Geochemistry and zircon U-Pb geochronology of Aligoodarz granitoid complex, Sanandaj-Sirjan Zone, Iran     

Amir Esna-Ashari  Massimo TiepoloMohammad-Vali Valizadeh  Jamshid HassanzadehAli-Asghar Sepahi 《Journal of Asian Earth Sciences》2012,43(1):11-22

The Aligoodarz granitoid complex (AGC) is located in the Sanandaj-Sirjan Zone (SSZ), western Iran and consists of quartz-diorites, granodiorites and subordinate granites. Whole rock major and trace element data mostly define linear trends on Harker diagrams suggesting a cogenetic origin of the different rock types. (⁸⁷Sr/⁸⁶Sr)_i and εNd_t ratios are in the ranges 0.7074-0.7110 and −3.56 to −5.50, respectively. The trace elements and Sr-Nd isotopic composition suggest that the granitoids from the AGC are similar to crustal derived I-type granitoids of continental arcs. The whole rock suite was produced by assimilation and fractional crystallization starting from a melt with intermediate composition likely possessing a mantle component. In situ zircon U-Pb data on the granites with LA-ICP-MS yield a crystallization age of ∼165 Ma. Inherited grains spanning in age from ∼180 Ma up to 2027 Ma were also found and confirm that assimilation of country rock has occurred.Chemical and chronological data on the AGC were compared with those available for other granitoid complexes of the central SSZ (e.g., Dehno, Boroujerd and Alvand). The comparison reveals that in spite of the different origins that have been proposed, all these granitoid complexes are likely genetically related. They share many chemical features and are derived from crustal melts with minor differences. Alvand granites have the most peculiar compositions most likely related to the presence of abundant pelitic component. All these intrusions are coeval and reveal the presence of an extensive magmatic activity in the central sector of the SSZ during middle Jurassic.  相似文献   

Turbulent Transfer Between Street Canyons and the Overlying Atmospheric Boundary Layer   总被引：1，自引：1，他引：0  

Pietro Salizzoni  Massimo Marro  Lionel Soulhac  Nathalie Grosjean  Richard J. Perkins 《Boundary-Layer Meteorology》2011,141(3):393-414

The turbulent exchange of momentum between a two-dimensional cavity and the overlying boundary layer has been studied experimentally, using hot-wire anemometry and particle image velocimetry (PIV). Conditions within the boundary layer were varied by changing the width of the canyons upstream of the test canyon, whilst maintaining the square geometry of the test canyon. The results show that turbulent transfer is due to the coupling between the instabilities generated in the shear layer above the canyons and the turbulent structures in the oncoming boundary layer. As a result, there is no single, unique velocity scale that correctly characterizes all the processes involved in the turbulent exchange of momentum across the boundary layer. Similarly, there is no single velocity scale that can characterize the different properties of the turbulent flow within the canyon, which depends strongly on the way in which turbulence from the outer flow is entrained into the cavity and carried round by the mean flow. The results from this study will be useful in developing simple parametrizations for momentum exchange in the urban canopy, in situations where the street geometry consists principally of relatively long, uniform streets arranged in grid-like patterns; they are unlikely to be applicable to sparse geometries composed of isolated three-dimensional obstacles.  相似文献   

High-temperature emplacement of the Cerro Galán and Toconquis Group ignimbrites (Puna plateau,NW Argentina) determined by TRM analyses     

Chiara Lesti  Massimiliano Porreca  Guido Giordano  Massimo Mattei  Raymond A. F. Cas  Heather M. N. Wright  Chris B. Folkes  Josè Viramonte 《Bulletin of Volcanology》2011,73(10):1535-1565

Estimates of pyroclastic flow emplacement temperatures in the Cerro Galán ignimbrite and Toconquis Group ignimbrites were determined using thermal remanent magnetization of lithic clasts embedded within the deposits. These ignimbrites belong to the Cerro Galán volcanic system, one of the largest calderas in the world, in the Puna plateau, NW Argentina. Temperature estimates for the 2.08-Ma Cerro Galán ignimbrite are retrieved from 40 sites in 14 localities (176 measured clasts), distributed at different distances from the caldera and different stratigraphic heights. Additionally, temperature estimates were obtained from 27 sample sites (125 measured clasts) from seven ignimbrite units forming the older Toconquis Group (5.60–4.51 Ma), mainly outcropping along a type section at Rio Las Pitas, Vega Real Grande. The paleomagnetic data obtained by progressive thermal demagnetization show that the clasts of the Cerro Galán ignimbrite have one single magnetic component, oriented close to the expected geomagnetic field at the time of emplacement. Results show therefore that most of the clasts acquired a new magnetization oriented parallel to the magnetic field at the moment of the ignimbrite deposition, suggesting that the clasts were heated up to or above the highest blocking temperature (T _b) of the magnetic minerals (T _b = 580°C for magnetite; T _b = 600–630°C for hematite). We obtained similar emplacement temperature estimations for six out of the seven volcanic units belonging to the Toconquis Group, with the exception of one unit (Lower Merihuaca), where we found two distinct magnetic components. The estimation of emplacement temperatures in this latter case is constrained at 580–610°C, which are lower than the other ignimbrites. These estimations are also in agreement with the lowest pre-eruptive magma temperatures calculated for the same unit (i.e., 790°C; hornblende–plagioclase thermometer; Folkes et al. 2011b). We conclude that the Cerro Galán ignimbrite and Toconquis Group ignimbrites were emplaced at temperatures equal to or higher than 620°C, except for Lower Merihuaca unit emplaced at lower temperatures. The homogeneity of high temperatures from proximal to distal facies in the Cerro Galán ignimbrite provides constraints for the emplacement model, marked by a relatively low eruption column, low levels of turbulence, air entrainment, surface–water interaction, and a high level of topographic confinement, all ensuring minimal heat loss.  相似文献   

