Combined Sr,Nd, Pb and Li isotope geochemistry of alkaline lavas from northern James Ross Island (Antarctic Peninsula) and implications for back-arc magma formation     

J. Košler  T. Magna  B. Mlčoch  P. Mixa  D. Nývlt  F.V. Holub 《Chemical Geology》2009,258(3-4):207-218

We present a comprehensive geochemical data set for a suite of back-arc alkaline volcanic rocks from James Ross Island Volcanic Group (JRIVG), Antarctic Peninsula. The elemental and isotopic (Sr, Nd, Pb and Li) composition of these Cenozoic basalts emplaced east of the Antarctic Peninsula is different from the compositions of the fore-arc alkaline volcanic rocks in Southern Shetlands and nearby Bransfield Strait. The variability in elemental and isotopic composition is not consistent with the JRIVG derivation from a single mantle source but rather it suggests that the magma was mainly derived from a depleted mantle with subordinate OIB-like enriched mantle component (EM II). The isotopic data are consistent with mantle melting during extension and possible roll-back of the subducted lithosphere of the Antarctic plate. Magma contamination by Triassic–Early Tertiary clastic sediments deposited in the back-arc basin was only localized and affected Li isotopic composition in two of the samples, while most of the basalts show very little variation in δ⁷Li values, as anticipated for “mantle-driven” Li isotopic composition. These variations are difficult to resolve with radiogenic isotope systematics but Li isotopes may prove sensitive in tracking complex geochemical processes acting through the oceanic crust pile, including hydrothermal leaching and seawater equilibration.  相似文献   

Modeling aluminum-silicon chemistries and application to Australian acidic playa lakes as analogues for Mars     

G.M. Marion  J.K. Crowley  J.S. Kargel  S.J. Hook  A.J. Brown  C.R. de Souza Filho 《Geochimica et cosmochimica acta》2009,73(11):3493-3511

Recent Mars missions have stimulated considerable thinking about the surficial geochemical evolution of Mars. Among the major relevant findings are the presence in Meridiani Planum sediments of the mineral jarosite (a ferric sulfate salt) and related minerals that require formation from an acid-salt brine and oxidizing environment. Similar mineralogies have been observed in acidic saline lake sediments in Western Australia (WA), and these lakes have been proposed as analogues for acidic sedimentary environments on Mars. The prior version of the equilibrium chemical thermodynamic FREZCHEM model lacked Al and Si chemistries that are needed to appropriately model acidic aqueous geochemistries on Earth and Mars. The objectives of this work were to (1) add Al and Si chemistries to the FREZCHEM model, (2) extend these chemistries to low temperatures (<0 °C), if possible, and (3) use the reformulated model to investigate parallels in the mineral precipitation behavior of acidic Australian lakes and hypothetical Martian brines.FREZCHEM is an equilibrium chemical thermodynamic model parameterized for concentrated electrolyte solutions using the Pitzer approach for the temperature range from <−70 to 25 °C and the pressure range from 1 to 1000 bars. Aluminum chloride and sulfate mineral parameterizations were based on experimental data. Aluminum hydroxide and silicon mineral parameterizations were based on Gibbs free energy and enthalpy data. New aluminum and silicon parameterizations added 12 new aluminum/silicon minerals to this Na-K-Mg-Ca-Fe(II)-Fe(III)-Al-H-Cl-Br-SO₄-NO₃-OH-HCO₃-CO₃-CO₂-O₂-CH₄-Si-H₂O system that now contain 95 solid phases.There were similarities, differences, and uncertainties between Australian acidic, saline playa lakes and waters that likely led to the Burns formation salt accumulations on Mars. Both systems are similar in that they are dominated by (1) acidic, saline ground waters and sediments, (2) Ca and/or Mg sulfates, and (3) iron precipitates such as jarosite and hematite. Differences include: (1) the dominance of NaCl in many WA lakes, versus the dominance of Fe-Mg-Ca-SO₄ in Meridiani Planum, (2) excessively low K⁺ concentrations in Meridiani Planum due to jarosite precipitation, (3) higher acid production in the presence of high iron concentrations in Meridiani Planum, and probably lower rates of acid neutralization and hence, higher acidities on Mars owing to colder temperatures, and (4) lateral salt patterns in WA lakes. The WA playa lakes display significant lateral variations in mineralogy and water chemistry over short distances, reflecting the interaction of acid ground waters with neutral to alkaline lake waters derived from ponded surface runoff. Meridiani Planum observations indicate that such lateral variations are much less pronounced, pointing to the dominant influence of ground water chemistry, vertical ground water movements, and aeolian processes on the Martian surface mineralogy.  相似文献   

