Glauconite pellets from the Lower Silurian Brassfield Formation on both limbs of the Cincinnati Arch in Ohio and Indiana give a RbSr age of 370 ± 11 Ma, which is substantially younger than the stratigraphic age of the formation. The age is concordantcwith conventional KAr ages of 355 ± 6 and 368 ± 5 Ma for two of the same glauconites. Concordant ages were also obtained from the Viburnum Trend in Missouri, where glauconite pellets from the Davis Formation in an ore-zone collapse structure into the underlying Bonneterre Formation give a RbSr age of 387 ± 21 Ma and conventional KAr ages of 368 ± 5 and 369 ± 5 and 369 ± 5 Ma. A third suite of glauconite from the Bonneterre Formation in the Old Lead Belt ～ 10 km from the nearest ore body has given a RbSr age of 423 ± 7 Ma and slightly older conventional KAr ages of 434 ± 6, 445 ± 6 and 441 ± 11 Ma.Because these glauconite-bearing rocks have been buried to depths of less than 1 km, thermal resetting of the RbSr and KAr systematics appears unlikely. The initial ratios of the RbSr isochrons are similar to the ratios for vein- and vug-filling dolomite and calcite. This is consistent with resetting of the RbSr and KAr systems during diagenetic changes which included the isotopic equilibration (perhaps by cation exchange) of the Sr in the glauconite with that in the diagenetic and Mississippi Valley-type ore fluids. This interpretation implies that the age of the Mississippi Valley-type mineralization in the Viburnum Trend is Devonian rather than Carboniferous—Permian as has been inferred from paleomagnetic measurements.Cation-exchange experiments with a dilute Sr-bearing solution and an artificial oilfield brine indicate that glauconite adsorbs large amounts of Sr, some of which is sufficiently strongly attached to the glauconite lattice as to resist leaching with ammonium acetate. The introduction of this strongly attached Sr may be the first step in the resetting of the RbSr systematics of glauconite by cation exchange. 相似文献
The distribution, stratigraphic relationships and fragmental components of the May 8 and 20, 1902, pyroclastic flows from Mt. Pelée, Martinique, together with eyewitness accounts, suggest the following explanation for those eruptions. The eruptions were vertically directed magmatic (perhaps initiated phreatically), and contained abundant juvenile lithics from congealed magma of the dome and neck. This resulted in a two-part eruption column having (1) a dense, lithic-charged part which collapsed into the crater and flowed out of a pre-existing notch in its side, giving rise to pyrochlastic flows, and (2) a magmatically derived column containing gases, juvenile vitric material and crystals which largely by-passed the neck and dome and escaped into the atmosphere. All of the energy of the flows was apparently focused through the notch. They emerged fully turbulent and flowed down Rivière Blanche. Gravity segregation of large and abundant fragments soon resulted in a dense, high-concentration, poorly fluidized block-and-ash flow confined to the valley, leaving above a fully turbulent, high-energy ash-cloud surge. As the ash-cloud surge moved down the mountain, it continued to expand outward. The process of gravity segregation continued as the ash-cloud surge expanded, resulting in secondary block-and-ash underflows. Toward St. Pierre, the secondary block-and-ash flows developed on a gently sloping upland surface 100 m or more above the valley of Rivière Blanche. The turbulent, fragment-depleted surges above the secondary block-and-ash flows maintained sufficient energy to devastate the landscape outward to about 3000 m, including St. Pierre. The surges refracted around obstacles and in one place, moved up a small valley in a direction opposite to the main flows. 相似文献
Sensible heat flux data obtained from the U.S. Environmental Protection Agency's Regional Air Pollution Study in St. Louis, Missouri are presented and discussed. Large spatial variations exist in heat flux on both a land-use scale and the urban scale. Arguments based upon empirical data and sampling theory show that estimates of heat flux representative of an upwind fetch lx require a minimum observation height proportional to z3/4. The influence of advection on the magnitude of the heat flux is also explored for both the urban and sub-urban or land-use scales. The data clearly indicate that advection can strongly modulate and even dominate the vertical heat flux above surfaces in areas which maintain large horizontal temperature gradients. The advection contribution is positive for cold air advection and negative for warm air advection, and may result from either the urban heat island or land-use mesoscale features. The depth of advective influence is directly proportional to the horizontal scale of the phenomenon and inversely proportional to horizontal temperature gradient. 相似文献
