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11.
The definition of a consistent stress framework is an essential prerequisite to the constitutive modelling of unsaturated soils. It is proposed to clarify the effective stress lexicon commonly used for unsaturated soils, one of the purposes being to contribute to a more accurate definition and understanding of conventional Bishop’s stress. The so-called generalised effective stress is formulated on the basis of previous studies and set within a complete constitutive context. A point by point comparison between Bishop’s stress and generalised framework is led. The usual analogies between suction effects, cementation and hardening are also discussed. Suction is shown not to be a hardening variable but rather a shape parameter for the yield surface expressed in the matric suction versus mean effective stress plane. Some advantages of the generalised effective stress are finally reviewed, with a particular accent laid on the uniqueness of the yield limit and the built-in hydro-mechanical coupling.  相似文献   
12.
We have conducted high-pressure experiments in the H2O-CH4 and H2O-CH4-NH3 systems in order to investigate the stability of methane clathrate hydrates, with an optical sapphire-anvil cell coupled to a Raman spectrometer for sample characterization. The results obtained confirm that three factors determine the stability of methane clathrate hydrates: (1) the bulk methane content of the samples; (2) the presence of additional gas compounds such as nitrogen; (3) the concentration of ammonia in the aqueous solution. We show that ammonia has a strong effect on the stability of methane clathrates. For example, a 10 wt.% NH3 solution decreases the dissociation temperature of methane clathrates by 14-25 K at pressures above 5 MPa. Then, we apply these new results to Titan’s conditions. Dissociation of methane clathrate hydrates and subsequent outgassing can only occur in Titan’s icy crust, in presence of locally large amounts of ammonia and in a warm context. We propose a model of cryomagma chamber within the crust that provides the required conditions for methane outgassing: emplacement of an ice plume triggers the melting (if solid) or heating (if liquid) of large ammonia-water pockets trapped at shallow depth, and the generated cryomagmas dissociate surrounding methane clathrate hydrates. We show that this model may allow for the outgassing of significant amounts of methane, which would be sufficient to maintain the presence of methane in Titan’s atmosphere for several tens of thousands of years after a large cryovolcanic event.  相似文献   
13.
Modelling land use and cover changes (LUCC) at local and landscape scales simultaneously, in terms of composition and configuration, remains today highly challenging. Agricultural landscapes offer an illustrative context for this purpose. This article presents a modelling platform (DYPAL) able to simulate LUCC at both local (agricultural parcel, farm) and landscape levels by combining LUCC processes with an optimization algorithm. The efficiency of this approach is assessed by comparing it with an approach applying the same LUCC processes without optimization. Simulations have been developed for two representative case studies of temperate intensive agricultural mosaics: (1) neutral landscapes with simple and theoretical rules and (2) observed landscapes with realistic crop successions rules. Results show that this modelling platform improves the simulation of LUCC achieved at fine resolution, although not systematically. Improvements are observed when compared to theoretical farming practices. But, when compared with an observed landscape, it is true for one type of (arable) farms only. Several hypotheses are discussed, such as the fact that farmers possibly do not follow optimized rules. Finally, this study illustrates that the use of several indices is crucial to assess whether a simulated landscape is realistic or not, because it does not rely to the assessment of the predictive power of the model.  相似文献   
14.
The capability of a current state-of-the-art regional climate model for simulating the diurnal and annual cycles of rainfall over a complex subtropical region is documented here. Hourly rainfall is simulated over Southern Africa for 1998–2006 by the non-hydrostatic model weather research and forecasting (WRF), and compared to a network of 103 stations covering South Africa. We used five simulations, four of which consist of different parameterizations for atmospheric convection at a 0.5 × 0.5° resolution, performed to test the physic-dependency of the results. The fifth experiment uses explicit convection over tropical South Africa at a 1/30° resolution. WRF simulates realistic mean rainfall fields, albeit wet biases over tropical Africa. The model mean biases are strongly modulated by the convective scheme used for the simulations. The annual cycle of rainfall is well simulated over South Africa, mostly influenced by tropical summer rainfall except in the Western Cape region experiencing winter rainfall. The diurnal cycle shows a timing bias, with atmospheric convection occurring too early in the afternoon, and causing too abundant rainfall. This result, particularly true in summer over the northeastern part of the country, is weakly physic-dependent. Cloud-resolving simulations do not clearly reduce the diurnal cycle biases. In the end, the rainfall overestimations appear to be mostly imputable to the afternoon hours of the austral summer rainy season, i.e., the periods during which convective activity is intense over the region.  相似文献   
15.
