Some results obtained on the study of the chemical composition of Eurasian oils depending on the depth and age of the reservoir rock     

Vilori V Ahn  Yuri M Polichtchouk  Irina G Yashchenko 《Organic Geochemistry》2002,33(12)

The sulfur, paraffin, resin and asphaltene contents of some 6570 Cenozoic, Mesozoic and Paleozoic Eurasian oils were analysed statistically in terms of reservoir age and depth. The database includes all principal oil-bearing basins from 60 Eurasian countries. The results of the studies of the relationships between the distribution of oils with different sulfur, paraffin, resin and asphaltene contents and the reservoir age and depth are presented. Predictive trends are established allowing polynomial predictions of average properties.  相似文献   

Geochronological constraints on the evolution of the Embu Complex, São Paulo, Brazil     

U. G. Cordani  J. M. V. Coutinho  A. P. Nutman   《Journal of South American Earth Sciences》2002,14(8)

Petrologic and geochronological work was carried out on a roadside outcrop of amphibolite facies orthogneisses near São Lourenço da Serra, about 50 km southwest of São Paulo City. These orthogneisses belong to the Embu Complex, within the Neoproterozoic Brasiliano Orogenic Cycle mobile belts of SE Brazil. The outcrop consists of predominantly foliated biotite tonalites and granodiorites, which were cut by granitic veins and pegmatites prior to final deformation. SHRIMP U/Pb measurements on zircons from one granodioritic–tonalitic gneiss indicate magmatic crystallization of the protolith at 811±13 Ma (MSWD=1.0). Zircons with dates of ca. 2000 and ca. 1000 Ma in this rock are interpreted as inherited from older crust. One zircon analyzed from the gneiss and three zircons from a discordant pegmatitic vein indicate an event at 650–700 Ma, perhaps related to the intrusion of the pegmatites. A regression of Rb–Sr whole rock data for four biotite gneisses yielded an imperfect isochron, giving an apparent age of 821±68 Ma and an elevated initial ⁸⁷Sr/⁸⁶Sr ratio of 0.719±0.005. The elevated initial ⁸⁷Sr/⁸⁶Sr ratio and the inherited zircons indicate involvement of older crust in the genesis of the gneisses. Rb–Sr feldspar and whole rock pairs yield ca. 560 Ma tielines, giving the time of final cooling below 300–350 °C, and the cessation of medium-grade metamorphism and ductile deformation. These results document a series of tectono-thermal events spanning 250 million years during the Brasiliano Orogenic Cycle. They relate to ca. 800 Ma magmatic arc activity and later allochthonous terrane assembly during closure of the Adamastor Ocean, resulting in the accretion of Western Gondwana.  相似文献   

Geochemistry of Coexisting Biotite and Muscovite of Portuguese Peraluminous Granitic Differentiation Series     

A.M.R. Neiva  M.M.V.G. Silva  M.E.P. Gomes  T.F.C. Campos 《Chemie der Erde / Geochemistry》2002,62(3):197-215

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Cation distribution in amphiboles synthesized along the Ga analogue of the tremolite–aluminotschermakite join     

