全文获取类型
收费全文 | 478篇 |
免费 | 13篇 |
国内免费 | 2篇 |
专业分类
测绘学 | 10篇 |
大气科学 | 58篇 |
地球物理 | 74篇 |
地质学 | 164篇 |
海洋学 | 47篇 |
天文学 | 105篇 |
综合类 | 2篇 |
自然地理 | 33篇 |
出版年
2024年 | 2篇 |
2022年 | 3篇 |
2019年 | 5篇 |
2018年 | 7篇 |
2017年 | 11篇 |
2016年 | 10篇 |
2015年 | 15篇 |
2014年 | 10篇 |
2013年 | 19篇 |
2012年 | 13篇 |
2011年 | 9篇 |
2010年 | 15篇 |
2009年 | 20篇 |
2008年 | 24篇 |
2007年 | 23篇 |
2006年 | 19篇 |
2005年 | 15篇 |
2004年 | 31篇 |
2003年 | 10篇 |
2002年 | 13篇 |
2001年 | 12篇 |
2000年 | 15篇 |
1999年 | 6篇 |
1998年 | 5篇 |
1997年 | 10篇 |
1996年 | 5篇 |
1995年 | 9篇 |
1994年 | 8篇 |
1993年 | 7篇 |
1992年 | 5篇 |
1991年 | 6篇 |
1990年 | 5篇 |
1989年 | 11篇 |
1988年 | 10篇 |
1987年 | 11篇 |
1986年 | 10篇 |
1985年 | 12篇 |
1984年 | 8篇 |
1983年 | 8篇 |
1982年 | 11篇 |
1981年 | 8篇 |
1980年 | 4篇 |
1977年 | 3篇 |
1976年 | 5篇 |
1975年 | 11篇 |
1972年 | 2篇 |
1971年 | 2篇 |
1956年 | 2篇 |
1955年 | 2篇 |
1935年 | 1篇 |
排序方式: 共有493条查询结果,搜索用时 875 毫秒
91.
Taro Takahashi Stewart C. Sutherland Rik Wanninkhof Colm Sweeney Richard A. Feely David W. Chipman Burke Hales Gernot Friederich Francisco Chavez Christopher Sabine Andrew Watson Dorothee C.E. Bakker Ute Schuster Nicolas Metzl Hisayuki Yoshikawa-Inoue Masao Ishii Takashi Midorikawa Yukihiro Nojiri Arne Krtzinger Tobias Steinhoff Mario Hoppema Jon Olafsson Thorarinn S. Arnarson Bronte Tilbrook Truls Johannessen Are Olsen Richard Bellerby C.S. Wong Bruno Delille N.R. Bates Hein J.W. de Baar 《Deep Sea Research Part I: Oceanographic Research Papers》2009,56(11):2075-2076
92.
93.
Mark A. Sephton Gordon D. Love Colin E. Snape Jonathan S. Watson 《Planetary and Space Science》2005,53(12):1280-1286
The carbonaceous chondrite meteorites are fragments of asteroids that have remained relatively unprocessed since the formation of the Solar System 4.56 billion years ago. The major organic component in these meteorites is a macromolecular phase that is resistant to solvent extraction. The information contained within macromolecular material can be accessed by degradative techniques such as pyrolysis. Hydropyrolysis refers to pyrolysis assisted by high hydrogen gas pressures and a dispersed sulphided molybdenum catalyst. Hydropyrolysis of the Murchison macromolecular material successfully releases much greater quantities of hydrocarbons than traditional pyrolysis techniques (twofold greater than hydrous pyrolysis) including significant amounts of high molecular weight polyaromatic hydrocarbons (PAH) such as phenanthrene, carbazole, fluoranthene, pyrene, chrysene, perylene, benzoperylene and coronene units with varying degrees of alkylation. When hydropyrolysis products are collected using a silica trap immersed in liquid nitrogen, the technique enables the solubilisation and retention of compounds with a wide range of volatilities (i.e. benzene to coronene). This report describes the hydropyrolysis method and the information it can provide about meteorite macromolecular material constitution. 相似文献
94.
Boundary integral equations for traction boundary-value problems of two-dimensional elastostatics are derived by the indirect boundary element method. Quadratic variation functions for the representation of geometry, fictitious forces and displacements over each boundary element are described. A system of equations approximating to the boundary integral equations is obtained by a Galerkin formulation in which the integral equation is written at Gauss integration points of elements. The method of computation of the Cauchy principal value is described. Examples of application to the analysis of stress and displacement around underground excavations demonstrate the accuracy and efficiency of the formulation. 相似文献
95.
Chemical concentration gradients in the interstitial waters of shallow (0–10 cm), reducing sediments are reported for four stations in the Tamar Estuary over a two-year period. The products of organic matter breakdown, sedimentary redox changes and diagenetic reactions have been determined and a multicomponent analytical approach has enabled the interactions of complementary processes to be examined. While many components show spatial and seasonal patterns related to the supply of organic matter and salinity associated sulphate distribution, the effects of temperature, sediment disturbance and river flow are also apparent.Sediment stored prior to the separation of interstitial water showed significant changes in chemical composition compared to samples processed within 24 h of collection. 相似文献
96.
97.
