HTP2₁/c–C2/c phase transition and kinetics of Fe²⁺–Mg order–disorder of an Fe-poor pigeonite: implications for the cooling history of ureilites     

Matteo Alvaro  Fernando Cámara  M. Chiara Domeneghetti  Fabrizio Nestola  Vittorio Tazzoli 《Contributions to Mineralogy and Petrology》2011,162(3):599-613

A natural Ca-poor pigeonite (Wo₆En₇₆Fs₁₈) from the ureilite meteorite sample PCA82506-3, free of exsolved augite, was studied by in situ high-temperature single-crystal X-ray diffraction. The sample, monoclinic P2₁/c, was annealed up to 1,093°C to induce a phase transition from P2₁/c to C2/c symmetry. The variation with increasing temperature of the lattice parameters and of the intensity of the b-type reflections (h + k = 2n + 1, present only in the P2₁/c phase) showed a displacive phase transition P2₁/c to C2/c at a transition temperature T _Tr = 944°C, first order in character. The Fe–Mg exchange kinetics was studied by ex situ single-crystal X-ray diffraction in a range of temperatures between the closure temperature of the Fe–Mg exchange reaction and the transition temperature. Isothermal disordering annealing experiments, using the IW buffer, were performed on three crystals at 790, 840 and 865°C. Linear regression of ln k _D versus 1/T yielded the following equation: ln k_\textD = - 3717( ±416)/T(K) + 1.290( ±0.378);    (R² = 0.988) \ln \,k_{\text{D}} = - 3717( \pm 416)/T(K) + 1.290( \pm 0.378);\quad (R^{2} = 0.988) . The closure temperature (T _c) calculated using this equation was ∼740(±30)°C. Analysis of the kinetic data carried out taking into account the e.s.d.'s of the atomic fractions used to define the Fe–Mg degree of order, performed according to Mueller’s model, allowed us to retrieve the disordering rate constants C ₀ K _dis⁺ for all three temperatures yielding the following Arrhenius relation: ln( C₀ K_\textdis ⁺ ) = ln K₀ - Q/(RT) = 20.99( ±3.74) - 26406( ±4165)/T(K);    (R² = 0.988) \ln \left( {C_{0} K_{\text{dis}}^{ + } } \right) = \ln \,K_{0} - Q/(RT) = 20.99( \pm 3.74) - 26406( \pm 4165)/T(K);\quad (R^{2} = 0.988) . An activation energy of 52.5(±4) kcal/mol for the Fe–Mg exchange process was obtained. The above relation was used to calculate the following Arrhenius relation modified as a function of X _Fe (in the range of X _Fe = 0.20–0.50): ln( C₀ K_\textdis ⁺ ) = (21.185 - 1.47X_\textFe ) - \frac(27267 - 4170X_\textFe )T(K) \ln \left( {C_{0} K_{\text{dis}}^{ + } } \right) = (21.185 - 1.47X_{\text{Fe}} ) - {\frac{{(27267 - 4170X_{\text{Fe}} )}}{T(K)}} . The cooling time constant, η = 6 × 10⁻¹ K⁻¹ year⁻¹ calculated on the PCA82506-3 sample, provided a cooling rate of the order of 1°C/min consistent with the extremely fast late cooling history of the ureilite parent body after impact excavation.  相似文献   

Geology and geochemistry of Iberian roofing slates     

Victor Cárdenes  Alvaro Rubio-Ordoñez  Carmela Monterroso  Lope Calleja 《Chemie der Erde / Geochemistry》2013

This article analyzes the geochemical and mineralogical composition of the roofing slate deposits of the Iberian Peninsula. Most roofing slate deposits are found on Middle and Upper Ordovician terrains, although there are also deposits in the Ediacaran, Cambrian and Devonian terrains. Samples of slate were taken in most of the active quarries of the Iberian Peninsula, and being analyzed by X-ray Diffraction and Fluorescence. Each lithotect or slate productive formation has its own specific proportions of major and trace elements, being able to differentiate between them by using these relationships. This fact is particularly interesting in geological exploration and prospecting, as it allows knowing exactly the slate lithotect, and also for restoration work in the architectural heritage, due to the ability of identifying the source of the original slate tiles.  相似文献   