The palaeontological site of Venta Micena (Orce, Andalusia, Spain) lies in the eastern sector of the Guadix–Baza basin, one of the best documented areas in Europe for Plio‐Pleistocene biostratigraphy. The combination of biochronological and palaeomagnetic results, combined with the radiometric data obtained for Atapuerca Sima del Elefante, indicated that the Venta Micena stratum was formed between the Jaramillo and Olduvai palaeomagnetic events, most likely between 1.22 and 1.77 Ma. Five fossil teeth from two outcrops (sites A and B) were selected to assess the potential of combined uranium series–electron spin resonance (US‐ESR) dating of Early Pleistocene sites. Although the US‐ESR results of the first outcrop showed a large scatter between the three teeth, the mean age of 1.37 ± 0.24 Ma can be considered a reasonable age estimate for Venta Micena. The mean ESR age of 0.62 ± 0.03 Ma obtained for site B seems to be a severe underestimation when compared with the independent age control. This underestimation is attributed to a relative recent U‐mobilization event that led to some U‐leaching. The results show that any ESR age calculations of old samples are extremely sensitive to variations in the measured 230Th/234U ratios in dental tissues. Although the results demonstrate that ESR can in principle be applied to Early Pleistocene sites, they also reveal the complexity of dating such old teeth. It is necessary to continue research in several directions, such as study of the behaviour of ESR signals in old teeth and understanding recent U‐mobilization processes, to improve the reliability of the combined US‐ESR dating method applied to Early Pleistocene times, a period for which the number of available numerical dating techniques is very limited. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
16.
Combining time–amplitude and time–frequency information from seismic reflection data sets of different resolutions allows the analysis of anomalous reflections from very-shallow to great subsurface depths. Thus, it can enhance the imaging of subsurface features which have a frequency-dependent reflectivity such as gas. Analysing seismic data of different resolution in the time–amplitude and time–frequency domains is a powerful method to determine hydrocarbon migration pathways from deep reservoirs to the seafloor. This interpretation method has been applied to the formerly-glaciated offshore Queen Charlotte Basin hosting several seafloor pockmarks and mounds associated with the leakage of underlying hydrocarbon reservoirs. Low-frequency shadows observed in the time–frequency domain provide evidence of different resolutions that several anomalous reflection amplitudes may be attributed to the occurrence of gas. The seismic imagery shows that gas uses a fault to migrate from deep reservoirs included in Upper Mesozoic strata towards secondary reservoirs located along the fault plane into Neogene layers. Once gas reaches a porous cut-and-fill succession, migration changes from structurally- to stratigraphically-controlled before gas leaks through unconsolidated Quaternary sediments forming the shallow subsurface to eventually seep at the seafloor where pockmarks and carbonate mounds are formed.  相似文献   
17.
