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The Radicofani Volcano is characterised by few lava flows, a cinder cone and a denudated neck, and is part of the Tuscan Magmatic Province, the northernmost volcanic region of the Italian peninsula. In spite of the short time span of activity, a large time-dependant chemical and isotopic variability is observed. Most of the rocks of the Radicofani volcano are ultrapotassic shoshonites associated to younger basaltic andesites, found at the bottom of the neck. K2O contents are positively correlated with trace element and isotopic variations. Shoshonitic and high-K calc-alkaline rocks of the Radicofani volcano are significantly different from shoshonites occurring in association with leucite-bearing ultrapotassic rocks in the southernmost portion of the Roman Magmatic Province. The studied rocks are characterised by high, but variable, levels of incompatible trace elements with a subduction-related signature, with troughs at Ba, Ta, Nb, and Ti, and peaks at Cs, K, Th, U, and Pb. Initial values of 87Sr/86Sr range from 0.71333 to 0.71588, 143Nd/144Nd ranges from 0.512050 to 0.512183, while the lead isotope ratios vary between 18.672 and 18.716 for 206Pb/204Pb, 15.665 to 15.696 for 207Pb/204Pb, and 39.981 to 39.081 for 208Pb/204Pb. Ultrapotassic shoshonites show the highest incompatible trace element contents coupled with the highest 87Sr/86Sr and the lowest 143Nd/144Nd. On the basis of geochemical and isotopic signatures it is argued that magmas were generated in a modified lithospheric peridotitic source containing metasomatic veins generated by K-rich melts from recycled sediments within the mantle via subduction. A further metasomatic event generated by slab-derived fluids pervasively enriched the peridotitic source. Partial melting of the veins produced leucite-free ultrapotassic magmas (i.e. lamproite), and was triggered by rising of the isotherms after the orogenic front migrated eastward in the Italian Peninsula. Further rise of the isotherms induced larger degrees of partial melting inducing melting of the surrounding wall peridotite. The variation of the degree of partial melting of such a heterogeneous peridotitic source produced a wide spectrum of magma compositions, which mimic a mixing line between two components: ultrapotassic magma from partial melting of the metasomatic vein and a basaltic andesitic magma from partial melting of the surrounding peridotite.  相似文献   
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The realization of a Laue lens for astronomical purposes involves the mass production of a series of crystalline tiles as optical components, allowing high-efficiency diffraction and high-resolution focusing of photons. Crystals with self-standing curved diffraction planes is a valid and promising solution. Exploiting the quasi-mosaic effect, it turns out to be possible to diffract radiation at higher resolution. In this paper we present the realization of 150 quasi-mosaic Ge samples, bent by grooving one of their largest surface. We show that grooving method is a viable technique to manufacture such crystals in a simple and very reproducible way, thus compatible with mass production. Realized samples present very homogenous curvature. Furthermore, with a specific chemical etch, it is possible to fine adjust one by one the radius of curvature of the grooved samples. Realized crystals was selected for the ASI’s Laue project, that involves the implementation of a prototype of a Laue lens for hard X- and soft γ-ray astronomy.  相似文献   
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There are serious concerns that ocean acidification will combine with the effects of global warming to cause major shifts in marine ecosystems, but there is a lack of field data on the combined ecological effects of these changes due to the difficulty of creating large‐scale, long‐term exposures to elevated CO2 and temperature. Here we report the first coastal transplant experiment designed to investigate the effects of naturally acidified seawater on the rates of net calcification and dissolution of the branched calcitic bryozoan Myriapora truncata (Pallas, 1766). Colonies were transplanted to normal (pH 8.1), high (mean pH 7.66, minimum value 7.33) and extremely high CO2 conditions (mean pH 7.43, minimum value 6.83) at gas vents off Ischia Island (Tyrrhenian Sea, Italy). The net calcification rates of live colonies and the dissolution rates of dead colonies were estimated by weighing after 45 days (May–June 2008) and after 128 days (July–October) to examine the hypothesis that high CO2 levels affect bryozoan growth and survival differently during moderate and warm water conditions. In the first observation period, seawater temperatures ranged from 19 to 24 °C; dead M. truncata colonies dissolved at high CO2 levels (pH 7.66), whereas live specimens maintained the same net calcification rate as those growing at normal pH. In extremely high CO2 conditions (mean pH 7.43), the live bryozoans calcified significantly less than those at normal pH. Therefore, established colonies of M. truncata seem well able to withstand the levels of ocean acidification predicted in the next 200 years, possibly because the soft tissues protect the skeleton from an external decrease in pH. However, during the second period of observation a prolonged period of high seawater temperatures (25–28 °C) halted calcification both in controls and at high CO2, and all transplants died when high temperatures were combined with extremely high CO2 levels. Clearly, attempts to predict the future response of organisms to ocean acidification need to consider the effects of concurrent changes such as the Mediterranean trend for increased summer temperatures in surface waters. Although M. truncata was resilient to short‐term exposure to high levels of ocean acidification at normal temperatures, our field transplants showed that its ability to calcify at higher temperatures was compromised, adding it to the growing list of species now potentially threatened by global warming.  相似文献   
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Abstract. The importance of sponge spicules in the turnover of biogenic silica (BSi) in the detritic bottoms of the Eastern Ligurian Riviera was evaluated by studying sediment cores and the detrital matter collected by a trap over a one year period.
