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81.
82.
Soil-gas sampling and analysis is a common tool used in vapor intrusion assessments; however, sample collection becomes more difficult in fine-grained, low-permeability soils because of limitations on the flow rate that can be sustained during purging and sampling. This affects the time required to extract sufficient volume to satisfy purging and sampling requirements. The soil-gas probe tubing or pipe and sandpack around the probe screen should generally be purged prior to sampling. After purging, additional soil gas must be extracted for chemical analysis, which may include field screening, laboratory analysis, occasional duplicate samples, or analysis for more than one analytical method (e.g., volatile organic compounds and semivolatile organic compounds). At present, most regulatory guidance documents do not distinguish between soil-gas sampling methods that are appropriate for high- or low-permeability soils. This paper discusses permeability influences on soil-gas sample collection and reports data from a case study involving soil-gas sampling from silt and clay-rich soils with moderate to extremely low gas permeability to identify a sampling approach that yields reproducible samples with data quality appropriate for vapor intrusion investigations for a wide range of gas-permeability conditions.  相似文献   
83.
Biological monitoring of marine contaminants often involves the analysis of metals accumulated in mussel tissues. Critiques of this type of monitoring suggest that although relatively good indications of ambient metal concentrations are determined, actual biological harm is not elucidated. Biomarkers, techniques originally developed in medicine, have recently been employed in an attempt to ascertain the health of marine mussels. Biomarkers have been used with good effect in temperate marine pollution monitoring programmes. The use of biomarkers in the toxicological evaluation of tropical and subtropical waters is, however, generally lacking, which is somewhat surprising, as considerable industrialisation and environmental degradation is taking place in the Pacific-rim countries of Southeast Asia. In the present study, a suite of cytological and physiological biomarkers have been measured from mussels (Perna viridis: Mytilidae) transplanted within the coastal waters of Hong Kong. Mussels from contaminated sites, had labile lysosomal membranes, whereas animals from a cleaner reference site had more stable membranes. These cytological responses have been related to metal-induced stress and are simple, cost-effective markers of pollution. Cardiac activity from mussels transplanted to polluted sites was generally similar to that of individuals from the reference site, although a mild tachycardia was associated with one site. The cause of the tachycardia and the use of heart rate in mussels as a biomarker is discussed. Integrated physiological responses to stress, condition indices, revealed mussels from a clean reference site had higher indices than animals from contaminated sites. The relative sensitivities of the cytological and physiological biomarkers deployed in this study and their application to pollution monitoring is discussed.  相似文献   
84.
Increased resolution and availability of remote sensing products, and advancements in small‐scale aerial drone systems, allows observations of glacial changes at unprecedented levels of detail. Software developments, such as structure‐from‐motion (SfM), now allow users an easy and efficient method to generate three‐dimensional (3D) models and orthoimages from aerial or terrestrial datasets. While these advancements show promise for current and future glacier monitoring, many regions still suffer a lack of observations from earlier time periods. We report on the use of SfM to extract spatial information from various historic imagery sources. We focus on three geographic regions, the European Alps, high Arctic Norway and the Nepal Himalayas. We used terrestrial field photographs from 1896, high oblique aerial photographs from 1936 and aerial handheld photographs from 1978 to generate digital elevation models (DEMs) and orthophotos of the Rhone glacier, Brøggerhalvøya and the lower Khumbu glacier, respectively. Our analysis shows that applying SfM to historic imagery can generate high quality models using only ground control points. Limited camera/orientation information was largely reproduced using self‐calibrated model data. Using these data, we calculated mean ground sampling distances across each site which demonstrates the high potential resolution of resulting models. Vertical errors for our models are ±5.4 m, ±5.2 m and ±3.3 m. Differencing shows similar patterns of thinning at lower Rhone (European Alps) and Brøggerhalvøya (Norway) glaciers, which have mean thinning rates of 0.31 m a?1 (1896–2010) to 0.86 m a?1 (1936–2010) respectively. On these clean ice glaciers thinning is highest in the terminus region and decreasing up‐glacier. In contrast to these glaciers, uneven topography, exposed ice‐cliffs and debris cover on the Khumbu glacier create a highly variable spatial distribution of thinning. The mean thinning rate for the Khumbu study area was found to be 0.54 ± 0.9 m a?1 (1978–2015). Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   
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86.
