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101.
We constrain a three-dimensional thermomechanical model of Greenland ice sheet (GrIS) evolution from the Last Glacial Maximum (LGM, 21 ka BP) to the present-day using, primarily, observations of relative sea level (RSL) as well as field data on past ice extent. Our new model (Huy2) fits a majority of the observations and is characterised by a number of key features: (i) the ice sheet had an excess volume (relative to present) of 4.1 m ice-equivalent sea level at the LGM, which increased to reach a maximum value of 4.6 m at 16.5 ka BP; (ii) retreat from the continental shelf was not continuous around the entire margin, as there was a Younger Dryas readvance in some areas. The final episode of marine retreat was rapid and relatively late (c. 12 ka BP), leaving the ice sheet land based by 10 ka BP; (iii) in response to the Holocene Thermal Maximum (HTM) the ice margin retreated behind its present-day position by up to 80 km in the southwest, 20 km in the south and 80 km in a small area of the northeast. As a result of this retreat the modelled ice sheet reaches a minimum extent between 5 and 4 ka BP, which corresponds to a deficit volume (relative to present) of 0.17 m ice-equivalent sea level. Our results suggest that remaining discrepancies between the model and the observations are likely associated with non-Greenland ice load, differences between modelled and observed present-day ice elevation around the margin, lateral variations in Earth structure and/or the pattern of ice margin retreat.  相似文献   
102.
The ice sheet that once covered Ireland has a long history of investigation. Much prior work focussed on localised evidence-based reconstructions and ice-marginal dynamics and chronologies, with less attention paid to an ice sheet wide view of the first order properties of the ice sheet: centres of mass, ice divide structure, ice flow geometry and behaviour and changes thereof. In this paper we focus on the latter aspect and use our new, countrywide glacial geomorphological mapping of the Irish landscape (>39 000 landforms), and our analysis of the palaeo-glaciological significance of observed landform assemblages (article Part 1), to build an ice sheet reconstruction yielding these fundamental ice sheet properties. We present a seven stage model of ice sheet evolution, from initiation to demise, in the form of palaeo-geographic maps. An early incursion of ice from Scotland likely coalesced with local ice caps and spread in a south-westerly direction 200 km across Ireland. A semi-independent Irish Ice Sheet was then established during ice sheet growth, with a branching ice divide structure whose main axis migrated up to 140 km from the west coast towards the east. Ice stream systems converging on Donegal Bay in the west and funnelling through the North Channel and Irish Sea Basin in the east emerge as major flow components of the maximum stages of glaciation. Ice cover is reconstructed as extending to the continental shelf break. The Irish Ice Sheet became autonomous (i.e. separate from the British Ice Sheet) during deglaciation and fragmented into multiple ice masses, each decaying towards the west. Final sites of demise were likely over the mountains of Donegal, Leitrim and Connemara. Patterns of growth and decay of the ice sheet are shown to be radically different: asynchronous and asymmetric in both spatial and temporal domains. We implicate collapse of the ice stream system in the North Channel – Irish Sea Basin in driving such asymmetry, since rapid collapse would sever the ties between the British and Irish Ice Sheets and drive flow configuration changes in response. Enhanced calving and flow acceleration in response to rising relative sea level is speculated to have undermined the integrity of the ice stream system, precipitating its collapse and driving the reconstructed pattern of ice sheet evolution.  相似文献   
103.
104.
Abar al' Uj (AaU) 012 is a clast‐rich, vesicular impact‐melt (IM) breccia, composed of lithic and mineral clasts set in a very fine‐grained and well‐crystallized matrix. It is a typical feldspathic lunar meteorite, most likely originating from the lunar farside. Bulk composition (31.0 wt% Al2O3, 3.85 wt% FeO) is close to the mean of feldspathic lunar meteorites and Apollo FAN‐suite rocks. The low concentration of incompatible trace elements (0.39 ppm Th, 0.13 ppm U) reflects the absence of a significant KREEP component. Plagioclase is highly anorthitic with a mean of An96.9Ab3.0Or0.1. Bulk rock Mg# is 63 and molar FeO/MnO is 76. The terrestrial age of the meteorite is 33.4 ± 5.2 kyr. AaU 012 contains a ~1.4 × 1.5 mm2 exotic clast different from the lithic clast population which is dominated by clasts of anorthosite breccias. Bulk composition and presence of relatively large vesicles indicate that the clast was most probably formed by an impact into a precursor having nonmare igneous origin most likely related to the rare alkali‐suite rocks. The IM clast is mainly composed of clinopyroxenes, contains a significant amount of cristobalite (9.0 vol%), and has a microcrystalline mesostasis. Although the clast shows similarities in texture and modal mineral abundances with some Apollo pigeonite basalts, it has lower FeO and higher SiO2 than any mare basalt. It also has higher FeO and lower Al2O3 than rocks from the FAN‐ or Mg‐suite. Its lower Mg# (59) compared to Mg‐suite rocks also excludes a relationship with these types of lunar material.  相似文献   
105.
