Equivocal carbonatite markers in the mantle xenoliths of the Patagonia backarc: the Gobernador Gregores case (Santa Cruz Province,Argentina)     

Giorgio?RivalentiEmail author  Alberto?Zanetti  Maurizio?Mazzucchelli  Riccardo?Vannucci  Carlos?A.?Cingolani 《Contributions to Mineralogy and Petrology》2004,147(6):647-670

Amphibole ± phlogopite ± apatite-bearing mantle xenoliths at Gobernador Gregores display modal, bulk-rock and phase geochemical characteristics held as indicators of carbonatitic metasomatism. However, part of these xenoliths has high TiO₂/Al₂O₃ and those displaying the most pronounced carbonatitic geochemical markers modally trend towards harzburgite. Bulk-rock, clinopyroxene and amphibole show Zr, Hf and Ti negative anomalies, which increase at decreasing Na₂O and high field strength elements (HFSE) concentrations. Steady variation trends between xenoliths which have and do not have carbonatitic characteristics suggest a control by reactive porous flow of only one agent, inferred to be initially a ne-normative hydrous basalt (because of the presence of wehrlites) evolving towards silica saturation. Variation trends exhibit cusps when amphibole appears in the mode. Appearance of amphibole may explain the Ti anomaly variations, but not those of Zr and Hf. Numerical modelling [Plate Model (Vernières et al. in J Geophys Res 102:24771–24784, 1997)] gives results consistent with the observed geochemical features by assuming the presence of loveringite. Modest HFSE anomalies in the infiltrating melt may be acquired during percolation in the garnet-facies.In memory of Carlo Rivalenti  相似文献   

The effect of organic compounds in the oxidation kinetics of Cr(III) by H₂O₂     

Maurizio Pettine  Francesca Gennari  Frank J. Millero 《Geochimica et cosmochimica acta》2008,72(23):5692-5707

The oxidation of Cr(III) has been studied in NaCl solutions in the presence of two siderophore models, acetohydroxamic acid (Aha) and benzohydroxamic acid (Bha), the natural siderophore Desferal (DFOB) and the synthetic aminocarboxilate (ethylenedinitrilo)-tetra-acetic acid (EDTA) as a function of pH (8-9), ionic strength (0.01-2 M) and temperature (10-50 °C), at different Cr(III)-organic compound ratios. The addition of Aha and Bha caused the rates to increase at low ligand/Cr(III) ratios and decrease at high ratios. The variation of the pseudo first order rate constant (k₁) as a function of the ligand concentration has been attributed to the formation of three Cr(III)-organo species (1:1, 1:2, 1:3), which can form in the presence of monohydroxamic acids. A kinetic model has been developed that gives a value of 600 (min⁻¹) for the pseudo first order rate constant k_1CrAha²⁺ and values approaching zero for and k_1CrAha3. These kinetic results demonstrate that these monohydroxamic acids are able to bind with Cr(III) under experimental conditions that may occur in natural waters and can increase the oxidation rates of Cr(III) with H₂O₂ by a factor of 3.5 at an Aha/Cr(III) ratio of about 50-100.The monohydroxamic acids also affect the rates on aged products of Cr(III), suggesting that these ligands are able to affect the oxidation rates by releasing reactive Cr(III). DFOB and EDTA do not have a great effect on the oxidation of Cr(III) with H₂O₂. This is thought to be due to the much longer times they need to form complexes with Cr(III) compared to Aha and Bha. The rates for the formation of DFOB and EDTA complexes with Cr(III) are not competitive with the rates of the formation of aged Cr(III). After allowing Cr(III) and DFOB to react for 5 days to form the complex, reaction rates of Cr(III) with H₂O₂ appear to be lowered probably because of steric hindrance of the chelated Cr(III).  相似文献   

Depth and morphology of reflectors from the non-linear inversion of arrival-time and waveform semblance data. Part I: method and applications to synthetic data     

Maurizio Vassallo  Aldo Zollo 《Geophysical Prospecting》2008,56(4):527-540

We propose a two-dimensional, non-linear method for the inversion of reflected/converted traveltimes and waveform semblance designed to obtain the location and morphology of seismic reflectors in a lateral heterogeneous medium and in any source-to-receiver acquisition lay-out. This method uses a scheme of non-linear optimization for the determination of the interface parameters where the calculation of the traveltimes is carried out using a finite-difference solver of the Eikonal equation, assuming an a priori known background velocity model. For the search for the optimal interface model, we used a multiscale approach and the genetic algorithm global optimization technique. During the initial stages of inversion, we used the arrival times of the reflection phase to retrieve the interface model that is defined by a small number of parameters. In the successive steps, the inversion is based on the optimization of the semblance value determined along the calculated traveltime curves. Errors in the final model parameters and the criteria for the choice of the best-fit model are also estimated from the shape of the semblance function in the model parameter space. The method is tested and validated on a synthetic dataset that simulates the acquisition of reflection data in a complex volcanic structure. This study shows that the proposed inversion approach is a valid tool for geophysical investigations in complex geological environments, in order to obtain the morphology and positions of embedded discontinuities.  相似文献   

