The influence of citric acid,EDTA, and fulvic acid on U(VI) sorption onto kaolinite     

Michelle Barger  Carla M. Koretsky 《Applied Geochemistry》2011

Uranium(VI) sorption onto kaolinite was investigated as a function of pH (3–12), sorbate/sorbent ratio (1 × 10^?6–1 × 10^?4 M U(VI) with 2 g/L kaolinite), ionic strength (0.001–0.1 M NaNO₃), and pCO₂ (0–5%) in the presence or absence of 1 × 10^?2–1 × 10^?4 M citric acid, 1 × 10^?2–1 × 10^?4 M EDTA, and 10 or 20 mg/L fulvic acid. Control experiments without-solids, containing 1 × 10^?6–1 × 10^?4 M U(VI) in 0.01 M NaNO₃ were used to evaluate sorption to the container wall and precipitation of U phases as a function of pH. Control experiments demonstrate significant loss (up to 100%) of U from solution. Although some loss, particularly in 1 × 10^?5 and 1 × 10^?4 M U experiments, is expected due to precipitation of schoepite, adsorption on the container walls is significant, particularly in 1 × 10^?6 M U experiments. In the absence of ligands, U(VI) sorption on kaolinite increases from pH ～3 to 7 and decreases from pH ～7.5 to 12. Increasing ionic strength from 0.001 to 0.1 M produces only a slight decrease in U(VI) sorption at pH < 7, whereas 10% pCO₂ greatly diminishes U(VI) sorption between pH ～5.5 and 11. Addition of fulvic acid produces a small increase in U(VI) sorption at pH < 5; in contrast, between pH 5 and 10 fulvic acid, citric acid, and EDTA all decrease U(VI) sorption. This suggests that fulvic acid enhances U(VI) sorption slightly via formation of ternary ligand bridges at low pH, whereas EDTA and citric acid do not form ternary surface complexes with the U(VI), and that all three ligands, as well as carbonate, form aqueous uranyl complexes that keep U(VI) in solution at higher pH.  相似文献   

Environmental assessment of water from a uranium mine (Caldas,Minas Gerais State,Brazil) in a decommissioning operation   总被引：1，自引：1，他引：0  

Michelle Burato Campos  Heliana de Azevedo  Marcos Roberto Lopes Nascimento  Cláudio Vítor Roque  Suzelei Rodgher 《Environmental Earth Sciences》2011,62(4):857-863

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Impacts of climate, lake size, and supra- and sub-permafrost groundwater flow on lake-talik evolution, Yukon Flats, Alaska (USA)   总被引：3，自引：2，他引：1  

Tristan P. Wellman  Clifford I. Voss  Michelle A. Walvoord 《Hydrogeology Journal》2013,21(1):281-298

In cold regions, hydrologic systems possess seasonal and perennial ice-free zones (taliks) within areas of permafrost that control and are enhanced by groundwater flow. Simulation of talik development that follows lake formation in watersheds modeled after those in the Yukon Flats of interior Alaska (USA) provides insight on the coupled interaction between groundwater flow and ice distribution. The SUTRA groundwater simulator with freeze–thaw physics is used to examine the effect of climate, lake size, and lake–groundwater relations on talik formation. Considering a range of these factors, simulated times for a through-going sub-lake talik to form through 90 m of permafrost range from ～200 to >?1,000  years (vertical thaw rates <?0.1–0.5  m?yr^?1). Seasonal temperature cycles along lake margins impact supra-permafrost flow and late-stage cryologic processes. Warmer climate accelerates complete permafrost thaw and enhances seasonal flow within the supra-permafrost layer. Prior to open talik formation, sub-lake permafrost thaw is dominated by heat conduction. When hydraulic conditions induce upward or downward flow between the lake and sub-permafrost aquifer, thaw rates are greatly increased. The complexity of ground-ice and water-flow interplay, together with anticipated warming in the arctic, underscores the utility of coupled groundwater-energy transport models in evaluating hydrologic systems impacted by permafrost.  相似文献   

A spatiotemporal calculus for reasoning about land-use trajectories   总被引：1，自引：0，他引：1  

