Dinoflagellate Cyst Assemblages in Surface Sediments from Three Shallow Mediterranean Lagoons (Sardinia,North Western Mediterranean Sea)     

Cecilia T. Satta  Sílvia Anglès  Esther Garcés  Nicola Sechi  Silvia Pulina  Bachisio Mario Padedda  Daniela Stacca  Antonella Lugliè 《Estuaries and Coasts》2014,37(3):646-663

The present study identified and quantified dinoflagellate cysts in surface sediments from three Mediterranean lagoons. Sediment samples were recovered from 11 stations in May 2009 at Cabras Lagoon, eight stations in May 2010 at Corru S'Ittiri Lagoon, and five stations in May 2011 at Santa Giusta Lagoon. Fifty-three dinoflagellate cyst morphotypes were identified. Sixteen species are first reports for the lagoons, and two for the Mediterranean Sea. Moreover, a new Scrippsiella species was discovered in Cabras. Seven harmful algal species were identified, primarily belonging to the potentially toxic genus Alexandrium. Total cyst abundance, number of morphotypes, and assemblages varied among lagoons, and each lagoon showed a distinct morphotype composition. A degree of heterogeneity was also detected within lagoon. Cabras and Santa Giusta cyst assemblages were characterised by morphotypes belonging to the autotrophic genus Scrippsiella, whereas Corru S'Ittiri assemblages showed dominance of heterotrophic morphotypes, including Protoperidinium cf tricingulatum. Differentiation among lagoons was also evident according to environmental conditions. Salinity proved to be a fundamental variable in determining total cyst abundance, morphotype number, and composition. This study was among the first to examine dinoflagellate cyst composition in coastal lagoons, especially from the Mediterranean region, and contributed data that increased our knowledge of cyst-producing dinoflagellates in these environments.  相似文献   

Tectonic and climatic control on the Late Messinian sedimentary evolution of the Nijar Basin (Betic Cordillera,Southern Spain)     

Silvia Omodeo Salé  Rocco Gennari  Stefano Lugli  Vinicio Manzi  Marco Roveri 《Basin Research》2012,24(3):314-337

The Late Messinian fill of the Nijar Basin (Betic Cordillera, southeastern Spain) mainly consists of clastic deposits of the Feos Formation that at basin margins rest unconformably above the primary evaporites of the Yesares Formation, the local equivalent of the Mediterranean Lower Gypsum. The Feos Fm. records the upward transition towards non‐marine environments before the abrupt return to fully marine conditions at the base of the Pliocene. The Feos Fm. is clearly two‐phase, with ‘lower’ and ‘upper’ members, which exhibit substantial differences in terms of facies, thickness, depositional trends and cyclical organization. These members record two distinct sedimentary and tectonic stages of Nijar Basin infilling. A high‐resolution, physical‐stratigraphic framework is proposed based on key beds and stratigraphic cyclicity and patterns that differ largely from those of most previously published studies. The predominant influence on stratigraphic cyclicity is interpreted to be precessionally driven climate changes, allowing their correlation to the Late Messinian astronomically calibrated chronostratigraphic framework. Detailed correlations suggest a phase of enhanced tectonic activity, possibly related to the Serrata‐Carboneras strike‐slip fault zone, during the first stage (‘lower’ member), resulting in a strongly articulated topography with structural lows and highs controlling sediment thickness and facies variation. Tectonic activity decreased during the second stage (‘upper’ member), which is characterized by (1) a progressively dampened and homogenized, (2) overall relative base‐level rise and (3) gradual establishment of hypohaline environments. Facies characteristics, overall stacking patterns and depositional trends of the Feos Fm. are analogous with uppermost Messinian successions of the Northern Apennines, Piedmont Basin and Calabria. Despite minor differences related to the local geodynamic setting, these basins experienced a common Late Messinian history that supports the development of a single, large Mediterranean water body characterized by high‐frequency, climatically‐driven changes in sediment flux and base‐level.  相似文献   

Petrographic, REE, fluid inclusion and stable isotope study of magnesite from the Upper Triassic Burano Evaporites (Secchia Valley, northern Apennines): contributions from sedimentary, hydrothermal and metasomatic sources     

Stefano Lugli  Giulio Morteani  Dominique Blamart 《Mineralium Deposita》2002,37(5):480-494