Flow analysis in a channel with flexible vegetation using double-averaging method     

Maurizio Righetti 《Acta Geophysica》2008,56(3):801-823

The paper addresses the problem of the resistance due to vegetation in an open channel flow, characterized by partially and fully submerged vegetation formed by colonies of bushes. The flow is characterized by significant spatial variations of velocity between vertical profiles that make the traditional approach based on time averaging of turbulent fluctuations inconvenient. A more useful procedure, based on time and spatial averaging (Double-Averaging Method) is applied for the flow field analysis and characterization. The vertical distribution of mean velocity and turbulent stresses at different spatial locations has been measured with a 3D Acoustic Doppler Velocimeter (ADV) for two different vegetation densities where fully submerged real bushes (salix pentandra) have been used. Velocity measurements were completed together with the measurements of drag exerted on the flow by bushes at different flow depths. The analysis of velocity measurements allows depicting the fundamental characteristics of both the mean flow field and turbulence. The experimental data show that the contribution of form-induced stresses to the momentum balance cannot be neglected. The mean velocity profiles and the spatially averaged turbulent intensity profiles allow inferring that the vegetation density is a driving parameter for the development of a mixing layer at the canopy top in the case of submerged vegetation. Moreover, the net upward turbulent momentum flux, evaluated with the methodology proposed by Lu and Willmarth (1973), appears to be damped for increased vegetation density; this finding can rationally explain the reduction of the suspended sediment transport capacity typically observed in free surface flows over a vegetated bed.  相似文献   

Gravity inversion by the Multi‐HOmogeneity Depth Estimation method for investigating salt domes and complex sources          下载免费PDF全文

Mahak Singh Chauhan  Maurizio Fedi  Mrinal K. Sen 《Geophysical Prospecting》2018,66(Z1):175-191

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Thorough wetting and drainage of a peat lysimeter in a climate change scenario     

Maurizio Previati  Davide Canone  Edoardo Iurato  Davide Gisolo  Stefano Ferrari  Pietro Teatini  Mario Putti  Stefano Ferraris 《水文研究》2020,34(5):1269-1284

A peat deposit (Zennare basin, Venice coastland, Italy) was monitored in previous field studies to investigate the hydrological response of organic soil to meteorological dynamics. Field tests and modelling predictions highlighted the risk of the complete loss of this peat layer during the next 50 years, due to oxidation enhanced by the increased frequency of warmer periods. Unfortunately, despite the considerable impacts that are expected to affect peat bogs (in this area and worldwide), only a few experimental studies have been carried out to assess the hydrologic response of peat to severe water scarcity. Because of that, an undisturbed 0.7 m³ peat monolith was collected, transferred to the laboratory and instrumented. The total weight (representative of the water content dynamics of the peat monolith as a whole), and two vertical profiles of matric potentials and water content were monitored in controlled water-scarce conditions. After an extended air-drying period, the monolith was used as an undisturbed peat lysimeter and a complete cycle of wetting and drainage was performed. Supplementary measurements of matric potential ψ and water content θ were collected by testing peat subsamples on a suction table apparatus. A set of water retention curves was determined in a range of matric potentials broader (ψ down to −7 m) than the current natural conditions in the field (minimum ψ = −1 m). While water content at saturation showed values similar to those in the original natural conditions (θ ≅ 0.8), a remarkable loss of water holding capacity (even for low potentials) has been highlighted, especially in deep layers that are now permanently below the water table. The retention curves changed shape and values, with a more pronounced hysteresis visible in an increasing distance between wetting and drying data. Hydraulic non-equilibrium between the water content and water potential could be a possible cause and it is worth modelling in future studies. The parameters of the van Genuchten retention curves were obtained for the wetting and the drying phases.  相似文献   

A multidisciplinary study of the Cape Peloro brackish area (Messina, Italy): characterisation of trophic conditions, microbial abundances and activities     

Marcella Leonardi  Filippo Azzaro  Maurizio Azzaro  Gabriella Caruso  Monique Mancuso  Luis Salvador Monticelli  Giovana Maimone  Rosabruna La Ferla  Francesco Raffa  & Renata Zaccone 《Marine Ecology》2009,30(S1):33-42