Magnetic properties and cation ordering of nanopowders of the synthetic analogue of kuramite, Cu3SnS4     

Francesco Di Benedetto  Daniele Borrini  Andrea Caneschi  Gabriele Fornaciai  Massimo Innocenti  Alessandro Lavacchi  Carlo Andrea Massa  Giordano Montegrossi  Werner Oberhauser  Luca A. Pardi  Maurizio Romanelli 《Physics and Chemistry of Minerals》2011,38(6):483-490

An extensive characterisation of the magnetic properties of synthetic powders of kuramite, with formal composition Cu₃SnS₄, was performed. Powders were investigated through superconducting quantum interference device (SQUID) magnetometry, electron paramagnetic resonance (EPR) spectroscopy, X-ray powder diffraction (XRPD), scanning and transmission electron microscopies (SEM and TEM) and microanalysis. SEM and TEM reveal the presence of nanodimensioned particles. XRPD clearly shows that Cu₃SnS₄ crystallised in a cubic sphalerite-type structural model, in spite of the stannite-type tetragonal structure described for the natural phase. This difference arises from a full random distribution of cations. Synthetic kuramite nanopowders exhibit a marked paramagnetism, originated by the presence of Cu(II), definitely assessed by EPR measurements. Moreover, the overall magnetic behaviour of the sample cannot be simply ascribed to diluted paramagnetism, and this suggests the presence of strong superexchange interactions among Cu(II) ions even at room temperature. The main consequences of these results are the definitive assessment of the chemical formula Cu(I)₂Cu(II)SnS₄ and of a random distribution of Cu(II), Cu(I) and Sn(IV) ions within the available tetrahedral sites.  相似文献   

A free software for sand and gravel embayed beach modelling: PhoEbuS- parabolic equation shape     

Chiara F. Schiaffino  Massimo Brignone  Marco Ferrari 《Earth Science Informatics》2013,6(3):165-173

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Geochemistry and Petrogenesis of Siwana Peralkaline Granites, West of Barmer, Rajasthan, India     

Anil Maheshwari  A.N. Sial  Massimo Coltorti  V.K. Chittora  Manoel J.M. Cruz 《Gondwana Research》2001,4(1)

The bimodal Malani suite, West of Barmer, Rajasthan is characterized by discontinuous, ring shaped outcrops of Siwana peralkaline granite with minor outcrops of basalt. The peralkaline, within- plate and A-type nature of granite are evident by its chemical characteristics. The granite is characterized by high Na₂O+K₂O, Fe/Mg, Zr, Nb, Y, Zn; low Al₂O₃, CaO and Sr and is significantly low in absolute abundance of trace and REE elements compared to type area Siwana granite. The granite is correlated to the “Pan-African” event and its petrogenesis and tectonic significance are discussed.  相似文献   

Bioremediation of petroleum hydrocarbons in anoxic marine sediments: Consequences on the speciation of heavy metals   总被引：3，自引：0，他引：3  

Antonio Dell’Anno  Francesca Beolchini  Massimo Gabellini  Laura Rocchetti  Antonio Pusceddu  Roberto Danovaro 《Marine pollution bulletin》2009,58(12):1808-1814

We investigated the effects of biostimulation and bioagumentation strategies applied to harbor sediments displaying reducing conditions and high concentrations of petroleum hydrocarbons and heavy metals. We compared the microbial efficiency of hydrocarbon removal from sediments maintained for 60 days in anoxic conditions and inoculated with acetate, sulfate-reducing bacterial strains and acetate and sulfate-reducing bacteria. All treatments determined a significant increase in the microbial growth and significant decreases of hydrocarbon contents and of redox potential values. The addition of sulfate-reducing bacterial strains to the sediment was the most efficient treatment for the hydrocarbon removal. In all experiments, significant changes of the heavy metals’ phase repartition were observed. The results reported here suggest that the biodegradation of petroleum hydrocarbons in anoxic marine sediments may be enhanced by stimulating microbial anaerobic metabolism, but care should be applied to monitor the potential changes in the mobility and bioavailability of heavy metals induced by bio-treatments.  相似文献   

Estimating the contribution of the authigenic mineral component to the long-term reactive silica accumulation on the western shelf of the Mississippi River Delta     

