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This paper describes the design of a star sensor based upon a high dynamic range CCD in order to reach an arcsec-level attitude determination in balloon-borne missions. A custom star identification software was developed and laboratory-tested on a prototype assembled using commercial components. A set of numerical simulations have been carried out to study the dependence on the pointing precision of the centroid position accuracy, the number of detected stars and the effect of the image focusing. Moreover, the role of the electronic noise and the discrete pixel structure on the light signals is identified by the analysis of numerical simulations. Laboratory tests confirm that the arcsec pointing accuracy with a 1 Hz update rate can be achieved with our combination of custom-developed software and selected hardware components.  相似文献   
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Mineralogy and Petrology - Limestone represents the main raw material for ordinary Portland cement clinker production. In this study eight natural limestones from different geological environments...  相似文献   
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A new method for analysis of acidic polar compounds, is described and discussed. It allows the simultaneous quantification of carboxylic acids, phenols and carbazoles and combines accuracy with a short turnaround time, a requirement strictly necessary for industrial applications. Routinely use of this methodology (more than 50 applications in many different sedimentary basins) has supplied many important pieces of information about oil origin, maturity, biodegradation and, in particular, has allowed to define a molecular migration index (MMI), based on relative abundance of phenol and alkyl phenols. The combination of well-established geochemical tools focused on saturated and aromatic fractions (such as biomarkers, compound specific isotope ratio analysis, and GC fingerprinting) with this methodology results in the definition of an integrated interpretative sequence. This last enhances the quality of interpretations through cross-checks and permits a better exploitation of oil samples by using also their less explored fraction, i.e. the polar compounds. Application results of this methodology are only shortly mentioned in this paper, which is mainly focused on analytical aspects. The results will be more extensively discussed in a future publication.  相似文献   
4.
This paper deals with natural temperature records in the heavy (asphaltenes) and the light fractions (C7—light hydrocarbons) of petroleum. Two sets of marine oils formed from different source rocks and petroleum systems were studied using asphaltene kinetics and light hydrocarbon analysis. Both fractions have been reported to contain information about the temperature the respective oils have been exposed to in the subsurface. These indicated temperatures generally correspond to the conditions in the source rock when expulsion occurred. Bulk kinetic analysis of reservoir oil asphaltenes as well as light hydrocarbon (LH) analysis (of dimethylpentanes) were used here in order to evaluate the expulsion temperatures. Surprisingly, when considering information coming from both fractions, an inverse trend between LHs expulsion temperatures (Ctemp) and asphaltenes (Tasph.) can be observed—high Tasph (asphaltene temperatures) occur with low LH Ctemp (light hydrocarbon expulsion temperatures) and low Tasph can be observed when Ctemp is high. These differences are of fundamental importance for the use of such geochemical data in calibrating numerical basin models. The reason for this inverse behaviour is possibly due to the different expulsion behaviour of light hydrocarbons and the heavy fraction of oils, especially when the source rocks contain only moderate amounts of organic matter. In addition it has to be considered that the temperature predictions obtained using asphaltene kinetic analysis are related to the onset temperature of petroleum expulsion, while light hydrocarbons provide, at best, average expulsion temperatures.  相似文献   
5.
In this study, we performed leaching experiments for timescales of hours-to-months in deionized water on fresh volcanic ash from Mt. Etna (Italy) and Popocatépetl (Mexico) volcanos to monitor Fe release as a function of ash mineral chemistry and size, with the aim of clarifying Fe release mechanisms and eventually evaluating the impact of volcanic ash on marine and lacustrine environments. To define sample mineralogy and Fe speciation, inclusive characterization was obtained by means of XRF, SEM, XRPD, EELS and Mössbauer spectroscopies. For Etna and Popocatépetl samples, glass proportions were quantified at 73 and 40%, Fe2O3 total contents at 11.6–13.2 and 5.8 wt%, and Fe3+/FeTot ratios at 0.33 and 0.23, respectively. Leaching experiments showed that significant amounts of iron, ~?30 to 150 and ~?750 nmol g?1 l?1 for pristine Etna and Popocatépetl samples, respectively, are released within the first 30 min as a function of decreasing particle size (from 1 to 0.125 mm). The Popocatépetl sample showed a very sustained Fe release (up to 10 times Etna samples) all along the first week, with lowest values never below 400 nmol g?1 l?1 and a maximum of 1672 nmol g?1 l?1 recorded after 5 days. This sample, being composed of very small particles (average particle size 0.125 mm) with large surface area, likely accumulated large quantities of Fe-bearing sublimates that quickly dissolved during leaching tests, determining high Fe release and local pH decrease (that contributed to release more Fe from the glass) at short timescale (hours-to-days). The fractional Fe solubility (FeS) was 0.004–0.011 and 0.23% for Etna and Popocatépetl samples, respectively, but no correlation was found between Fe released in solution and either ash Fe content, glass/mineral ratio or mineral assemblage. Results obtained suggest that volcanic ash chemistry, mineralogy and particle size assume a relevant role on Fe release mostly in the medium-to-long timescale, while Fe release in the short timescale is dominated by dissolution of surface sublimates (formed by physicochemical processes occurring within the eruption plume and volcanic cloud) and the effects of such a dissolution on the local pH conditions. For all samples, a moderate to sustained Fe release occurred for leaching times comparable with their residence time within the euphotic zone of marine and lacustrine environments (variable from few minutes to few hours), revealing their possible contribution to increase Fe bioavailability.  相似文献   
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