ESEEM of industrial silica-bearing powders: reactivity of defects during wet processing in the ceramics production     

Maurizio Romanelli  Francesco Di Benedetto  Gabriele Fornaciai  Massimo Innocenti  Giordano Montegrossi  Luca A. Pardi  Alfonso Zoleo  Fabio Capacci 《Physics and Chemistry of Minerals》2015,42(5):363-372

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Magnetic properties and cation ordering of nanopowders of the synthetic analogue of kuramite, Cu3SnS4     

Francesco Di Benedetto  Daniele Borrini  Andrea Caneschi  Gabriele Fornaciai  Massimo Innocenti  Alessandro Lavacchi  Carlo Andrea Massa  Giordano Montegrossi  Werner Oberhauser  Luca A. Pardi  Maurizio Romanelli 《Physics and Chemistry of Minerals》2011,38(6):483-490

An extensive characterisation of the magnetic properties of synthetic powders of kuramite, with formal composition Cu₃SnS₄, was performed. Powders were investigated through superconducting quantum interference device (SQUID) magnetometry, electron paramagnetic resonance (EPR) spectroscopy, X-ray powder diffraction (XRPD), scanning and transmission electron microscopies (SEM and TEM) and microanalysis. SEM and TEM reveal the presence of nanodimensioned particles. XRPD clearly shows that Cu₃SnS₄ crystallised in a cubic sphalerite-type structural model, in spite of the stannite-type tetragonal structure described for the natural phase. This difference arises from a full random distribution of cations. Synthetic kuramite nanopowders exhibit a marked paramagnetism, originated by the presence of Cu(II), definitely assessed by EPR measurements. Moreover, the overall magnetic behaviour of the sample cannot be simply ascribed to diluted paramagnetism, and this suggests the presence of strong superexchange interactions among Cu(II) ions even at room temperature. The main consequences of these results are the definitive assessment of the chemical formula Cu(I)₂Cu(II)SnS₄ and of a random distribution of Cu(II), Cu(I) and Sn(IV) ions within the available tetrahedral sites.  相似文献   

Chemical Analysis of Iron Meteorites Using a Hand‐Held X‐Ray Fluorescence Spectrometer          下载免费PDF全文

Maurizio Gemelli  Massimo D'Orazio  Luigi Folco 《Geostandards and Geoanalytical Research》2015,39(1):55-69

We evaluate the performance of a hand‐held XRF (HHXRF) spectrometer for the bulk analysis of iron meteorites. Analytical precision and accuracy were tested on metal alloy certified reference materials and iron meteorites of known chemical composition. With minimal sample preparation (i.e., flat or roughly polished surfaces) HHXRF allowed the precise and accurate determination of most elements heavier than Mg, with concentrations > 0.01% m/m in metal alloy CRMs, and of major elements Fe and Ni and minor elements Co, P and S (generally ranging from 0.1 to 1% m/m) in iron meteorites. In addition, multiple HHXRF spot analyses could be used to determine the bulk chemical composition of iron meteorites, which are often characterised by sulfide and phosphide accessory minerals. In particular, it was possible to estimate the P and S bulk contents, which are of critical importance for the petrogenesis and evolution of Fe‐Ni‐rich liquids and iron meteorites. This study thus validates HHXRF as a valuable tool for use in meteoritics, allowing the rapid, non‐destructive (a) identification of the extraterrestrial origin of metallic objects (i.e., archaeological artefacts); (b) preliminary chemical classification of iron meteorites; (c) identification of mislabelled/unlabelled specimens in museums and private collections and (d) bulk analysis of iron meteorites.  相似文献   

Hydrodynamic and isotopic investigations for evaluating the mechanisms and amount of groundwater seepage through a rockslide dam     

Marco Petitta  Gabriele Scarascia Mugnozza  Maurizio Barbieri  Gianluca Bianchi Fasani  Carlo Esposito 《水文研究》2010,24(24):3510-3520

