Messinian deposits and erosion in northern Tunisia: inferences on Strait of Sicily during the Messinian Salinity Crisis     

Narjess El Euch-El Koundi  Serge Ferry  Jean-Pierre Suc  Georges Clauzon  Mihaela Carmen Melinte-Dobrinescu  Christian Gorini  Anissa Safra  Fouad Zargouni 《地学学报》2009,21(1):41-48

Outcrops, offshore wells, electric logs and seismic profiles from northern Tunisia provide an opportunity to decipher the Messinian Salinity Crisis in the Strait of Sicily. Messinian deposits (including gypsum beds) near the Tellian Range reveal two successive subaerial erosional surfaces overlain by breccias and marine Zanclean clays, respectively. In the Gulf of Tunis, Messinian thick evaporites (mostly halite) are strongly eroded by a fluvial canyon infilled with Zanclean clays. The first erosional phase is referred to the intra-Messinian tectonic phase and is analogous to that found in Sicily. The second phase corresponds to the Messinian Erosional Surface that postdates the marginal evaporites, to which the entire Sicilian evaporitic series must refer. The Western and Eastern Mediterranean basins were separated during deposition of the central evaporites.  相似文献   

X-ray Computed Tomography study of the influence of consolidants on the hydric properties of sandstones for stone conservation studies     

Vicente G. Ruiz de Argandoa  Lope Calleja  ngel Rodríguez-Rey  Luis Miguel Surez del Río  Carmen Celorio 《Engineering Geology》2009,103(3-4):69-75

X-ray Computed Tomography (X-ray CT) has been used to study the petrophysical characteristics of a Jurassic sandstone from Asturias (Northern Spain) used as building stone in several monuments in the region. CT monitoring of water capillarity tests has made it possible to visualize the movement of water inside the samples, to relate this movement with texture characteristics, and to measure the height reached in successive images, thereby determining the capillary penetration coefficient; based on this coefficient, the effective capillary pore radius has also been estimated. An advantage of the use of CT is that, as the information comes from the sample interior, border effects that can be generated in the external faces can be avoided.The CT was also used to visualize how a commercial organosilicon consolidant penetrates inside the rock by means of capillarity, a usual way of consolidant application in stone restoration processes. The coefficient of capillary penetration of the product, determined on the basis of the measurements made on the tomographic images, is 53% less than that of water. The influence of rock texture characteristics on the capillarity both of the consolidant and the water was also observed.The samples underwent CT water capillarity studies before and after the consolidant application, proving that the treatment improves the rock's hydric properties. The coefficient of capillary penetration decreased by 24% following the application of the consolidant, whereas the effective pore radius decreased by more than 40%.  相似文献   

Valorization of olive stone as adsorbent of chromium(VI): comparison between laboratory- and pilot-scale fixed-bed columns     

M. Ángeles Martín-Lara  Mª Carmen Trujillo Miranda  A. Ronda Gálvez  A. Pérez Muñoz  M. Calero de Hoces 《International Journal of Environmental Science and Technology》2017,14(12):2661-2674

The main aim of this work is to study the effect of scaling in the biosorption of chromium(VI) onto olive stone in two different fixed-bed columns. Firstly, the effect of flow rate, bed depth and inlet concentration of Cr(VI) in both columns was analyzed. The results revealed a better operation for lower flow rates, higher bed heights and lower inlet concentrations of metal. When decreasing flow rate, the operation time of the column increases. Therefore, as the solution flow rate increased the breakthrough and the exhaustion times decreased. An increase in bed depth increases the quantity of chromium eliminated and thus, the higher sorption capacity of the system. A decrease in the inlet concentration of chromium produces a delay in exhaustion time, and larger volumes of solution could be treated. The results were fitted to the BDST model, obtaining that the adsorptive capacity of the bed depth is similar in laboratory- and pilot-scale fixed-bed columns, considering the biosorption capacity as a biosorption-coupled reduction process. Results also could indicate that scaling affects more to the reduction process than properly biosorption process. The experimental data were also fitted to Adams–Bohart, Thomas, Yoon–Nelson and dose–response models. A good fit of the biosorption process of Cr(VI) was found for dose–response and Adams–Bohart models.  相似文献   

Surface evolution of salt‐encrusted playas under extreme and continued dryness          下载免费PDF全文

Octavio Artieda  Alfonso Davila  Jacek Wierzchos  Peter Buhler  Rafael Rodríguez‐Ochoa  Juan Pueyo  Carmen Ascaso 《地球表面变化过程与地形》2015,40(14):1939-1950