This work is part of a project to build an infrared database in order to link IR data of planetary materials (and therefore possible Mercury material) with remote sensing observations of Mercury, which will probably be obtained by the MERTIS instrument on the forthcoming BepiColombo mission. The unique achondrite Northwest Africa (NWA) 7325, which has previously been suggested to represent the first sample from Mercury, was investigated by optical and electron microscopy, and infrared and Raman spectroscopy. In addition, the oxygen, strontium, xenon, and argon isotopes were measured and the abundance of selected trace elements determined. The meteorite is a cumulate rock with subchondritic abundances of HFSE and REE and elevated Sr contents, which underwent a second heating and partial remelting process. Oxygen isotope measurements show that NWA 7325 plots in the ureilite field, close to the ALM‐A trachyandesitic fragment found in the unique Almahata Sitta meteorite breccia. On the other hand, mineralogical investigations of the pyroxenes in NWA 7325 provide evidence for similarities to the lodranites and acapulcoites. Furthermore, the rock is weakly shocked and argon isotope data record ancient (~4.5 Ga) plateau ages that have not been reset. The sample records a cosmogenic exposure age of ~19 Ma. Systematics of Rb‐Sr indicate an extreme early volatile depletion of the precursor material, similar to many other achondrite groups. However, despite its compositional similarities to other meteorite groups, our results suggest that this meteorite is unique and unrelated to any other known achondrite group. An origin for NWA 7325 as a sample from the planet Mercury is not supported by the results of our investigation. In particular, the evidence from infrared spectroscopy indicates that a direct relationship between NWA 7325 and the planet Mercury can be ruled out: no acceptable spectral match between laboratory analyses and remote sensing observations from Mercury has been obtained. However, we demonstrate that infrared spectroscopy is a rapid and nondestructive method to characterize mineral phases and thus an excellent tool for planetary surface characterization in space missions.  相似文献   
106.
An important aspect of shellfish restoration projects is to evaluate whether potential sites are likely to be recolonised naturally once disturbances are removed and habitats are restored. Similarly, if active translocation or reseeding of juveniles or adults is undertaken, it is important to understand whether these introduced populations will be self‐maintaining in future, and whether any seed they produce are likely to be retained within the restored area. We used a combined hydrodynamic and particle tracking model to predict larval dispersion patterns for the common cockle Austrovenus stutchburyi under different hydrodynamic scenarios for seven release locations in Whangarei Harbour, New Zealand. Our results implied that sites varied substantially in their potential for self‐seeding and for exporting seed to other locations. For sites with more restricted dispersal, the model predicted that most larvae originating at these sites would settle inside the release region (68–94% for passive particle simulations), whereas relatively few larvae originating from the other release sites settled at these sites. In contrast, model larvae released from sites exhibiting high connectivity dispersed to all sub‐regions in the harbour, and export outside of the model region was high. Forthcoming field validation of these model predictions will result in better integration of hydrodynamic connectivity in whole estuary restoration programs.  相似文献   
107.
Macroinvertebrate community composition was compared across streams draining catchments dominated by either native bush, agricultural or urban land uses within the Water of Leith stream catchment near Dunedin, New Zealand. Land use was associated with differences in taxon richness and faunal composition of communities present in each stream. The mean abundance levels of Ephemeroptera, Plecoptera, and Trichoptera were highest in native bush catchments, and lowest in urban catchments. In contrast, the mean abundance of Oligochaeta exhibited the opposite pattern. Increasing dominance of the urban and agricultural streams by pollution tolerant taxa was reflected in the Macroinvertebrate Community Index and Quantitative Macroinvertebrate Community Index scores.  相似文献   
108.