D. M. Jenkins  K. Ishida  V. Liogys  D. Ghosh 《Physics and Chemistry of Minerals》2002,29(2):87-97

 Amphiboles were synthesized from bulk compositions prepared along the join Ca_1.8Mg_5.2Si₈O₂₂(OH)₂–Ca_1.8Mg₃Ga₄Si₆O₂₂(OH)₂ hydrothermally at 750–850 °C and 1.0–1.8 GPa, and along the join Ca₂Mg₅Si₈O₂₂F₂–Ca₂Mg₃Ga₄Si₆O₂₂F₂, anhydrously at 1000 °C and 0.7 GPa to document how closely the tschermak-type substitution is obeyed in these analogues of aluminous amphiboles. Electron-microprobe analyses and Rietveld X-ray diffraction structure refinements were performed to determine cation site occupancies. The extent of Ga substitution was found to be limited in both joins, but with the fluorine series having about twice the Ga content (0.6 atoms per formula unit, apfu) of the hydroxyl-series amphiboles (0.3 apfu). The tschermak-type substitution was followed very closely in the hydroxyl series with essentially equal partitioning of Ga between tetrahedral and octahedral sites. The fluorine-series amphiboles deviated significantly from the tschermak-type substitution and, instead, appeared to follow a substitution that is close to a Ca-pargasite substitution of the type: ^[6]Ga³⁺+2^[4]Ga³⁺+1/2^[A] Ca²⁺ = ^[6]Mg²⁺+2^[4]Si⁴⁺+1/2^[A]□. Infrared spectroscopy revealed an inverse correlation between the intensity of the OH-stretching bands and the Ga content for the hydroxyl- and fluorine-series amphiboles. The direct correlation between the Ga and F content and inverse relationship between the Ga and OH content may be a general phenomenon present in other minerals and suggests, for example, that high F contents in titanite are controlled by the Al content of the host rock and that there may be similar direct Al–F correlations in tschermakitic amphiboles. Evidence for the possibility that Al (Ga) might substitute onto only a subset of the tetrahedral sites in tschermakitic amphiboles was sought but not observed in this study. Received: 5 March 2001 / Accepted: 31 July 2001  相似文献   

Al hematites prepared by homogeneous precipitation of oxinates: material characterization and determination of the Morin transition     

G. M. da Costa  E. Van San  E. De Grave  R. E. Vandenberghe  V. Barrón  L. Datas 《Physics and Chemistry of Minerals》2002,29(2):122-131

A novel method for synthesis of aluminium hematites, based upon the homogeneous precipitation of Fe and Al oxinates in various proportions, is presented. The precursor precipitates are heated in air at 700?°C. X-ray diffraction, thermal analyses, BET, FTIR, optical reflection analysis, TEM and Mössbauer spectroscopy at room temperature and 80?K of the resulting products indicate that single-phase hematites are formed with structural Al substitution of up to 10 at%. Interestingly, the particle size (>100?nm) is not substantially reduced by the Al content. Although it remains difficult to obtain a homogeneously distributed Al substitution in the final hematite, this processing line offers a unique opportunity to separate the effects of grain size and Al substitution on the Morin transition temperature (T _M) of Al hematite. From the comparison between the present hematites and a series of Al-substituted hematites with lepidocrocite as precursor, it could be shown that the effect on T _M, associated with a change of a factor 10 in grain size, is about 1/3 of the effect caused by a change of 10 in the degree of substitution. Finally, it is suggested that proper thermal treatments under different conditions of the same precursors are likely to produce spinel phases.  相似文献   

Milan: The city of constant renewal     

Anna Trono  Maria Chiara Zerbi 《GeoJournal》2002,58(1):65-72

Traditional models of urban development are no longer adequate to describe current metropolitan transformations. These are now at the centre of a debate concerning management and administration. In Italy, delays in resolving problems of urban and metropolitan government, despite the legal framework provided by Law 142/90, have weighed heavily on the larger urban areas of the country: Rome, Naples, Milan, which have not been able to tackle the issue of metropolitan government. Recent legislation, while not providing a pre-defined institutional solution, allows separate administrative districts to collectively establish metropolitan institutions of `variable geometry'. The Milan urban area is not one city, but a system of mutually-dependent cities, linked to each other and the rest of the world by a transport network still requiring much investment. The vitality of its economic structure (especially its small firms) is held back by seriously inadequate infrastructure and low external economic efficiency. The provincial capital may boast `historic centrality' but the most interesting potential for development is to be found on the periphery and in the administrative districts immediately surrounding it, in the recovery of derelict industrial areas and dormitory towns established in the 1950s and 1960s, especially to the north. Recovery of derelict areas, green areas, and better transport links within the urban area and with the outside world are the key elements in the reorganization of `Greater Milan'. In this situation of rapid transformation the most appropriate political strategies involve negotiated planning. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   

