure time.  相似文献   
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