Petrographische und Kalium-Argon-Untersuchungen an basischen tertiären Vulkaniten zwischen Westerwald und Vogelsberg     

Dipl.-Min. P. -G. Turk  Prof. Dr. H. -H. Lohse  Dr. K. Schürmann  Dr. U. Fuhrmann  Prof. Dr. H. J. Lippolt 《International Journal of Earth Sciences》1984,73(2):599-617

Between the upper tertiary volcanic areas of Westerwald and Vogelsberg (central Western Germany) occur more than 40 isolated tertiary volcanic dikes, eroded necks, plugs and domes. Twelve of these volcanic rocks have been investigated petrographically and chemically and classified by means of their modal and chemical composition. Additional modal analyses have been performed on seven other volcanics. On seventeen volcanic occurences K-Ar-whole rock age determinations have been made. The K-Ar age determinations yield- with the exception of an olivine-nephelinite — values between 27 and 15 Ma. Regarding the known intervals of volcanic activities of the Westerwald- and Voge1sberg-areas, most of the examined volcanics can be related genetically with one of the adjacent volcanic areas. There seems to be no geographical overlapping of volcanics showing Westerwaldages and Vogelsberg-ages. A possible influence of excess-Ar-bearing phases (e. g. mantle xenoliths) and an Ar-loss of constituent matter of the groundmass have been estimated by additional age determinations of enriched samples. These influences — partially compensating each other — may shift the K-Ar whole rock age to a maximum of 5 % and thus do not exceed the dimension of the standard deviations. A distinct NNE-SSW-striking fault in the region between Marburg and Gießen is situated parallel with the eastern border of the “Rheinisches Schiefergebirge”. Volcanics showing Westerwald-age and Vogelsberg-age respectively reach this fault, but obviously do not overlap it. Relations between rock-type an rock age, as it has been observed for the volcanics of the northern Hessian Depression (Kreuzer et al. 1973;Wedepohl 1982) cannot be proved certainly. On the other hand, similar to the basaltic rocks of the northern Hessian Depression, the youngest volcanic product is an olivine-nephelinite (9 Ma).  相似文献   

The multivariate chemical space, and the integration of the chemical, geographical, and geophysical spaces     

M. Mellinger  S.C.Y. Chork  S. Dijkstra  K.H. Esbensen  H. Kürzl  L. Lindqvist  J.-P. Saheurs  O. Schermann  U. Siewers  K. Westerberg 《Journal of Geochemical Exploration》1984,21(1-3)

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Measurements of tropospheric OH concentrations: A comparison of field data with model predictions     

D. Perner  U. Platt  M. Trainer  G. Hübler  J. Drummond  W. Junkermann  J. Rudolph  B. Schubert  A. Volz  D. H. Ehhalt  K. J. Rumpel  G. Helas 《Journal of Atmospheric Chemistry》1987,5(2):185-216

Using long path UV absorption spectroscopy we have measured OH concentrations close to the earth's surface. The OH values observed at two locations in Germany during 1980 through 1983 range from 0.7×10⁶ to 3.2×10⁶ cm^-3. Simultaneously we measured the concentrations of O₃, H₂O, NO, NO₂, CH₄, CO, and the light non methane hydrocarbons. We also determined the photolysis rates of O₃ and NO₂. This allows calculations of OH using a zero dimensional time depdendent model. The modelled OH concentrations significantly exceed the measured values for low NO _x concentrations. It is argued that additional, so far unidentified. HO _x loss reactions must be responsible for that discrepancy.  相似文献   

蛇纹石族矿物及其热转变产物的红外光谱研究     

彭文世  刘高魁 《矿物学报》1986,(2)

本文报道了蛇纹石族矿物及其热转变产物的红外光谱。在室温下斜纤蛇纹石,正纤蛇纹石,叶蛇纹石和利蛇纹石都具有各自的特征光谱。在结构资料基础上,我们解释了它们之间的光谱差异。无疑,红外光谱是区分各种蛇纹石矿物的有效手段。 样品加热到600—700℃时,3680cm~(-1)羟基带消失,这表明在该温度下蛇纹石矿物完全脱羟。与此同时,光谱中出现橄榄石870cm~(-1)的最强带和一个宽带1000cm~(-1),这说明蛇纹石已部分地转变为晶质橄榄石和形成一个无定形的中间相。800℃时,1060cm~(-1)新带的出现标志着顽火辉石的生成。在所有加热样品的光谱中都没有发现SiO_2吸收带,故可认为,在蛇纹石的热转变过程中没有出现SiO_2相。  相似文献   

衍射指标h和k的互换问题     

张冠英 《矿物学报》1986,(2)

