Determination of mercury biogeochemical fluxes in the remote Mackenzie River Basin,northwest Canada,using speciation of sulfur and organic carbon     

Jesse Carrie  Gary A. Stern  Hamed Sanei  Robie W. Macdonald  Feiyue Wang 《Applied Geochemistry》2012

The Mackenzie River Basin (MRB) in NW Canada is one of the least human-impacted large watersheds in the world. The western and eastern sub-basins of the MRB are also marked by contrasting geology, geomorphology, hydrology, and biology. These remarkable differences in a remote river basin provide a unique opportunity to probe the biogeochemical processes governing the sources, transport, and bioavailability of Hg at the terrestrial-marine interface and ultimately in the Arctic Ocean. Based on a large dataset of the concentration and speciation of Hg, S and organic matter in surface sediments across the MRB, a source-apportioned budget was constructed for Hg in the MRB. The results indicate that the Hg flux in the basin originates primarily from the weathering of sulfide minerals in the western mountainous sub-basin (∼78% of the total), followed by the erosion of coal deposits along the mainstream of the Mackenzie River (∼10%), with the remainder split between atmospheric inputs and organic matter-bound Hg (6% and 5%, respectively). Although the Hg flux from the eastern peatland sub-basin only accounts for ∼10% of the total riverine Hg flux, Hg in this region correlates strongly with labile organic matter, and will likely have a much stronger influence on local biota.  相似文献   

Identification and isotopic studies of early Cambrian magmatism (El Carancho Igneous Complex) at the boundary between Pampia terrane and the Río de la Plata craton,La Pampa province,Argentina     

Carlos J. Chernicoff  Eduardo O. Zappettini  João O.S. Santos  Marta C. Godeas  E. Belousova  Neal J. McNaughton 《Gondwana Research》2012,21(2-3):378-393

We have identified late Early Cambrian metaigneous rocks very poorly exposed at the Estancia El Carancho, in central La Pampa province, Argentina. They comprise calc–alkaline metadiorite and metagranite, and tholeiitic metapyroxenite and metagabbro. They are jointly referred to as the El Carancho Igneous Complex, and regarded to pertain to the Pampean magmatic arc and backarc, respectively. Titanite U–Pb SHRIMP dating of the metapyroxenite yielded 528 ± 5 Ma, and zircon U–Pb SHRIMP dating of the metadiorite yielded 520 ± 1.4 Ma. Hafnium isotope determinations on the dated zircons show ¹⁷⁶Hf/¹⁷⁷Hf ratios corresponding to positive εHf values from + 7.18 to + 9.37; Hf model ages of the Cambrian zircons yielded 884 Ma. It is interpreted that the metadiorites of the Complex crystallized from an Early Neoproterozoic (Tonian) juvenile source. We argue that the inferred occurrence of juvenile Tonian magmatic rocks in the (otherwise, mostly Paleo-Mesoproterozoic) substratum of the southern Pampia terrane could indicate a zone of thinned basement possibly associated with the early stage of Rodinia's breakup. In addition, the studied segment of the Pampean magmatic arc is contaminated by also juvenile, Late Mesoproterozoic crust, as evidenced by the presence of xenocrystic cores of 1140–1194 Ma – T_DM-Hf 1720 Ma and εHf values of + 3.24 to + 4.85 – in the Cambrian zircons, hence suggesting that the studied segment of the Pampean magmatic arc was intruded into juvenile Late Mesoproterozoic magmatic arc rocks. The El Carancho Igneous Complex would be located at the tectonic boundary between the Pampia terrane and the Río de la Plata craton. This boundary stands out in the aeromagnetic data as a change in the structural orientation about a roughly N-S line located approximately at 65° W and representing the suture zone between the Pampia terrane and the Río de la Plata craton. Our geotectonic model envisages westward dipping subduction of oceanic crust beneath the Pampia terrane; the El Carancho Igneous Complex would, therefore, have been originated on the Pampia side (upper plate) of the suture. Slivers of the arc- and backarc-type rocks would have been tectonically imbricated in the suture zone during the Pampean orogeny.  相似文献   

Retrowedge-related Carboniferous units and coeval magmatism in the northwestern Neuquén province, Argentina     

Eduardo O. Zappettini  Carlos J. Chernicoff  Joao O. S. Santos  Marcelo Dalponte  Elena Belousova  Neal McNaughton 《International Journal of Earth Sciences》2012,101(8):2083-2104