Massimo Presti  Panagiotis Michalopoulos 《Continental Shelf Research》2008

Previous studies have shown how biogenic silica particles undergo conversion to aluminosilicate phases in large tropical deltaic systems, thus affecting the world ocean budget of major seawater cations. This study tackles the important question of the silica budget in the coastal zone of the Mississippi River Delta, providing evidence for the role of biogenic silica diagenesis in this subtropical system from direct examination of individual diatom particles, sediment leachates and pore-water composition. The estimated reactive silica stored in the study area (5990 km²) is based on operational leaches that account for altered biogenic silica particles and other authigenic aluminosilicate phases in addition to fresh biogenic silica. Early diagenesis of silica in the delta front occurs mainly where more siliceous material is deposited. An inner-shelf area, where hypoxic conditions are found, significantly contributes to the formation of authigenic products of Si alteration. Data suggest that the limiting factor of silica alteration processes is the availability of detrital phases such as Al and Fe. The estimated total reactive silica accumulation in the study area is 1.45×10¹⁰ mol Si year⁻¹, representing ∼2.2% of the long-term bulk sediment accumulation. On the basis of a conservative appraisal, the authigenic mineral components account for ∼40% of the long-term reactive silica storage. This study shows that non-tropical deltaic systems are significantly more important sinks of silica than previously thought and that, where conditions are favourable, a consistent portion of reactive silica not leaving the shelf is stored within the delta in the form of authigenic components.  相似文献   

The Holocene Secche di Lazzaro phreatomagmatic succession (Stromboli,Italy): evidence of pyroclastic density current origin deduced by facies analysis and AMS flow directions     

Guido Giordano  Massimiliano Porreca  Pietro Musacchio  Massimo Mattei 《Bulletin of Volcanology》2008,70(10):1221-1236

The edifice of Stromboli volcano gravitationally collapsed several times during its volcanic history (>100 ka–present). The largest Holocene event occurred during the final stage of the Neostromboli activity (∼13–5 ka), and was accompanied by the emplacement of phreatomagmatic and lahar deposits, known as the Secche di Lazzaro succession. A stratigraphic and paleomagnetic study of the Secche di Lazzaro deposits allows the interpretation of the emplacement and the eruptive processes. We identify three main units within the succession that correspond to changing eruption conditions. The lower unit (UA) consists of accretionary lapilli-rich, thinly bedded, parallel- to cross-stratified ash deposits, interpreted to indicate the early stages of the eruption and emplacement of dilute pyroclastic density currents. Upward, the second unit (UB) of the deposit is more massive and the beds thicker, indicating an increase in the sedimentation rate from pyroclastic density currents. The upper unit (UC) caps the succession with thick, immediately post-eruptive lahars, which reworked ash deposited on the volcano’s slope. Flow directions obtained by Anisotropy of Magnetic Susceptibility (AMS) analysis of the basal bed of UA at the type locality suggest a provenance of pyroclastic currents from the sea. This is interpreted to be related to the initial base-surges associated with water–magma interaction that occurred immediately after the lateral collapse, which wrapped around the shoulder of the sector collapse scar. Upward in the stratigraphy (upper beds of UA and UB) paleoflow directions change and show a provenance from the summit vent, probably related to the multiple collapses of a vertical, pulsatory eruptive column.  相似文献   

A full-scale study of Darcy-Weisbach friction factor for channels vegetated by riparian species     

Alessio Nicosia  Gian Battista Bischetti  Enrico Chiaradia  Claudio Gandolfi  Vito Ferro 《水文研究》2021,35(3):e14009

In this article, an open channel flow resistance equation, deduced applying dimensional analysis and incomplete self-similarity condition for the flow velocity distribution, was tested using measurements carried out in a full-scale channel equipped with three types of riparian plants (Salix alba L., Salix caprea L. and Alnus glutinosa L.). In the experimental channel, having banks lined with boulders, the vegetation branches were anchored in a concrete bottom. For each species, the measurements were carried out with plants having different amounts of leaves, different plant density and plant area index. The relationship between the scale factor Γ of the velocity profile and the Froude number was separately calibrated by measurements carried out without and with vegetation. The component of Darcy-Weisbach friction factor corresponding to the riparian vegetation f_v was calculated as the difference between the measured friction factor value (channel grain roughness + vegetation) and that calculated for the channel without vegetation in the same hydraulic conditions. Using these f_v values, the relationship between the scale factor Γ and the Froude number was calibrated. In this last relationship, a scaling coefficient a varying with the investigated vegetation type was introduced. This coefficient, as expected, gives the highest friction factor values for vegetation having branches with leaves. The theoretical flow resistance law, coupled with the relationship for estimating the Γ function having a scaling coefficient different for each investigated vegetation type, allowed an accurate estimate of the Darcy-Weisbach friction factor (errors less than or equal to 20% for 82.6% of the investigated cases). Finally, for the investigated vegetation species that are characterized by a condition with few leaves or leafless, the scaling coefficient a resulted strongly related to the bending stiffness. This analysis demonstrated that the highest Darcy-Weisbach friction factors correspond to vegetation species characterized by the highest values of bending stiffness. The friction factor values calculated for this last condition are characterized by errors that were less than or equal to ±20% for 90.6% of cases.  相似文献