Site characterization and monitoring of natural attenuation indicator parameters in a fuel contaminated coastal aquifer: Karaduvar (Mersin,SE Turkey)     

Cüneyt Güler 《Environmental Earth Sciences》2009,59(3):631-643

This paper presents results from a site characterization and monitoring study at Karaduvar area (Mersin, SE Turkey), where high concentrations of refined petroleum products have been detected in domestic and irrigation water wells. The saturated and unsaturated zones in the deltaic aquifer are contaminated by large quantities of gasoline and diesel range fuel hydrocarbons (GRHs and DRHs) released from diverse sources that include accidental spills, storage tank fires, pipeline breaks, deliberate discharge of waste petroleum products from slop tanks and illegal tanker truck washing facilities. At the site, due to the complex nature of the pollution sources, overlapping contaminant plumes exist and cover an area of about 0.5 km². In both polluted and unpolluted parts of the aquifer, monitoring of groundwater physicochemical parameters in a total of 55 sampling points was carried out between 2006 and 2007. The results show that the terminal electron acceptors (e.g. dissolved oxygen, nitrate, Mn(IV), Fe(III), sulfate) were reduced near the source area(s) indicating presence of actively operating biodegradation processes at the site. Close to the contaminant source area(s), conditions in the plume are highly anoxic and reducing; where high amounts of transformation products (e.g. bicarbonate, dissolved iron, and manganese) are present in solution. Additionally, at the site, excessive pumping, careless land use, and deliberate wastewater discharges significantly deteriorated the quality and quantity of groundwater. Excessive groundwater pumping for industrial and agricultural uses has resulted in substantial water level declines (2–3 m) near the coastal part where seawater intrusion threatens the groundwater resources.  相似文献   

Study of the initiation and propagation of excavation damaged zones around openings in argillaceous rock     

Alain Millard  Jobst Maßmann  Amel Rejeb  Shin Uehara 《Environmental Geology》2009,57(6):1325-1335

The study of the creation and evolution of the excavation disturbed zone (EDZ) in argillaceous rocks is a major issue for the safety of nuclear wastes underground repositories. In this context, the argillaceous Tournemire site has provided a unique opportunity to study the evolution of the EDZ with time thanks to the existence of three openings of different ages. A thorough characterization of the EDZ has been conducted by different means such as visual observation, analysis of samples extracted from drilled boreholes, EDZ permeability measurements, etc. On the basis of these measurements, a conceptual model of the EDZ initiation and propagation at the Tournemire site has been proposed. In order to validate this model, numerical simulations of increasing complexity have been carried out. In a first attempt, the response of the rock mass to the excavation phase, followed by seasonal cyclic variations of temperature and relative humidity inside the opening, has been simulated by means of a purely mechanical analysis, using a simple elastic material model. The EDZ has been estimated by post-processing the calculated stress states, using a Mohr–Coulomb failure criterion. The results obtained show that no EDZ could be predicted unless adopting a low cohesion value for the rock mass. Moreover, the deferred nature of the EDZ formation in Tournemire could not be reproduced. These limitations have then been suppressed by using a coupled viscoplastic-damaging mechanical model, the parameters of which have been identified from different laboratory experiments. With this model, a time evolution of the EDZ could be predicted, but the EDZ pattern could not match the one observed in situ. Finally, in view of the importance of the hydraulic couplings, unsaturated hydro-mechanical calculations have been carried out to investigate the effect of the numerous seasonal variations cycles and the resulting shrinkage.  相似文献   

