Assimilation of Crustal Material by Basaltic Magma: Strontium Isotopic and Trace Element Data from the Edgecumbe Volcanic Field, SE Alaska     

MYERS  JAMES D.; SINHA  A. KRISHNA; MARSH  BRUCE D. 《Journal of Petrology》1984,25(1):1-26

The Edgecumbe volcanics, which range from basalt through rhyodacite,have Sr contents between 125 and 370 p.p.m., Rb contents of1 to 70 p.p.m., Ba ranging from 50–550 p.p.m. and initial⁸⁷Sr/⁸⁶Sr ratios between 0.70291 and 0.70404. No simple correlationexists between these components and silica. The highest ⁸⁷Sr/⁸⁶Srvalues occur in a group of intermediate lavas (55–60 wt.per cent SiO₂) while the rhyodacites have initial ratios between0.7035 and 0.7038. With increasing silica, Sr increases to amaximum in the andesites and then steadily decreases; Ba andRb increase over the same compositional range. The highest ⁸⁷Sr/⁸⁶Srlavas have major and trace element concentrations which departfrom trends defined by most of the lavas. The variation in strontiumisotopic compositions suggests interaction between parentalbasaltic magma and crustal material. Attempts to model the assimilationprocess using fixed end-member assimilation and assimilation-fractionalcrystallization models have failed to produce the observed chemicaltrends. Because the parental basaltic liquid underwent littlefractionation, the variability in hybrid lavas is attributedto variation in contaminant composition. Initial melts werelow in CaO, A1₂O₃, MgO and Sr and enriched in SiO₂. K₂O, Na₂O,Rb and Ba. As melting progressed, melts became enriched in themore refractory components. Because hybrid strontium isotopiccomposition is a function of Sr concentration as well as isotopiccompositions, the Sr content of the assimilant strongly influencesresultant isotopic systematics. The development of the assimilantssuggests plagioclase was a residual phase during early melting.This model of crustal assimilation represents one end-memberin the spectrum of processes responsible for the generationof continental volcanic suites.  相似文献   

Coupling of deformation and reactions during mid-crustal shear zone development: an in situ frictional–viscous transition     

J. H. MARSH  S. E. JOHNSON  M. G. YATES  D. P. WEST JR 《Journal of Metamorphic Geology》2009,27(8):531-553

A well preserved strain and reaction gradient records the progressive transformation of a megacrystic Kfs+Cpx+Opx+Bt₁±Qtz syenitic pluton to a strongly sheared Kfs+Act+Bt₂+Ab+Qtz tectonite within the exhumed Norumbega Fault System, Maine, USA. Detailed microstructural analysis indicates that fracturing and localized fluid infiltration initiated the deconstruction of the existing K-feldspar and two-pyroxene load-bearing framework, and that feedback among metamorphic reactions, fabric development and enhanced permeability during progressive shearing led to the development of an interconnected, biotite- and actinolite-rich foliation. The activation of dislocation creep in biotite and quartz, and dissolution–precipitation creep in actinolite and feldspar, with increasing strain ultimately resulted in a transition from dominantly frictional to dominantly viscous deformation processes. Petrological data show that various scales of geochemical disequilibrium exist across the strain and reaction gradient, and that reaction progress was limited by slow chemical diffusion during the early stages of deformation. Petrological modelling results indicate that the existing plutonic assemblage was metastable at mid-crustal conditions, and that fluid infiltration and deformation allowed the product assemblage to advance towards chemical equilibration. Comparison of the observed microstructures and deformation mechanisms with experimental and numerical modelling results suggest that the development of an interconnected biotite-dominated fabric probably caused a major (up to three fold) reduction in bulk rock strength and localization of strain into the foliated margin.  相似文献   

Organic and inorganic matter in Louisiana coastal waters: Vermilion, Atchafalaya, Terrebonne, Barataria, and Mississippi regions     

Schaeffer BA  Conmy RN  Aukamp J  Craven G  Ferer EJ 《Marine pollution bulletin》2011,62(2):415-422

Chromophoric dissolved organic matter (CDOM) spectral absorption, dissolved organic carbon (DOC) concentration, and the particulate fraction of inorganic (PIM) and organic matter (POM) were measured in Louisiana coastal waters at Vermilion, Atchafalaya, Terrebonne, Barataria, and Mississippi River locations, in 2007-2008. The range of CDOM was 0.092 m⁻¹ at Barataria in June 2008 to 11.225 m⁻¹ at Mississippi in February 2008. An indicator of organic matter quality was predicted by the spectral slope of absorption coefficients from 350 to 412 nm which was between 0.0087 m⁻¹ at Mississippi in May 2008 and 0.0261 m⁻¹ at Barataria in June 2008. CDOM was the dominant component of light attenuation at Terrebonne and Barataria. Detritus and CDOM were the primary components of light attenuation at Vermilion, Atchafalaya, and Mississippi. DOC ranged between 65 and 1235 μM. PIM ranged between 1.1 and 426.3 mg L⁻¹ and POM was between 0.3 and 49.6 mg L⁻¹.  相似文献   