The studied Carboniferous units comprise metasedimentary (Guaraco Norte Formation), pyroclastic (Arroyo del Torreón Formation), and sedimentary (Huaraco Formation) rocks that crop out in the northwestern Neuquén province, Argentina. They form part of the basement of the Neuquén Basin and are mostly coeval with the Late Paleozoic accretionary prism complex of the Coastal Cordillera, south-central Chile. U–Pb SHRIMP dating of detrital zircon yielded a maximum depositional age of 374?Ma (Upper Devonian) for the Guaraco Norte Formation and 389?Ma for the Arroyo del Torreón Formation. Detrital magmatic zircon from the Guaraco Norte Formation are grouped into two main populations of Devonian and Ordovician (Famatinian) ages. In the Arroyo del Torreón Formation, zircon populations are also of Devonian and Ordovician (Famatinian), as well as of Late Neoproterozoic and Mesoproterozoic ages. In both units, there is a conspicuous population of Devonian magmatic zircon grains (from 406?±?4?Ma to 369?±?5?Ma), indicative of active magmatism at that time range. The ε_Hf values of this population range between ?2.84 and ?0.7, and the TDM-(Hf) are mostly Mesoproterozoic, suggesting that the primary sources of the Devonian magmatism contained small amounts of Mesoproterozoic recycled crustal components. The chemical composition of the Guaraco Norte Formation corresponds to recycled, mature polycyclic sediment of mature continental provenance, pointing to a passive margin with minor inputs from continental margin magmatic rocks. The chemical signature of the Huaraco Formation indicates that a magmatic arc was the main provenance for sediments of this unit, which is consistent with the occurrence of tuff—mostly in the Arroyo del Torreón Formation and very scarcely in the Huaraco Formation—with a volcanic-arc signature, jointly indicating the occurrence of a Carboniferous active arc magmatism during the deposition of the two units. The Guaraco Norte Formation is interpreted to represent passive margin deposits of mostly Lower Carboniferous age (younger than 374?Ma and older than 326?Ma) that precede the onset of the accretionary prism in Chile and extend into the earliest stage of the accretion, in a retrowedge position. The Arroyo del Torreón and Huaraco formations are considered to be retrowedge basin deposits to the early frontal accretionary prism (Eastern Series) of Chile. The presence of volcanism with arc signature in the units provides evidence of a Mississippian magmatic arc that can be correlated with limited exposures of the same age in the Frontal Cordillera (Argentina). The arc would have migrated to the West (Coastal Batholith) during Pennsylvanian–Permian times (coevally with the later basal accretionary prism/Western Series). The source of a conspicuous population of Devonian detrital zircon interpreted to be of magmatic origin in the studied units is discussed in various possible geotectonic scenarios, the preferred model being a magmatic arc developed in the Chilenia block, related to a west-dipping subduction beneath Chilenia before and shortly after its collision against Cuyania/Gondwana, at around 390?Ma and not linked to the independent, Devonian–Mississippian arc, developed to the south, in Patagonia.  相似文献   

Winter daily precipitation variability over Cumbria, Northwest England     

Robert A. Neal  Ian D. Phillips 《Theoretical and Applied Climatology》2011,106(1-2):245-262

Daily precipitation totals at 55 sites were used to investigate geographic variability in winter (DJF) rainfall over Cumbria, NW England, over an 11-year period. Winter is the wettest season (>800?mm in the mountainous Lake District), with rainfall mechanisms closely linked to North Atlantic forcing. The Lamb weather type catalogue was used to identify rainfall distributions under different wind directions. Precipitation magnitude over Cumbria is much more sensitive to a change in wind direction than the geographic pattern in rainfall, with southwesterly (easterly) winds producing the highest (lowest) spatially averaged daily rainfall totals of 8.2?mm (0.6?mm). S-mode principal components analysis was used to identify the main patterns of precipitation variability. Three principal components (PCs) were retained as being statistically significant (cumulative explained variance for unrotated PCs?=?84.3%), with a correlated PC structure (direct oblimin rotation) best describing the spatial variance in rainfall. PC 1 has a very high index of strength (variance measure?=?40.9), indicating that there is one dominant rainfall pattern. PC 1 shows a gradient between wetter conditions in southwest Cumbria and over the central Lake District and drier conditions in NE Cumbria, and is usually caused by active zonal west to southwest flows. Almost of equal importance to PC 1 is PC 3 (variance measure?=?39.3), which has a more uniform rainfall distribution than PC 1 and is usually caused by fronts stalling over the region. PC 2, which shows an east to west decline in rainfall totals, is much less important than PCs 1 and 3 (variance measure?=?18.6). PC 2??s rainfall pattern can be caused by easterly flows with high pressure over Scandinavia and low pressure over the Continent, or by strong southwesterly flows, with depressions often centred over Scotland. Finally, cluster analysis was carried out to identify precipitation regions for all days and for each wind direction. Clusters were found to be largely stable to changes in wind direction, with stations in the central Lake District often clustered together, thus highlighting the importance of orographic enhancement of rainfall in this region.  相似文献   

