An experimental investigation of LNAPL migration in an unsaturated/saturated sand   总被引：4，自引：0，他引：4  

Radhey S. Sharma  Mostafa H. A. Mohamed 《Engineering Geology》2003,70(3-4):305-313

Accidental spills of hydrocarbons, such as Light Non-Aqueous Phase Liquids (LNAPLs), are one of the most common sources of subsurface contamination. Migration of LNAPL in a porous medium is influenced by various factors such as the number of fluids present in the unsaturated/saturated zones and the proportion of pores occupied by each fluid. The results for relationship between matric suction and degree of saturation are presented in this paper for water–air, water–LNAPL and LNAPL–air systems in a sand. A simple and reliable setup using Buchner funnel was designed to obtain these relations. It was found that the relationship between matric suction head and degree of saturation is hysteretic for all the fluid systems (water–air, water–LNAPL and LNAPL–air). Furthermore, the amount of hysteresis depended upon the fluid system, with the maximum hysteresis occurring for water–air system. The results suggest that the amount of trapped air depends upon the reversal degree of saturation from drying to wetting.  相似文献   

Geochemistry of an island-arc plutonic suite: Wadi Dabr intrusive complex, Eastern Desert, Egypt     

Fawzy F. Abu El-Ela 《Journal of African Earth Sciences》1997,24(4):473-496

The Wadi Dabr intrusive complex, west of Mersa-Alam, Eastern Desert, Egypt ranges in composition from gabbro to diorite, quartz diorite and tonalite. The gabbroic rocks include pyroxene-horn blend e gabbro, hornblende gabbro, quartz-hornblende gabbro, metagabbro and amphibolite. Mineral chemistry data for the gabbroic rocks indicate that the composition of clinopyroxenes ranges from diopside to augite and the corresponding magma is equivalent to a volcanic-arc basalt. Plagioclase cores range from An₇₅ to An₃₄ for the gabbroic varieties, except for the metagabbro which has An _11–18. The brown amphiboles are primary phases and classified as calcic amphiboles, which range from tschermakitic hornblende to magnesiohornblende. Green hornblende and actinolite are secondary phases. Hornblende barometry and hornblende-plagioclase themometry for the gabbroic rocks estimate crystallisation conditions of 2–5 kb and 885–716°C.The intrusive rocks cover an extensive silica range (47.86–72.54 wt%) and do not exhibit simple straight-line variation on Harker diagrams for many elements (e.g. TiO₂, Al₂O₃, FeO^*, MgP, CaO, P₂O₅, Cr, Ni, V, Sr, Zr and Y). Most of these elements exhibit two geochemical trends suggesting two magma sources.The gabbroic rocks are relatively enriched in large ion lithophile elements (K, Rb, Sr and Ba) and depleted in high field strength elements (Nb, Zr, Ti and Y) which suggest subduction-related magma. Rare earth element (REE) data demonstrate that the gabbroic rocks have a slight enrichment of light REE [(La/Yb)_N=2.67−3.91] and depletion of heavy REE ((Tb/Yb)_N=1.42−1.47], which suggest the parent magma was of relatively primitive mantle source.The diorites and tonalites are clearly calc-alkaline and have negative anomalies of Nb, Zr, and Y which also suggest subduction-related magma. They are related to continental trondhjemites in terms of Rb---Sr, K---Na---Ca, and to volcanic-arc granites in terms of Rb---and Nb---Y.The Wadi Dabr intrusive complex is analogous to intrusions emplaced in immature ensimatic island-arcs and represents a mixture of mantle (gabbroic rocks) and crustal fusion products (diorites and tonalites) modified by fractional processes.  相似文献   

Geochemistry and petrogenesis of Sikait leucogranite, Egypt: an example of S-type granite in a metapelitic sequence   总被引：1，自引：0，他引：1  

F. H. Mohamed  M. A. Hassanen 《International Journal of Earth Sciences》1997,86(1):81-92

 The Sikait leucogranite (SLG) is a body of porphyritic garnet granite intruded a metapelitic sequence and interlayered orthogneisses. Multiple deformation and low- to medium-grade metamorphism of the sequence was closely associated with pluton emplacement. Textural features of the SLG indicate that subsolidus plastic deformation was induced during the extensive thrusting. The granite is strongly peraluminous, alkali-rich and HFS (high field-strength) elements-depleted with low contents of REE, all facts that substantiate the geochemical characteristics of S-type granites. The geologic and geochemical features are consistent with a dehydration melting model of the hosted metapelites to generate the peraluminous SLG. However, geochemical modelling of trace elements and REEs suggest that the anatectic partial melt was subsequently affected by fractional crystallization of feldspars. This could explain much of the chemical attributes of SLG. Received: 20 September 1994 / Accepted: 2 August 1996  相似文献   

