Impacts of Methane on Carbon Dioxide Storage in Brine Formations          下载免费PDF全文

Mohamad R. Soltanian  Mohammad A. Amooie  David R. Cole  Thomas H. Darrah  David E. Graham  Susan M. Pfiffner  Tommy J. Phelps  Joachim Moortgat 《Ground water》2018,56(2):176-186

In the context of geological carbon sequestration (GCS), carbon dioxide (CO₂) is often injected into deep formations saturated with a brine that may contain dissolved light hydrocarbons, such as methane (CH₄). In this multicomponent multiphase displacement process, CO₂ competes with CH₄ in terms of dissolution, and CH₄ tends to exsolve from the aqueous into a gaseous phase. Because CH₄ has a lower viscosity than injected CO₂, CH₄ is swept up into a ‘bank’ of CH₄‐rich gas ahead of the CO₂ displacement front. On the one hand, this may provide a useful tracer signal of an approaching CO₂ front. On the other hand, the emergence of gaseous CH₄ is undesirable because it poses a leakage risk of a far more potent greenhouse gas than CO₂ if the cap rock is compromised. Open fractures or faults and wells could result in CH₄ contamination of overlying groundwater aquifers as well as surface emissions. We investigate this process through detailed numerical simulations for a large‐scale GCS pilot project (near Cranfield, Mississippi) for which a rich set of field data is available. An accurate cubic‐plus‐association equation‐of‐state is used to describe the non‐linear phase behavior of multiphase brine‐CH₄‐CO₂ mixtures, and breakthrough curves in two observation wells are used to constrain transport processes. Both field data and simulations indeed show the development of an extensive plume of CH₄‐rich (up to 90 mol%) gas as a consequence of CO₂ injection, with important implications for the risk assessment of future GCS projects.  相似文献   

The Influence of Streambed Heterogeneity on Hyporheic Flow in Gravelly Rivers     

YaoQuan Zhou  Robert W. Ritzi Jr.  Mohamad Reza Soltanian  David F. Dominic 《Ground water》2014,52(2):206-216

Deposits of open‐framework gravel occurring in gravelly streambeds can exert a significant influence on hyporheic flow. The influence was quantified using a numerical model of the hyporheic zone. The model included open‐framework gravel stratasets represented with commonly observed characteristics including a volume fraction of about one‐third of the streambed sediment, a hydraulic conductivity two orders of magnitude greater than other strata present, and a spatial connectivity forming preferential‐flow pathways. The influence of open‐framework gravel stratasets on hyporheic flow was much greater than the influence of the channel morphology including meanders, point bars, dunes, and ripples. Seventy percent of the total hyporheic exchange occurred across 30% of the channel boundary at locations of open‐framework gravel stratasets. The maximum local interfacial flux rates occurred at these locations, and were orders of magnitude greater than those at other locations. The local flux rates varied by six orders of magnitude over the channel boundary. The composite flow rate through the model with open‐framework gravel stratsets was an order of magnitude greater than that through an equivalent but homogeneous model.  相似文献   

Behavior of Weak Soils Reinforced with End-Bearing Soil-Cement Columns Formed by the Deep Mixing Method     

Ahmad Safuan A. Rashid  Jonathan A. Black  Hisham Mohamad  Norhazilan Mohd Noor 《Marine Georesources & Geotechnology》2013,31(6):473-486

This article reports on a series of small-scale, plane strain, 1 g physical model tests designed to investigate the bearing capacity and failure mechanics of end-bearing soil-cement columns formed via Deep Mixing (DM). Pre-formed soil-cement columns, 24 mm in diameter and 200 mm in length, were installed in a soft clay bed using a replacement method; the columns represented improvement area ratios, a_p, of 17%, 26%, and 35% beneath a rigid foundation of width 100 mm. Particle Image Velocimetry (PIV) was implemented in conjunction with close-range photogrammetry in order to track soil displacement during loading, from which the failure mechanisms were derived. Bearing capacity performance was verified using Ultimate Limit State numerical analysis, with the results comparing favorably to the analytical static and kinematic solutions proposed by previous researchers. A new equation for bearing capacity was derived from this numerical analysis based on the improvement area ratio and cohesion ratio of the soil column and ground model.  相似文献   

Evaluation of statistical tropospheric scintillation models using SUPERBIRD-C satellite for Malaysia     

Jit Singh Mandeep  Mohamad Tariqul Islam 《Acta Geophysica》2012,60(4):1180-1191

The main purpose of this paper is to evaluate and compare some of the statistical tropospheric scintillation models for one-year data (1999–2000) measured using SUPERBIRD-C satellite in Tronoh, Malaysia. Eight statistical models of monthly mean scintillation intensity are briefly reviewed and their predictions compared with measurements. Results are discussed in order to understand the potentials and the limits of each prediction model within this case study. In the context of our measurements, the Karasawa and Ortgies-T models have the best overall performance. The agreement with satellite measurements is found to be mainly dependent on the parameterization of prediction models to the radiometeorological variables along the earth-space path.  相似文献   

