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41.
Paolo Benettin Magali F. Nehemy Lucas A. Cernusak Ansgar Kahmen Jeffrey J. McDonnell 《水文研究》2021,35(3):e14073
Source water apportionment studies using the dual isotopes of oxygen and hydrogen have revolutionized our understanding of ecohydrology. But despite these developments—mostly over the past decade—many technical problems still exist in terms of linking xylem water to its soil water and groundwater sources. This is mainly due to sampling issues and possible fractionation of xylem water. Here we explore whether or not leaf water alone can be used to quantify the blend of rainfall event inputs from which the leaf water originates. Leaf water has historically been avoided in plant water uptake studies due to the extreme fractionation processes at the leaf surface. In our proof of concept work we embrace those processes and use the well-known Craig and Gordon model to map leaf water back to its individual precipitation event water sources. We also employ a Bayesian uncertainty estimation approach to quantify source apportionment uncertainties. We show this using a controlled, vegetated lysimeter experiment where we were able to use leaf water to correctly identify the mean seasonal rainfall that was taken up by the plant, with an uncertainty typically within ± 1‰ for δ18O. While not appropriate for all source water studies, this work shows that leaf water isotope composition may provide a new, relatively un-intrusive method for addressing questions about the plant water source. 相似文献
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Video-based hydrometry continues to develop for contactless discharge measurements, automated flood gauging stations and the use of crowd-sourced flood videos for discharge reconstruction. Irrespective of the velocimetry algorithm used (LSPIV, STIV, PTV…), orthorectification of the images is necessary beforehand, so that each pixel has the same known physical size. Most times, the orthorectification transformation is a plane-to-plane projection from the water surface to the camera sensor. Two approaches are typically used to compute the coefficients of this transformation: their calibration from ground reference points (GRPs) with known image and real-world coordinates (“implicit calibration”) or their calculation from the values of the intrinsic (focal length, sensor size) and extrinsic (position, angles) parameters of the camera (“explicit calibration”). In this paper, we develop a Bayesian method which makes it possible to combine the implicit and explicit approaches in a probabilistic framework. The Bayesian approach can be used from situations suitable for the implicit approach (plenty of GRPs) to situations propitious to the explicit approach (well-known camera parameters). The method is illustrated using synthetic views of a typical streamgauging scene with known true values of the parameters and GRP coordinates. We show that combining observational and prior information is generally beneficial to get precise estimates. Further tests carried out with a real scene of the Arc River at Randens, France, in flood conditions illustrate the impact of the number, uncertainty and spatial distribution of GRPs on the final uncertainty of flow velocity and discharge. 相似文献
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Measurement of 34S/32S Ratios of NBS 120c and BCR 32 Phosphorites Using Purge and Trap EA‐IRMS Technology 
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下载免费PDF全文 François Fourel François Martineau Magali Seris Christophe Lécuyer 《Geostandards and Geoanalytical Research》2015,39(1):47-53
Measurements of sulfur stable isotope ratios (34S/32S) have suffered from technical difficulties in analysing low‐S materials reducing their use despite their undeniable scientific interest. The measurement of 34S/32S ratios is a powerful tool for deciphering problems such as determining the sources of environmental pollutants, to detect adulteration, tracking the evolution of the redox state of the oceans and quantifying the role of the bacterial activity in sulfide minerals genesis. We have used a high‐precision method of sulfur isotope determination using a new type of elemental analyser based on ‘purge and trap’ technology. This new technique demonstrates the high quality of 34S/32S measurements for samples with S concentrations lower than 1% m/m. International calibrated references of diverse sulfur‐bearing materials were used to calibrate two low (< 1%) S‐bearing phosphorites used as compositional reference material for future use as isotopic references: BCR 32 and NBS 120c. δ34SCDT values of, respectively, 18.2‰ (1s = 0.3; n = 23) and 18.3‰ (1s = 0.4; n = 20) are proposed for these. Calibration of both phosphorites with international reference materials led to calculation of a mean standard error close to 0.4‰. The demonstration of a capability to reliably measure S isotope ratios in low‐S phosphate minerals or rocks opens up new fields of palaeoenvironmental reconstructions. 相似文献
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Florian Mermillod‐Blondin Jean‐Paul Gaudet Magali Grino Gaston Desrosiers Michel Creuz des Chtelliers 《水文研究》2003,17(4):779-794
