Modelling potential impacts of bottom trawl fisheries on soft sediment biogeochemistry in the North Sea†     

Daniel E Duplisea  Simon Jennings  Stephen J Malcolm  Ruth Parker  David B Sivyer 《Geochemical transactions》2001,2(1):1-6

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Feasibility of AFC models for the petrogenesis of calc-alkaline magma series     

Malcolm P. Roberts  John D. Clemens 《Contributions to Mineralogy and Petrology》1995,121(2):139-147

 One of the most popular petrogenetic concepts is that of simultaneous assimilation and fractional crystallisation (AFC). The equations governing these processes are well known and widely applied. The power and attraction of the model are that, with the minimum of constraints, petrogenetic schemes can be erected for essentially any group of rocks. These models are usually based on the observed variations in a small number of trace elements and/or isotopic systems. In this paper we have generated well-constrained AFC models for the Variscan, calc-alkaline Quérigut complex in the French Pyrénées. Our models are based on geological constraints on the identities of the parent magma and candidate assimilants, and the Sm-Nd and Rb-Sr isotope systematics of the rocks. The modelling is successful in mimicking the isotope array for the actual rocks. However, the results are massively inconsistent with those produced using the major- and trace-element concentrations. Our major conclusion is that AFC modelling should be undertaken only with robust initial constraints on the compositions of the parent magma and the proposed assimilant, with due respect for crystal-liquid partition coefficients, in so far as they are known. The results should then be accepted only if the isotope-based model parameters are consistent with those derived from major- and trace-element variations. Received: 19 August 1994/Accepted: 23 March 1995  相似文献   

Equilibrium coexistence of three amphiboles     

Peter Robinson  Howard W. Jaffe  Cornelis Klein Jr.  Malcolm Ross 《Contributions to Mineralogy and Petrology》1969,22(3):248-258

Electron probe and wet chemical analyses of amphibole pairs from the sillimanite zone of central Massachusetts and adjacent New Hampshire indicated that for a particular metamorphic grade there should be a restricted composition range in which three amphiboles can coexist stably. An unequivocal example of such an equilibrium three amphibole rock has been found in the sillimanite-orthoclase zone. It contains a colorless primitive clinoamphibole, space group P2₁/m, optically and chemically like cummingtonite with blue-green hornblende exsolution lamellae on (100) and (¯101) of the host; blue-green hornblende, space group C2/m, with primitive cummingtonite exsolution lamellae on (100) and (¯101) of the host; and pale pinkish tan anthophyllite, space group Pnma, that is free of visible exsolution lamellae but is a submicroscopic intergrowth of two orthorhombic amphiboles. Mutual contacts and coarse, oriented intergrowths of two and three host amphiboles indicate the three grew as an equilibrium assemblage prior to exsolution. Electron probe analyses at mutual three-amphibole contacts showed little variation in the composition of each amphibole. Analyses believed to represent most closely the primary amphibole compositions gave atomic proportions on the basis of 23 oxygens per formula unit as follows: for primitive cummingtonite (Na_0.02Ca_0.21 ^– Mn_0.06Fe²⁺ _2.28Mg_4.12Al_0.28) (Al_0.17Si_7.83), for hornblende (Na_0.35Ca_1.56Mn_0.02Fe_1.71Mg_2.85Al_0.92) (Al_1.37Si_6.63), and for anthophyllite (Na_0.10Ca_0.06Mn_0.06Fe_2.25Mg_4.11Al_0.47) (Al_0.47Si_7.53). The reflections violating C-symmetry, on X-ray single crystal photographs of the primitive cummingtonite, are weak and diffuse, and suggest a partial inversion from a C-centered to a primitive clinoamphibole. Single crystal photographs of the anthophyllite show split reflections indicating it is an intergrowth of about 80% anthophyllite and about 20% gedrite which differ in their b crystallographic dimensions. Split reflections are characteristic of all analyzed orthorhombic amphiboles so far examined from Massachusetts and New Hampshire except the most aluminous gedrites, and the relative intensity of the gedrite reflections is roughly proportional to the degree of Na and Al substitution. Thin sections of a few of these anthophyllite specimens show lamellae parallel to (010) that are just resolved with a high power objective.Publication approved by the Director, U.S. Geological Survey.  相似文献   