Vulnerability before adaptation: Toward transformative climate action     

Jesse Ribot Associate Professor 《Global Environmental Change》2011,21(4):1160-1162

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Landscape response to tipping points in granite weathering: The case of stepped topography in the Southern Sierra Critical Zone Observatory     

Barbara S. Jessup  W. Jesse Hahm  Scott N. Miller  James W. Kirchner  Clifford S. Riebe 《Applied Geochemistry》2011

The dynamics of granitic landscapes are modulated by bimodal weathering, which produces patchy granular soils and expanses of bare rock ranging from meter-scale boulders to mountain-scale domes. We used terrain analysis and with cosmogenic nuclide measurements of erosion rates to quantitatively explore Wahrhaftig’s decades-old hypothesis for the development of “stepped topography” by differential weathering of bare and soil-mantled granite. According to Wahrhaftig’s hypothesis, bare granite weathers slower than soil-mantled granite; thus random erosional exposure of bare rock leads to an alternating sequence of steep, slowly weathering bedrock “steps” and gently sloped, but rapidly weathering, soil-mantled “treads.” Our investigation focused on the terrain surrounding the Southern Sierra Critical Zone Observatory (CZO), which is underlain by granitic bedrock and lies outside the limits of recent glaciation, in the heart of the stepped topography described by Wahrhaftig. Our digital terrain analysis confirms that steep steps often grade into gentle treads, consistent with Wahrhaftig’s hypothesis. However, we observe a mix-and-match of soil and bare rock on treads and steps, contrary to one of the hypothesis’ major underpinnings – that bare rock should be much more common on steps than on treads. Moreover, the data show that bare rock is not as common as expected at step tops; Wahrhaftig’s hypothesis dictates that step tops should act as slowly eroding base levels for the treads above them. The data indicate that, within each landscape class (i.e., the steps and treads), bare rock erodes more slowly than surrounding soil. This suggests that the coupling between soil production and denudation in granitic landscapes harbors a tipping point wherein erosion rates decrease when soils are stripped to bedrock. Although broadly consistent with the differential weathering invoked by Wahrhaftig, the data also show that steps are eroding faster than treads, undermining Wahrhaftig’s explanation for the origins of the steps. The revised interpretation proposed here is that the landscape evolves by back-wearing of steps in addition to differential erosion due to differences in weathering of bare and soil-mantled granite.  相似文献   

People helping turtles, turtles helping people: Understanding resident attitudes towards sea turtle conservation and opportunities for enhanced community participation in Bahia Magdalena, Mexico     

Jesse Senko  Andrew J. SchnellerJulio Solis  Francisco Ollervides  Wallace J. Nichols 《Ocean & Coastal Management》2011,54(2):148-157

In Pacific Mexico, all five sea turtle species have declined over the past century due to intense overexploitation of meat and eggs, fisheries bycatch, and degradation of marine and nesting habitats. One of the most heavily impacted areas has been the Baja California peninsula, where sea turtle populations remain historically low despite existing conservation measures that include a complete moratorium on the use of sea turtles, over three decades of widespread protection of nesting beaches, and in-water monitoring of sea turtles at coastal foraging areas. We recognize the need for alternative sea turtle conservation strategies that rely on increased participation of civil society and Mexican citizens. The purpose of this paper was to identify resident attitudes towards sea turtle conservation and opportunities for enhanced community participation in Bahia Magdalena, a region in Baja California Sur, Mexico experiencing high levels of sea turtle poaching and bycatch in fisheries. Through semi-structured interviews we found that while residents were overwhelmingly interested in participating in sea turtle conservation, peer pressure and conflict within the community presented major challenges. The majority of residents indicated that sea turtle voluntourism would have a positive impact on their community. Economic incentives and increased protection for sea turtles were mentioned as benefits of sea turtle voluntourism, whereas peer pressure, difficulty obtaining permits and producing effective marketing materials, and doubt about direct economic benefits were cited as constraints. We discuss our results in terms of opportunities, challenges, and recommendations for improving community-focused sea turtle conservation throughout the region.  相似文献   

Stream water chemistry and quality along an upland–lowland rural land-use continuum, south west England     

H.P. Jarvie  P.M. Haygarth  C. Neal  P. Butler  B. Smith  P.S. Naden  A. Joynes  M. Neal  H. Wickham  L. Armstrong  S. Harman  E.J. Palmer-Felgate 《Journal of Hydrology》2008,350(3-4):215-231