通过衍射线指标和面网指标的联系讨论了晶体的对称性对衍射指标h和k互换的影响。在下列情况下衍射指标h和k是不能互换的:在低级晶族;在四方晶系C_(4h)—4/m劳厄点群,六方品系C_(6h)—6/m劳厄点群和立方晶系T_h—m3劳厄点群对于hko和kkl型衍射;在三方晶系选取六方晶胞的情况下,在C_(3i)—3劳厄点群对于hol,okl,hko和hkl型衍射,在D_(3d)—3m劳厄点群对于holokl和hkl型衍射,以及在菱面体点阵除非h和k都是三的倍数。  相似文献   

浙江缙云斜发沸石水的核磁共振分析   总被引：1，自引：0，他引：1  

李新安 《矿物学报》1986,(2)

本文应用宽线NMR技术,结合红外测定,研究了缙云斜发沸石中水的结构类型、存在状态、运动特征和热稳定性。结果表明:缙云斜发沸石中的沸石水按其运动特性可以分为受阻旋转水、自由旋转水和自扩散运动水三种类型,它们以谱线中分裂的双线和线宽不同的单峰相区别。低温时,受阻旋转运动的水在晶格中转变为刚性配置。其脱水次序决定于各类型水与沸石结构骨架键合的强弱,脱水是连续的。研究显示缙云斜发沸石的结构骨架相当疏宽,骨架对水分子的吸引力没有严格的方向性,这一特性有利于阳离子的交换。  相似文献   

沉积岩中蒙脱石-伊利石混层矿物的SEM/EDAX分析   总被引：1，自引：1，他引：1  

奚可棠 《矿物学报》1986,(3)

本文利用扫描电子显微镜与X射线能量色散分析联合法,对沉积岩中蒙脱石-伊利石混层矿物进行系统微区成分分析,求出混合层中伊利石的百分含量。  相似文献   

Zum Umweltverhalten von Fluortensiden. Teil 3: Reinigung der industriellen Abwässer     

D. Prescher  U. Gross  J. Wotzka  M. Tscheu-Schlüter  W. Starke 《洁净——土壤、空气、水》1986,14(3):293-304

Four fluorotensides which are used mainly industrially are investigated with respect to their removability from waters. Since, in general, fluorotensides are difficult to remove or not at all removable biochemically, the effects of chemical or physicochemical treatment processes are tested. As the results represented in pictures and tables show, different modes of behaviour can be recognized with respect to the respective purification effect for the investigated fluorotensides, partly among them. Flocculation with Al- and Fe-salts as well as chlorination and ozonization show only partial effects. But all the investigated fluorotensides can be adsorptively eliminated by means of powder or granular active charcoal and adsorbent resin Wofatit EA₆₀.  相似文献   

The Chemical Composition of Global Subducting Sediments and Its Geological Significance     

Renjie Zhao  Quanshu Yan  Haitao Zhang  Yili Guan  Zhenmin Ge  Long Yuan  Shishuai Yan 《地球科学进展》1986,35(8):789-803

Subducted sediments play an important role in crust-mantle interaction and deep mantle processes, especially for subduction zone magmatism and mantle geochemistry. The current rate of Global Subducting Sediments (GLOSS) is 0.5~0.7 km³/a. The GLOSS are composed of terrigenous material(76 wt.%), calcium carbonate(7 wt.%), opal(10 wt.%) and mineral-bound H₂O⁺(7 wt.%). The chemical compositions of GLOSS are similar to those of upper continental crust which is mainly controlled by the terrigenous materials, and yet the materials formed by marine processes will dilute the terrigenous materials. The components of subducted sediments are different among trenches. In the accretionary margin, the components of subducted sediments are similar to those of the upper crust, while in the non-accretionary margin the components are terrigenous materials plus those produced by marine processes. During subduction, subducted sediments will released fluids, melt or supercritical fluid to affect island arc/back-arc basin magmatism by means of aqueous fluid or sediment melt. In addition, a part of subducted sediments, together with underlying altered oceanic crust/lithosphere, recycle into the mantle and contribute to the mantle heterogeneity. Geochemical tracers indicate that subducted sediments play variable contributions to the magmatic processes in different tectonic setting. Thus, subducted sediments play an important role in two relatively independent dynamics systems (plate tectonics and mantle plume), as well as related mantle evolution models. As a result, by accurately calculating the compositions of subduction sediments and using various geochemical indicators, we can further limit the input and output fluxes of various elements or isotopes, and then obtain more accurately residual subducted components, which can provide us some important clues for geodynamic process.  相似文献   

Transportation as a limitation to rural development: The case of Abak in Nigeria     

Obot  J. U. 《GeoJournal》1986,12(3):317-321

Abak was opened by the colonial government as an administrative centre in the early 1900s. Since then the town and its surrounding areas are still rural in outlook. Development possibilities are very slim unless transportation is viewed seriously by both the government.The difficulty here is that the Kwa Iboe River with its tributaries that crosses the area has created transport bottlenecks. Entry into the area from the E, W and S is through narrow onelane bridges on the rivers. The inefficient transport development has led to difficulties in the movement of farm products to the market. The prices of manufactured goods are higher in the area than in other places about 12 or 14 kilometres away.  相似文献