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41.
Carbonate-bearing mantle peridotite xenoliths from Spitsbergen: phase relationships,mineral compositions and trace-element residence 总被引：11，自引：0，他引：11
D. A. Ionov Suzanne Y. O’Reilly Yuri S. Genshaft Maya G. Kopylova 《Contributions to Mineralogy and Petrology》1996,125(4):375-392
Carbonates of mantle origin have been found in xenoliths from Quaternary basaltic volcanoes in NW Spitsbergen. The carbonates
range from dolomite to Mg-bearing calcite and have high Mg-numbers [Mg/(Mg+Fe)=(0.92–0.99)]. In some samples they occur interstitially,
e.g. at triple junctions of silicate minerals and appear to be in textural and chemical equilibrium with host lherzolite.
Most commonly, however, the carbonates make up fine-grained aggregates together with (Ca,Mg)-rich olivine and (Al,Cr,Ti)-rich
clinopyroxene that typically replace spinel, amphibole, and orthopyroxene as well as primary clinopyroxene and olivine. Some
lherzolites contain amphibole and apatite that appear to have formed before precipitation of the carbonates. In situ analyses by proton microprobe show very high contents of Sr in the clinopyroxene, carbonates and apatite; the apatite is
also very rich in LREE, U, Th, Cl, Br. Disseminated amphibole in carbonate-bearing rocks is very poor in Nb and Zr, in contrast
to vein amphibole and mica from carbonate-free rocks that are rich in Nb and Zr. Overall, the Spitsbergen xenoliths provide
evidence both for the occurrence of primary carbonate in apparent equilibrium with the spinel lherzolites (regardless of the
nature of events that emplaced them) and for the formation of carbonate-bearing pockets consistent with metasomatism by carbonate
melts. Calcite and amorphous carbonate-rich materials occur in com- posite carbonate-fluid inclusions, veins and partial melting
zones that appear to be related to fluid action in the mantle, heating of the xenoliths during their entrainment in basaltic
magma, and to decompression melting of the carbonates. Magnesite is a product of secondary, post-eruption alteration of the
xenoliths.
Received: 6 October 1995/Accepted: 17 June 1996 相似文献
42.
Functionalised aromatic constituents of Chukurovo resinite are compared here with the chemical composition of a macrofossil assigned paleobotanically as Taxodium dubium (Sternb.) Heer. Terpenoids and lipids of fossil wood tissue embedded in a clay sediment were extracted and analyzed for comparison. The information was interpreted in relation to the biomarker compositions of different conifer families, as well as to the effects of contamination by inward migration of organic matter from the adjacent sediments.Many of identified geolipids, i.e., alkanes, alkanols, alkan-2-ones, and steranes/triterpanes have no chemosystematic value because they are ubiquitous in the plant kingdom. Ferruginol, sugiol, and products of their diagenetic transformations were identified as the dominant specific biomarkers in the resinite. Ferruginol and its analogues were the most abundant diterpenoids in Taxodium dubium sample. Thus, the biomarker composition of the extractable matter of the resinite strongly suggests that species of Cupressaceae contributed significantly to the Chukurovo paleoenvironment. 相似文献
43.
Two homogeneous (humovitrain and xylain) and one heterogeneous (humoclarain) lithotype macerals, separated from a lignite, were subjected to mild reductive treatment by NaH. The extensive chromatographic separation of the decalin-soluble fraction revealed some structural peculiarities. A strong predominance of α-phyllocladane was characteristic for all macerals. Series of n-, iso-, and anteiso-alkanes, regular isoprenoids, alkylbenzenes and 1-methyl-4-n-alkylcyclohexanes were identified by mass spectrometry. An angiosperm source input was represented by friedelane, lupane and seco-hopane structures. Products of des-A and des-E-ring cleavages and C-10 demethylation were registered by mass spectrometry. The main difference was in the hopane distribution pattern. A strong prevalence of extended ββ-hopanes was found in the humoclarain sample. The mass spectral data revealed the existence of a basic difference in hopane precursors—diploptent or diplopterol for the homogeneous lithotypes and bacteriohopanetetrol for the heterogeneous lithotype. 相似文献
44.
