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31.
In order to determine the metal-bearing phases with special emphasis on Cu, a sequential extraction has been carried out on seven soil samples from a sulphide-bearing spodosol profile in Liikavaara Östra, close to the Aitik Copper Mine in northern Sweden. A reference spodosol profile with very low abundances of sulphides located far from anthropogenic emissions was also studied. Five fractions were selected for the extraction: (I) CH3COONa-extractable (exchangeable/adsorbed/carbonate); (II) Na4P2O7-extractable (labile organics); (III) 0.25 M NH2OH·HCl-extractable (amorphous Fe oxyhydroxides/Mn oxides); (IV) 1 M NH2OH·HCl-extractable (crystalline Fe oxides); and (V) KClO3/HCl-extractable (organics and sulphides). The distribution of trace elements (Co, Cr, Cu, Ni, Pb and Zn) in the profile in Liikavaara Östra is different from that in the reference profile. Possible explanations for these differences are (i) the presence of sulphides in the soil, (ii) atmospheric deposition of dust derived from mining activities at the Aitik Copper Mine, and (iii) mineralogical heterogeneities inherited from the deposition of the till. There is no straightforward correlation between the amount of the extracted phases and the metal extractability in the soils. This fact indicates that other factors are important for the retention of trace metals as well. The data presented in this study suggest that Co, Cr and Ni, to a fairly large extent, are associated with the organic matter in the B-horizon in both profiles, while in the C-horizon in Liikavaara Östra, sulphides are probably the more important carriers of these elements. For Co and Ni, Fe oxyhydroxides seem to be important. Most of the Cr occurred in the residual remaining after the leaching procedure. Copper and Zn seem to be associated with the organic matter to some extent in the B-horizon. The concentration of Cu in the C-horizon in Liikavaara Östra is high (2310 ppm), but only a very small fraction is likely to be hosted by sulphides. It is concluded that the major part of Cu in the C-horizon and a prominent fraction in the B-horizon in Liikavaara Östra are associated with some secondary phase that is extractable during extractions III and IV. Possible candidates for this phase are goethite and inclusions of native Cu in weathered biotite.  相似文献   
32.
A fundamental understanding of the factors influencing particle shape is of central importance for optimisation of the output quality from crushing plants for aggregate production. The literature reports that the wear on and setting of a cone crusher influence particle shape, The fact that wear on and the setting of a cone crusher influence particle shape is considered common knowledge and is also reported in the literature. To date, no mathematical model for predicting particle shape has been presented.  相似文献   
33.
In this article we solve the equations for a 2D model of compaction of sedimentary basins saturated with water by the finite-element method. This compaction model considers the rock described by the porosity as a function of effective stress, and both the anisotropic permeability and the anisotropic heat conductivity as functions of porosity. The water density is approximated linearly in the water pressure and temperature, and the water viscosity is a function of temperature. The main variables in the model are the water excess pressure and the temperature, and we account for an implicit solution scheme where we solve for both main variables simultaneously. The non-linearities in the model are either dealt with by the Newton method or by fixed-point iterations. We compare the coupled solution of temperature and pressure with the same decoupled equations. Then we study the contribution to the temperature by convection, the effect of the non-constant water density, and some anisotropic case examples.  相似文献   
34.
A new numerical model was developed to simulate regional sediment transport and shoreline response in the vicinity of tidal inlets based on the one-line theory combined with the reservoir analogy approach for volumetric evolution of inlet shoals. Sand bypassing onshore and sheltering effects on wave action from the inlet bar and shoals were taken into account. The model was applied to unique field data from the south coast of Long Island, United States, including inlet opening and closure. The simulation area extended from Montauk Point to Fire Island Inlet, including Shinnecock and Moriches Inlets. A 20-year long time series of hindcast wave data at three stations along the coast were used as input data to the model. The capacity of the inlet shoals and bars to store sand was estimated based on measured cross-sectional areas of the inlets as well as on comprehensive bathymetric surveys of the areas around the inlet. Several types of sediment sources and sinks were represented, including beach fills, groin systems, jetty blocking, inlet bypassing, and flood shoal and ebb shoal feeding. The model simulations were validated against annual net longshore transport rates reported in the literature, measured shorelines, and recorded sediment volumes in the flood and ebb shoal complexes. Overall, the model simulations were in good agreement with the measured data.  相似文献   
35.
The world is generally becoming less violent, but the debate on climate change raises the specter of a new source of instability and conflict. In this field, the policy debate is running well ahead of its academic foundation—and sometimes even contrary to the best evidence. Although comparative research on security implications of climate change is rapidly expanding, major gaps in knowledge still exist. Taken together, extant studies provide mostly inconclusive insights, with contradictory or weak demonstrated effects of climate variability and change on armed conflict. This article reviews the empirical literature on short-term climate/environmental change and intrastate conflict, with special attention to possible insecurity consequences of precipitation and temperature anomalies and weather-related natural disasters. Based on this assessment, it outlines priorities for future research in this area.  相似文献   
36.