Archaeol as a methanogen biomarker in ombrotrophic bogs     

Richard D. Pancost  Erin L. McClymont  Elizabeth M. BinghamZoë Roberts  Dan J. CharmanEdward R.C. Hornibrook  Anthony BlundellFrank M. Chambers  Katie L.H. LimRichard P. Evershed 《Organic Geochemistry》2011,42(10):1279-1287

In order to develop new tools in the reconstruction of microbiological processes in ancient continental settings, we determined the concentration of archaeol and sn-2-hydroxyarchaeol in four Holocene ombrotrophic peatlands, spanning a range of European climate zones. Neither ether lipid was present in the aerobic acrotelm peat, consistent with an origin from anaerobic archaea, presumably methanogens. At the depth of the maximum seasonal water table, archaeol and sn-2-hydroxyarchaeol concentration markedly increased at all four sites, again consistent with an anaerobic source, but differed strongly among sites. The differences apparently reflect a combination of vegetation - ericaceous and graminoid plants as opposed to Sphagnum spp. and other mosses lacking root systems - and temperature influence on methanogenesis. In particular, low ether lipid concentrations in Finland probably reflect the lack of vascular vegetation possessing well-developed root systems, together with low mean annual temperature. Similarly low concentrations of archaeol and sn-2-hydroxyarchaeol in a German bog likely result from winter temperatures below 0 °C and a relatively shorter growing season. The occurrence of sn-2-hydroxyarchaeol is limited to a narrow and shallow depth range, indicating that it is poorly preserved, but archaeol persists throughout the cores. Decoupling the concentration of archaeol and the more labile sn-2-hydroxyarchaeol below ca. 50 cm suggests that the former records fossil biomass rather than living biomass. If so, then downcore variation in archaeol concentration likely reflects past changes in methane cycling, and archaeol, pending further developmental research, could serve as a new tool for reconstruction of past peatland biogeochemistry.  相似文献   

Pyrolysis GC-MS as a rapid screening tool for determination of peat-forming plant composition in cores from ombrotrophic peat     

Erin L. McClymont  Elizabeth M. BinghamChris J. Nott  Frank M. ChambersRichard D. Pancost  Richard P. Evershed 《Organic Geochemistry》2011,42(11):1420-1435

Peat cores provide decadal to centennial records of climatic and environmental change, including evidence for human/environment interaction. Existing palaeoenvironmental proxies (macrofossils, pollen, humification, testate amoebae, lipid composition) require multiple laboratory preparation steps and may be subject to differential preservation that can limit production of a continuous time series. The potential for pyrolysis gas-chromatography-mass-spectrometry (Py-GC-MS) to be applied to bulk peat samples is investigated here. The only preparatory step required was freeze drying. Analysis of a range of important peat-forming plants demonstrates that Sphagnum moss species are unique in containing the pyrolysis product of sphagnum acid, 4-isopropenylphenol. In contrast, non-Sphagnum species are rich in lignin pyrolysis products, which are absent from Sphagnum. The presence of these pyrolysis markers is reflected in bulk peat composition and tested here using archives from Bolton Fell Moss and Butterburn Flow (UK), Kontolanrahka (Finland) and Bissendorfer Moor (Germany). A ratio between 4-isopropenylphenol and two lignin pyrolysis products is proposed as a proxy for total Sphagnum input to peat archives and shows potential for use as a rapid screening tool for characterising bulk peat composition before more intensive analysis.  相似文献   

Mineralogy,microtexture, and composition of shock‐induced melt pockets in thi Los Angeles basaltic shergottite     

Erin L. WALTON  John G. SPRAY 《Meteoritics & planetary science》2003,38(12):1865-1875

Abstract— Analytical electron microscopy of shock features in the basaltic shergottite Los Angeles (stone 1) reveals: 1) shock recorded in the bulk sample; and 2) localized pressure and temperature excursions that have generated melt pockets up to 4 mm in diameter. Bulk shock effects include microfaulting (offsets 1–200 μm), mosaicism, deformed exsolution lamellae and planar fracturing in pyroxene, undulose extinction in whitlockite, mechanical twinning in titanomagnetite and ilmenite, and the transformation of plagioclase to maskelynite (≤4% remnant reduced birefringence). The pressure estimates for bulk shock are 35–40 GPa. Localized shock excursions have generated three types of discrete melt zones (0.07 times 1.3 mm to 3.0 times 3.5 mm apparent diameter) possessing glassy to microcrystalline groundmasses. These melt pockets are differentiated on the basis of size, clast volume, and degree of crystallization and vesiculation. Melt veins and melt dikelets emanate from the melt pockets up to 3 mm into the host rock but do not necessarily connect with other melt pockets. The melt pockets were generated by pressure‐temperature excursions of 60–80 GPa and 1600–2000°C, resulting in discrete melting of adjacent host rock minerals at grain boundary margins. Concentric zoning in the margins of clinopyroxenes coincides with a progressive reduction in birefringence as melt pockets are approached. This suggests that the shock excursions were focused as point sources in the wake of the shock front that induced bulk damage.  相似文献   