This article analyzes the life trajectories of twelve early-career geographers in relation to their life–work experiences in an increasingly neoliberal academia and its constant demands of hypermobility. Using (auto)ethnographic research methods, it delves into the manifestations and effects of the pervasive myth of the detached, always ready-to-move scholar. We analyze the role of mobility in imaginaries and practices of academia and its close relationship with privilege and precarity. Our findings show how academic work is inescapably located despite the systematic erasure of the bodies, places, and networks that scholars are part of. By taking into account the centrality of place making in academic experience, our conclusions point to more comprehensive ways in which academic mobility can be understood, reflected on as part of geographers’ professional training, and transformed. 相似文献
45.
Gaudet Matthew Kopylova Maya Muntener Colleen Zhuk Vlad Nathwani Chetan 《Mineralogy and Petrology》2018,112(2):433-445
Renard 65, a diamondiferous pipe in the Neoproterozoic Renard kimberlite cluster (Québec, Canada), is a steeply-dipping and downward-tapering diatreme comprised of three pipe-filling units: kimb65a, kimb65b, and kimb65d. The pipe is surrounded by a marginal and variably-brecciated country rock aureole and is crosscut by numerous hypabyssal dykes: kimb65c. Extensive petrographic and mineralogical characterization of over 700 m of drill core from four separate drill holes, suggests that Renard 65 is a Group I kimberlite, mineralogically classified as phlogopite kimberlite and serpentine-phlogopite kimberlite. Kimb65a is a massive volcaniclastic kimberlite dominated by lithic clasts, magmaclasts, and discrete olivine macrocrysts, hosted within a fine-grained diopside and serpentine-rich matrix. Kimb65b is massive, macrocrystic, coherent kimberlite with a groundmass assemblage of phlogopite, spinel, perovskite, apatite, calcite, serpentine and rare monticellite. Kimb65c is a massive, macrocrystic, hypabyssal kimberlite with a groundmass assemblage of phlogopite, serpentine, calcite, perovskite, spinel, and apatite. Kimb65d is massive volcaniclastic kimberlite with localized textures that are intermediate between volcaniclastic and coherent, with tightly packed magmaclasts separated by a diopside- and serpentine-rich matrix. Lithic clasts of granite-gneiss in kimb65a are weakly reacted, with partial melting of feldspars and crystallization of richterite and actinolite. Lithic clasts in kimb65b and kimb65d are entirely recrystallized to calcite + serpentine/chlorite + pectolite and display inner coronas of diopside-aegirine and an outer corona of phlogopite. Compositions are reported for all minerals in the groundmass of coherent kimberlites, magmaclasts, interclast matrices, and reacted lithic clasts. The Renard 65 rocks are texturally classified as Kimberley-type pyroclastic kimberlites and display transitional textures. The kimberlite units are interpreted to have formed in three melt batches based on their distinct spinel chemistry: kimb65a, kimb65b and kimb65d. We note a strong correlation between the modal abundances of lithic clasts and the textures of the kimberlites, where increasing modal abundances of granite/gneiss are observed in kimberlites with increasingly fragmental textures.
相似文献46.