This study examined stream water quality across a range of catchments which are representative of the key environments and land uses of rural south-west England. These catchments included: (a) an acidic upland headwater catchment, rising on the moorlands of Dartmoor, with low-intensity sheep rearing; (b) a headwater catchment rising on the weathered granite lower slopes of Dartmoor, with cattle farming; (c) a lowland headwater clay catchment with sub-surface drainage and high intensity livestock farming, fodder crop cultivation, and hard-standing/slurry storage; and (d) the main River Taw, a lowland river system receiving drainage from a range of tributaries, exemplified by the above catchment types. Variations in water chemistry and quality were observed along an upland–lowland transition, from headwater streams to the main river channel. Within the livestock-dominated headwater streams, total phosphorus (TP) was dominated by particulate phosphorus (PP). These PP concentrations appeared to be mainly linked to two sets of processes: (1) in-stream sediment precipitation with sorption/co-precipitation of phosphate and/or localised in-channel mobilisation of sediment (by cattle or channel-clearing operations) under low flow conditions, and (2) sediment erosion and transportation associated with near-surface runoff during storm events. Under baseflow conditions, in-stream and/or riparian processes played a significant role in controlling general nutrient chemistry, particularly in the headwater streams which were heavily impacted by livestock.  相似文献   

Stratigraphic spatial variation on the inner shelf of a high-yield river,Waiapu River,New Zealand: Implications for fine-sediment dispersal and preservation     

Heidi M. Wadman  Jesse E. McNinch 《Continental Shelf Research》2008

The inner shelves of active, energetic continental margins are frequently defined as regions of sediment segregation and fine-sediment bypassing. The Waiapu River, North Island, New Zealand presents an opportunity to study fine-sediment segregation and strata formation in a spatially constrained, highly energetic, aggradational setting, with one of the highest sediment yields on earth. We present evidence that the inner shelf of the Waiapu River plays a significant role in both the fate of fine-grained (<63 μm) riverine sediments and the formation of continental margin stratigraphy. Results obtained from high-resolution interferometric bathymetry and high-frequency seismic mapping ground-truthed by cores show significant stratigraphic spatial variation preserved on the Waiapu inner shelf. This spatial variation is likely controlled by spatially-distinct sediment deposition and resuspension processes as well as antecedent geology. Two distinct depositional regions are interpreted as: (1) surface plume-dominated with partial resuspension, characterized by acoustically transparent seismic reflection profiles and muddy sands; and (2) event-layer dominated, characterized by thickly laminated sediments. A modern-day bathymetric low overlying an observed paleochannel may influence the fate of hyperpycnal flows transiting the shelf via bathymetric steering. Fining-upward sequences found over the entire shelf are interpreted to represent deforestation-induced sedimentation that has overwhelmed the ability of the energetic system to resuspend and segregate fine sediments. We conclude that the primary control on strata formation on the inner shelf of the Waiapu River is local sediment supply.  相似文献   

哈达门沟金矿床成岩成矿时代的定点定年研究   总被引：25，自引：3，他引：22  

苗来成  Yum in Qiu  关康  Neal M cNaughton  裘有守  罗镇宽  David G roves 《矿床地质》2000,19(2):182-190

哈达门沟大型钾长石 -石英脉型金矿床位于华北地台北缘西段的乌拉山地区。矿区西部的大桦背花岗岩和矿区内的伟晶岩脉与金矿化均具有较为密切的空间关系 ,这导致不少研究者认为哈达门沟金矿床与大桦背岩体或伟晶岩之间也具有时间和成因联系。通过采用先进的高灵敏的高分辨率的离子探针 (SHRIMP)对大桦背岩体、伟晶岩脉和钾长石化蚀变岩进行的锆石 U- Pb定点定年研究表明 :伟晶岩脉形成于 (1836± 5)× 10 6a,属吕梁旋回 ;大桦背岩体形成于 (353± 7)× 10 6a,应为海西旋回早期产物 ;金矿化年龄小于或等于 (132± 2 )× 10 6a,应为燕山晚期。这些年龄结果说明 ,本区金矿化比大桦背岩体晚至少 2 2 0× 10 6a,这排除了金矿化与大桦背岩体和伟晶岩脉之间有任何成因联系的可能性。蚀变岩的年龄还证明 ,虽然乌拉山和胶东地区金矿床的围岩和年龄不同 ,但两地区的金矿化却几乎同时发生。此外 ,大桦背岩体的形成年龄与华北地块和蒙古古陆块碰撞作用发生的时间基本一致 ,因此大桦背岩体的 SHRIMP年龄为这一碰撞作用提供了可靠的年代学证据。  相似文献