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51.
52.
The trophic status classification of coastal waters at the European scale requires the availability of harmonised indicators and procedures. The composite trophic status index (TRIX) provides useful metrics for the assessment of the trophic status of coastal waters. It was originally developed for Italian coastal waters and then applied in many European seas (Adriatic, Tyrrhenian, Baltic, Black and Northern seas). The TRIX index does not fulfil the classification procedure suggested by the WFD for two reasons: (a) it is based on an absolute trophic scale without any normalization to type-specific reference conditions; (b) it makes an ex ante aggregation of biological (Chl-a) and physico-chemical (oxygen, nutrients) quality elements, instead of an ex post integration of separate evaluations of biological and subsequent chemical quality elements. A revisitation of the TRIX index in the light of the European Water Framework Directive (WFD, 2000/60/EC) and new TRIX derived tools are presented in this paper. A number of Italian coastal sites were grouped into different types based on a thorough analysis of their hydro-morphological conditions, and type-specific reference sites were selected. Unscaled TRIX values (UNTRIX) for reference and impacted sites have been calculated and two alternative UNTRIX-based classification procedures are discussed. The proposed procedures, to be validated on a broader scale, provide users with simple tools that give an integrated view of nutrient enrichment and its effects on algal biomass (Chl-a) and on oxygen levels. This trophic evaluation along with phytoplankton indicator species and algal blooms contribute to the comprehensive assessment of phytoplankton, one of the biological quality elements in coastal waters.  相似文献   
53.
The chemical composition of PM10 and PM2.5 samples collected during two seasonal monitoring campaigns at residential, urban and industrial Apulia Region- sites was investigated. Ionic fraction, carbonaceous compounds and Polycyclic Aromatic Hydrocarbons were determined for all samples. High correlations among PM data collected in the investigated sites suggested the regional character of particulate matter. It was also confirmed by five days back trajectories analysis. Moreover, no significant seasonal trend in PM mass concentration was observed in the investigated sites. These results, relevant for the area under investigations, were not observed in the North of Italy and Europe and allow to conclude that PM10 and PM2.5 cannot be considered ‘good’ indicators for the evaluation of local anthropic contributions to air quality. On the contrary, the high levels of Polycyclic Aromatic Hydrocarbons found in Taranto sampling sites suggested that PAHs can be a better indicator for this purpose. This result is also relevant in order to weigh the importance of industrial area and to suggest right policy control to decision makers.  相似文献   
54.
 Field, mineralogical and petrological data are presented on a newly found carbonatite occurrence associated with “kamafugite” lava at Cupaello, central Italy. This carbonatite occurrence is part of the Late Pleistocene Umbria-Latium ultra-alkaline district (ULUD) which extends southwards within the Apennines to Mount Vulture, delineating an important magmatic province along the most peripheral belt of the Tyrrhenian extensional tectonic system. This province is distinct, but probably related genetically with the more abundant and common leucite-bearing assemblages of the Roman Comagmatic Region and represents the first reported occurrence of carbonatite assemblages in the Mediterranean Basin. The Cupaello suite indicates that primary or near-primary mantle silicate melts of “kamafugitic” composition are transitional with Ca-carbonatite liquid and provides direct evidence of immiscibility of carbonatite from “kamafugite” magma. It is inferred that a primary mantle origin of Ca-carbonatites is conditional upon a potential silicate magma that may be coupled with the carbonatite, but may not have reached the surface. The data indicate a strong genetic link between ULUD Ca-carbonatites and some African analogues, supporting the view that their genesis depends on similar source and associated tectonic conditions. Received: 17 January 1995 / Accepted: 14 June 1995  相似文献   
55.
Summary The magnetosphere depends on the astronomical orientation of the geomagnetic field with respect to the solar wind. The statistical distribution of polar auroras must therefore depend on the orientation of the geomagnetic field with respect to the ecliptic plane. We have investigated this peculiar feature of auroras that we call auroral astronomical geometry. We give here some preliminary results concerning a limited set of pre-IGY auroras. The criteria that we have chosen to prepare the auroral collection are also briefly summarized. The results conform to the hypothesis of the auroral origin from the magnetospheric neutral sheet. Auroral particles are found to impinge over the earth with low angles with respect to the ecliptic plane (40°). Only in a 4-hours interval around midnight they are found to impinge with angles up to 70°. Definite evidence of these facts requires further investigation with a larger amount of data. — We have also prepared a complex code for recording the morphological features of each aurora, namely: standard information, movement. intensity, color, sunlight illumination, period of pulsation, location in the sky among stars and planets, time evolution, duration and general features of the auroral display. It is well known in fact that the auroral morphology affects auroral heights and latitudes, etc.; presumably it should also affect its astronomical geometry, which we will investigate later.Presented at the Inter-Union Symposium on Solar-Terrestrial Physics — Belgrade 1966.  相似文献   
56.
ABSTRACT

In this work, we have studied the largest earthquake magnitudes on the Ecuadorian coast by using the principles of Extreme Value Analysis based on its two approaches: Block Maxima and Peaks-over-Threshold. First, before modelling the recorded earthquakes, the K-means clustering technique was applied to determine a classification according to the level of magnitude of the earthquakes. Then, models based on the Extreme Value theory of earthquake magnitudes were developed for each of the four clusters that were found, and finally, the best-fitted models were those known as Fréchet and Gumbel ones. The zone with the greatest earthquake magnitudes on the Ecuadorian coast is located between the north of the province of Manabí and the south of the province of Esmeraldas, with a return period of 50 years for an earthquake with magnitude greater than 7.7 MW.  相似文献   
57.