The objective of this study was to measure the effects of invertebrates on the physical characteristics and microbial processes in hyporheic sediments. We investigated the impacts of an assemblage of three taxa (asellids, chironomid larvae, and tubificid worms) on sediment distribution, water fluxes, sediment organic carbon, biofilm (attached bacteria) characteristics, and O2, dissolved organic carbon NO3?, NO2?, and NH4+ concentrations in slow filtration sand–gravel columns. The results showed that invertebrates clearly modified the distribution of particles in the sediment column, probably because of the structures (tubes, macropores, and faecal pellets) produced by the three taxa in the sediment. Our assessment of water fluxes indicated that invertebrate activities led to an increase in the porosity of the sediment columns. In addition, aerobic (O2 consumption) and anaerobic (denitrification and fermentative decomposition of organic matter) microbial processes occurring in the sediment were stimulated in the presence of invertebrates. Finally, the present study demonstrates that invertebrates can act as ecosystem engineers in heterogeneous sediments that are under the influence of an advective flux of water. The solute residence time increased in columns containing the faunal assemblage. Micro‐organisms used more dissolved organic matter and nutrients in the presence of invertebrates because invertebrate activities increased the contact between the biofilm and water. We conclude that engineering by invertebrates in natural conditions modifies characteristics of the hyporheic zone and thereby enhances both the porosity of the sediment and the solute transport across the benthic interface. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
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We present a chronology of ice recession in the eastern Pyrenees based on in situ-produced 10Be data obtained from the Têt paleoglacier complex. The sampling strategy is based on the relative chronology provided by a detailed geomorphological map of glacial landforms. Results indicate that the last maximum ice advance occurred late (i.e., during Marine Isotope Stage 2) compared to the chronology currently established for the rest of the Pyrenees. Despite debatable evidence for a glacial readvance during the Oldest Dryas stade, ice-cap melt-out was rapid, residual cirque glaciers having disappeared by the Allerød interstade. This is consistent both with North Atlantic excursions established by the Greenland ice cores and paleoenvironmental data for the region. The rapid response of the east-Pyrenean ice cap to temperature variations is primarily linked to its small size compared to larger Pyrenean ice fields, to the dry Mediterranean climate, and to topography-related nonlinearities in which a small vertical rise in equilibrium line altitude generates a large change in ice mass. Possible sources of age uncertainty are discussed in the context of sampling design for single-nuclide (10Be) dating of landform sequences in formerly glaciated landscapes. 相似文献
46.
Glaciers erode bedrock but are also efficient conveyors of debris supplied during a cycle of glaciation by processes other than basal erosion. In this dual capacity as both an eroding and a transporting agent lies the ambiguity of ‘glacial erosion’ as a geomorphic process, with implications for methods of measuring the removal of rock mass by glaciers in the geological past, and for interpreting what exactly the consequences have been on topography and elevation change. A global review of ～400 Quaternary glacial denudation rates estimated from five different measurement techniques provides values ranging between 10?4 and 10 mm yr?1. We investigate the causes of such wide variability by examining the respective influences of environmental setting and methodological bias. A reference frame chosen for assessing these issues is the Massif du Carlit (Pyrenees, France), where a quantified mass balance of the well preserved glacial, periglacial and paraglacial deposits was made possible by detailed geomorphological mapping and terrestrial cosmogenic nuclide dating of extant erosional and depositional landform sequences. Resulting age brackets helped to define three main episodes of ice-cap growth and decline, each characterized by a volume of debris and a mappable source area. Erosion rates were expressed in two ways: (i) as spatially averaged denudation rates (D) during the successive stages of glacial advance to the line of maximum ice extent (MIE), post-MIE ice recession, and Lateglacial cirque readvance, respectively; and (ii) as cirque-wall recession rates (R) where moraine facies criteria indicated a supraglacial provenance of debris. Results indicate low erosion (D ≈ 0.05 mm yr?1) during the ice advance phase, probably because of thin or passive ice covering the low-gradient subglacial topography that occurs just above the late Pleistocene equilibrium line altitude (2.2–2.4 km). Erosion rates peaked (D ≈ 0.6 mm yr?1 and R ≈ 2.4–4.5 mm yr?1) during the main transition to ice-free conditions, when deglacial debuttressing promoted the rapid response of freshly exposed slope systems to new equilibrium conditions in the steep crest zone. Lateglacial D- and R-values declined to 0.2–0.3 mm yr?1, with indications of spatially variable R controlled by lithology. In this environment glaciers overall behaved more as conveyors of debris supplied by supraglacial rock exposures in the mountain crest zone than as powerful modifiers of subglacial topography. This explains the widespread preservation of deep, in situ preglacial weathering profiles on relict Cenozoic land surfaces in the deglacierized part of the Eastern Pyrenees. When plotted on the global data set analyzed and discussed in the review, the East Pyrenean erosion rates stand out as being amongst the lowest on record. 相似文献
47.