The WFD has introduced an international commitment to assess the ecological status of transitional waters (TWs), within which fish communities are a key biological monitoring component. The Transitional Fish Classification Index (TFCI) outlined in this paper uses 10 ecological measures to analyse fish populations caught from various ecological niches using a variety of gear types within the Thames estuary. These reach and method-specific communities are then compared to a reference population created from a 'healthy' population from TWs of a similar type. The results indicate a progressive downstream increase the quality of fish communities, consistent with previous work; variation between methods can be accounted for by gear selectivity. Overall, the TFCI is an effective communication tool for converting ecological information into an easily understood format for managers, policy makers and the general public.  相似文献   
109.
Metamorphic assemblages within Karoo basalt xenoliths, found within volcaniclastic kimberlite of the B/K9 pipe, Damtshaa, Botswana, constrain conditions of kimberlite alteration. Bultfonteinite and chlorite partially replace the original augite-plagioclase assemblage, driven by the serpentinisation of the kimberlite creating strong chemical potential gradients for Si and Mg. Hydrogarnet and serpentine replace these earlier metamorphic assemblages as the deposits cool. The bultfonteinite (ideally Ca2SiO2[OH,F]4) and hydrogarnet assemblages require a water-rich fluid containing F, and imply hydrothermal alteration dominated by external fluids rather than autometamorphism from deuteric fluids. Bultfonteinite and hydrogarnet are estimated to form at temperatures of ca. 350–250°C, which are similar to those for serpentinisation. Alteration within the B/K9 kimberlite predominantly occurs between 250 and 400°C. We attribute these conditions to increased efficiency of mass transfer and chemical reactions below the critical point of water and a consequence of volume-increasing serpentinisation and metasomatic reactions that take place over this temperature range. A comparison of the B/K9 kimberlite with kimberlites from Venetia, South Africa suggests that the composition and mineralogy of included xenoliths affects the alteration assemblages within kimberlite deposits.  相似文献   
110.
Microbial SO42− reduction limits accumulation of aqueous As in reducing aquifers where the sulfide that is produced forms minerals that sequester As. We examined the potential for As partitioning into As- and Fe-sulfide minerals in anaerobic, semi-continuous flow bioreactors inoculated with 0.5% (g mL−1) fine-grained alluvial aquifer sediment. A fluid residence time of three weeks was maintained over a ca. 300-d incubation period by replacing one-third of the aqueous phase volume of the reactors with fresh medium every seven days. The medium had a composition comparable to natural As-contaminated groundwater with slightly basic pH (7.3) and 7.5 μM aqueous As(V) and also contained 0.8 mM acetate to stimulate microbial activity. Medium was delivered to a reactor system with and without 10 mmol L−1 synthetic goethite (α-FeOOH). In both reactors, influent As(V) was almost completely reduced to As(III). Pure As-sulfide minerals did not form in the Fe-limited reactor. Realgar (As4S4) and As2S3(am) were undersaturated throughout the experiment. Orpiment (As2S3) was saturated while sulfide content was low (∼50 to 150 μM), but precipitation was likely limited by slow kinetics. Reaction-path modeling suggests that, even if these minerals had formed, the dissolved As content of the reactor would have remained at hazardous levels. Mackinawite (Fe1 + xS; x ? 0.07) formed readily in the Fe-bearing reactor and held dissolved sulfide at levels below saturation for orpiment and realgar. The mackinawite sequestered little As (<0.1 wt.%), however, and aqueous As accumulated to levels above the influent concentration as microbial Fe(III) reduction consumed goethite and mobilized adsorbed As. A relatively small amount of pyrite (FeS2) and greigite (Fe3S4) formed in the Fe-bearing reactor when we injected a polysulfide solution (Na2S4) to a final concentration of 0.5 mM after 216, 230, 279, and 286 days. The pyrite, and to a lesser extent the greigite, that formed did sequester As from solution, containing 0.84 and 0.23 wt.% As on average, respectively. Our results suggest that As precipitation during Fe-sulfide formation in nature occurs mainly in conjunction with pyrite formation. Our findings imply that the effectiveness of stimulating microbial SO42− reduction to remediate As contamination may be limited by the rate and extent of pyrite formation and the solubility of As-sulfides.  相似文献   
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