Stepwise mass extinctions: the case for the Late Cenomanian event     

Malcolm B. Hart  Paul N. Leary 《地学学报》1991,3(2):142-147

The various extinctions of marine taxa in the Late Cenomanian can be shown as conforming to the 'step-wise extinction' model. The order of such extinctions is, however, compatible with the presence of an expanded oxygen minimum zone in the world ocean. The occurrence of iridium anomalies at this level in the succession may, however, indicate a volcanogenic control on the global environment. Detailed time-analysis of the Late Cenomanian event has been used to produce a correlation of some key successions.  相似文献   

The dynamics of explosion and its use. Developments in civil engineering, 1, Josef Henrych (Ed.), Elsevier,Amsterdam (1979), 558 pp., U.S. $107.25, Dfl 220.00     

Malcolm Mellor 《Engineering Geology》1981,17(3):204-207

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A three-dimensional numerical model of particulate transport for coastal waters     

Malcolm L. Spaulding  Daniel Pavish 《Continental Shelf Research》1984,3(1):55-67

A Lagrangian marker particle in Eulerian finite difference cell solution to the three-dimensional incompressible mass transport equation was developed for predicting particulate transport in coastal and estuarine waters. Special features of the solution procedure include a finite difference grid network which translates horizontally and vertically with the mean particle motion and expands with the dispersive growth of the marker particle cloud. The cartesian vertical coordinate of the three-dimensional mass transport equation has been transformed, using instantaneous water column depth to allow adaptation to flow situations with a temporally and spatially varying bottom topography and free surface. Results from this model for turbulent diffusion and advection of a uniform plug flow of sediment in an unbounded uniform flow field with various sediment settling velocities were in excellent agreement with the corresponding analytic solutions. Using current information from a two-dimensional vertically averaged hydrodynamic's model, the model was utilized to predict the long term diffusion and advection of dilute neutrally and negatively buoyant suspended sediment clouds resulting from a hypothetical instantaneous release of dredge spoil waste at Brown's Ledge in Rhode Island Sound.  相似文献   

An Intercomparison of Large-Eddy Simulations of the Stable Boundary Layer   总被引：2，自引：27，他引：2  

Robert J. Beare  Malcolm K. Macvean  Albert A. M. Holtslag  Joan Cuxart  Igor Esau  Jean-Christophe Golaz  Maria A. Jimenez  Marat Khairoutdinov  Branko Kosovic  David Lewellen  Thomas S. Lund  Julie K. Lundquist  Anne Mccabe  Arnold F. Moene  Yign Noh  Siegfried Raasch  Peter Sullivan 《Boundary-Layer Meteorology》2006,118(2):247-272

Results are presented from the first intercomparison of large-eddy simulation (LES) models for the stable boundary layer (SBL), as part of the Global Energy and Water Cycle Experiment Atmospheric Boundary Layer Study initiative. A moderately stable case is used, based on Arctic observations. All models produce successful simulations, in as much as they generate resolved turbulence and reflect many of the results from local scaling theory and observations. Simulations performed at 1-m and 2-m resolution show only small changes in the mean profiles compared to coarser resolutions. Also, sensitivity to subgrid models for individual models highlights their importance in SBL simulation at moderate resolution (6.25 m). Stability functions are derived from the LES using typical mixing lengths used in numerical weather prediction (NWP) and climate models. The functions have smaller values than those used in NWP. There is also support for the use of K-profile similarity in parametrizations. Thus, the results provide improved understanding and motivate future developments of the parametrization of the SBL.  相似文献   

Trace Metal Solid State Speciation in Aerosols of the Northern Levantine Basin,East Mediterranean   总被引：3，自引：0，他引：3  