Mapping the crustal thickness in southwest Japan using Moho-reflected waves     

Mohamed K Salah  Dapeng Zhao 《Physics of the Earth and Planetary Interiors》2004,141(2):79-94

In this work we have tried to detect and collect later phases associated with the Moho discontinuity and use them to study the lateral variations of the crustal thickness in southwest (SW) Japan. We first compute synthetic seismograms for local earthquakes taking into account the focal mechanism solutions estimated from first motion polarity data. Then we compare the synthetics with the observed waveforms to detect the major later phases in seismograms of shallow crustal earthquakes in SW Japan. Taking the advantage of the high quality and great quantity of Hi-net waveform data now available throughout the entire Japan Islands, we have detected 1659 Moho-reflected phases (PmP and SmS) from shallow events in SW Japan. We estimated the crustal thickness in the study area using travel time differences between these later phases and the first P and S arrivals. Our results show that the Moho is deep in Chubu district and becomes shallower along the coastlines of the Japan Sea and the Pacific Ocean. A thinner crust appears in Osaka Bay and Awajii Island where the 1995 Kobe earthquake (M7.2) occurred.  相似文献   

Hydro-thermal performance of multilayer capillary barriers in arid lands     

A. M. O. Mohamed  I. Shooshpasha 《Geotechnical and Geological Engineering》2004,22(1):19-42

In this study, a capillary barrier system was designed and tested for an arid land environment. To simulate arid land conditions of high temperature and sub-irrigation systems, the barrier was subjected to thermal and hydraulic gradients in opposite directions; to test the barrier system under these severe conditions, an experimental apparatus was designed and fabricated. The multilayer capillary barrier consisted of three layers made of silica sand, a mixture of sand and bentonite in equal portions, and a mixture of clay (25%) and aggregate (75%). Several one dimensional coupled heat and moisture tests were performed. Temperature variations along the thickness of the barrier were recorded as a function of time, and at the end of each test, the barrier was sliced into small sections, for the determination of volumetric water content as a function of distance from the heat source. The experimental results were discussed in view of the barrier's intended purpose of its ability to store moisture for long time durations. Coupled heat and moisture flow equations were developed and solved numerically via a finite difference method. Diffusivity parameters were calculated by using experimental results, a numerical model, and Powell's conjugate directions method of nonlinear optimization. The model was calibrated and the results were discussed. Good agreement between calculated and experimental results was obtained. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Origin of layering in cumulate gabbros in the Oman ophiolite: Insights from magnetic susceptibility measurements in the Wadi Sadm area     

Kiichiro  Kawamura  Takahiro  Hosono  Huda Mohamed  Allawati  Yujiro  Ogawa  Hidetsugu  Taniguchi 《Island Arc》2005,14(4):564-570

Abstract   Magnetic susceptibility and the anisotropy of magnetic susceptibility were measured on an 800-cm-thick succession of cumulate gabbro in the Sadm area of the Oman ophiolite. The section contained three distinct cumulate units. The susceptibility tends to decrease upward in each from a melanocratic layer (several tens of centimeters thick) to a leucocratic layer (a few meters thick). The susceptibility decreases in accordance with the decreasing number of magnetite grains, which are the alteration product mainly of olivine minerals. This suggests the cyclic downward accumulation of olivine in the cumulate gabbro. The apparent strain deduced from the patterns of magnetic and grain fabrics was the result mostly of simple shear, so that the layering of gabbro is understood to be formed primarily by a crystal cumulus process followed by simple shear deformation.  相似文献   

Interpretation of gamma-ray logs: The distribution of uranium in carbonate platform     

Mohamed Chaker Raddadi  Annie Arnaud Vanneau  Grard Poupeau  Elisabeth Carrio-Schaffhauser  Hubert Arnaud  Alice Rivera 《Comptes Rendus Geoscience》2005,337(16):96

