The vibrational frequencies of forsterite Mg2SiO4: an all-electron ab initio study with the CRYSTAL code     

Y. Noel  M. Catti  Ph. D’Arco  R. Dovesi 《Physics and Chemistry of Minerals》2006,33(6):383-393

The vibrational spectrum of Mg₂SiO₄ olivine was calculated at the Γ point by using the periodic ab initio CRYSTAL program. An all electron localized Gaussian-type basis set and the B3LYP Hamiltonian were employed. The full set of frequencies (35 IR active, 36 Raman active, 10 “silent” modes) was computed and compared to experimental data from different sources (four for IR and four for Raman). A generally good agreement is observed with experiment (the mean absolute difference ranging from 7 to 10 cm⁻¹ for the various sets), when some of the experimental frequencies, whose attribution is uncertain or appears to be affected by large errors, are not taken into account. A small number of observed peaks are not consistent with calculated frequencies, and a few theoretical peaks do not correspond to measured values. The implications are discussed in detail. The full set of modes are characterized using different tools, namely isotopic substitution, direct inspection of the eigenvectors and graphical representation, so as to obtain a consistent mode assignment.  相似文献   

Evolution of stress fields in the Por’ya Guba dike field (Kandalaksha Gulf, White Sea)     

T. I. Vasil’eva  E. S. Przhiyalgovskii 《Geotectonics》2006,40(1):53-63

The tectonic evolution of the Por’ya Guba segment of the White Sea Rift System began in the late Paleoproterozoic, i.e., soon after completion of the Svecofennian collision. The fracture system that controlled localization of the lamproite dike complex was formed under conditions of horizontal compression combined with shear. Subsequently, this system predetermined the location of a rift-graben segment that formed as a result of simple shear. The reactivation of the rift system in the Middle Paleozoic proceeded in two stages. The first stage, when strike-slip movements along previously formed faults predominated, resulted in formation of quartz-carbonate veins bearing base-metal mineralization. The veins that filled the shear fractures opened owing to local reorientation of the stress field. The second stage fitted the transtension conditions, and the Late Devonian alkaline ultramafic dikes of this stage introded into the already existing fracture system, which was oriented at a roughly right angle to the predominant stress orientation.  相似文献   

A study of three massive star-forming regions in CS lines     

G. M. Larionov  I. Zinchenko  I. E. Val’tts 《Astronomy Reports》2006,50(2):107-115

We have mapped three star-forming regions (G265.14+1.45, G269.16?1.14, G291.27?0.71) in the CS(3–2) and C³⁴S(2–1) lines using the 15 m SEST telescope (Chile), and analyzed the relative positions of methanol and H₂O masers, IRAS sources, and emission maxima in the CS lines. In most cases, the maser positions are close to those of the IRAS sources. We compared the radial velocities of the maser sources and high-density CS cores, and estimated the CS column densities assuming LTE. The sizes, densities, and masses of the dense core are estimated; the masses obtained in the LTE approximation agree with the virial masses.  相似文献   

Mineralogy and PT formation conditions of lead-zinc ore at the Dzhimidon deposit, north Ossetia     

E. O. Groznova  M. G. Dobrovol’skaya  V. A. Kovalenker  K. V. Davydov  V. T. Bitarov  M. V. Razin 《Geology of Ore Deposits》2006,48(2):108-133