Combined X-ray powder diffraction, Mössbauer, and XANES spectroscopy in situ experiments revealed the transformation of cubic (Mg0.8Fe0.2)O ferropericlase to a rhombohedrally distorted phase at 35(1) GPa and room temperature. The Mössbauer spectroscopy results show that the rhombohedral distortion does not involve magnetic ordering. Combined with data from the literature, our results imply that the cubic to rhombodedral transition occurs in (Mg,Fe)O under conditions of non-hydrostatic stress over a wide range of composition (0.2≤x Fe≤1).  相似文献   
58.
The meaning of the large variety of seismic waveforms showing different frequencies associated with volcanic activity is still uncertain. No definitive model for source dynamics has been proposed yet. At present, seismic models explaining the origin of the spectral content of the seismic signal are mainly linked to geometrical features of the volcanic conduit and to resonant effects induced by pressure fluctuations in a fluid-filled conduit. Such models assume the physical system to be in a steady state over a long interval of time. At Stromboli, the seismicity produced by each of the three active vents is not stable and can suddenly change in time. Therefore, the application of stable resonator models appears to be unwarranted.On the basis of infrared image analyses, atmospheric pressure, and seismic wavefield signals, we show that different frequency contents and different explosive styles occur at Stromboli at the same time at different vents. Moreover, we give evidence to support the idea that seismicity and explosivity are both controlled by a variable gas flow regime released during explosions at the top of the magma column. We have recognized two main pressure regimes, controlling the explositivity at Stromboli: one is impulsive, short and possibly produced by a gas accumulation beneath a cap rock; the other has an intermittent regime feature, and lasts longer. We demonstrate how the first one generates a monochromatic low-frequency wavefield, while the second shows a high-frequency spectrum where the frequency content depends on pressure fluctuations and on pressure gradient. We suggest different pressure growth and gas flow in the magma as the common source for both explosive style and seismic wavefield.  相似文献   
59.
Biotites from mafic rocks occurring at different stratigraphic levels of the Ivrea-Verbano Mafic Complex are studied. The rocks are gabbros and diorites. All the biotites are intermediate between phlogopite and annite [0.282 (up to 7.14 and 9.32 wt%, respectively) with respect to those of the diorites (up to 1.26 and 6.26 wt%, respectively). Systematic compositional variations support the substitution model 2 IV Si+( IV R2+)2 IV Al+ VI Ti (R2+=Fe+Mg+Mn) in gabbros and IV Si+ VI Al IV Al+ VI Ti in diorites. A predominance of disordered stacking sequences, coexisting with 1M, 2M 1 and 3T polytypes was observed in all biotites. It was possible to carry out structural refinements only on three biotites-2M 1 from diorites (R-values between 2.68 and 3.77) and one biotite-1M from gabbros (R-value=3.09). It was shown that: (1) the reduced thickness of the tetrahedral sheet in Ba-rich biotites supports the coupled substitution IV Si+ XII K IV Al+ XII Ba; (2) the interlayer site geometry is affected by the whole layer chemistry and does not reflect only local chemical variations; (3) in two samples of the 2M 1 polytype, the M(1) octahedral site is larger and more distorted than the M(2) sites because of the preferential ordering of Fe2+ in the M(1) site, whereas one sample shows complete cation disorder in the octahedral sites. Biotite-1M shows that Fe2+ can also be located in the M(2) site. Some of the differences between the biotites of gabbros and diorites (e.g. Ba concentration and exchange vectors) may be linked to the host rock composition and to its crystallization process. Biotite occurs in trace amounts in gabbros and its crystallization is related to the interstitial melt which contributed to the adcumulus growth of the main rock forming phases and became highly enriched in K, Ba and Ti. Diorites are the result of equilibrium crystallization of a residual melt rich in incompatible elements, where biotite is a major constituent.  相似文献   
60.
In this study we evaluated the capability of a 213 nm laser ablation system coupled to a quadrupole-based ICP-MS in delivering accurate and precise U-Pb ages on zircons and monazites. Four zircon samples ( ca. 50 Ma to ca. 600 Ma) and four monazite samples ( ca. 30 Ma to ca. 1390 Ma) of known ages were analysed utilising laser ablation pits with diameters of 20 μm and 60 μm. Instrument mass bias and laser induced time-dependent elemental fractionation were corrected for by calibration against a matrix-matched reference material. Tera-Wasserburg plots of the calculated U-Pb data were employed to assess, and correct for, common Pb contributions. The results indicated that the LA-ICP-MS technique employed in this study allowed precise and accurate U-Pb isotope dating of zircon and monazite on sample areas 20 μm in diameter. At this spot size, the precisions achieved for single spot 206Pb/238U ages, were better than 5% (2s) for monazites and zircons with ages down to 30 Ma and 50 Ma, respectively. The precisions reported are comparable to those generally reported in SIMS and LA-MC-ICP-MS U-Pb isotope determinations.  相似文献   
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