In the framework of the VECTOR DIVCOST Project, a 2-year investigation was started in 2006, with the aim of testing the sensibility of microbial parameters to environmental changes and of assessing whether they can provide information about functional changes in the carbon cycle. The investigation was performed in the surface waters of two small brackish ponds (Ganzirri and Faro), located in the Cape Peloro transitional area (Sicily, Italy). The seasonal changes in both the microbial compartment [bacterioplankton, vibrios, exoenzymatic hydrolysis of proteins and polysaccharides, bacterial secondary production (HBP) and community respiration] and the trophic state of suspended matter [total suspended matter (TSM), particulate organic carbon (POC), particulate organic nitrogen (PON), C/N] were analysed in relation to the hydrological characteristics [temperature, salinity, oxygen, fluorescence, NH₄, NO₂, NO₃, PO₄]. Despite marked differences in the nutritional input and the diversification in both carbon budget and trophic level, the two ponds show similar trends in many of the investigated factors, hardly influenced by seasonal variations. Temporally coupled trends were observed for some parameters (enzyme activities, vibrios abundances, respiratory activity), whereas others (POC, PON, heterotrophic bacterial production, bacterioplankton) showed a seasonal shift between the two lakes. The different behaviour found for the some biotic parameters suggests that their response to environmental conditions may be modulated differently between the two lakes, which, despite their spatial proximity and reciprocal connection, do not always show contemporaneous functional processes.  相似文献   

Keratose-dominated sponge grounds from temperate mesophotic ecosystems (NW Mediterranean Sea)     

Francesco Enrichetti  Giorgio Bavestrello  Federico Betti  Martina Coppari  Margherita Toma  Roberto Pronzato  Simonepietro Canese  Marco Bertolino  Gabriele Costa  Maurizio Pansini  Marzia Bo 《Marine Ecology》2020,41(6):e12620

Differently from the North Atlantic Ocean, only few examples of sponge grounds are known from the Mediterranean Sea, mainly thriving in the deep sea. In this study, a novel temperate mesophotic ecosystem dominated by massive keratose sponges is reported from the Ligurian deep continental shelf. An extensive Remotely Operated Vehicle (ROV) survey allowed to study the structure and large-scale distribution of this biocoenosis. The sponge grounds here described are highly fragmented, being formed by a large number of dense, discrete aggregations of Sarcotragus foetidus (up to 7.7 specimens/m²) and other sponges, including Spongia lamella and Axinella polypoides. They mainly occur on flat, patchy and highly silted hardgrounds between 40 and 70 m depth. These sponge-dominated ecosystems have an exceptionally wide spatial distribution, estimated to cover up to nearly 200 hectares, with the largest sponge grounds occurring along the westernmost part of the Ligurian coast, probably in relation to more suitable oceanographic conditions. The dominant sponge species reach considerable heights (up to 65 cm), greatly increasing the habitat three-dimensionality and acting as poles of attraction for a diverse sessile and vagile fauna. In addition, the high abundance of the keratose sponge grounds at mesophotic depths might represent a larval source for shallow-water populations that in the last decades have been stricken by several mass mortality events.  相似文献   

MgAl2O4 spinels from Allende and NWA 763 carbonaceous chondrites: Structural refinement,cooling history,and trace element contents     

Davide Lenaz  Vanni Lughi  Diego Perugini  Maurizio Petrelli  Gianluca Turco  Birger Schmitz 《Meteoritics & planetary science》2019,54(12):3089-3100

MgAl₂O₄ spinels from Allende and NWA 763 carbonaceous chondrites were studied by X‐ray single crystal diffraction, SEM, electron microprobe, LA‐ICP‐MS, and Raman spectroscopy. Those from Allende are almost pure, but, in one case, we found a strong FeO_tot zonation. Spinels from NWA 763 show Mg‐Fe²⁺ substitutions. Almost pure MgAl₂O₄ spinels from both meteorites underwent slow cooling and reached their intracrystalline closure temperature (T_c) in the range 460–520 °C. The NWA 763 spinel with higher FeO content shows a T_c of about 720 °C. X‐ray single crystal diffraction and Raman spectroscopy suggest a slow cooling and an ordered structure with trivalent cations in M site and divalent in T site. Among the trace elements, Ti and Co are enriched with respect to the terrestrial analogs, while Mn, Ni, and Sn show intermediate values between different terrestrial occurrences. Vanadium cannot be used as a tracer of extraterrestrial origin as for Cr‐spinels, because its content is similar in extraterrestrial and terrestrial spinels. In the zoned crystal from Allende, Co show a strong zonation similar to that of FeO.  相似文献   

Insights on the spreading of the Tyrrhenian Sea from the magnetic anomaly pattern     

Giovanni Florio  Maurizio Fedi  Federico Cella 《地学学报》2011,23(2):127-133

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