Miocene continental saltpans are scattered in the Central Valley of the Atacama Desert, one of the driest regions on Earth. These evaporitic deposits are hydrologically inactive, and are detached from groundwater brines or aquifers. The surface of the saltpans, also known as salars, comprises desiccation polygons, commonly with nodular salt structures along their sides. The morphology and bulk mineralogy of salt polygons differs between and within salars, and the shape and internal structure of salt nodules varies between different polygon types. Based on field observation, and mineralogy and crystallography data, we generated a conceptual model for the genesis and evolution of these surface features, whereby rare rainfall events are responsible for the transformation of desiccation salt polygons and the initial formation of salt nodules along polygon borders. In addition, frequent, but less intense, deliquescence events further drive the evolution of salt nodules, resulting in a characteristic internal structure that includes laminations, and changes in porosity and crystal morphologies. As a result, and despite the extreme dryness, the surfaces of fossil salars are dynamic on timescales of several years to decades, in response to daily cycles in atmospheric moisture, and also to rare and meager rainfall events. We propose that fossil salars in the Atacama Desert represent an end stage in the evolution of evaporitic deposits under extreme and prolonged dryness. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Identification of extreme events using drought indices and their impact on the Danube lower basin discharge          下载免费PDF全文

Constantin Mares  Ileana Mares  Mihaela Mihailescu 《水文研究》2016,30(21):3839-3854

In this study extreme droughts and extremely wet periods in the Danube upper and middle basin (DUMB) have been highlighted with specific indices. The most widely used indices have been considered to estimate both the dry and wet phenomena severity and the frequency or spatio‐temporal extension. The climatic condition of 15 meteorological stations situated in the Danube basin has been evaluated using four indices: Palmer Drought Severity Index (PDSI), Palmer Hydrological Drought Index (PHDI), Weighted PDSI (WPLM) and Palmer Z‐index (ZIND). The four indices have been analysed separately for each of the four seasons between 1901 and 2000. First the internal structure of the time series of the four indices has been analysed separately. Then the overall temporal characteristic has been analysed by means of the principal component of the Multivariate Empirical Orthogonal Functions decomposition of the four indices (PC1‐MEOF). For the discharge in the Danube lower basin, station Orsova has been chosen, representing an integrator of the discharges from the DUMB. A very close connection has been found between Palmer indices and Danube discharge in all seasons (with correlation coefficients greater then 0.80) excepting the spring season. A classification in five classes of both the four indices separately and the PC1‐MEOF has been achieved in order to highlight extreme events. The impact of phenomena quantified by Palmer indices in DUMB upon discharges in Danube lower basin is evident. It was demonstrated in this study that the Greenland‐Balkan Oscillation (GBO) influences the south‐east European hydro‐climatic regime more than the North Atlantic Oscillation (NAO) Index. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

The Lateglacial interstadial at the southeastern limit of the Sonoran Desert,Mexico: vegetation and climate reconstruction based on pollen sequences from Ciénega San Marcial and comparison with the subrecent record          下载免费PDF全文

Carmen I. Ortega‐Rosas  María C. Pealba  Joel Guiot 《Boreas: An International Journal of Quaternary Research》2016,45(4):773-789

The last glacial–interglacial transition encompassed rapid climate oscillations that affected both hemispheres. At low latitudes, the pattern of oscillations is not well established. To address this issue, pollen analysis was performed at Ciénega San Marcial, a monsoon‐influenced site located on the southeastern edge of the Sonoran Desert at the limit of the tropical thornscrub. The pollen record covers the Late Wisconsinan glacial termination II, from 15 650 to 13 400 cal. a BP, including GS‐2 and the Lateglacial interstadial, and a recent historical period (AD c. 1919 to 2004). We applied the modern analogue technique, in which pollen taxa are assigned to plant functional types (PFTs), to reconstruct the past climates. At the end of GS‐2, a Juniperus–Pinus woodland is indicative of annual temperatures 10±2 °C colder than present and higher annual precipitation dominated by winter rains. The onset of the Lateglacial interstadial occurs at c. 15 500 cal. a BP, resulting in a lower sedimentation rate and the spread of a xeric grassland. This period is associated with an increase in summer insolation. A weak signal of summer monsoon intensification is dated to 14 825 cal. a BP but is associated with colder winter temperatures. A wider spread of tropical taxa occurs after 13 800 cal. a BP, along with the loss of Juniperus, suggesting a temperature increase of approximately 3 °C. In spite of the earlier Lateglacial warming, the transition from glacial to interstadial conditions seems to be related to North Atlantic atmospheric variations. We conclude that during the last glacial–interglacial transition, the Sonoran Desert at 28.5° latitude was sensitive to climate variations originating in northern latitudes. The recent historical sequence displays summer‐dominant precipitation and additional drivers of climate change, including anthropogenic factors and El Niño, thus showing a stronger Pacific circulation influence in the subrecent period.  相似文献   

Inorganic ions and trace metals bulk deposition at an Atlantic Coastal European region     