The movement of slugs of bedload from a discrete input point down a river has proved difficult to model using conventional finite-difference formulations of equations of motion. A model is proposed which makes explicit allowance for the mean sediment velocity and, through a dispersion coefficient, the distribution of sediment velocity about the mean. A second comparative model uses the normal mass conservation or sediment transport continuity approach. The models have been tested over a 43-month period using data from seven monitored cross-sections of the Kawerong River on Bougainville Island, Papua New Guinea, a system which receives waste from a large copper mine. The dispersion model performs considerably better than the mass-conservation model. 相似文献
The Winnipeg Formation is the basal sedimentary unit throughout much of southern and central Manitoba, Canada, where it forms
a regional aquifer over most of its extent. This aquifer is an important source of water in southeastern Manitoba and in Manitoba’s
Interlake area, but in most other areas, groundwater within the aquifer is saline. Chemical and isotopic evidence indicate
the presence of groundwaters of three different origins: (1) basin brines; (2) modern meteoric recharge; and (3) subglacial
recharge that occurred during the late Pleistocene. Hydraulic head and sedimentary facies distributions indicate that the
flow system in parts of the area is not in a state of equilibrium and saline waters will encroach on areas currently occupied
by freshwater in some areas, while in other areas, freshwater will replace saline water. These features must be considered
in groundwater resource management, as groundwater withdrawals will likely hasten these processes.
Resumen La Formación Winnipeg es la unidad sedimentaria basal en la mayor parte de Manitoba central, Canadá, donde forma un acuífero
regional en la mayor parte de su extensión. Este acuífero es una fuente importante de agua en el Sureste de Manitoba y el
área de entrelagos de Manitoba, pero en la mayoría de las otras zonas del acuífero, el agua es salina. Las evidencias químicas
e isotópicas indican que existen aguas subterráneas de tres orígenes diferentes: (1) salmueras de cuenca; (2) recarga meteórica
actual; y (3) recarga subglacial ocurrida durante el Pleistoceno Superior. Los niveles piezométricos y la distribución de
las facies sedimentarias indican que el sistema de flujo no se encuentra en estado de equilibrio en parte del área y las aguas
salinas irán invadiendo áreas actualmente ocupadas con aguas dulces, mientras que en otras zonas el agua dulce está reemplazando
al agua salina. Estos hechos deben ser considerados en la gestión de las aguas subterráneas como recurso, ya que las extracciones
de agua acelerarán probablemente estos procesos.
Résumé La Formation de Winnipeg est l’unité sédimentaire de base sur la plus grande partie du Sud et du centre du Manitoba au Canada,
où elle forme un aquifère régional sur pratiquement toute son extension. Cet aquifère représente une ressource en eau importante
dans le Sud-Est du Manitoba et dans les zones d’entre les lacs, mais salée dans la plus part des autres zones. Les indications
isotopiques et chimiques permettent de distinguer trois différentes origines des eaux souterraines: (1) les saumures de bassin;
(2) la recharge météoritique moderne; (3) la recharge sub-glaciaire qui est apparue durant le Pléistocène récent. Les charges
hydrauliques et la distribution des faciès sédimentaires indiquent que le système d’écoulement dans certaines zones n’est
pas dans un état d’équilibre et que les eaux salées empièteront sur des zones d’eau douce, tandis que dans d’autres zones
l’eau douce remplacera les eaux salées. Ces aspects doivent être considérés dans la gestion des ressources en eau souterraine,
car le prélèvement des eaux souterraines pourrait accentuer ces processus.