This study addresses the influence of landslide dams on surface water drainage and groundwater flow. In the study area of Scanno Lake and Sagittario River (Central Italy), a limestone rockslide‐avalanche formed a lake, which has an outlet that is occasionally active, showing infiltration into the rockslide dam. Several springs are present at the lake's base and are partly fed by seepage through the rockslide debris. Piezometric surveys, discharge measurements, pumping tests and chemical analyses are tools used to build a conceptual model of the groundwater flow and to evaluate the flow through the rockslide debris. Seasonal water isotopic signatures validate the assumed model, showing a mixing of infiltration recharge and groundwater seepage throughout the rockslide debris. Various recharge areas have been found for springs, pointing out those directly fed by the rockslide debris aquifer. Hypotheses about seasonal groundwater mixing between the regional carbonate aquifer and the rockslide debris aquifer are supported by isotope results. Seasonal changes in groundwater table level due to recharge and surface losses from seasonal outlet have been correlated with isotopic groundwater composition from the rockslide debris aquifer and the downstream springs; this relationship highlights the role of the rockslide dam body on the hydrodynamics of the studied area. Relationships between surface waters and groundwater in the area have been completely understood on the basis of water isotopic fingerprinting, finally obtaining a complete evaluation of groundwater renewable resources and its regimen. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Effects of limestone petrography and calcite microstructure on OPC clinker raw meals burnability     

Galimberti  Matteo  Marinoni  Nicoletta  Della Porta  Giovanna  Marchi  Maurizio  Dapiaggi  Monica 《Mineralogy and Petrology》2017,111(5):793-806

Mineralogy and Petrology - Limestone represents the main raw material for ordinary Portland cement clinker production. In this study eight natural limestones from different geological environments...  相似文献   

Structural integrity of Ellisolandia elongata reefs: A mechanical approach to compare tensile strengths in natural and controlled environments          下载免费PDF全文

Federica Ragazzola  Paride Fabbri  Matteo Scafè  Maurizio Florio  Matteo Nannini  Chiara Lombardi 《Marine Ecology》2017,38(5)

Geniculate coralline algae are oases of biodiversity, providing nursery areas and shelter for the species that live amongst their fronds. The key to their success in the inter‐tidal is the ability to withstand hydrodynamic forces. Under culturing conditions most of the physical and ecological stressors such as intense hydrodynamic forces and grazing are extremely reduced, thus affecting species mechanical properties and their response to external threats. The aim of the present study was to investigate tensile mechanical properties of clusters of fronds of Ellisolandia elongata from natural (sheltered and exposed reef) and culturing conditions (after 1 month of culturing). The tensile test showed that the first failure stress (σ_I) was not significantly different between the natural and culturing conditions, indicating that the two reefs (sheltered and exposed) were characterized by the same distribution of pre‐existing, inherent structural flaws. Interestingly, the σ_max (maximum stress before rupture) was significantly different between the two conditions, with the culturing condition being more resistant to average load compared to the natural conditions. The maximum stress before rupture (σ_max) showed the influence of the environment in reducing the strength and elasticity of the fronds.  相似文献   

Dynamic response and optimal design of structures with large mass ratio TMD     

Maurizio De Angelis  Salvatore Perno  Anna Reggio 《地震工程与结构动力学》2012,41(1):41-60

This paper investigates the dynamic behavior and the seismic effectiveness of a non‐conventional Tuned Mass Damper (TMD) with large mass ratio. Compared with conventional TMD, the device mass is increased up to be comparable with the mass of the structure to be protected, aiming at a better control performance. In order to avoid the introduction of an excessive additional weight, masses already present on the structure are converted into tuned masses, retaining structural or architectural functions beyond the mere control function. A reduced order model is introduced for design purposes and the optimal design of a large mass ratio TMD for seismic applications is then formulated. The design method is specifically developed to implement High‐Damping Rubber Bearings (HDRB) to connect the device mass to the main structure, taking advantage of combining stiffness and noticeable damping characteristics. Ground acceleration is modeled as a Gaussian random process with white noise power spectral density. A numerical searching technique is used to obtain the optimal design parameter, the frequency ratio alpha, which minimizes the root‐mean‐square displacement response of the main structure. The study finally comprises shaking table tests on a 1:5 scale model under a wide selection of accelerograms, both artificial and natural, to assess the seismic effectiveness of the proposed large mass ratio TMD. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Multiridge Euler deconvolution   总被引：1，自引：0，他引：1  