Jorge Moreda-Piñeiro  Elia Alonso-Rodríguez  Isabel Turnes-Carou  Carmen Moscoso-Pérez  Gustavo Blanco-Heras  Loreto Gómez Tellado  Purificación López-Mahía  Soledad Muniategui-Lorenzo  Darío Prada-Rodríguez 《Journal of Atmospheric Chemistry》2017,74(1):1-21

The inorganic chemical composition (major ions and trace metals) of bulk deposition samples collected monthly with bulk collectors at seven Atlantic Coastal European cities (Galicia, Northwest of Spain) during wet season (September 2011 to March 2012) has been assessed and compared. Trace metals (Al, As, Ba, Co, Cr, Cu, Fe, Mn, Ni, Pb, Sr, V and Zn) were analysed in soluble fraction and non-soluble fraction (after acid extraction) of the bulk deposition by inductively coupled plasma-mass spectrometry. Major inorganic ions (Cl^?, NO₃ ^?, SO₄ ^2?, Na⁺, K⁺, Ca²⁺, Mg²⁺ and NH₄ ⁺) were analysed in the soluble fraction of the bulk deposition by capillary zone electrophoresis. Univariate analysis (ANOVA and Multiple Range Test) according to the location of each sampling site was performed. Results also suggest a great influence of cleaner Atlantic air masses. After partition coefficients and enrichment factor estimation, similar sources could be assigned for the ionic and metal composition of bulk deposition at seven urban sites.  相似文献   

Temporal changes of mollusc populations from a Zostera marina bed in southern Spain (Alboran Sea), with biogeographic considerations     

María del Carmen Arroyo  Carmen Salas  José Luis Rueda  & Serge Gofas 《Marine Ecology》2006,27(4):417-430

Molluscs associated with a Zostera marina bed from Cantarriján bay (Southern Spain, Alboran Sea) at 14–16 m depth were sampled monthly from October 1996 to September 1997. A total of 44,819 individuals belonging to 80 species were identified. In spite of the high species richness, only seven species of gastropods showed a dominance value (D) higher than 1%. Jujubinus striatus was the dominant species of the assemblage with 70.8% of the total abundance. The other dominant species were Rissoa membranacea (9.8%), Nassarius pygmaeus (5.8%), Mitrella minor (4%), Smaragdia viridis (1.9%), Rissoa monodonta (1.4%), Bittium reticulatum (1.3%). The dynamic pattern of the mollusc populations showed a temporal trend with monthly values of species richness and abundance ranging between 10 and 25 species and between 178 and 4412 individuals·222 m⁻². The species richness and abundance were higher in the spring and summer months than in the autumn and winter ones. The diversity (Shannon–Wiener, H’) follows a similar trend, with increases from April to September and decreases from October to March. H’ values (ranging from 0.45 to 3.10) are more influenced by the evenness (J) than by the species richness. A multivariate analysis (Cluster, Multi-dimensional Scaling) based on both presence/absence and quantitative data has also pointed out a temporal trend, with spring–summer samples significantly different from autumn–winter samples. The temporal changes in abundance seem related with the species’ biology, such as recruitment events, as well as to the canopy features and shoot density variation in the Zostera meadow. From the biogeographical point of view, most of the molluscs (65%) found in the Cantarriján bed, have a Lusitanian–Mediterranean distribution (sensu Ekman 1953 ). The proximity to Africa is shown by the presence of four species with a mainly West African distribution. Only R. membranacea has a typical Atlantic distribution, driven by that of Z. marina in NW Europe.  相似文献   

Quantitative paleolimnological inference models applied to a high-resolution biostratigraphic study of lake degradation and recovery,Onondaga Lake,New York (USA)     

H. Chandler Rowell  Mihaela D. Enache  Roberto Quinlan  Alison J. Smith  Jay A. Bloomfield  Donald F. Charles  Steven W. Effler 《Journal of Paleolimnology》2016,55(3):241-258

  相似文献   

Trace element associations with Fe- and Mn-oxides in soil nodules: Comparison of selective dissolution with electron probe microanalysis   总被引：1，自引：0，他引：1  

Alexander Neaman  Carmen Enid Martínez  Fabienne Trolard  Guilhem Bourrié 《Applied Geochemistry》2008

Selective dissolution methods have been largely used to get insight on trace element association with solid phases. Modern instrumental techniques offer many tools to test the validity of selective dissolution methods and should be systematically used to this end. The association of trace elements with Fe- and Mn-oxides in soil nodules has been studied here by electron probe microanalysis. The results were compared with findings from an earlier study on selective dissolution of the same nodules by hydroxylamine hydrochloride, acidified hydrogen peroxide, and Na-citrate-bicarbonate-dithionite. Electron probe microanalysis results were consistent with previous findings using selective dissolution and showed that P, As and Cr were mainly present in Fe-oxides, while Co was mainly associated with Mn-oxide phases. These results support the applicability of the studied selective dissolution methods for fractionation of trace elements in soils and sediments containing appreciable amounts of Fe and Mn-oxide phases.  相似文献