Crack damage stress as a composite function of porosity and elastic matrix stiffness in dolomites and limestones   总被引：4，自引：0，他引：4  

V. Palchik  Y. H. Hatzor 《Engineering Geology》2002,63(3-4):233-245

Twenty-five uniaxial compression tests were performed to determine stress at onset of dilation, referred to herein as “the crack damage stress,” in heterogeneous dolomites and limestones. A simplified model for crack damage stress (σ_cd) is developed here using porosity, elastic modulus, Poisson's ratio and three empirical coefficients. The model shows that when porosity decreases and elastic modulus increases, σ_cd rapidly increases and approaches its maximum value. On the other hand, when porosity increases and elastic modulus decreases, σ_cd rapidly decreases and approaches its minimum value. The proposed model is validated for six heterogeneous limestone and dolomite formations which are widely distributed in Israel.  相似文献   

The Port Mouton Shear Zone: intersection of a regional fault with a crystallizing granitoid pluton   总被引：2，自引：0，他引：2  

D. Barrie Clarke  Krista L. McCuish  Ron H. Vernon  Victor Maksaev  Brent V. Miller   《Lithos》2002,61(3-4):141-159

The peraluminous tonalite–monzogranite Port Mouton Pluton is a petrological, geochemical, structural, and geochronological anomaly among the many Late Devonian granitoid intrusions of the Meguma Lithotectonic Zone of southern Nova Scotia. The most remarkable structural feature of this pluton is a 4-km-wide zone of strongly foliated (040/subvertical) monzogranites culminating in a narrow (10–30 m), straight, zone of compositionally banded rocks that extends for at least 3 km along strike. The banded monzogranites consist of alternating melanocratic and leucocratic compositions that are complementary to the overall composition of that part of the pluton, suggesting an origin by mineral–melt and mineral–mineral sorting. Biotite and feldspar are strongly foliated in the plane of the compositional bands. These compositional variations and foliations originated by a process of segregation flow during shearing of the main magma with a crystallinity of 55–75%. Subsequent minor brittle fracturing of feldspars, twinning of microcline, development of blocky sub-grains in quartz, and kinking of micas demonstrate overprinting by a high-temperature deformation straddling the monzogranite solidus. Small folds and late sigmoidal dykes indicate dextral movement on the shear zone. This Port Mouton Shear Zone (PMSZ) is approximately co-linear with the only outcrops of Late Devonian mafic intrusions in the area, two of which are syn-plutonic with well-developed mingling textures in the marginal tonalite of the Port Mouton Pluton. Also closely co-linear with the mafic intrusions are a granitoid dyke that extends well beyond the outer contact of the Port Mouton Pluton, a swarm of large aligned angular xenolithic slabs, a zone of thin wispy schlieren banding, a large Be-bearing pegmatite, and a breccia pipe with abundant garnetiferous metapelitic xenoliths. In various ways, the shear zone may control all of these features. The Port Mouton Shear Zone is parallel to many other NE-trending faults and shear zones in the northern Appalachians, probably related to the docking of the Meguma Zone along the Cobequid–Chedabucto Fault system.  相似文献   

Environmental response to a large, explosive rhyolite eruption: sedimentology of post-1.8 ka pumice-rich Taupo volcaniclastics in the Hawke''s Bay region, New Zealand     

B. Segschneider  C. A. Landis  V. Manville  J. D. L. White  C. J. N. Wilson 《Sedimentary Geology》2002,150(3-4):275-299

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Confinement Effects and Energy Balance Analyses for Buckling Failure Under Eccentric Loading Conditions     

V. N. Kazakidis 《Rock Mechanics and Rock Engineering》2002,35(2):115-126

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