Mustafa Koçak  Nilgun Kubilay  Barak Herut  Malcolm Nimmo 《Journal of Atmospheric Chemistry》2007,56(3):239-257

An established three stage sequential leach scheme was applied to a series of selected high volume aerosol samples (n = 35) collected from the Turkish Eastern Mediterranean coastline (Erdemli). Samples were selected according to their air mass back trajectory history to reflect the contrasting mixtures of aerosol material present in the Eastern Mediterranean marine aerosol. Two populations were adopted, those samples which were classed as “anthropogenic” and those which were “Saharan” dominated aerosol populations. Applying the three stage leach it was possible to define the proportion for each of the considered metals (Al, Fe, Cu, Pb, Cd, Zn and Mn) present in the (a) “exchangeable” (b) “carbonate / oxide” and (c) “refractory” phases, representing novel solid state aerosol speciation data for this marine system. Clear trends were established, conforming with data from previous studies with mainly crustal derived metals (Al and Fe) being present in the refractory phases (Al > 88%; Fe > 84%) and those influenced by anthropogenic sources being dominating in the exchangeable phase, although for these metals the variability was comparatively high (12–64%; 19–85%; 40–100% for Zn, Pb and Cd, respectively). For the majority, greater exchangeable fractions were present the lower the crustal source contribution to the aerosol population, whereas the “refractory” fraction exhibited contrasting behaviour. This was illustrated by the novel application of the mixing diagram, presenting each of the three speciation stages against the corresponding percent anthropogenic contribution to each collected sample. Zn, Pb and Cd all illustrated progressive decrease in the percent exchangeable with increasing crustal contribution to the aerosol population. The percent exchangeable was discussed in terms of its use to represent the upper limit of the bioavailable fraction of metal associated with the aerosol, post deposition. The mixing diagram approach enabled the prediction of the residual fractions for Cd, Pb and Zn (41 ± 4%; 62 ± 4% and 82 ± 5%, respectively,) in Saharan end-member material.  相似文献   

Blast vibration analysis     

Malcolm Mellor 《Engineering Geology》1981,17(4):285-286

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A Model of Conductive Heat Flow in Forest Edges and Fragmented Landscapes     

Jay R. Malcolm 《Climatic change》1998,39(2-3):487-502

Although the creation of edges during forest fragmentation can have important abiotic and biotic impacts, especially under conditions of future climate change, mechanistic models of edge effects have not been forthcoming. A simple numerical model of two-dimensional heat flow is developed and applied to a vertical forest/clearcut edge profile and to simulated fragmented landscapes. Height-specific thermal diffusivity and conductivity in the forest were assumed to vary in proportion to foliage densities measured in the central Amazon. In the edge profile, the clearcut that abutted the edge served as a heat source and its temperature was maintained at a constant value higher than in the initially cooler forest. In the fragmented landscapes, simulated treefall gaps were heat sources whose temperature varied with sun movements during the day. Gap frequency was varied so as to approximate the gap coverage observed in selectively logged forests. In one set of simulations, temperature in the openings was systematically varied; in another, thermal diffusivity of the forest was varied. Along the edge profile, high temperatures in the clearcut were rapidly transmitted into the upper canopy due to additive edge effects. Temperatures in the forest understory were also very sensitive to clearcut temperatures due to relatively sparse understory foliage. An overall increase in forest diffusivity led to markedly higher temperatures close to the edge and a more even temperature distribution among height strata. In fragmented landscapes, total gap coverage and additivity from neighboring gaps strongly influenced forest temperatures. At low conductivities, heat flowed only into the forest close to the gaps and hence forest temperature increased almost linearly with gap area. However, at high conductivities, heat flowed far into the forest and forest temperature varied as a function of gap density in the surrounding neighborhood. Because of these additive effects, slight increases in total gap area led to disproportionate changes in the thermal profile of the landscape. These results have important implications for the conservation of forest ecosystems.  相似文献