Estimated supply of RED credits 2011–2035     

Michael J. Coren  Erin Myers Madeira 《Climate Policy》2013,13(6):1272-1288

Previous attempts to estimate the supply of greenhouse gas emission reductions from reduced emissions from deforestation (RED) have generally failed to incorporate policy developments, country-specific abilities and political willingness to supply offsets for developed countries’ emissions. To address this, we estimate policy-appropriate projections of creditable emission reductions from RED. Two global forest carbon models are used to examine major assumptions affecting the generation of credits. The results show that the estimated feasible supply of RED credits is significantly below the biophysical mitigation potential from deforestation. A literature review identified an annual RED emission reduction potential between 1.6 and 4.3 Gt CO₂e. Feasible RED supply estimates applying the OSIRIS model were 1.74 Gt CO₂e annually between 2011 and 2020, with a cumulative supply of 17.4 Gt CO₂e under an ‘own-efforts’ scenario. Estimates from the Forest Carbon Index were very low at $5/t CO₂e with 8 million tonne CO₂e annually, rising to 1.8 Gt CO₂e at $20/t CO₂e. Cumulative abatement between 2011 and 2020 was 9 billion Gt CO₂e ($20/t CO₂e). These volumes were lower, sometimes dramatically, at prices of $5/t CO₂e suggesting a non-linear supply of credits in relation to price at a low payment level. For policy makers, the results suggest that inclusion of RED in a climate framework increases abatement potential, although significant constraints are imposed by political and technical issues.  相似文献   

Presence, infectivity, and stability of enteric viruses in seawater: relationship to marine water quality in the Florida Keys     

Wetz JJ  Lipp EK  Griffin DW  Lukasik J  Wait D  Sobsey MD  Scott TM  Rose JB 《Marine pollution bulletin》2004,48(7-8):698-704

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Evaluation of Vapor Intrusion Risk from Ethylene Dibromide Using the Vertical Screening Distance Approach     

Ravi V. Kolhatkar  Hong Luo  Erin C. Berns  Christopher Gaule  Joe Watterson 《Ground Water Monitoring & Remediation》2021,41(2):48-60

Vapor intrusion (VI) occurs when volatile contaminants in the subsurface migrate through the vadose zone into overlying buildings. The 2015 U.S. EPA petroleum VI guidance recommends that additional investigation of the VI risk from gasoline hydrocarbons at the underground storage tank (UST) sites is not necessary where the vertical distance between a building and a vapor source exceeds a recommended vertical screening distance. However, due to the lack of soil-gas data on the attenuation of ethylene dibromide (EDB), additional VI investigations to evaluate VI risk from EDB are recommended at UST sites with leaded gasoline releases containing EDB. We analyzed soil-gas and groundwater concentrations of EDB from eight petroleum UST sites using a new analytical method with soil-gas detection limit <0.16 μg/m³ EDB (VI screening level at the 10⁻⁶ risk level). The analysis included (1) assessing the frequency of EDB detections ≤0.16 μg/m³ at various vertical separation distances and (2) predicting vertical screening distances for EDB using the U.S. EPA PVIScreen model for different soil types in the vadose zone above dissolved-phase and LNAPL sources. Ranges of estimated aerobic biodegradation rate constants for EDB, air exchange rates for residential buildings, and source vapor concentrations for other constituents were combined with conservative estimates of EDB source concentrations as model inputs. Concentrations of EDB in soil-gas indicated that the U.S. EPA recommended vertical screening distances are protective of VI risk from EDB. Conversely, vertical screening distances predicted by modeling were >6 ft (1.8 m) for sites with sand and loam soil above dissolved phase sources and >15 ft (4.6 m) for sites with sand soil above LNAPL sources. This predicted dependence on the vapor source type and soil type in the vadose zone highlights the importance of soil characterization for VI screening at sites with EDB sources.  相似文献   

Family or Enterprise? What shapes the business structures of Australian farming?     

Sally Weller  Erin F. Smith  Bill Pritchard 《The Australian geographer》2013,44(2):129-142

Australian farmers navigate their contemporary circumstances through the use of different business and legal arrangements that are shaped by the commercial realities of farming and the aspirations of farm-owning households. In posing the question ‘Family or Enterprise?’, this paper examines the extent to which various household and farm business indicators are associated with different forms of farm ownership, namely sole proprietorships, partnerships, trusts and companies. Results from a postal survey of farm enterprises in Victoria, Australia suggest that both household and enterprise factors contribute to the business structure used, although the strongest determinants appear to be those factors that are less well understood in the rural geographical and sociological literature: household composition, farmer age and farm size. Greater scrutiny of the business instruments deployed by farmers to manage family and enterprise pressures should inform expectations of the fate of family farming in advanced financialised economies.  相似文献