Adeline Marinho Maciel  Gilberto Camara  Lubia Vinhas  Michelle Cristina Araújo Picoli  Rodrigo Anzolin Begotti  Luiz Fernando Ferreira Gomes de Assis 《International journal of geographical information science》2019,33(1):176-192

Earth observation images are a powerful source of data about changes in our planet. Given the magnitude of global environmental changes taking place, it is important that Earth Science researchers have access to spatiotemporal reasoning tools. One area of particular interest is land-use change. Using data obtained from images, researchers would like to express abstractions such as ‘land abandonment’, ‘forest regrowth’, and ‘agricultural intensification’. These abstractions are specific types of land-use trajectories, defined as multi-year paths from one land cover into another. Given this need, this paper introduces a spatiotemporal calculus for reasoning about land-use trajectories. Using Allen’s interval logic as a basis, we introduce new predicates that express cases of recurrence, conversion and evolution in land-use change. The proposed predicates are sufficient and necessary to express different kinds of land-use trajectories. Users can build expressions that describe how humans modify Earth’s terrestrial surface. In this way, scientists can better understand the environmental and economic effects of land-use change.  相似文献   

Can spatial statistics help decipher impact crater saturation?     

Michelle R. Kirchoff 《Meteoritics & planetary science》2018,53(4):874-890

Impact crater saturation equilibrium is a state where a surface is so densely cratered that a new crater cannot form without removing older craters and the observed crater density is in (quasi-)equilibrium. Whether densely cratered surfaces throughout the solar system are saturated for large, kilometer-sized craters has been debated for decades. This work explores if spatial statistics can provide insight if these crater distributions are in saturation equilibrium. The supposition is that crater distributions become more spatially uniform (more evenly spaced) as they reach saturation (Squyres et al. 1997 ). A numerical simulation of crater saturation is combined with observations of cratered terrains throughout the solar system to assess the utility of using spatial statistics. The numerical simulations examine spatial statistics and saturation equilibrium for crater distributions for various input population size-frequency distribution (SFD) slopes, along with a range in the effective crater erasure size, effectiveness of smaller craters erasing the rims of larger craters, and the amount of rim needed to recognize a crater. Simulations show that saturated terrains do become more spatially uniform, and that the degree of uniformity appears to be most dependent on the input SFD slope. When simulation results are compared to observed crater distributions, I find that large, kilometer-sized craters on densely cratered terrains throughout the solar system are likely in saturation equilibrium.  相似文献   

Revised recommended methods for analyzing crater size-frequency distributions          下载免费PDF全文

Stuart J. Robbins  Jamie D. Riggs  Brian P. Weaver  Edward B. Bierhaus  Clark R. Chapman  Michelle R. Kirchoff  Kelsi N. Singer  Lisa R. Gaddis 《Meteoritics & planetary science》2018,53(4):891-931

Impact crater populations help us to understand solar system dynamics, planetary surface histories, and surface modification processes. A single previous effort to standardize how crater data are displayed in graphs, tables, and archives was in a 1978 NASA report by the Crater Analysis Techniques Working Group, published in 1979 in Icarus. The report had a significant lasting effect, but later decades brought major advances in statistical and computer sciences while the crater field has remained fairly stagnant. In this new work, we revisit the fundamental techniques for displaying and analyzing crater population data and demonstrate better statistical methods that can be used. Specifically, we address (1) how crater size-frequency distributions (SFDs) are constructed, (2) how error bars are assigned to SFDs, and (3) how SFDs are fit to power-laws and other models. We show how the new methods yield results similar to those of previous techniques in that the SFDs have familiar shapes but better account for multiple sources of uncertainty. We also recommend graphic, display, and archiving methods that reflect computers’ capabilities and fulfill NASA's current requirements for Data Management Plans.  相似文献   

A new hematite formation mechanism for Mars     

Michelle E. MINITTI  Melissa D. LANE  Janice L. BISHOP 《Meteoritics & planetary science》2005,40(1):55-69