In Toulon Bay (France), very high phosphatase activities have been found in the zooplankton fraction>90 microm. This work was intended to specify their origin. For that purpose, larvae, juvenile and adult Crustacea (Copepods: Calanoids, Cyclopoids, Branchiopods: Cladocera, and Cirripeds) were isolated. Their activities were measured using paranitrophenyl phosphate dissolved in sea water in order to calculate Km (the enzyme half saturation concentration) and Vmax (the reaction rate when the enzyme is saturated with substrate). Vmax were referred to protein contents of the isolated organisms to calculate specific activities. For all zooplankton groups high and low affinity phosphatase activities were found. The low affinity enzyme was responsible for at least 70% of the total phosphatase activity. Its specific activity was higher for larvae than for copepodites and adults. In Cirriped nauplii this activity was particularly high with values which were several hundred times higher than that in other Crustacea. These enzymes had optimum pH close to 8.4, magnesium requirement and were competitively inhibited by orthophosphate. Experiments with intact and lysed Cirriped nauplii confirmed that living organisms had only a weak external activity and showed that most of the activity of these larvae was primarily intracellular. 相似文献
48.
Ammonia (NH3) is the major intermediate phase in the pathway of nitrogen (N) transfer from the fixed N phases (e.g., in crustal material) to free N2 (e.g., in natural gas reservoirs and volcanic gases). Yet the N isotopic behavior during these N-cycling processes remains poorly known. In an attempt to contribute to the understanding of N cycling using N isotopes, we carried out laboratory experiments to investigate the N isotopic effect associated with thermal decomposition of ammonia (2NH3 → N2 + 3H2). Pure NH3 (with initial δ15NNH3 of ∼ −2‰, relative to air standard) was sealed into quartz tubes and thermally decomposed at 600, 700 or 800 °C from 2 hours to 500 days. With the progress of the reaction, the δ15N of the remaining NH3 and the accumulated N2 increased from −2 to +35‰ and from −20 to −2‰, respectively. The differences of the N-isotope fractionations at the three temperatures are not significant. Modeling using the Rayleigh distillation model yielded similar kinetic N-isotope fractionation factors (αN2-NH3) of 0.983 ± 0.002 for 600, 700 and 800 °C. Applied to geological settings, this significant isotope discrimination (∼17‰) associated with partial decomposition of NH3/NH4+ from crustal sources (δ15Naverage ∼ +6.3‰) can produce mantle-like (i.e. ∼ −5‰) or even lower δ15N values of N2. This may explain the large variation of δ15N (−20 to +30‰) of N2 in natural gas reservoirs. It can also possibly explain the extreme 15N-depletion of N2 in some volcanic gases. This possibility has to be carefully considered when using N isotopes to trace geological N cycling across subduction zones by analysis of volcanic N2. 相似文献
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Vincent P. Milesi Didier Jzquel Mathieu Debure Pierre Cadeau Franois Guyot Grard Sarazin Francis Claret Emmanuelle Vennin Carine Chaduteau Aurlien Virgone Eric C. Gaucher Magali Ader 《Sedimentology》2019,66(3):983-1001
The volcanic crater lake of Dziani Dzaha in Mayotte is studied to constrain the geochemical settings and the diagenetic processes at the origin of Mg‐phyllosilicates associated with carbonate rocks. The Dziani Dzaha is characterized by intense primary productivity, volcanic gases bubbling in three locations and a volcanic catchment of phonolitic/alkaline composition. The lake water has an alkalinity of ca 0·2 mol l?1 and pH values of ca 9·3. Cores of the lake sediments reaching up to one metre in length were collected and studied by means of carbon–hydrogen–nitrogen elemental analyzer, X‐ray fluorescence spectrometry and X‐ray powder diffraction. In surface sediments, the content of total organic carbon reaches up to 20 weight %. The mineral content consists of aragonite and hydromagnesite with minor amounts of alkaline feldspar and clinopyroxene from the volcanic catchment. Below 30 cm depth, X‐ray diffraction analyses of the <2 μm clay fraction indicate the presence of a saponite‐like mineral, a Mg‐rich smectite. The saponite‐like mineral accumulates at depth to reach up to ca 30 weight %, concurrent with a decrease of the contents of hydromagnesite and organic matter. Thermodynamic considerations and mineral assemblages suggest that the evolution of the sediment composition resulted from early diagenetic reactions. The formation of the saponite‐like mineral instead of Al‐free Mg‐silicates resulted from high aluminum availability, which is favoured in restricted lacustrine environments hosted in alkaline volcanic terrains commonly emplaced during early stages of continental rifting. Supersaturation of the lake water relative to saponite is especially due to high pH values, themselves derived from high primary productivity. This suggests that a genetic link may exist between saponite and the development of organic‐rich carbonate rocks, which may be fuelled by the input of CO2‐rich volcanic gases. This provides novel insights into the composition and formation of saponite‐rich deposits under a specific geodynamic context such as the Cretaceous South Atlantic carbonate reservoirs. 相似文献