Seasonal variation in the toxicity of sediment-associated contaminants in Corpus Christi Bay, TX     

Wauhob TJ  Nipper M  Billiot E 《Marine pollution bulletin》2007,54(8):1116-1126

Seasonal variation in pore water and sediment-water interface (SWI) toxicity at two sites of suspected contamination was investigated using sea urchin embryological development (Arbacia punctulata) and copepod hatching success (Schizopera knabeni). Site S1, located inside a marina, was fine-grained and S2, located near a neighboring stormwater outfall, was sandy. Both sites were cored in summer and winter, along with reference sites of equivalent grain sizes. Whereas the muddy contaminated site displayed a slight decrease in sea urchin toxicity from summer to winter, pore water from the sandy contaminated site exhibited an increase in sea urchin toxicity. The sandy sites displayed slight toxicity increase to copepod hatching success in winter, which occurred in the SWI of S2 and in the pore water from the reference site, R2, where it coincided with sedimentation. Cu was the most prevalent metal in the sediment samples. Although Cu concentration increased in the whole sediments and pore waters from summer to winter, its concentration in overlying SWI exposure decreased from summer to winter. Organic compounds exhibited opposite behavior, with smaller variety identified in the winter pore water samples, but more chemicals detected in the SWI samples in winter.  相似文献   

Evidence for herbivorous cave bears (Ursus spelaeus) in Goyet Cave,Belgium: implications for palaeodietary reconstruction of fossil bears using amino acid δ15N approaches          下载免费PDF全文

Yuichi I. Naito  Mietje Germonpré  Yoshito Chikaraishi  Naohiko Ohkouchi  Dorothée G. Drucker  Keith A. Hobson  Mark A. Edwards  Christoph Wißing  Hervé Bocherens 《第四纪科学杂志》2016,31(6):598-606

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Hydrothermal activity during tectonic building of the Variscan orogen recorded by U-Pb systematics of xenotime in the Grès Armoricain formation,Massif Armoricain,France     

Romain Tartèse  Marc Poujol  Eric Gloaguen  Philippe Boulvais  Kerstin Drost  Jan Košler  Theodoros Ntaflos 《Mineralogy and Petrology》2015,109(4):485-500

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Concentrations and loads of dissolved xenobiotics and hormones in two small river catchments of different land use in Luxembourg     

A. Krein  S. Keßler  B. Meyer  J.‐Y. Pailler  C. Guignard  L. Hoffmann 《水文研究》2013,27(2):284-296

The investigation focuses on the analysis of dissolved sulfonamides, tetracyclines, analgesics, anticonvulsants and hormones in surface water. Runoff event and baseflow samples were analysed in two small river catchments of different land use in Luxembourg. For most of the flood events, similar pollutant loads to those transported during 1 day with average baseflow discharge were observed. The maximum contents during flood events and the event mean concentrations are controlled by pre‐event hydro‐climatological conditions. For all substances under investigation, maximum concentrations and event mean concentrations show a decrease with raising antecedent rainfall. In addition, the interstorm and intrastorm variability of the pollutant transport was determined. Runoff generation and corresponding transport of xenobiotic compounds show a complex pattern with many interrelated processes, taking place within bedrock, soil, anthropogenic facilities and channel and in different parts of the basins under investigation. Different sources of pollutants can be identified and related to particular locations in the basin. The influence of the sewer systems is obvious. In the agricultural Mess basin, higher rainfall amounts lead to greater quantities of laterally inflowing soil water with higher concentrations of dissolved oxytetracycline. This originates from veterinary medicines administered to livestock and enters the environment through the application of organic fertilisers, especially by slurry that is applied to the fields. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Skill assessment of three earth system models with common marine biogeochemistry   总被引：1，自引：0，他引：1  