Large woody debris (LWD) is an integral component of forested streams of the Pacific Northwest and elsewhere, yet little is known about how far wood is transported and where it is deposited in streams. In this paper, we report the results of flume experiments that examine interactions among hydraulics, channel geometry, transport distance and deposition of floating wood. These experiments were carried out in a 1.22-m-wide×9.14-m-long gravel bed flume using wooden dowels of various sizes as surrogate logs. Channel planforms were either self-formed or created by hand, and ranged from meanders to alternate bars. Floating pieces tended to orient with long axes parallel to flow in the center of the channel. Pieces were deposited where channel depth was less than buoyant depth, typically at the head of mid-channel bars, in shallow zones where flow expanded, and on the outside of bends. We hypothesize that the distance logs travel may be a function of the channel's debris roughness, a dimensionless index incorporating ratios of piece length and diameter to channel width, depth and sinuosity. Travel distance decreased as the ratio of piece length to both channel width and radius of curvature increased, but the relative importance of these variables changed with channel planform. Large pieces can move further than our debris roughness models predict if greater than 50% of the active channel area is deeper than the buoyant depth of the piece, or if momentum is high enough to carry pieces across shallows. Our debris roughness model allows first-order prediction of the amount of wood transport under various channel geometries. 相似文献
Salt-loaded effluents were introduced into the river Wipper during the mining period for almost a century. Beginning with the year 1990, the waste water load was strongly reduced due to the termination of the potash industry. Prior to 1990, monthly means of the chloride concentrations at times exceeded 6,000 mg l−1 in the strongly polluted sections. Maximum concentrations reached twice these values. Up to 1998, mean annual chloride concentrations decreased to values below 2,000 mg l−1. This led to more balanced fluctuations in salinity which had been pronounced before, depending on discharge and short-term changes in production. Similarly, the physiologically adverse ion conditions improved due to decrasing potassium and increasing calcium proportions.
In 1963/64, 1986 and 1998, samples of epilithic, epiphytic and epipsammic diatoms were taken at locations of different salinities along the river and examined for the effects of the salinization on the structure of the diatom assemblages. These structures changed in dependence on salinity. Increasing salt concentrations coincided with decreasing oligohalophilic and increasing mesohalophilic and polyhalophilic species numbers. Above a chloride concentration of about 3,000 mg l−1, the proportion of the latter exceed that of the former (halobion index > 50). Corresponding to different conditions of salinization along the river, characteristic diatom assemblages occur differring from each other and which are specific for the river section. Spring and autumn aspects of the diatom assemblages show also salt-dependent differences. The assemblages found in 1998 after decrease of salinization have changed markedly in comparison to those from 1963/64 and 1986. Halobiontic species predominating formerly occurred only occasionally or not at all. They were replaced by oligohalobic-indifferent forms.
An ecological assessment of the changes was performed based on the halobion index calculated from all the samples. For the strongly salinized section of the river Wipper, a shift from -mesohalobic/polyhalobic conditions in 1963/64 and 1986 to -oligohalobic/β-mesohalobic conditions in 1998 was found. However, constant -oligohalobic conditions are still not given. With regard to the transition from -oligohalobic (limnetic) to β-mesohalobic (brackish) conditions, a maximum chloride concentration of 600 mg l−1 was found. To guarantee -oligohalobic conditions, a maximum chloride concentration of 400 mg l−1 should not be exceeded. 相似文献
Since the commissioning of the three major deepwater outfalls in Sydney, there has been a dramatic improvement in general beach water quality at Sydney's ocean beaches. This has required the NSW Environment Protection Authority's Beachwatch Programme to shift from assessing the impacts of gross sewage pollution due to nearshore outfalls to more diffuse pollution from stormwater and sewer overflows.
The visual indicators of gross sewage pollution originally used by Beachwatch for the daily assessment of bacterial water quality are now of limited value. General linear models (with multiple effects) were constructed to identify the secondary indicators which best describe the levels of bacterial contamination due to stormwater pollution. Data from four representative Sydney beaches were modelled separately due to the site-specific effects of pollution sources and hydrodynamics. Factors which were built into the models and were known on the day of prediction were rain amount, presence of stormwater material, the maximum daily stormwater rating, drain or lagoon flows at the time of sampling, and the drain/lagoon bacterial concentration two days before sampling.
Results indicate that there is a general linear relationship between visual indicators and bacterial density; however, the reliability of the prediction on a daily basis is poor and rainfall alone as a predictor is equivalent to or better than visual assessment alone. The primary source of information for the preparation of Beachwatch daily pollution bulletins now is rainfall reports from a telemetered network of rain gauges along the coast. This is a more cost-effective approach and has allowed the reallocation of resources to address more directly the problem of stormwater pollution at higher risk beaches. 相似文献