A single-run multi-mode pushover analysis to account for the effect of higher modes in estimating the seismic demands of tall buildings   总被引：1，自引：1，他引：0  

Mehdi Poursha  Mohamad Amin Amini 《Bulletin of Earthquake Engineering》2015,13(8):2347-2365

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A probabilistic model to improve reconciliation of estimated and actual grade in open-pit mining     

Ali Parhizkar  Mohamad Ataei  Parviz Moarefvand  Vamegh Rasouli 《Arabian Journal of Geosciences》2012,5(6):1279-1288

Many of the open-pit mines suffer from the lack of reconciliation between estimated and actual grades. In a mining operation, grade reconciliation is the comparison between the values of the estimated grade calculated in exploration stage and the actual grade obtained from more reliable data such as blast holes?? samples. Many different factors affect the degree of reconciliation in a mining operation. In this paper, the factors related to estimated grade which affect the reconciliation process in the exploration stage of the orebody are investigated. These factors constitute the sources of uncertainty for the upcoming phases of the mining life. Among these parameters, the inherent variability, statistical uncertainty, and systematic uncertainty are the most important factors. In this work, these parameters are studied in further detail, and, accordingly, for each of these uncertainties, a correction factor is determined in the proposed model. The model was applied to the study of real data taken from an iron open-pit mine in Iran. The results of the case study indicated that the systematic uncertainty, inherent variability, and statistical uncertainty are, in order, the main sources of uncertainty on grade reconciliation process. Applying the correction factors to estimated grade values has increased the amount of grade reconciliation from 10%, at original condition, to 50%, at new condition, in the case study.  相似文献   

Composition and source identification of polycyclic aromatic hydrocarbons in mangrove sediments of Peninsular Malaysia: indication of anthropogenic input   总被引：1，自引：1，他引：0  

Muhammad Raza  Mohamad Pauzi Zakaria  Nor Rasidah Hashim  Un Hyuk Yim  Narayanan Kannan  Sung Yong Ha 《Environmental Earth Sciences》2013,70(6):2425-2436

This is a comprehensive study of the composition, origin and sources of specific polycyclic aromatic hydrocarbons (PAHs) in sediments of mangrove estuary in the western part of Peninsular Malaysia. Mangrove sediments were analyzed for 17 PAHs by gas chromatography–mass spectrometry. Total PAH concentrations in the sediments ranged from 20 to 112 ng/g on a dry-weight basis. High molecular weight PAHs were abundant in the sediments. Parent PAH ratios revealed that pyrogenic input has important contribution to the sedimentary PAHs. Ratios of alkylated PAHs indicate that the sedimentary PAHs were influenced by petrogenic PAHs, which implies that petrogenic input has contribution to the sedimentary PAHs but that it is not a major factor in distribution of PAHs within the estuary. Combustion-derived PAHs show a positive and very strong correlation with total PAHs (R ² = 0.926, p < 0.05). Total methylphenanthrenes show very weak correlation with total PAHs (R ² = 0.0928, p < 0.05). The PAH concentrations were found to increase with distance from the upstream of the estuary to the coastal area of the Straits of Malacca. For the assessment of sediment contamination using biological thresholds, none of the individual studied PAH compounds exceeded the values of the effect range low–effect range median guideline and the threshold effects level–probable effects level guideline. This study demonstrates that the sediments of the mangrove ecosystem facing the Straits of Malacca and Sumatra are influenced by anthropogenic PAH inputs as a result of human activities such as biomass burning, vehicle emissions and boating activities.  相似文献   

Sources of sedimentary PAHs in tropical Asian waters: Differentiation between pyrogenic and petrogenic sources by alkyl homolog abundance   总被引：2，自引：0，他引：2  

Mahua Saha  Kaoruko Mizukawa  Hideshige Takada  Mohamad P. Zakaria  Bui Cach Tuyen  Ruchaya Boonyatumanond  Badal Bhattacharya  Touch Seang Tana 《Marine pollution bulletin》2009,58(2):189-200

