Magnetic Removal of Reactive Black 5 from Wastewater Using Ionic Liquid Grafted‐Magnetic Nanoparticles     

Tahereh Poursaberi  Mostafa Hassanisadi 《洁净——土壤、空气、水》2013,41(12):1208-1215

Due to the unique chemical properties and therefore wide range of applications, significant amounts of reactive dyes often end up in waste waters and this issue raises the need for more efficient treatment technologies. This work investigates the ability of magnetite nanoparticles functionalized with imidazolium based ionic liquid (IL) as an efficient sorbent for the removal of the Reactive black 5 from wastewater. Fourier transform infrared spectroscopy, X‐ray diffraction, transmission electron microscopy, thermo‐gravimetric analysis, and zeta potential measurement were used to characterize the synthesized nanosorbent. The results showed that under optimal conditions, the dye removal efficiency of the grafted IL is 98.5% after a single run. Regeneration of the used sorbent could be possible and the modified magnetic nanoparticles exhibited good reusability. The isothermal data of RB5 sorption conformed well to the Langmuir model and the maximum sorption capacity of IL@Fe₃O₄ for RB5 was 161.29 mg g^?1. Thermodynamic study indicated that the adsorption is endothermic and spontaneous. The use of such a system can provide fast and efficient removal of the reactive dyes from wastewater by using an external magnetic field.  相似文献   

Identifying geological hazards related to tunneling in carbonate karstic rocks - Zagros, Iran   总被引：1，自引：0，他引：1  

Hamid Reza Zarei  Ali Uromeihy  Mostafa Sharifzadeh 《Arabian Journal of Geosciences》2012,5(3):457-464

The construction of tunnels in carbonate karstic rocks has always been the most hazardous and problematic task in civil and mining engineering, as it can threaten tunneling project from safety, time and economic aspects. Therefore, it is essential to identify hazards resulting from construction in early stages of a project. The present paper is aimed to identify main geological hazards related to tunneling in carbonate karstic rocks in the Zagros Mountains. The process of identification relies upon a review of construction experiences obtained from several projects with a focus on the Kuhrang Tunnels. Obviously, groundwater inrush and tunnel flooding, ground inflow and fill-back of the tunnel, instability of weak fill materials, and TBM jamming are the main potential hazards of tunneling in the Zagros Mountains, imposing huge problems during construction. Inadequate understanding of hazards and not being prepared enough to take appropriate countermeasures are the main sources of the problems. In addition, the investigation of the present study provides guidelines to reduce the risks of tunneling in the carbonate karstic rocks with similar geological condition.  相似文献   

Influence of climate, mineralogy and mineral processing on the weathering behaviour within two, low-sulfide, high-carbonate, gold mine tailings in the Eastern Desert of Egypt     

Mostafa Redwan  Dieter Rammlmair 《Environmental Earth Sciences》2012,65(7):2179-2193

Despite its importance within environmental management strategies, little concern is shown to sulfide oxidation and/or hardpan formation at neutral pH where dry condition prevails. Two gold mine tailings in Egypt, El Sid and Barramiya, were studied for their geochemical/mineralogical properties, and climate influence on hardpan formation. The tailings are characterised by homogeneous silt-sized sediments (>42%), have high carbonate, predominantly as calcite for El Sid and dolomite-ankerite for Barramiya, and low-sulfide contents, chiefly as pyrite, galena and sphalerite for El Sid, and arsenopyrite–pyrite for Barramiya. El Sid is characterised by high average concentrations of Pb (2,758 mg/Kg) and Zn (2,314 mg/Kg), its lower part dominated by mafics, overlaid by granitoids. Barramiya has higher As (average 2,836 mg/Kg) content and represents a mixture of mica-schists/mafics-ultramafics. During field investigations, no hardpans were identified, only bassanite and gypsum were found at the surface of El Sid tailings, forming thin layers and desiccation crack fillings. Column experiments showed a thin crust consisting of gypsum, halite and sodium sulfate formed at the top of the column of El Sid tailings after 2 weeks, this was not recognized in the column from Barramiya. The homogenous thickened tailings deposition in both areas did not favour hardpan formation, since the critical amounts of reacting sulfides were never achieved in individual lamina, due to missing mineral/grain size fractionation. The high-temperature/low-water availability, characteristic for desert climate regions did not allow significant sulfides oxidation. Therefore, both tailings will suffer from continuous erosion and spreading out of contaminants to the environment for a prolonged period of time by sporadic flash floods.  相似文献   