Sparry and microcrystalline magnesite are minor constituents of the Upper Triassic Burano Evaporite Formation of the northern Apennines in Italy. Petrography and geochemistry of magnesite suggest three modes of formation. (1) Evaporitic precipitation of stratified microcrystalline magnesite layers associated with sulfate and carbonate rocks. Most REE are below ICP-MS detection limits. '¹⁸O is +20.2‰ (SMOW) and '¹³C is -2.6‰ (PDB). (2) Hydrothermal infill of Fe-rich (9.78 wt% FeO) lenticular sparry magnesite. This type of magnesite is characterized by very low LREE concentrations, whereas HREEs are relatively high. The fluid inclusion composition is NaCl-MgCl₂-H₂O, salinity is ~30 wt% NaCl equiv., and total homogenization temperatures range from 204-309 °C; '¹⁸O is +17.5‰ and '¹³C is +1‰. (3) The partial or total replacement of dolostones by lenticular sparry magnesite. LREEs are lower in magnesite compared with the partly replaced dolostones. Magnesite yields '¹⁸O and '¹³C compositions of +17.3 to +23.6‰ and +0.5 to +1.4‰, respectively, whereas the partly replaced dolostones yield '¹⁸O and '¹³C values of +25.0 to +26.2 and +1.3 to +1.9, respectively. Complete replacement of dolostones produced massive lenticular sparry magnesite rock containing ooids and axe-head anhydrite relicts; LREEs are depleted compared to unaffected dolostones; '¹⁸O and '¹³C compositions range from +16.4 to +18.4‰ and +0.4 to +0.9‰, respectively. These data and the association between fracture-filling and replacive magnesite suggests a metasomatic system induced by hydrothermal circulation of hot and saline Mg-rich fluids. These processes probably occurred in the Oligocene-Miocene, when the Burano Formation acted as main detachment horizon for the Tuscan Nappe during the greenschist facies metamorphism of the Apuane complex. Thrusting over the Apuane zone produced large scale fluid flow focused at the Tuscan Nappe front. Sources of Mg-rich fluids were metamorphic reactions in the Apuane complex and dissolution of Mg-salts at the thrust front. Considering a maximum tectonic burial depth of 10 km, as inferred from the geometry of the chain, the pressure-corrected temperature of magnesite precipitation (380 to 400 °C) and the calculated fluid composition ('¹⁸O=+13.3ǃ.2‰) are in the range of the published Apuane metamorphic temperatures (300-450 °C) and fluid compositions ('¹⁸O=7-16‰). The results of this study support the hydrothermal-metasomatic model for the formation of sparry magnesite deposits at the expense of dolostone units involved in thrusting and low-grade metamorphism, as proposed for the Northern Graywacke Zone (Alps) and the Eugui deposit (western Pyrenees).  相似文献   

Nano‐Powdered Calcium Carbonate Reference Materials: Significant Progress for Microanalysis?     

Klaus Peter Jochum  Dieter Garbe‐Schnberg  Marina Veter  Brigitte Stoll  Ulrike Weis  Michael Weber  Federico Lugli  Anna Jentzen  Ralf Schiebel  Jasper A. Wassenburg  Dorrit E. Jacob  Gerald H. Haug 《Geostandards and Geoanalytical Research》2019,43(4):595-609

Homogeneity, mass fractions of about forty trace elements and Sr isotope composition of Ca carbonate reference materials (RMs) between original and nano‐powdered pellets are compared. Our results using nanosecond and femtosecond LA‐(MC)‐ICP‐MS show that the nano‐pellets of the RMs MACS‐3NP, JCp‐1NP and JCt‐1NP are about a factor of 2–3 more homogeneous than the original samples MACS‐3, JCp‐1 and JCt‐1, and are therefore much more suitable for microanalytical purposes. With the exception of Si, the mass fractions of the synthetic RM MACS‐3 agree with its fine‐grained analogue MACS‐3NP. Very small, but significant, differences between original and nano‐pellets are observed in the RMs JCp‐1 and JCt‐1 for some trace elements with very low contents, indicating the need for re‐certification. Strontium mass fractions in the analysed RMs are high (1500–7000 mg kg^?1), and their isotope compositions determined by LA‐MC‐ICP‐MS in the original and the nano‐pellets agree within uncertainty limits.  相似文献   

The synthetic seismic expression of the Messinian salinity crisis from onshore records: Implications for shallow‐ to deep‐water correlations     