Magnetic flares and the optical variability of the X-ray transient XTE J1118+480     

A. Merloni  T. Di Matteo †  A. C. Fabian 《Monthly notices of the Royal Astronomical Society》2000,318(1):L15-L19

The simultaneous presence of a strong quasi-periodic oscillation, of period ∼10 s, in the optical and X-ray light curves of the X-ray transient XTE J1118+480 suggests that a significant fraction of the optical flux originates from the inner part of the accretion flow, where most of the X-rays are produced. We present a model of magnetic flares in an accretion disc corona where thermal cyclo-synchrotron emission contributes significantly to the optical emission, while the X-rays are produced by inverse Compton scattering of the soft photons produced by dissipation in the underlying disc and by the synchrotron process itself. Given the observational constraints, we estimate the values for the coronal temperature, optical depth and magnetic field intensity, as well as the accretion rate for the source. Within our model we predict a correlation between optical and hard X-ray variability and an anticorrelation between optical and soft X-rays. We also expect optical variability on flaring time-scales (∼tens of ms), with a power-density spectrum similar to that observed in the X-ray band. Finally, we use both the available optical/extreme-ultraviolet/X-ray spectral energy distribution and the low-frequency time variability to discuss limits on the inner radius of the optically thick disc.  相似文献   

Remote leveling of tide gauges using GNSS reflectometry: case study at Spring Bay,Australia   总被引：1，自引：1，他引：0  

Alvaro Santamaría-Gómez  Christopher Watson 《GPS Solutions》2017,21(2):451-459

We further developed a new approach using GNSS reflectometry to determine the leveling connection between a tide gauge and a GNSS antenna. This approach includes the optimization of the unknown receiver bandwidth and the estimation of frequency changes in the signal-to-noise ratio (SNR) oscillation through an extended Kalman filter/smoother algorithm. We also corrected the geometric bending of the GNSS signals due to tropospheric refraction using local meteorological observations. Using 3 weeks of SNR data in Spring Bay, Australia, from a GNSS antenna placed sideways (i.e., ground plane orientated vertically and directed in azimuth toward the sea surface) to improve the SNR interference near the horizon, we obtained mean leveling differences of approximately 5 mm, with an RMS of approximately 3 cm level with respect to the nominal leveling from classical surveying techniques. SNR data from three different receiver manufacturers, coupled to the same antenna, provided similar leveling results. With a second antenna in the usual upright configuration, we obtained mean leveling differences of 1–2 cm and a RMS of about 10 cm. In the upright configuration, the leveling differences may include errors in the GNSS antenna phase center calibration, which are avoided in our technique but not in the classical surveying techniques. These results demonstrate the usefulness of the reflectometry technique to obtain precisely and remotely the leveling between a GNSS antenna and a tide gauge. In addition, this technique can be applied continuously, providing an independent and economical means to monitor the stability of the tide gauge zero.  相似文献   

Thermodynamics and phonon dispersion of pyrope and grossular silicate garnets from ab initio simulations     

Jacopo Baima  Matteo Ferrabone  Roberto Orlando  Alessandro Erba  Roberto Dovesi 《Physics and Chemistry of Minerals》2016,43(2):137-149

The phonon dispersion and thermodynamic properties of pyrope (\(\hbox {Mg}_3\hbox {Al}_2\hbox {Si}_3\hbox {O}_{12}\)) and grossular (\(\hbox {Ca}_3\hbox {Al}_2\hbox {Si}_3\hbox {O}_{12}\) ) have been computed by using an ab initio quantum mechanical approach, an all-electron variational Gaussian-type basis set and the B3LYP hybrid functional, as implemented in the Crystal program. Dispersion effects in the phonon bands have been simulated by using supercells of increasing size, containing 80, 160, 320, 640, 1280 and 2160 atoms, corresponding to 1, 2, 4, 8, 16 and 27 \(\mathbf {k}\) points in the first Brillouin zone. Phonon band structures, density of states and corresponding inelastic neutron scattering spectra are reported. Full convergence of the various thermodynamic properties, in particular entropy (S) and specific heat at constant volume (\(C_\mathrm{{V}}\)), with the number of \(\mathbf {k}\) points is achieved with 27 \(\mathbf {k}\) points. The very regular behavior of the S(T) and \(C_\mathrm{{V}}(T)\) curves as a function of the number of \(\mathbf {k}\) points, determined by high numerical stability of the code, permits extrapolation to an infinite number of \(\mathbf {k}\) points. The limiting value differs from the 27-\(\mathbf {k}\) case by only 0.40 % at 100 K for S (the difference decreasing to 0.11 % at 1000 K) and by 0.29 % (0.05 % at 1000 K) for \(C_\mathrm{{V}}\). The agreement with the experimental data is rather satisfactory. We also address the problem of the relative entropy of pyrope and grossular, a still debated question. Our lattice dynamical calculations correctly describe the larger entropy of pyrope than grossular by taking into account merely vibrational contributions and without invoking “static disorder” of the Mg ions in dodecahedral sites. However, as the computed entropy difference is found to be larger than the experimental one by a factor of 2–3, present calculations cannot exclude possible thermally induced structural changes, which could lead to further conformational contributions to the entropy.  相似文献   