We collected surface sediment samples from 174 locations in India, Indonesia, Malaysia, Thailand, Vietnam, Cambodia, Laos, and the Philippines and analyzed them for polycyclic aromatic hydrocarbons (PAHs) and hopanes. PAHs were widely distributed in the sediments, with comparatively higher concentrations in urban areas (∑PAHs: ∼1000 to ∼100 000 ng/g-dry) than in rural areas (∼10 to ∼100 g-dry), indicating large sources of PAHs in urban areas. To distinguish petrogenic and pyrogenic sources of PAHs, we calculated the ratios of alkyl PAHs to parent PAHs: methylphenanthrenes to phenanthrene (MP/P), methylpyrenes + methylfluoranthenes to pyrene + fluoranthene (MPy/Py), and methylchrysenes + methylbenz[a]anthracenes to chrysene + benz[a]anthracene (MC/C). Analysis of source materials (crude oil, automobile exhaust, and coal and wood combustion products) gave thresholds of MP/P = 0.4, MPy/Py = 0.5, and MC/C = 1.0 for exclusive combustion origin. All the combustion product samples had the ratios of alkyl PAHs to parent PAHs below these threshold values. Contributions of petrogenic and pyrogenic sources to the sedimentary PAHs were uneven among the homologs: the phenanthrene series had a greater petrogenic contribution, whereas the chrysene series had a greater pyrogenic contribution. All the Indian sediments showed a strong pyrogenic signature with MP/P ≈ 0.5, MPy/Py ≈ 0.1, and MC/C ≈ 0.2, together with depletion of hopanes indicating intensive inputs of combustion products of coal and/or wood, probably due to the heavy dependence on these fuels as sources of energy. In contrast, sedimentary PAHs from all other tropical Asian cities were abundant in alkylated PAHs with MP/P ≈ 1-4, MPy/Py ≈ 0.3-1, and MC/C ≈ 0.2-1.0, suggesting a ubiquitous input of petrogenic PAHs. Petrogenic contributions to PAH homologs varied among the countries: largest in Malaysia whereas inferior in Laos. The higher abundance of alkylated PAHs together with constant hopane profiles suggests widespread inputs of automobile-derived petrogenic PAHs to Asian waters.  相似文献   

Separation of Vanillin from Oil Palm Empty Fruit Bunch Lignin     

Mohamad Nasir Mohamad Ibrahim  Mohamad Yusof Nor Nadiah  Mohd Salleh Norliyana  Coswald Stephen Sipaut  Sollehuddin Shuib 《洁净——土壤、空气、水》2008,36(3):287-291

The separation of vanillin from the lignin of empty fruit bunch oil palm is presented in this study. The lignin was extracted from soda black liquor derived from oil palm empty fruit bunches (EFB) using 20% sulfuric acid. Nitrobenzene oxidation was carried out by adding 50 mg of dry EFB lignin into a mixture of 7 mL of 2 M NaOH and 4 mL of nitrobenzene in a 15 mL steel autoclave. The autoclave was sealed tightly with a screw cap fitted with a Teflon gasket and heated to 165°C for 3 h in a preheated thermostatic oil bath. High performance liquid chromatography (HPLC) was used to determine the concentration of each compound present in the lignin. There were eight compounds detected in the HPLC chromatogram. The crystallization process was then used as a method to separate vanillin from other compounds. Based on the solubility of vanillin in acetone, 15 mL of acetone was added to the residue of the oxidized products and heated to 60°C for 10 min. A yield of 1.6% vanillin was isolated from a 50 mg lignin sample. The isolated compound was analyzed with HPLC, Fourier transform infrared spectrophotometry (FT‐IR) and nuclear magnetic resonance (¹³C‐NMR) for structural verification. The results of the characterization studies proved that the isolated compound is vanillin.  相似文献   

Identifying spatial heterogeneity of coal resource quality in a multilayer coal deposit by multivariate geostatistics     

Mohamad Nur Heriawan  Katsuaki Koike   《International Journal of Coal Geology》2008,73(3-4):307-330

This study presents a new geostatistical approach to characterization of the geometry and quality of a multilayer coal deposit using the data of seam thickness as a geometric property and the contents of ash, sodium, total sulphur, and the heating value as quality properties. A coal deposit in East Kalimantan (Borneo), Indonesia, which has a synclinal geological structure, was chosen as the study site. Semivariogram analysis clarified the strong dependence of heating value on ash content in the top and bottom parts of each seam and the existence of a strong correlation with sodium content over the sub-seams in the same location. The correlations between the geometry and quality of the seams were generally weak. A linear coregionalization model was used to derive the spatial correlation coefficients of two variables at each scale component from the single- and cross-semivariogram matrices. Because the data were correlated spatially in the same seam or over different seams, multivariate techniques (ordinary cokriging and factorial cokriging) were mainly used and the resultant spatial estimates were compared to those derived using a univariate technique (ordinary kriging). A factorial cokriging was effective to decompose the spatial correlation structures with different scales. Another important characteristic was that the sodium content shows distinct segregation: the low zones are concentrated near the boundary of the sedimentary basin, while the high zones are concentrated in the central part. The main component of sodium originates from the abundance of saline water. Therefore, it can be inferred that seawater had stronger effects on the coal depositional process in the central basin than in the border part. The geostatistical modeling results suggest that the thicknesses of all the major seams were controlled by the syncline structure, while the coal qualities chiefly were originated from the coal depositional and diagenetic processes.  相似文献