M. Roveri  R. Gennari  M. Ligi  S. Lugli  V. Manzi  M. Reghizzi 《Basin Research》2019,31(6):1121-1152

The onshore–offshore correlation of sedimentary successions is a common problem in basin analysis, but it becomes critical for the full understanding of the Messinian salinity crisis (MSC), a complex array of palaeoenvironmental events which affected the Mediterranean basin at the end of the Miocene. The outcrop records show that the Messinian stratigraphic architectures may be highly complex as the deposits of the different MSC evolutionary stages can be lithologically similar and separated by erosional surfaces and/or morphostructural highs. The correct definition of the nature and stratigraphic position of Messinian deposits in offshore areas through seismic data may be almost impossible, especially where core data are sparse. To bridge the gap between onshore and offshore records, we have built synthetic seismic sections from well‐constrained outcrop successions. Our results provide useful insights and warnings for the interpretation of offshore data, pointing out that MSC units having different age, nature and depositional settings, may show similar seismic facies and geometries. Conversely, the same deposit may result in different seismic facies, either with parallel and high‐amplitude reflections or even transparent or chaotic due to interference patterns of seismic reflections related to dominant frequency. It follows that a correct interpretation of the nature and age of deep‐seated Messinian deposits can only be obtained through the integration of seismic and core data, and considering the onshore record. The application of our approach to the Balearic Promontory results in an alternative interpretation with respect to previous models. We show that this offshore area has good analogues in the onshore of the Betic Cordillera and includes both shallow and intermediate depth sub‐basins that underwent a strong post‐Messinian subsidence.  相似文献   

The onset of the Messinian salinity crisis in the deep Eastern Mediterranean basin   总被引：1，自引：0，他引：1       下载免费PDF全文

Vinicio Manzi  Rocco Gennari  Stefano Lugli  Davide Persico  Matteo Reghizzi  Marco Roveri  B. Charlotte Schreiber  Ran Calvo  Ittai Gavrieli  Zohar Gvirtzman 《地学学报》2018,30(3):189-198

Astronomical tuning of the Messinian pre‐salt succession in the Levant Basin allows for the first time the reconstruction of a detailed chronology of the Messinian salinity crisis (MSC) events in deep setting and their correlation with marginal records that supports the CIESM ( 2008 ) 3‐stage model. Our main conclusions are (1) MSC events were synchronous across marginal and deep basins, (2) MSC onset in deep basins occurred at 5.97 Ma, (3) only foraminifera‐barren, evaporite‐free shales accumulated in deep settings between 5.97 and 5.60 Ma, (4) deep evaporites (anhydrite and halite) deposition started later, at 5.60 Ma and (5) new and published ⁸⁷Sr/⁸⁶Sr data indicate that during all stages, evaporites precipitated from the same water body in all the Mediterranean sub‐basins. The wide synchrony of events and ⁸⁷Sr/⁸⁶Sr homogeneity implies inter‐sub‐basin connection during the whole MSC and is not compatible with large sea‐level fall and desiccation of the Mediterranean.  相似文献   

Calcium Carbonate and Phosphate Reference Materials for Monitoring Bulk and Microanalytical Determination of Sr Isotopes          下载免费PDF全文

Michael Weber  Federico Lugli  Klaus Peter Jochum  Anna Cipriani  Denis Scholz 《Geostandards and Geoanalytical Research》2018,42(1):77-89

In situ laser ablation analyses rely on the microanalytical homogeneity of reference materials (RMs) and a similar matrix and mass fraction between unknown samples and RMs to obtain reliable results. Suitable carbonate and phosphate RMs for determination of Sr isotope ratios in such materials are limited. Thus, we determined ⁸⁷Sr/⁸⁶Sr ratios of several carbonate (JCt‐1, JCp‐1, MACS‐1, MACS‐3) and phosphate (MAPS‐4, MAPS‐5, NIST SRM 1400, NIST SRM 1486) international RMs using dissolved samples and two different multi‐collector inductively coupled plasma‐mass spectrometers (MC‐ICP‐MS). Our Sr isotope data are in agreement with published data and have an improved measurement precision for some RMs. For MACS‐1, we present the first ⁸⁷Sr/⁸⁶Sr value. We tested the suitability of these materials for microanalytical analyses by LA‐MC‐ICP‐MS, with two different laser ablation systems: a conventional nanosecond laser and a state‐of‐the‐art femtosecond laser. We investigated the RMs micro‐homogeneity and compared the data with our solution data. Both laser ablation systems yielded identical ⁸⁷Sr/⁸⁶Sr ratios within uncertainty to the solution data for RMs with low interferences of REEs. Therefore, these carbonate and phosphate RMs can be used to achieve accurate and precise results for in situ Sr isotope investigations by LA‐MC‐ICP‐MS of similar materials.  相似文献   

The Hf-INATOR: A free data reduction spreadsheet for Lu/Hf isotope analysis     

T. Giovanardi  F. Lugli 《Earth Science Informatics》2017,10(4):517-523

During the last decade, the in situ Lu-Hf isotope methodology has been widely used in Earth sciences and the number of laboratories performing Lu-Hf analysis has increased together with dedicated scientific software. However, free and user-friendly software for the Lu-Hf data reduction is currently missing. We present the ‘Hf-INATOR’, a new interactive Excel spreadsheet, simple to use and completely free (compatible with Libreoffice and Openoffice) that performs data reduction of the Lu-Hf analytical outputs and calculates the main parameters of the Lu-Hf systematic, such as the 2σ errors, the εHf₍₀₎, the εHf_(t), the T_DM, the T_DM ^C and the f_Lu/Hf.  相似文献