A multi-disciplinary study of deformation of the basaltic cover over fine-grained valley fills: a case study from Eastern Sardinia,Italy     

Rita Deiana  Iginio Dieni  Francesco Massari  Maria Teresa Perri  Matteo Rossi  Alessandro Brovelli 《International Journal of Earth Sciences》2016,105(4):1245-1255

  相似文献   

Erratum to: Melilite-type and melilite-related compounds: structural variations along the join Sr2?x Ba x MgSi2O7 (0?≤?x?≤?2) and high-pressure behavior of the two end-members     

Matteo Ardit  Michele Dondi  Marco Merlini  Giuseppe Cruciani 《Physics and Chemistry of Minerals》2012,39(7):599-599

  相似文献   

Last Glacial Maximum and the Gschnitz stadial in the Maritime Alps according to 10Be cosmogenic dating     

Paolo Roberto Federici  Darryl E. Granger  Adriano Ribolini  Matteo Spagnolo  Marta Pappalardo  Andrew J. Cyr 《Boreas: An International Journal of Quaternary Research》2012,41(2):277-291

  相似文献   

Socioeconomic impacts of environmental risks in the western Makran zone (Chabahar,Iran)     

Pourkerman  Majid  Marriner  Nick  Hamzeh  Mohammad-Ali  Lahijani  Hamid  Morhange  Christophe  Amjadi  Sedigheh  Vacchi  Matteo  Maghsoudi  Mehran  Shah-Hosseini  Majid  Afarin  Mohammad 《Natural Hazards》2022,112(2):1823-1849

Natural Hazards - The western Makran subduction zone is capable of producing considerable tsunami run-up heights that penetrate up to 5 km inland. In this study, we show how climate change...  相似文献   

A new calibration to determine the closure temperatures of Fe‐Mg ordering in augite from nakhlites          下载免费PDF全文

M. Alvaro  M. C. Domeneghetti  A. M. Fioretti  F. Cámara  L. Marinangeli 《Meteoritics & planetary science》2015,50(3):499-507

Recently it has been shown that the relatively low closure temperature (T_c) of 500 (100)°C calculated for augite from Miller Range nakhlite (MIL 03346,13) using the available geothermometers would correspond to a slow cooling rate inconsistent with the petrologic evidence for an origin from a fast‐cooled lava flow. Moreover, previous annealing experiments combined with HR‐SC‐XRD on an augite crystal from MIL 03346 clearly showed that at 600 °C, the Fe²⁺‐Mg degree of order remained unchanged, thus suggesting that the actual T_c is close to this temperature. In order to clarify this discrepancy, we undertook an ex situ annealing experimental study at 700, 800, and 900 °C, until the equilibrium in the intracrystalline Fe²⁺‐Mg exchange is reached, using an augite crystal from Miller Range nakhlite (MIL 03346,13) with a composition of about En₃₆Fs₂₄Wo₄₀. These data allowed us to calculate the following new geothermometer calibration for Martian nakhlites: where The application of this new equation to other Martian nakhlites (NWA 988 and Nakhla) suggests that for augite with composition close to that of MIL 03346, the T_c is up to 170 °C higher with respect to the one calculated using the previous available geothermometer equation, thus suggesting a significantly faster cooling in agreement with petrologic evidence.  相似文献