This study made evident that: i) Sponge spicules represent the main component of the BSi both in the sediments and in the trapped matter; ii) A correlation exists between the sponge biomass present on the overhanging cliff and the amount of sponge spicules found in the sediment below; iii) Inside the sediments, a superficial layer (10 cm deep) characterized by intensive silica dissolution processes can be observed; and iv) The amount of spicules collected using the trap is not constant throughout the year, but shows a characteristic trend with low values in spring and summer and high values in autumn and winter.  相似文献   
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The structural framework of the southern part of the Shackleton Fracture Zone has been investigated through the analysis of a 130-km-long multichannel seismic reflection profile acquired orthogonally to the fracture zone near 60° S. The Shackleton Fracture Zone is a 800-km-long, mostly rectilinear and pronounced bathymetric lineation joining the westernmost South Scotia Ridge to southern South America south of Cape Horn, separating the western Scotia Sea plate from the Antarctic plate. Conventional processing applied to the seismic data outlines the main structures of the Shackleton Fracture Zone, but only the use of enhanced techniques, such as accurate velocity analyses and pre-stack depth migration, provides a good definition of the acoustic basement and the architecture of the sedimentary sequences. In particular, a strong and mostly continuous reflector found at about 8.0 s two-way traveltime is very clear across the entire section and is interpreted as the Moho discontinuity. Data show a complex system of troughs developed along the eastern flank of the crustal ridge, containing tilted and rotated blocks, and the presence of a prominent listric normal fault developed within the oceanic crust. Positive flower structures developed within the oceanic basement indicate strike-slip tectonism and partial reactivation of pre-existing faults. Present-day tectonic activity is found mostly in correspondence to the relief, whereas fault-induced deformation is negligible across the entire trough system. This indicates that the E–W-directed stress regime present in the Drake Passage region is mainly dissipated along a narrow zone within the Shackleton Ridge axis. A reappraisal of all available magnetic anomaly identifications in the western Scotia Sea and in the former Phoenix plate, in conjunction with new magnetic profiles acquired to the east of the Shackleton Fracture Zone off the Tierra del Fuego continental margin, has allowed us to propose a simple reconstruction of Shackleton Fracture Zone development in the general context of the Drake Passage opening.  相似文献   
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Acta Geotechnica - The most common cause of slope instability is intense or sustained rainfall, which may induce reduction in soil suction, and thus, shear strength. Capillary barrier systems...  相似文献   
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The scopes of this work are to study the mechanisms of load transfer and the deformations of the ground during slurry trenching and concreting in dry sand and to evaluate their effects on service structural loads, wall deflections and ground displacements behind the wall caused by subsequent excavation. A series of three-dimensional finite element analyses was carried out modelling the installation of diaphragm walls consisting of panels of different length. The soil was modelled as either linearly elastic-perfectly plastic or incrementally non-linear (hypoplastic) with elastic strain range. Plane strain analyses of diaphragm walls of identical cross section were also carried out in which wall installation was either modelled or the wall was wished in place (WIP). The analyses predict ground movements consistent with the experimental observations both in magnitude and trend. The results also show that the maximum horizontal wall deflections and structural loads reduce with increasing panel aspect ratio towards a minimum which is about twice the value computed for WIP analyses. Panel aspect ratios should be larger than about three to take advantage of the three-dimensional effects. The pattern and magnitude of surface vertical displacements obtained from linearly elastic-perfectly plastic analyses, no matter whether three- or two-dimensional, are unrealistic.  相似文献   
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