The nominal tour of the Cassini mission enabled the first spectra and solar phase curves of the small inner satellites of Saturn. We present spectra from the Visual Infrared Mapping Spectrometer (VIMS) and the Imaging Science Subsystem (ISS) that span the 0.25-5.1 μm spectral range. The composition of Atlas, Pandora, Janus, Epimetheus, Calypso, and Telesto is primarily water ice, with a small amount (∼5%) of contaminant, which most likely consists of hydrocarbons. The optical properties of the “shepherd” satellites and the coorbitals are tied to the A-ring, while those of the Tethys Lagrangians are tied to the E-ring of Saturn. The color of the satellites becomes progressively bluer with distance from Saturn, presumably from the increased influence of the E-ring; Telesto is as blue as Enceladus. Janus and Epimetheus have very similar spectra, although the latter appears to have a thicker coating of ring material. For at least four of the satellites, we find evidence for the spectral line at 0.68 μm that Vilas et al. [Vilas, F., Larsen, S.M., Stockstill, K.R., Gaffley, M.J., 1996. Icarus 124, 262-267] attributed to hydrated iron minerals on Iapetus and Hyperion. However, it is difficult to produce a spectral mixing model that includes this component. We find no evidence for CO2 on any of the small satellites. There was a sufficient excursion in solar phase angle to create solar phase curves for Janus and Telesto. They bear a close similarity to the solar phase curves of the medium-sized inner icy satellites. Preliminary spectral modeling suggests that the contaminant on these bodies is not the same as the exogenously placed low-albedo material on Iapetus, but is rather a native material. The lack of CO2 on the small inner satellites also suggests that their low-albedo material is distinct from that on Iapetus, Phoebe, and Hyperion.  相似文献   
87.
This article presents an overview of the land ITCZ (Intertropical Convergence Zone) over West Africa, based on analysis of NCAR–NCEP Reanalysis data. The picture that emerges is much different than the classic one. The most important feature is that the ITCZ is effectively independent of the system that produces most of the rainfall. Rainfall linked directly to this zone of surface convergence generally affects only the southern Sahara and the northern-most Sahel, and only in abnormally wet years in the region. A second feature is that the rainbelt normally assumed to represent the ITCZ is instead produced by a large core of ascent lying between the African Easterly Jet and the Tropical Easterly Jet. This region corresponds to the southern track of African Easterly Waves, which distribute the rainfall. This finding underscores the need to distinguish between the ITCZ and the feature better termed the “tropical rainbelt”. The latter is conventionally but improperly used in remote sensing studies to denote the surface ITCZ over West Africa. The new picture also suggests that the moisture available for convection is strongly coupled to the strength of the uplift, which in turn is controlled by the characteristics of the African Easterly Jet and Tropical Easterly Jet, rather than by moisture convergence. This new picture also includes a circulation feature not generally considered in most analyses of the region. This feature, a low-level westerly jet termed the African Westerly Jet, plays a significant role in interannual and multidecadal variability in the Sahel region of West Africa. Included are discussions of the how this new view relates to other aspects of West Africa meteorology, such as moisture sources, rainfall production and forecasting, desertification, climate monitoring, hurricanes and interannual variability. The West African monsoon is also related to a new paradigm for examining the interannual variability of rainfall over West Africa, one that relates changes in annual rainfall to changes in either the intensity of the rainbelt or north–south displacements of this feature. The new view presented here is consistent with a plethora of research on the synoptic and dynamic aspects of the African Easterly Waves, the disturbances that are linked to rainfall over West Africa and spawn hurricanes over the Atlantic, and with our knowledge of the prevailing synoptic and dynamic features. This article demonstrate a new aspect of the West Africa monsoon, a bimodal state, with one mode linked to dry conditions in the Sahel and the other linked to wet conditions. The switch between modes appears to be linked to an inertial instability mechanism, with the cross-equatorial pressure gradient being a critical factor. The biomodal state has been shown for the month of August only, but this month contributes most of the interannual variability. This new picture of the monsoon and interannual variability shown here appears to be relevant not only to interannual variability, but also to the multidecadal variability evidenced in the region between the 1950s and 1980s.  相似文献   
88.
89.