Nickeliferous pyrite tracks pervasive hydrothermal alteration in Martian regolith breccia: A study in NWA 7533 
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下载免费PDF全文 Jean‐Pierre Lorand Roger H. Hewins Laurent Remusat Brigitte Zanda Sylvain Pont Hugues Leroux Maya Marinova Damien Jacob Munir Humayun Alexander Nemchin Marion Grange Allen Kennedy Christa Göpel 《Meteoritics & planetary science》2015,50(12):2099-2120
Martian regolith breccia NWA 7533 (and the seven paired samples) is unique among Martian meteorites in showing accessory pyrite (up to 1% by weight). Pyrite is a late mineral, crystallized after the final assembly of the breccia. It is present in all of the lithologies, i.e., the fine‐grained matrix (ICM), clast‐laden impact melt rocks (CLIMR), melt spherules, microbasalts, lithic clasts, and mineral clasts, all lacking magmatic sulfides due to degassing. Pyrite crystals show combinations of cubes, truncated cubes, and octahedra. Polycrystalline clusters can reach 200 μm in maximum dimensions. Regardless of their shape, pyrite crystals display evidence of very weak shock metamorphism such as planar features, fracture networks, and disruption into subgrains. The late fracture systems acted as preferential pathways for partial replacement of pyrite by iron oxyhydroxides interpreted as resulting from hot desert terrestrial alteration. The distribution and shape of pyrite crystals argue for growth at moderate to low growth rate from just‐saturated near neutral (6 < pH<10), H2S‐HS‐rich fluids at minimum log fO2 of >FMQ + 2 log units. It is inferred from the maximum Ni contents (4.5 wt%) that pyrite started crystallizing at 400–500 °C, during or shortly after a short‐duration, relatively low temperature, thermal event that lithified and sintered the regolith breccias, 1.4 Ga ago as deduced from disturbance in several isotope systematics. 相似文献
47.
Olivine in the Udachnaya-East Kimberlite (Yakutia, Russia): Types, Compositions and Origins 总被引：4，自引：0，他引：4
Kamenetsky Vadim S.; Kamenetsky Maya B.; Sobolev Alexander V.; Golovin Alexander V.; Demouchy Sylvie; Faure Kevin; Sharygin Victor V.; Kuzmin Dmitry V. 《Journal of Petrology》2008,49(4):823-839
Olivine is the principal mineral of kimberlite magmas, and isthe main contributor to the ultramafic composition of kimberliterocks. Olivine is partly or completely altered in common kimberlites,and thus unavailable for studies of the origin and evolutionof kimberlite magmas. The masking effects of alteration, commonin kimberlites worldwide, are overcome in this study of theexceptionally fresh diamondiferous kimberlites of the Udachnaya-Eastpipe from the Daldyn–Alakit province, Yakutia, northernSiberia. These serpentine-free kimberlites contain large amountsof olivine (50 vol.%) in a chloride–carbonate groundmass.Olivine is represented by two populations (olivine-I and groundmassolivine-II) differing in morphology, colour and grain size,and trapped mineral and melt inclusions. The large fragmentalolivine-I is compositionally variable in terms of major (Fo85–94)and trace element concentrations, including H2O content (10–136ppm). Multiple sources of olivine-I, such as convecting andlithospheric mantle, are suggested. The groundmass olivine-IIis recognized by smaller grain sizes and perfect crystallographicshapes that indicate crystallization during magma ascent andemplacement. However, a simple crystallization history for olivine-IIis complicated by complex zoning in terms of Fo values and traceelement contents. The cores of olivine-II are compositionallysimilar to olivine-I, which suggests a genetic link betweenthese two types of olivine. Olivine-I and olivine-II have oxygenisotope values (+ 5·6 ± 0·1 VSMOW, 1 SD)that are indistinguishable from one another, but higher thanvalues (+ 5·18 ± 0·28) in ‘typical’mantle olivine. These elevated values probably reflect equilibriumwith the Udachnaya carbonate melt at low temperatures and 18O-enrichedmantle source. The volumetrically significant rims of olivine-IIhave constant Fo values (89·0 ± 0·2 mol%),but variable trace element compositions. The uniform Fo compositionsof the rims imply an absence of fractionation of the melt'sFe2+/Mg, which is possible in the carbonatite melt–olivinesystem. The kimberlite melt is argued to have originated inthe mantle as a chloride–carbonate liquid, devoid of ‘ultramafic’or ‘basaltic’ aluminosilicate components, but becameolivine-laden and olivine-saturated by scavenging olivine crystalsfrom the pathway rocks and dissolving them en route to the surface.During emplacement the kimberlite magma changed progressivelytowards an original alkali-rich chloride–carbonate meltby extensively crystallizing groundmass olivine and gravitationalseparation of solids in the pipe. KEY WORDS: kimberlite; olivine; partial melting; carbonatitic melt; oxygen isotopes; H2O 相似文献
48.