We have investigated the kinetics of Fe(III) complexation by several organic ligands including fulvic acid, citrate and ethylenediaminetetraacetic acid (EDTA). Particular attention was given to examination of the effect of competitive divalent cations (Me: Ca2+ and Mg2+) at concentrations typical of seawater on the complexation rate. All experiments were conducted in 0.5 M NaCl solution buffered with 2 mM bicarbonate at pH 8.0 in the absence and presence of Me (25 μM-250 mM). The rate constants of complex formation determined by using the competitive ligand (5-sulfosalicylic acid) method combined with visible spectrophotometry ranged from 3.3 × 104 to 3.2 × 106 M−1 s−1. The mechanism of complexation was then examined based on a kinetic model. When EDTA was used as a ligand, Me at concentrations comparable to the ligand markedly retarded the rate of iron complex formation due to the predominance of an adjunctive pathway (where iron-ligand complex is formed via direct association of iron to Me-ligand complex). In contrast, the competing effect of Me on iron complexation by citrate and fulvic acid was observed only when the Me concentration was in excess of the ligand by more than a factor of 10-1000. The kinetic model suggests that iron complexation by fulvic acid occurs predominantly via a disjunctive pathway (where iron complexation by ligand occurs after dissociation of Me from Me-ligand complex) at concentrations of divalent cations and natural organic matter typical of natural waters including seawater and freshwater. 相似文献
98.
Two types of laboratory experiments were used to quantify magnesium isotopic fractionations associated with chemical and thermal (Soret) diffusion in silicate liquids. Chemical diffusion couples juxtaposing a molten natural basalt (SUNY MORB) and a molten natural rhyolite (Lake County Obsidian) were run in a piston cylinder apparatus and used to determine the isotopic fractionation of magnesium as it diffused from molten basalt to molten rhyolite. The thermal diffusion experiments were also run in a piston cylinder apparatus but with a sample made entirely of molten SUNY MORB displaced from the hotspot of the assembly furnace so that the sample would have a temperature difference of about 100-200 °C from one end to the other. The chemical diffusion experiments showed fractionations of 26Mg/24Mg by as much as 7‰, which resulted in an estimate for the mass dependence of the self-diffusion coefficients of the magnesium isotopes corresponding to D26Mg/D24Mg=(24/26)β with β = 0.05. The thermal diffusion experiments showed that a temperature difference of about 100 °C resulted in the MgO, CaO, and FeO components of the basalt becoming slightly enriched by about 1 wt% in the colder end while SiO2 was enriched by several wt% in the hotter end. The temperature gradient also fractionated the magnesium isotopes. A temperature difference of about 150 °C produced an 8‰ enrichment of 26Mg/24Mg at the colder end relative to the hotter end. The magnesium isotopic fractionation as a function of temperature in molten basalt corresponds to 3.6 × 10−2‰/°C/amu. 相似文献
99.
Remote leveling of tide gauges using GNSS reflectometry: case study at Spring Bay,Australia 总被引:1,自引:1,他引:0
We further developed a new approach using GNSS reflectometry to determine the leveling connection between a tide gauge and a GNSS antenna. This approach includes the optimization of the unknown receiver bandwidth and the estimation of frequency changes in the signal-to-noise ratio (SNR) oscillation through an extended Kalman filter/smoother algorithm. We also corrected the geometric bending of the GNSS signals due to tropospheric refraction using local meteorological observations. Using 3 weeks of SNR data in Spring Bay, Australia, from a GNSS antenna placed sideways (i.e., ground plane orientated vertically and directed in azimuth toward the sea surface) to improve the SNR interference near the horizon, we obtained mean leveling differences of approximately 5 mm, with an RMS of approximately 3 cm level with respect to the nominal leveling from classical surveying techniques. SNR data from three different receiver manufacturers, coupled to the same antenna, provided similar leveling results. With a second antenna in the usual upright configuration, we obtained mean leveling differences of 1–2 cm and a RMS of about 10 cm. In the upright configuration, the leveling differences may include errors in the GNSS antenna phase center calibration, which are avoided in our technique but not in the classical surveying techniques. These results demonstrate the usefulness of the reflectometry technique to obtain precisely and remotely the leveling between a GNSS antenna and a tide gauge. In addition, this technique can be applied continuously, providing an independent and economical means to monitor the stability of the tide gauge zero. 相似文献
100.
`Kanpachi Street Cloud (KSC)' is an unusual small-scalecumulus cloud line visible during calm summer conditions over a major street in the Tokyo metropolitanarea. In order to understand the mechanism leading to the formation of this cloud line,numerical simulations have been performed using the Regional Atmospheric Modelling System.The general characteristics of the simulated KSC agree well with observations. On alarge-scale view, the KSC can be characterized as a cumulus cloud line generated at the convergenceline of two sea breezes on the western side of Tokyo Bay, while on the microscale view, it resemblesBenard-type thermal convection modified longitudinally by wind shear.The location of the convergence line leading to the KSCformation coincides withthe Kanpachi street location, although the street itself does notmake any direct effect on the KSC formation. Additional numerical experiments were performed toidentify causes of the KSC formation in accordance with urbanization, by changing anthropogenicheat impact, land-cover and grid resolution.They confirmed that the formation of the KSC requirestwo meteorological processes at the same time:(1) the convergence of two sea breezes – the localsouth-eastern sea breeze from Tokyo Bay andan extended southern sea breeze from thePacific Ocean, respectively; (2) Forcing due to an urban heat island. It is shown that urbanization couldchange the intensity and position of the KSC through enhancement of local upward motions and changesin the near-surface horizontal pressure gradient between urban and sub-urban areas. Further,fine horizontal grid resolution is needed to be able to resolve these local thermal convection issues. 相似文献