In order to fulfill the society demand for climate information at the spatial scale allowing impact studies, long-term high-resolution climate simulations are produced, over an area covering metropolitan France. One of the major goals of this article is to investigate whether such simulations appropriately simulate the spatial and temporal variability of the current climate, using two simulation chains. These start from the global IPSL-CM4 climate model, using two regional models (LMDz and MM5) at moderate resolution (15–20 km), followed with a statistical downscaling method in order to reach a target resolution of 8 km. The statistical downscaling technique includes a non-parametric method that corrects the distribution by using high-resolution analyses over France. First the uncorrected simulations are evaluated against a set of high-resolution analyses, with a focus on temperature and precipitation. Uncorrected downscaled temperatures suffer from a cold bias that is present in the global model as well. Precipitations biases have a season- and model-dependent behavior. Dynamical models overestimate rainfall but with different patterns and amplitude, but both have underestimations in the South-Eastern area (Cevennes mountains) in winter. A variance decomposition shows that uncorrected simulations fairly well capture observed variances from inter-annual to high-frequency intra-seasonal time scales. After correction, distributions match with analyses by construction, but it is shown that spatial coherence, persistence properties of warm, cold and dry episodes also match to a certain extent. Another aim of the article is to describe the changes for future climate obtained using these simulations under Scenario A1B. Results are presented on the changes between current and mid-term future (2021–2050) averages and variability over France. Interestingly, even though the same global climate model is used at the boundaries, regional climate change responses from the two models significantly differ.  相似文献   
18.
The solar system, as we know it today, is about 4.5 billion years old. It is widely believed that it was essentially completed 100 million years after the formation of the Sun, which itself took less than 1 million years, although the exact chronology remains highly uncertain. For instance: which, of the giant planets or the terrestrial planets, formed first, and how? How did they acquire their mass? What was the early evolution of the “primitive solar nebula” (solar nebula for short)? What is its relation with the circumstellar disks that are ubiquitous around young low-mass stars today? Is it possible to define a “time zero” (t 0), the epoch of the formation of the solar system? Is the solar system exceptional or common? This astronomical chapter focuses on the early stages, which determine in large part the subsequent evolution of the proto-solar system. This evolution is logarithmic, being very fast initially, then gradually slowing down. The chapter is thus divided in three parts: (1) The first million years: the stellar era. The dominant phase is the formation of the Sun in a stellar cluster, via accretion of material from a circumstellar disk, itself fed by a progressively vanishing circumstellar envelope. (2) The first 10 million years: the disk era. The dominant phase is the evolution and progressive disappearance of circumstellar disks around evolved young stars; planets will start to form at this stage. Important constraints on the solar nebula and on planet formation are drawn from the most primitive objects in the solar system, i.e., meteorites. (3) The first 100 million years: the “telluric” era. This phase is dominated by terrestrial (rocky) planet formation and differentiation, and the appearance of oceans and atmospheres.  相似文献   
19.
We have demonstrated that the diffuse band spectrum could not originate as a series of vibronic transitions from atomic impurities in interstellar MgO grains as has recently been proposed since laboratory spectra of such materials show no evidence for such complex structure. Furthermore, recent observational evidence indicates that the extinction feature at 160 nm in the standard interstellar extinction curve upon which the identification of interstellar MgO was founded is actually the result of a calibration error in the original observational data.  相似文献   
20.
Abstract— We have measured Ne, Ar, Kr and Xe in Si2O3 “smokes” that were condensed on Al substrates, vapor-deposited with various mixtures of CH4, NH3, H2O and noble gases at 10 K and subsequently irradiated with 1 MeV protons to simulate conditions during grain mantle formation in interstellar clouds. The noble gases were analyzed using conventional stepwise heating and static noble gas mass spectrometry. Neither Ne nor Ar is retained by the samples upon warming to room temperature, but Xe is very efficiently trapped and retained. Kr is somewhat less effectively retained, typically depleted by factors of about 10–20 relative to Xe. Isotopic fractionation favoring the heavy isotopes of Xe and Kr of about 5–10‰/amu is observed. Correlations between the specific chemistry of the vapor deposition and heavy noble gas retention are most likely the result of competition by the various species for irradiation-produced trapping sites. The concentration of Xe retained by some of these smokes exceeds that observed in phase Q of meteorites and, like phase Q, they do not seem to be carriers of the light noble gases. Such artificially prepared material may, therefore, offer clues concerning the incorporation of the heavy planetary noble gases in meteoritic material and the nature of phase Q.  相似文献   
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