Abstract— The origin of hematite detected in Martian surface materials is commonly attributed to weathering processes or aqueous precipitation. Here, we present a new hematite formation mechanism that requires neither water nor weathering. Glass‐rich basalts with Martian meteorite‐like chemistry (high FeO, low Al₂O₃) oxidized at high (700 and 900 °C) temperatures in air and CO₂, respectively, form thin (<1 μm) hematite coatings on their outermost surfaces. Hematite is manifested macroscopically by development of magnetism and a gray, metallic sheen on the glass surface and microscopically by Fe enrichment at the glass surface observed in element maps. Visible and near‐infrared, thermal infrared, and Raman spectroscopy confirm that the Fe enrichment at the oxidized glass surfaces corresponds to hematite mineralization. Hematite formation on basaltic glass is enabled by a mechanism that induces migration of Fe²⁺ to the surface of an oxidizing glass and subsequent oxidation to form hematite. A natural example of the hematite formation mechanism is provided by a Hawaiian basalt hosting a gray, metallic sheen that corresponds to a thin hematite coating. Hematite coating development on the Hawaiian basalt demonstrates that Martian meteorite‐like FeO contents are not required for hematite coating formation on basalt glass and that such coatings form during initial extrusion of the glassy basalt flows. If gray hematite originating as coatings on glassy basalt flows is an important source of Martian hematite, which is feasible given the predominance of igneous features on Mars, then the requirement of water as an agent of hematite formation is eliminated.  相似文献   

Radiation transfer of gyrosynchrotron emission in stellar environments     

Michelle C. Storey 《Solar physics》1996,168(2):435-447

Non-thermal radio emission has been detected from several kinds of active stars. Polarization and intensity measurements of the quiescent (i.e. non-flaring) emission indicate gyrosynchrotron emission. A three-dimensional magnetic field model for the stellar field is presented and the gyrosynchrotron intensity and polarization emerging from such a model is calculated and compared with observations. Model spectra agree well with observations. Model polarization results indicate that the emission region is more complex than the simple model and may indicate the presence of multipole components in the field, small loops of flux near the stellar surface and significant energy loss in the radiating electron distribution over time.  相似文献   

Eolian controlled modification of the martian south polar layered deposits     

Michelle R. Koutnik  Shane Byrne  Anthony D. Toigo 《Icarus》2005,174(2):490-501

Data from the Mars Orbiter Laser Altimeter (MOLA) and Mars Orbiter Camera (MOC) aboard the Mars Global Surveyor (MGS) mission and the Thermal Emission Imaging System (THEMIS) aboard the Mars Odyssey mission have revealed unique surface features in a particular region of the South Polar Layered Deposits (SPLD). The dominant morphology is large-scale quasi-parallel grooves that extend for hundreds of kilometers with only tens of meters of vertical relief, that we have termed here the “Wire Brush” terrain. The grooves are also transected by disjointed, yet roughly continuous, low-relief sinuous ridges that cross roughly perpendicular to the trend-direction of the large-scale grooves and show only tens of meters of relief. We interpret these ridges to be eroded remnants of folded layers. At the northern end of the large-scale grooves there are non-symmetric mounds. They are frequently preceded by a significant depression and/or trailing grooves that are parallel to the Wire Brush trend. We find that a two-stage process involving winds that intermittently remove a low-density crust exposing the underlying ice to ablation is the interpretation that best explains the multitude of features observed here. These features appear to be currently inactive indicating higher winds in previous epochs.  相似文献   

Erratum to: The Quadrennial Ozone Symposium 2016     

Sophie GODIN-BEEKMANN  Irina PETROPAVLOSKIKH  Stefan REIS  Paul NEWMAN  Wolfgang STEINBRECHT  Markus REX  Michelle L. SANTEE  Richard S. ECKMAN  Xiangdong ZHENG  Matthew B. TULLY  David S. STEVENSON  Paul YOUNG  John PYLE  Mark WEBER  Johanna TAMMINEN  Gina MILLS  Alkiviadis F. BAIS  Clare HEAVISIDE  Christos ZEREFOS 《大气科学进展》2018,35(3):368-369

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