High gamma-radioactivity in carbonates is usually ascribed to uranium of detrital minerals and organic matter, and to thorium and potassium of clays. The present study based on Urgonian marls and marly limestones (France) shows that some of the most radioactive values correspond instead to some ‘pure’ limestones. These peaks are generally associated with a sequence boundary or a maximum flooding surface. Low-level γ-spectrometry and ICP–MS analyses show that although high radioactivities are mostly associated with uranium, there is no obvious correlation between uranium enrichment and lithology. Also, correlation between high radioactivity and argillaceous beds might not be systematic. To cite this article: M.C. Raddadi et al., C. R. Geoscience 337 (2005).  相似文献   

Production of a molybdophore during metal-targeted dissolution of silicates by soil bacteria   总被引：1，自引：0，他引：1  

Laura J. Liermann  Robin L. Guynn  Ariel Anbar  Susan L. Brantley   《Chemical Geology》2005,220(3-4):285-302

Although many bioessential metals are scarce in natural water and rock systems, microbial secretion of high-affinity ligands for metal extraction from solid phases has only been documented for Fe. However, we have discovered that Mo is extracted from a silicate by a high-affinity ligand (a possible “molybdophore”) secreted by an N₂-fixing soil bacterium. The putative molybdophore, aminochelin, is secreted as a siderophore under Fe-depleted conditions, but is also secreted under Fe-sufficient, Mo-depleted conditions. Presumably, molybdophore production facilitates uptake of Mo for use in Mo enzymes. In contrast, an Fe-requiring soil bacterium without a special Mo requirement only enhances the release of Fe from the silicate. Fractionation of Mo stable isotopes during uptake to cells may provide a “fingerprint” for the importance of chelating ligands in such systems. Many such metal-specific ligands secreted by prokaryotes for extraction of bioessential metals, their effects on Earth materials, and their possible utility in the recovery of economic metals remain to be discovered.  相似文献   

Halocinèse précoce associée au rifting jurassique dans l'Atlas central de Tunisie (région de Majoura–El Hfay)     

Dorra Tanfous Amri  Mourad Bédir  Mohamed Soussi  Hajer Azaiez  Lahoussine Zitouni  M. Hédi Inoubli  Kamel Ben Boubaker 《Comptes Rendus Geoscience》2005,337(7):703-711

Seismic and sequence stratigraphy analyses, petroleum-well control and surface data studies of the Majoura–El Hfay region in the Central Atlas of Tunisia had led to identify and calibrate Jurassic seismic horizons. Seismic stratigraphic sections, seismic tectonics analyses, isochron and isopach mapping of Jurassic sequences show a differentiated structuring of platform and depocentre blocks limited by deep-seated NE–SW, north–south east–west and NW–SE faults intruded by Upper Triassic salt. The early salt migration seems to have started by the platform fracturing during the Lower Liassic rifting event. These movements are fossilized by thickness variations of Jurassic horizons, aggrading and retrograding onlap and toplap structures between subsiding rim-syncline gutters and high platform flanks intruded by salt pillows and domes. The salt migration is also attested by Middle and Upper Jurassic space depocentre migrations. Around the Majoura–El Hfay study blocks bounded by master faults, Triassic salt have pierced the Cretaceous and Tertiary sedimentary cover in a salt diapir extrusion and salt wall structures. To cite this article: D. Tanfous Amri et al., C. R. Geoscience 337 (2005).  相似文献   

Structure de socle,sismostratigraphie et héritage structural au cours du rifting au niveau de la marge d'Ifni/Tan-Tan (Maroc sud-occidental)     

Naïma AbouAli  Mohamad Hafid  El Hassane Chellaï  Mohamed Nahim  Mahmoud Zizi 《Comptes Rendus Geoscience》2005,337(14):1267-1276

Seismic reflection profiles from the Ifni/Tan-Tan Atlantic margin of southern Morocco, interpreted in the light of well data and field geology from the Western Anti-Atlas, allowed us to establish the seismostratigraphic framework of the syn-rift series and to reveal (i) a compressional structural style in the pre-Triassic basement similar to that established in the adjacent outcropping onshore basement but with an opposed western vergence, (ii) the importance of inherited anterior structures in the formation of Triassic-Liassic rift structures and (iii) an east–west propagation of these rift structures. To cite this article: N. AbouAli et al., C. R. Geoscience 337 (2005).  相似文献