The nature of the Lower Crustal Body (LCB) underneath the western part of the Vøring margin (NE Atlantic) is studied with three scenarios of its extension history: (a) The LCB is Caledonian crust. (b) Half the LCB is Caledonian crust and the other half is emplaced as magmatic underplating in Late Palaeocene. (c) The entire LCB is emplaced as magmatic underplating. The extension of the margin transect is obtained with a procedure that accounts for the extension and thinning of the sedimentary basins. This procedure has been extended to include magmatic underplating. The lithosphere is modelled with deposition of sediments and four rift phases since the Early Devonian until today. The forward modelling is mass conservative and the present‐day thicknesses of the formations, crust, LCB and magmatic underplate are reproduced. The state of the lithosphere and the sedimentary basins are shown and compared at the beginning and at the end of the rift phases. It is concluded that the scenario with the LCB as only underplating requires an unrealistic amount of extension. A scenario where underplating accounts for maximum half the LCB is more likely. Two different interpretations for the Moho underneath the Utgard High are tested: one with a shallow base‐crust and another with a deeper and flatter base‐crust. Tectonic modelling of the two versions favours the latter interpretation. The modelling shows that the Late Jurassic rift phase was much more prominent than the Late Cretaceous and Palaeocene rift phase for all cases of underplating. A strong Late Jurassic rift phase is consistent with the accumulation space needed for the thick Cretaceous formations. There are no observations of magmatism from the Late Jurassic, although this rift phase is stronger than the Cretaceous and Palaeocene rift phase.  相似文献   
37.
Quantitative rock physics analyses were used to determine the lithology and pore fluid of a reservoir in the Niger Delta. Inaccurate prediction of lithology and pore fluid results in the inaccurate determination of other petrophysical properties and parameters such as porosity, permeability, and net pay. This research is to predict lithology and pore fluid using rock physics analysis. However, reservoir zones were also predicted. Density, compressional wave velocity, and shear wave velocity logs were used as input to calculate elastic parameters such as velocity ratio, Poisson’s ratio, and bulk modulus. The calculated velocity ratio log was used to differentiate between sand and shale. Poisson’s ratio and velocity ratio using Goodway interpretation template were carried out and used to delineate pore fluid content, gas sand, oil sand, and sandstone formation from crossplot analysis.  相似文献   
38.
There is a broad correlation between the εNd values for rivers (including both the water and the particulate material it carries) and the age of the source terrain. This paper presents Nd isotope distribution data for soil, soil water, groundwater, and stream water samples gathered in a small catchment in northern Sweden. The results show that the release of Nd and Sm from boreal forests into streams and, eventually, into the oceans is more complicated than previously realized. The weathering of till causes changes in both the Nd isotopic composition and Sm/Nd ratios. Both the Sm/Nd ratio and εNd were higher in strongly weathered soils horizons than in less weathered till, since minerals with high Sm/Nd ratios were, on average, more resistant to weathering than those with low Sm/Nd ratios. In contrast to the situation for the main minerals and the major elements, the weathering of rare earth elements (REE) was not restricted to the E-horizon: the measured REE concentrations continued to increase with depth in the C-horizon. In addition, REE released by weathering in the upper parts of the soil profile were partly secondarily retained at deeper levels. Therefore, the dissolved Nd released by weathering in the upper soil horizons was trapped and did not enter the groundwater directly. Rather, the Nd in the groundwater largely originated from weathering within the groundwater zone. However, this was not the only source of Nd in the stream water. The Nd isotope composition and Sm/Nd ratio were determined by the mixing between of Nd and Sm in the groundwater and REE-carrying organic material washed out of the soil profile. The groundwater close to the stream reaches the upper soil horizons during high discharge events such as snowmelts, and organic matter carrying Nd and Sm is washed out of the soils and thus released into the stream. Therefore, the Nd exported from catchment is derived from both the weathering within the groundwater zone, and the organic matter washed out from the soil. If longer timescales with more advanced weathering stages in the groundwater zone are considered, it cannot be ruled out that there will be a shift towards more radiogenic values in the exported Nd. Recorded shifts in the Nd isotopic composition in the ocean may thus not only reflect changed source regions, but also the weathering history of the same source region.  相似文献   
39.
Abstract

Mercator depicted Croatia on several general maps. In accordance with the level of geographical knowledge, map scales and technical possibilities of the time, Mercator provided a relatively detailed depiction of basic geographical features on these maps. His interest in mapping Croatia was probably motivated by the fact that the Venetian Republic, the Habsburg Monarchy and the Ottoman Empire had fought over this area in the sixteenth century, contributing to the fragmentation of the medieval Croatian State, while at the same time facilitating economic, religious, linguistic, artistic and scientific communication between Central, South East and Mediterranean Europe. Mercator paid special attention to toponyms that enabled geographical objects to be identified and the decoding of cartographic contents. Research into Mercator’s maps has shown that geographical names, among other things, clearly indicate the sources of spatial data that he used. Additionally, geographical names on Mercator’s maps are significant indicators of the linguistic and cultural contacts that were particularly prominent in border areas, for example, along the eastern Adriatic coast, or the courses of the Danube, Sava and Drava.  相似文献   
40.
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