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Yeşim Çoban-Yildiz Alec F. Gaines Pat E. Keating Gordon D. Love Dennis McLoughlin Colin E. Snape 《Organic Geochemistry》2009,40(2):270-282
The suspended particulate organic matter, SPOM, in the autumnal Black Sea has been characterised using catalytic hydropyrolysis (HyPy) of the total (bound plus free) lipid material. The technique, which generates maximum yields of volatile products from sediments, kerogens and phytoplankton, was followed using gas chromatography and gas chromatography/mass spectrometry. The generated alkanes were dominated by n-C18, hypothesised to arise predominantly from unsaturated C18 fatty acids. Steranes were generated from reductive conversion of free and bound sterols. The generation of branched alkanes and especially of hopanes provided formal evidence for the participation of bacteria in the mineralisation of the SPOM. Whereas similar distributions of n-alkanes were generated from SPOM sampled from different depths of the comparatively well-stirred Rhodes Gyre (eastern Mediterranean), mineralisation of the SPOM at each depth of the central Black Sea produced characteristic changes in the composition and concentration of the HyPy products. Depth profiles of the n-alkanes generated from SPOM in the region of the Rim Current were affected by the local hydrography. Polynuclear aromatic hydrocarbons (PAHs) of anthropogenic origin were present in the surface waters of the central Black Sea. Some methyl benzenes, thiophenes and pyrroles were also generated. 相似文献
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The aim of the study is to investigate the interaction between waters of Lake Girdev and groundwater in the allochthonous
limestone units exposed in the area between Lake Girdev and Kazanpınarı Spring, southwestern Turkey. The features analyzed
include the flow direction and apparent groundwater velocity, their relationship with Lake Girdev, and the effect of lithological
and structural features on the groundwater circulation. The results of a fluorescein tracer test indicate that groundwater
flows east-northeast and the apparent flow velocity ranges from 26.2 to 35.6 m h–1 between the injection site and various observation points. Tritium data suggest that the water of Lake Girdev and groundwater
are probably similar in age, and oxygen-18 isotope data indicate that water derived from Lake Girdev is the main source of
recharge to the aquifer. The aquifer is fed not only by Lake Girdev but also by rainfall percolating through allochthonous
limestones; together, these provide the discharge of springs in Elmalı Polje. The permeability of the allochthonous limestone
aquifer has been enhanced as a result of jointing and faulting.
Received, June 1997 / Revised, June 1998, March 1999 / Accepted, July 1999 相似文献
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S. Türk Çulha M. Çulha İ. Karayücel M. Y. Çelik Y. Işler 《International Journal of Environmental Science and Technology》2017,14(2):385-396
The study was performed between March 2009 and March 2010 at the Sinop Inner Harbor on cultured mussels at the offshore submerged longline system. The samples of mussels, sediment and suspended particulate matter were seasonally taken for the purpose of monitoring differences of metal contents. In addition, burnable organic matter, contamination factors (CF), pollution load index (PLI) in sediment samples, meat yield of mussels were seasonally determined. All metals in suspended particulate matter were found to be above the national limit. Cd concentration in sediment was above the limit according to sediment quality guidelines, and Cd concentration in mussel was above both national and international limit values. According to CF and PLI identified in sediment, it was found that Inner Harbor was under the effect of anthropogenic pollution in terms of Cd accumulation. Provisional tolerable weekly intake calculated in mussel did not exceed the tolerable consumption values. In conclusion, it can be said that this region considered for commercial mussel cultivation is not a suitable area. 相似文献
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This study describes the seismic performance of an existing five storey reinforced concrete building which represents the typical properties of low-rise non-ductile buildings in Turkey. The effectiveness of shear walls and the steel bracings in retrofitting the building was examined through nonlinear static and dynamic analyses. By using the nonlinear static analysis, retrofitted buildings seismic performances under lateral seismic load were compared with each other. Moreover, the performance points and response levels of the existing and retrofitting cases were determined by way of the capacity-spectrum method described in ATC-40 (1996). For the nonlinear dynamic analysis the records were selected torepresent wide ranges of duration and frequency content. Considering the change in the stiffness and the energy dissipation capacities, the performance of the existing and retrofitted buildings were evaluated in terms of story drifts and damage states. It was found that each earthquake record exhibited its own peculiarities, dictated by frequency content, duration, sequence of peaks and their amplitude. The seismic performance of retrofitted buildings resulted in lower displacements and higher energy dissipation capacity depending mainly on the properties of the ground motions and the retrofitting strategies. Moreover, severe structural damage (irreparable or collapse) was observed for the existing building. However, buildings with retrofit alternatives exhibited lower damage levels changing from no damage to irreparable damage states. 相似文献
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Sorption behavior of Lanaset Red (LR) G on lentil straw (LS) was studied as a function of particle size, adsorbent dose, initial pH value, initial dye concentration, and contact time. Sorption kinetics data was well described by logistic model. Modified logistic equation can be used to explain effects of initial dye concentrations and contact time on the sorption of LR G with high R2 value. Freundlich model was found to be excellent in representing the equilibrium data. Thermodynamic parameters like free energy (ΔG0), enthalpy (ΔH0), and entropy (ΔS0) were calculated by the use of Langmuir constant. Thermodynamic data showed that the sorption processes were spontaneous and endothermic in nature. Desorption process suggested that strong binding and weak interactions could be formed between adsorbent surface and dye molecules. Results revealed that LS has a remarkable potential for the sorption of LR G. 相似文献
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In this study, the adsorption of reactive red 120 (RR 120) on pistachio husk, and the modeling of the adsorption was investigated. Characterization of the pistachio husk was confirmed by Fourier transform infrared spectroscopy. The pHzpc of pistachio husk was found to be pH 8.5. Increasing the initial pH value decreased (p < 0.01) the amount of dye adsorbed. However, increasing the initial dye concentration from 50 to 900 mg/L at pH 1 increased (p < 0.01) the equilibrium dye uptake from 20.83 to 182.10 mg/g. Results indicated that this adsorbent had great potential for the removal of RR 120 dye. The logistic model was found to be the most suitable of the kinetic and equilibrium models tested to describe the adsorption of the dye. The parameters determined from the logistic model were well correlated with the initial dye concentration, and were seen to increase with the increasing initial dye concentration, but this was not observed from pseudo‐second order kinetics. 相似文献