Degradation of Linear Alkyl Benzene Using an Immobilized Nano TiO2 Photocatalytic Reactor: Process Analysis and Modeling          下载免费PDF全文

Hadis Zangeneh  Ali Akbar Lorestani Zinatizadeh  Mostafa Feyzi 《洁净——土壤、空气、水》2016,44(1):78-88

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Turbulence-particle interactions under surface gravity waves     

Mostafa Bakhoday Paskyabi 《Ocean Dynamics》2016,66(11):1429-1448

The dispersion and transport of single inertial particles through an oscillatory turbulent aquatic environment are examined numerically by a Lagrangian particle tracking model using a series of idealised test cases. The turbulent mixing is incorporated into the Lagrangian model by the means of a stochastic scheme in which the inhomogeneous turbulent quantities are governed by a one-dimensional k- ε turbulence closure scheme. This vertical mixing model is further modified to include the effects of surface gravity waves including Coriolis-Stokes forcing, wave breaking, and Langmuir circulations. To simplify the complex interactions between the deterministic and the stochastic phases of flow, we assume a time-invariant turbulent flow field and exclude the hydrodynamic biases due to the effects of ambient mean current. The numerical results show that the inertial particles acquire perturbed oscillations traced out as time-varying sinking/rising orbits in the vicinity of the sea surface under linear and cnoidal waves and acquire a non-looping single arc superimposed with the high-frequency fluctuations beneath the nonlinear solitary waves. Furthermore, we briefly summarise some recipes through the course of this paper on the implementation of the stochastic particle tracking models to realistically describe the drift and suspension of inertial particles throughout the water column.  相似文献   

A novel approach to estimate the variations in stresses and fault state due to depletion of reservoirs     

Pouria Behnoud far  Mohammad Javad Ameri  Mostafa Orooji 《Arabian Journal of Geosciences》2017,10(18):397

Geomechanical changes may occur in reservoirs due to production from reservoirs. Study of these changes has an important role in upcoming operations. Frictional equilibrium is one of the items that should be determined during the depletion as it may vary with respect to time. Pre-existing faults and fractures will slide in regions where there is no frictional equilibrium. Hence, it may be concluded that reduction in pore pressure can initiate the sliding of faults. Whereas, it is also possible that faults will not exist after a certain time as production recovers the equilibrium. Casing shearing or lost circulation may be occurred due to faulting. In reservoirs which depletion leads to frictional equilibrium, decrease of fractures and faults leads to some variations in permeability. Hence, predicting the effect of depletion on frictional equilibrium is required in dealing with casing shearing or lost circulation in drilling of new wells. In addition, permeability modeling will be more precise during the life of reservoirs. Estimation of necessary time to create or vanish faults is vital to be successful in production from wells or drilling new wells. Achieving or loosing of equilibrium mainly depends on in situ stresses and rate of production. Estimation of the in situ stresses at the initiation state of reservoir is the key to study the state of faults. The next step is to predict the effects of depletion on in situ stresses. Different models are suggested in which decrease of horizontal stresses is predicted as function of pore pressure variation. In these models, different assumptions are made such as simplifying the poroelastic theory, ignoring the passing time, and considering the geometry of reservoir. In this article, a new model is proposed based on theory of inclusions and boundary element method. This state-of-the-art model considers the geometry of reservoir. In addition, changes of in situ are obtained as a function of time to reach to a more precise model capable of applying during the reservoir life. Finally, the model is imposed on real cases. The effect of depletion on faults is studied in reservoirs of normal and strike-slip stress regimes, and conventional and proposed models are compared. For this aim, in the first step, mechanical earth models of these two reservoirs are built using logging and coring data. Stress polygon method and poroelastic horizontal strain model are used for strike-slip and normal regimes, respectively. In reservoir 1 which is in a strike-slip stress regime, a fault is distinguished in formation microimaging (FMI) log. For this reservoir, the required time to achieve to frictional equilibrium is calculated. In the reservoir 2, the potential depth of fault sliding is analyzed and required time for faulting in that depth is predicted. The predicted time for satisfaction of frictional equilibrium using the proposed model has a significant difference with the predicted time using the previous methods. In addition, the proposed model predicts that different parts of reservoir 2 are willing for faulting during depletion. The previous model determines only one point that faulting may happen. It is necessary to use this new model to consider different important factors such as geometry and time to gain more accurate predictions.  相似文献   

Trace Elements in Sediments and Mussels – Spatial Distribution,Chemical Partitioning,and Risk Assessment     