The mineralogy and PT formation conditions of the Dzhimidon Pb-Zn deposit in the Sadon ore district are considered. The deposit is localized in metamorphic rocks of the Buron Formation, which pertain to the pre-Jurassic basement (lower structural stage) and are cut through by Upper Paleozoic granitoids, and in the Lower Jurassic terrigenous sequence (upper structural stage). Orebodies as quartz-sulfide veins are mainly hosted in the metamorphic rocks. Galena, sphalerite, chalcopyrite, pyrite, pyrrhotite, and arsenopyrite are the most abundant sulfides, while quartz, carbonates, chlorite, sericite, and feldspar are gangue minerals. The bismuth mineralization identified at this deposit for the first time is represented by diverse phases of the Ag-Pb-Bi-S system. Five stages of the ore deposit formation are recognized: a premineral stage (quartz-feldspar), three ore-bearing stages (pyrite-arsenopyrite, pyrrhotite-chalcopyrite-sphalerite, and arsenopyrite-sphalerite-galena), and a postmineral stage (quartz-calcite); each stage comprises one or several mineral assemblages. The study of fluid inclusions in quartz, calcite, and sphalerite of the premineral, ore-forming, and postmineral stages has shown that the ore was deposited mainly from Na chloride solution with a salinity varying from >22 to <1.0 wt % NaCl equiv at a temperature from 460 to ～120°C and 430–290 bars pressure. The third stage was characterized by an abrupt increase in temperature and by the appearance of Mg(Fe,Ca) chloride solutions equally with Na chloride fluids, presumably owing to the emplacement of granite porphyry.  相似文献   

松溪县域城镇体系发展研究     

翁清光林皆敏  伍世代白晓 《福建地理》2006,21(2):20-22,27

城镇体系建设是当今加快城市化进程的重要组成部分。本文通过对松溪县域城镇现状的调查,从城镇体系的等级规模结构、空间布局结构、职能结构3个方面剖析其发展中存在的一些问题。从建设社会主义新农村、改善人居环境的角度出发,提出相应的发展思路和建议,为松溪县“十一五”期间制定城镇发展战略提供一定的参考。  相似文献   

Radio and optical spectra of objects from three complete samples of radio sources     

V. L. Afanas’ev  S. N. Dodonov  A. V. Moiseev  A. G. Gorshkov  V. K. Konnikova  M. G. Mingaliev 《Astronomy Reports》2006,50(4):255-272

We present classifications, optical identifications, and radio spectra for 19 radio sources from three complete samples, with declinations 4°–6° (B1950, S _{3.9 GHz} > 200 mJy), 10°–12°30′ (J2000, S _{4.85 GHz} > 200 mJy), and 74°–75° (J2000, S _{4.85 GHz} > 100 mJy). We also present corresponding information for the radio source J0527+0331. The right ascensions are 0–24^h and the Galactic latitudes |b| > 15° for all the samples. Our observations were obtained with the 6 m telescope from the Special Astrophysical Observatory in the range 4000–9000 Å or 4000–7500 Å and the RATAN-600 radio telescope at frequencies in the range 0.97–21.7 GHz. We obtained flux densities for the radio sources and optical spectra for their optical counterparts. Nine objects were classified as quasars with redshifts from z = 1.029 to 3.212; nine objects are emission-line galaxies with redshifts from 0.172 to 0.546, and one is a galaxy with burstlike star formation at z = 0.156, and one is a BL Lac object with z = 0.509. The spectra of five radio sources were decomposed into extended and compact components. The radio source J0527+0331, identified with a BL Lac object, displays significant variations of time scales from several days to several years. Data on flux variations are presented for 11 radio sources, as well as their spectra at several epochs.  相似文献   

New data on Upper Kimmeridgian-Tithonian biostratigraphy and ammonites of the eastern Crimea     

V. V. Arkad’ev  M. A. Rogov 《Stratigraphy and Geological Correlation》2006,14(2):185-199

Based on ammonites, Upper Kimmeridgian sediments are first established in the Crimean Mountains. The Kimmeridgian-Tithonian boundary recognizable in a continuous section is placed inside the Dvuyakomaya Formation of uniform largely clayey sediments. Assemblages of Kimmeridgian ammonites Lingulaticeras cf. procurvum (Ziegler), Pseudowaagenia gemmellariana Oloriz, Euvirgalithacoceras cf. tantalus (Herbich), Subplanites sp.) and Tithonian forms (?Lingulaticeras efimovi (Rogov), Phylloceras consaguineum Gemmellaro, Oloriziceras cf. schneidi Tavera, and Paraulacosphinctes cf. transitorius (Oppel) are described. A new biostratigraphic scheme proposed for the upper Tithonian-Berriasian of the Crimean Mountains includes the following new biostratigraphic units: the Euvirgalithacoceras cf. tantalus Beds of the upper Kimmeridgian, ?Lingulaticeras efimovi Beds of the lower Tithonian, and Oloriziceras cf. schneidi and Paraulacosphinctes cf. transitorius beds of the upper Tithonian. The middle Tithonian is proposed to consist of the fallauxi and semiforme (presumably) zones. The ammonities found determine the early Kimmeridgian-Berriasian age of the Dvuyakornaya Formation that is most likely in tectonic contact with the underlying Khutoran Formation.  相似文献   