Maya K. Buchanan Robert E. Kopp Michael Oppenheimer Claudia Tebaldi 《Climatic change》2016,137(3-4):347-362
Estimates of future flood hazards made under the assumption of stationary mean sea level are biased low due to sea-level rise (SLR). However, adjustments to flood return levels made assuming fixed increases of sea level are also inadequate when applied to sea level that is rising over time at an uncertain rate. SLR allowances—the height adjustment from historic flood levels that maintain under uncertainty the annual expected probability of flooding—are typically estimated independently of individual decision-makers’ preferences, such as time horizon, risk tolerance, and confidence in SLR projections. We provide a framework of SLR allowances that employs complete probability distributions of local SLR and a range of user-defined flood risk management preferences. Given non-stationary and uncertain sea-level rise, these metrics provide estimates of flood protection heights and offsets for different planning horizons in coastal areas. We illustrate the calculation of various allowance types for a set of long-duration tide gauges along U.S. coastlines. 相似文献
49.
Maya Pasgaard Tania Fredborg Nielsen 《Geografisk tidskrift / udgivet af Bestyrelsen for Det Kongelige danske geografiske selskab》2016,116(2):134-146
Explicit notions of “communities”, as key actors in conservation and development projects across the Global South, are common. Narratives about “indigenous people” or “forest-dependent communities” in forest conservation programmes prevail, portraying a picture of “communities” as homogeneous and harmonious entities. In this study, we unfold “communities” as a construct with an empirical example of a community-based forest protection project, Northern Cambodia. Based on qualitative interviews, field observations and document analysis, we examine the “community” construct in terms of establishment of boundaries, geographical composition and social coherence. We not only find that the establishment of forest “community” boundaries are dominated by powerful external actors rather than the “community members” themselves, but that the spatial composition of “communities” is complex, and affects the ability of local people to benefit from the project. We also find that the studied “communities” show low levels of social coherence and mainly consist of migrant farmers, as opposed to common policy narratives. Taking these inconsistencies into account, we discuss implications of constructing “communities” for the success of forest conservation projects, and argue in favour of more discursive and political analyses to better understand, acknowledge and adapt to existing and changing conditions in present and prospective project locations. 相似文献
50.
Recurrent climate‐induced mass mortality episodes have been recorded in the Mediterranean Sea over the past 15 years, affecting rocky benthic communities. In this study, we provide for the first time a report on the annual mortality events of benthic sessile invertebrates occurring in the eastern part of the Adriatic Sea. Over the course of 14 consecutive years, we studied the sea temperature gradient to a depth of 40 m and found an abnormal summer warming trend and an increased frequency of above‐average temperatures. Mortality events were recorded in the summers of 10 observed years, in particular in 2009, when the highest mortality rates were recorded. Late in summer 2009, extensive mass mortality of sessile invertebrates was observed in the entire Eastern Adriatic Sea. We performed an analysis of selected target benthic species associated with mass mortality events with inter‐regional differences in hydrological and temperature conditions. We were able to characterize the mortality event by studying five areas covering the northern, central and southern regions of the Eastern Adriatic Sea. The degree of impact on each study area was quantified at 28 sites by estimating the proportion of affected target species. According to the obtained data, the northern sites (Cres area) were the least affected, whereas sites in the Central and Southern Adriatic [Tela??ica and Lastovo Nature Parks, Mljet National Park (NP)] displayed the highest impact. In summer 2009, sea surface temperatures reached values of 28 °C in the Cres area and 30 °C in Mljet NP. These thermal conditions were concomitant with moderate to severe mass mortalities of benthic populations. Mass mortality events reached depths of 45 m in most parts of the affected areas. Amongst studied species, the scleractinian coral and gorgonian populations suffered the most extensive damage during the mass mortality events. 相似文献