Mohammed A. Khairy  Marit Kolb  Christiane Schmidt  Dieter W. Zachmann  Alaa R. Mostafa  Anwar A. EL‐Fiky  Müfit Bahadir 《洁净——土壤、空气、水》2010,38(12):1184-1193

Sediment samples were collected from 30 different locations in Abu Qir Bay (Mediterranean Sea), East Alexandria, Egypt and analyzed for trace elements. The highest concentrations of most of the elements were observed in the nearshore stations in the vicinity of the major anthropogenic activities as industrial settlements, wastewater discharges, and agricultural drainage. In addition, mussel samples of Mactra corallina and Tapes decussata were collected corresponding to the sediment samples. Concentrations of As, Cd, Cr, Mn, and Zn in the mussel tissues were higher than concentrations in sediments, thus indicating their relatively high bioavailability. Sequential extraction procedure was performed on selected sediment samples. Significant correlations were observed between the concentrations of Cu, Mn, Pb, and Zn in the exchangeable fraction of the sediments and the corresponding tissues of M. corallina. The output of the risk assessment applied on the sediments revealed that adverse ecological effects to benthic species could occur and that a higher level of risk is expected from the exposure to Cd, Cr, Hg, and Zn. No adverse carcinogenic or non‐carcinogenic human health effects are expected from the consumption of the two mussel species from Abu Qir Bay.  相似文献   

Design and Application of Underground Mine Paste Backfill Technology   总被引：2，自引：0，他引：2  

Tikou Belem  Mostafa Benzaazoua 《Geotechnical and Geological Engineering》2008,26(2):147-174

This paper reviews the design and application of paste backfill in underground hard rock mines used as ground support for pillars and walls, to help prevent caving and roof falls, and to enhance pillar recovery for improved productivity. Arching after stope filling reduces vertical stress and increases horizontal stress distribution within the fill mass. It is therefore important to determine horizontal stress on stope sidewalls using various predictive models in the design of paste backfill. Required uniaxial compressive strength (UCS) for paste backfill depends on the intended function, such as vertical roof support, development opening within the backfill, pillar recovery, ground or pillar support, and working platform. UCS design models for these functions are given. Laboratory and backfill plant scale designs for paste backfill mix design and optimization are presented, with emphasis on initial tailings density control to prevent under-proportioning of binder content. Once prepared, paste backfill is transported (or pumped) and placed underground by pipeline reticulation. The governing elements of paste backfill transport are rheological factors such as shear yield stress, viscosity, and slump height (consistency). Different models (analytical, semi-empirical, and empirical) are given to predict the rheological factors of paste backfill (shear yield stress and viscosity). Following backfill placement underground, self-weight consolidation settlement, internal pressure build-up, the arching effect, shrinkage, stope volume, and wall convergence against backfill affect mechanical integrity. An erratum to this article can be found at  相似文献   

Tidal asymmetry in a tidal creek with mixed mainly semidiurnal tide,Bushehr Port,Persian Gulf     

Seyed Taleb Hosseini  Vahid Chegini  Masoud Sadrinasab  Seyed Mostafa Siadatmousavi  Sadegh Yari 《Ocean Science Journal》2016,51(2):195-208

This study investigated the tidal asymmetry imposed by both the interaction of principal tides and the higher harmonics generated by distortions within a tidal creek network with mixed mainly semidiurnal tide in the Bushehr Port, Persian Gulf. Since velocity and water-level imposed by principal triad tides K₁-O₁-M₂ are in quadrature, duration asymmetries during a tidal period in this short, shallow inverse estuary should be manifest as skewed velocities. The principal tides produce periodic asymmetries including a strong ebb-dominance and a weak flood-dominance condition during spring and neap tides respectively. The higher harmonics induced by nonlinearities engender a flood-dominance condition where the convergence effects are higher than frictional effects, and an ebbdominance condition where intertidal storage are extended. Since the triad K₁-O₁-M₂ driven asymmetry is not overcome by higher harmonics close to the mouth, the periodic asymmetry dominates within the creek in which higher harmonics reinforce the weak flood-dominance (strong ebb-dominance) condition in the convergent channel (divergent area). Also, the maximum flood and the maximum ebb from all harmonic constituents occurred close to high water slack time during both spring and neap tides in this short creek. Since occational wetting of intertidal areas happened close to the high water (HW) time during spring tide, the water level flooded slowly close to the HW time of the spring tide.  相似文献