Computer microtomography of zircon: A new approach to the selection of targets for U-Pb geochronologic studies     

Yu. V. Plotkina  E. B. Sal’nikova  A. B. Kotov  M. D. Tolkachev  M. R. Pavlov 《Petrology》2006,14(2):201-208

The paper reports results obtained by the complex studying of zircon crystals from rocks of various genesis. Zircon is one of the minerals most often used as geochronometers. It also provides genetic information on superimposed processes that is “recorded” in the external and internal morphology of its crystals. This mineral is thoroughly examined to select its unaltered crystals for U-Pb dating by the single-grain method. Zircon grains are selected with the use of optical and electron microscopy and cathodoluminescence. This publication presents the first results obtained by examining zircon by computer microtomography (μCT) and the results of the studying of the external and internal structure by conventional techniques ([optical microscopy and SEM (SE and CL)]. The paper demonstrates the advantages of the application of the μCT techniques to the selection of targets for U-Pb zircon dating: there is no need for the special preparation of the samples and no material is destructed. However, this technique may be not informative enough if the zircon contains inherited core whose density does not differ from the density of the surrounding mineral.  相似文献   

Hydrothermal sulfide deposits of the Lucky Strike vent field, Mid-Atlantic Ridge     

Yu. A. Bogdanov  A. Yu. Lein  A. M. Sagalevich  A. A. Ul’yanov  S. A. Dorofeev  N. V. Ul’yanova 《Geochemistry International》2006,44(4):403-418

Several hydrothermal sulfide structures were sampled using Mir manned submersibles in the relatively shallow Lucky Strike vent field, Mid-Atlantic Ridge; the bathymetric position of these structures varies by approximately 100 m. The investigation of the chemical and mineral compositions of hydrothermal ore occurrences led to the conclusion that the initial high-temperature ore-bearing solution ascending toward the surface became unstable and experienced phase separation beneath the ocean floor. The phase separation was responsible for the bathymetric control of hydrothermal ore formation in the ocean.  相似文献   

Early Proterozoic syn-and postcollision granites in the northern part of the Baikal fold area     

A. M. Larin  E. B. Sal’nikova  A. B. Kotov  L. B. Makar’ev  S. Z. Yakovleva  V. P. Kovach 《Stratigraphy and Geological Correlation》2006,14(5):463-474

Early Proterozoic granitoids are of a limited occurrence in the Baikal fold area being confined here exclusively to an arcuate belt delineating the outer contour of Baikalides, where rocks of the Early Precambrian basement are exposed. Geochronological and geochemical study of the Kevakta granite massif and Nichatka complex showed that their origin was related with different stages of geological evolution of the Baikal fold area that progressed in diverse geodynamic environments. The Nichatka complex of syncollision granites was emplaced 1908 ± 5 Ma ago, when the Aldan-Olekma microplate collided with the Nechera terrane. Granites of the Kevakta massif (1846 ± 8 Ma) belong to the South Siberian postcollision magmatic belt that developed since ～1.9 Ga during successive accretion of microplates, continental blocks and island arcs to the Siberian craton. In age and other characteristics, these granites sharply differ from granitoids of the Chuya complex they have been formerly attributed to. Accordingly, it is suggested to divide the former association of granitoids into the Chuya complex proper of diorite-granodiorite association ～2.02 Ga old (Neymark et al., 1998) with geochemical characteristics of island-arc granitoids and the Chuya-Kodar complex of postcollision S-type granitoids 1.85 Ga old. The Early Proterozoic evolution of the Baikal fold area and junction zone with Aldan shield lasted about 170 m.y. that is comparable with development periods of analogous structures in other regions of the world.  相似文献