Giovanni Florio  Maurizio Fedi 《Geophysical Prospecting》2014,62(2):333-351

Potential field interpretation can be carried out using multiscale methods. This class of methods analyses a multiscale data set, which is built by upward continuation of the original data to a number of altitudes conveniently chosen. Euler deconvolution can be cast into this multiscale environment by analysing data along ridges of potential fields, e.g., at those points along lines across scales where the field or its horizontal or vertical derivative respectively is zero. Previous work has shown that Euler equations are notably simplified along any of these ridges. Since a given anomaly may generate one or more ridges we describe in this paper how Euler deconvolution may be used to jointly invert data along all of them, so performing a multiridge Euler deconvolution. The method enjoys the stable and high‐resolution properties of multiscale methods, due to the composite upward continuation/vertical differentiation filter used. Such a physically‐based field transformation can have a positive effect on reducing both high‐wavenumber noise and interference or regional field effects. Multiridge Euler deconvolution can also be applied to the modulus of an analytic signal, gravity/magnetic gradient tensor components or Hilbert transform components. The advantages of using multiridge Euler deconvolution compared to single ridge Euler deconvolution include improved solution clustering, increased number of solutions, improvement of accuracy of the results obtainable from some types of ridges and greater ease in the selection of ridges to invert. The multiscale approach is particularly well suited to deal with non‐ideal sources. In these cases, our strategy is to find the optimal combination of upward continuation altitude range and data differentiation order, such that the field could be sensed as approximately homogeneous and then characterized by a structural index close to an integer value. This allows us to estimate depths related to the top or the centre of the structure.  相似文献   

Nearshore bar migration and sediment-induced buoyancy effects     

Silvia Falchetti  Daniel C. Conley  Maurizio Brocchini  Steve Elgar 《Continental Shelf Research》2010

A 1-D General Ocean Turbulence Model that includes the effects of sediment-induced stratification is shown to simulate the observed onshore and offshore migration of a nearshore sandbar. The only two free parameters of the model, the bed reference concentration and the sediment diffusivity, are taken from the literature, rather than tuned to the data used here. The model results suggest that predictions of onshore bar migration, in which wave-induced sediment transport confined to within a few centimeters of the bottom dominates, are not greatly affected by accounting for buoyancy effects. The model results also suggest that both mean flows and waves transport sediment during offshore bar migration, with different components of transport dominating at different cross-shore locations across the bar-trough bathymetry. Neglecting the effects of sediment-induced stratification results in higher model skill during the largest waves, likely because the excess turbulence production simulated by the non-stratified model is counterbalanced by neglected breaking-wave-generated turbulence. Considering both onshore and offshore migration, the model that includes sediment-induced stratification has higher skill than the model without stratification.  相似文献   

Research Note: Compact Depth from Extreme Points: a tool for fast potential field imaging          下载免费PDF全文

Jamaledin Baniamerian  Maurizio Fedi  Behrooz Oskooi 《Geophysical Prospecting》2016,64(5):1386-1398

We propose a fast method for imaging potential field sources. The new method is a variant of the “Depth from Extreme Points,” which yields an image of a quantity proportional to the source distribution (magnetization or density). Such transformed field is here transformed into source‐density units by determining a constant with adequate physical dimension by a linear regression of the observed field versus the field computed from the “Depth from Extreme Points” image. Such source images are often smooth and too extended, reflecting the loss of spatial resolution for increasing altitudes. Consequently, they also present too low values of the source density. We here show that this initial image can be improved and made more compact to achieve a more realistic model, which reproduces a field consistent with the observed one. The new algorithm, which is called “Compact Depth from Extreme Points” iteratively produces different source distributions models, with an increasing degree of compactness and, correspondingly, increasing source‐density values. This is done through weighting the model with a compacting function. The compacting function may be conveniently expressed as a matrix that is modified at any iteration, based on the model obtained in the previous step. At any iteration step the process may be stopped when the density reaches values higher than prefixed bounds based on known or assumed geological information. As no matrix inversion is needed, the method is fast and allows analysing massive datasets. Due to the high stability of the “Depth from Extreme Points” transformation, the algorithm may be also applied to any derivatives of the measured field, thus yielding an improved resolution. The method is investigated by application to 2D and 3D synthetic gravity source distributions, and the imaged sources are a good reconstruction of the geometry and density distributions of the causative bodies. Finally, the method is applied to microgravity data to model underground crypts in St. Venceslas Church, Tovacov, Czech Republic.  相似文献