Soon after the Cassini-Huygens spacecraft entered orbit about Saturn on 1 July 2004, its Visual and Infrared Mapping Spectrometer obtained two continuous spectral scans across the rings, covering the wavelength range 0.35-5.1 μm, at a spatial resolution of 15-25 km. The first scan covers the outer C and inner B rings, while the second covers the Cassini Division and the entire A ring. Comparisons of the VIMS radial reflectance profile at 1.08 μm with similar profiles at a wavelength of 0.45 μm assembled from Voyager images show very little change in ring structure over the intervening 24 years, with the exception of a few features already known to be noncircular. A model for single-scattering by a classical, many-particle-thick slab of material with normal optical depths derived from the Voyager photopolarimeter stellar occultation is found to provide an excellent fit to the observed VIMS reflectance profiles for the C ring and Cassini Division, and an acceptable fit for the inner B ring. The A ring deviates significantly from such a model, consistent with previous suggestions that this region may be closer to a monolayer. An additional complication here is the azimuthally-variable average optical depth associated with “self-gravity wakes” in this region and the fact that much of the A ring may be a mixture of almost opaque wakes and relatively transparent interwake zones. Consistently with previous studies, we find that the near-infrared spectra of all main ring regions are dominated by water ice, with a typical regolith grain radius of 5-20 μm, while the steep decrease in visual reflectance shortward of 0.6 μm is suggestive of an organic contaminant, perhaps tholin-like. Although no materials other than H2O ice have been identified with any certainty in the VIMS spectra of the rings, significant radial variations are seen in the strength of the water-ice absorption bands. Across the boundary between the C and B rings, over a radial range of ∼7000 km, the near-IR band depths strengthen considerably. A very similar pattern is seen across the outer half of the Cassini Division and into the inner A ring, accompanied by a steepening of the red slope in the visible spectrum shortward of 0.55 μm. We attribute these trends—as well as smaller-scale variations associated with strong density waves in the A ring—to differing grain sizes in the tholin-contaminated icy regolith that covers the surfaces of the decimeter-to-meter sized ring particles. On the largest scale, the spectral variations seen by VIMS suggest that the rings may be divided into two larger ‘ring complexes,’ with similar internal variations in structure, optical depth, particle size, regolith texture and composition. The inner complex comprises the C and B rings, while the outer comprises the Cassini Division and A ring.  相似文献   
90.
The surface composition of Titan is of great importance for understanding both the internal evolution of Titan and its atmosphere. The Visual and Infrared Mapping Spectrometer (VIMS) investigation on Cassini is observing Titan from 0.35 to 5.11 μm with spatial resolution down to a few kilometers during each flyby of the spacecraft as it orbits Saturn. Our search for spectral diversity using seven methane transmission windows in the near infrared suggests that spectrally distinct units exist on the surface of Titan and that most of the surface can be modeled using only a few distinct spectral units: water frost, CO2 frost, atmospheric scattering, and an unknown material bright at 2 μm. A dark, spectrally neutral material is also implied. Use of an atmospheric scattering component with spectral mixing analysis may provide a method for partially removing atmospheric effects. In some locations, atmospheric scattering accounts for the majority of the signal. There are also small regions with unusual spectra that may be due to low signal and high noise and/or may be exotic materials of interest. Further, we searched within the methane windows for spectral features associated with Titan's surface. Only the 5-μm and, to a lesser extent, the 2-μm window provide a reasonable opportunity for this, as the shorter-wavelength windows are too narrow and the 2.8-μm window is cluttered with an unknown atmospheric constituent. We find evidence for only one spectral feature: near 4.92 μm for the 5-μm bright Tui Regio region. CO2 frost with grains smaller than about 10 μm is the best candidate we have found so far to explain this absorption as well as the feature's spectral contrast between the 2.7- and the 2.8-μm atmosphere subwindows. This suggested CO2 identification is supported by the presence of an endmember in the spectral mixture analysis that is consistent with CO2 frost with large grain sizes. We find no other absorption features that are statistically significant, including those reported earlier by others. These results are consistent with but greatly extend our early analysis that treated only the Ta data set [McCord, T.B., et al., 2006a. Planet. Space Sci. 54, 1524-1539]. In the spectral feature search process, we explored in detail the noise characteristics of the VIMS data within the 5-μm window, which has generally very low signal (4-20 DN), due to the measurement conditions and low illumination levels. We find noise of nearly Gaussian statistics except for some erratic darks and noise spikes, and the data set seems generally well behaved. We present examples of our attempt to improve on the standard VIMS pipeline data calibration.  相似文献   
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