Roland Séférian  Laurent Bopp  Marion Gehlen  James C. Orr  Christian Ethé  Patricia Cadule  Olivier Aumont  David Salas y Mélia  Aurore Voldoire  Gurvan Madec 《Climate Dynamics》2013,40(9-10):2549-2573

We have assessed the ability of a common ocean biogeochemical model, PISCES, to match relevant modern data fields across a range of ocean circulation fields from three distinct Earth system models: IPSL-CM4-LOOP, IPSL-CM5A-LR and CNRM-CM5.1. The first of these Earth system models has contributed to the IPCC 4th assessment report, while the latter two are contributing to the ongoing IPCC 5th assessment report. These models differ with respect to their atmospheric component, ocean subgrid-scale physics and resolution. The simulated vertical distribution of biogeochemical tracers suffer from biases in ocean circulation and a poor representation of the sinking fluxes of matter. Nevertheless, differences between upper and deep ocean model skills significantly point to changes in the underlying model representations of ocean circulation. IPSL-CM5A-LR and CNRM-CM5.1 poorly represent deep-ocean circulation compared to IPSL-CM4-LOOP degrading the vertical distribution of biogeochemical tracers. However, their representations of surface wind, wind stress, mixed-layer depth and geostrophic circulations (e.g., Antarctic Circumpolar Current) have been improved compared to IPSL-CM4-LOOP. These improvements result in a better representation of large-scale structure of biogeochemical fields in the upper ocean. In particular, a deepening of 20–40 m of the summer mixed-layer depth allows to capture the 0–0.5 μgChl L^?1 concentrations class of surface chlorophyll in the Southern Ocean. Further improvements in the representation of the ocean mixed-layer and deep-ocean ventilation are needed for the next generations of models development to better simulate marine biogeochemistry. In order to better constrain ocean dynamics, we suggest that biogeochemical or passive tracer modules should be used routinely for both model development and model intercomparisons.  相似文献   

Nickeliferous pyrite tracks pervasive hydrothermal alteration in Martian regolith breccia: A study in NWA 7533          下载免费PDF全文

Jean‐Pierre Lorand  Roger H. Hewins  Laurent Remusat  Brigitte Zanda  Sylvain Pont  Hugues Leroux  Maya Marinova  Damien Jacob  Munir Humayun  Alexander Nemchin  Marion Grange  Allen Kennedy  Christa Göpel 《Meteoritics & planetary science》2015,50(12):2099-2120

Martian regolith breccia NWA 7533 (and the seven paired samples) is unique among Martian meteorites in showing accessory pyrite (up to 1% by weight). Pyrite is a late mineral, crystallized after the final assembly of the breccia. It is present in all of the lithologies, i.e., the fine‐grained matrix (ICM), clast‐laden impact melt rocks (CLIMR), melt spherules, microbasalts, lithic clasts, and mineral clasts, all lacking magmatic sulfides due to degassing. Pyrite crystals show combinations of cubes, truncated cubes, and octahedra. Polycrystalline clusters can reach 200 μm in maximum dimensions. Regardless of their shape, pyrite crystals display evidence of very weak shock metamorphism such as planar features, fracture networks, and disruption into subgrains. The late fracture systems acted as preferential pathways for partial replacement of pyrite by iron oxyhydroxides interpreted as resulting from hot desert terrestrial alteration. The distribution and shape of pyrite crystals argue for growth at moderate to low growth rate from just‐saturated near neutral (6 < pH<10), H₂S‐HS‐rich fluids at minimum log fO₂ of >FMQ + 2 log units. It is inferred from the maximum Ni contents (4.5 wt%) that pyrite started crystallizing at 400–500 °C, during or shortly after a short‐duration, relatively low temperature, thermal event that lithified and sintered the regolith breccias, 1.4 Ga ago as deduced from disturbance in several isotope systematics.  相似文献