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The potential for trichloroethene (TCE) biodegradation in a fractured dolomite aquifer at a former chemical disposal site in Smithville, Ontario, Canada, is assessed using chemical analysis and TCE and cis‐DCE compound‐specific isotope analysis of carbon and chlorine collected over a 16‐month period. Groundwater redox conditions change from suboxic to much more reducing environments within and around the plume, indicating that oxidation of organic contaminants and degradation products is occurring at the study site. TCE and cis‐DCE were observed in 13 of 14 wells sampled. VC, ethene, and/or ethane were also observed in ten wells, indicating that partial/full dechlorination has occurred. Chlorine isotopic values (δ37Cl) range between 1.39 to 4.69‰ SMOC for TCE, and 3.57 to 13.86‰ SMOC for cis‐DCE. Carbon isotopic values range between ?28.9 and ?20.7‰ VPDB for TCE, and ?26.5 and ?11.8‰ VPDB for cis‐DCE. In most wells, isotopic values remained steady over the 15‐month study. Isotopic enrichment from TCE to cis‐DCE varied between 0 and 13‰ for carbon and 1 and 4‰ for chlorine. Calculated chlorine‐carbon isotopic enrichment ratios (?Cl/?C) were 0.18 for TCE and 0.69 for cis‐DCE. Combined, isotopic and chemical data indicate very little dechlorination is occurring near the source zone, but suggest bacterially mediated degradation is occurring closer to the edges of the plume.  相似文献   
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There is overwhelming evidence that many local-scale human activities (e.g. fishing) have a deleterious effect on coral reef fish assemblages. Our understanding of how broad social phenomena (e.g. socioeconomic development) affect the diversity and function of coral reef fish assemblages however, is still poor. Here, we use structural equation models to reveal how human population density, socioeconomic development, and market access affect fishing pressure and coral cover to, in turn, explain the diversity and biomass of key functional groups of reef fish assemblages within Solomon Islands. Fishing pressure is predominantly driven by both market access and local population density, and has a clear negative effect on the diversity and function of coral reef fishes. The strong positive effect of market access on fishing pressure makes clear the importance of understanding social-ecological linkages in the context of increasingly connected societies. This study highlights the need to address broad social phenomena rather than focusing on proximate threats such as fishing pressure, to ensure the continued flow of coral reef goods and services in this time of rapid global social and environmental change.  相似文献   
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Five different coastal area morphodynamic models have been set up to run on the same offshore breakwater layout and an intercomparison carried out on the hydrodynamic and morphodynamic output produced by each scheme. In addition, the predicted morphodynamics was checked against available laboratory and field data.It is concluded that the models are capable of producing realistic estimates for the dominant morphodynamic features associated with offshore breakwaters. Coupling of the wave, current and sediment transport components of each scheme is shown to yield bathymetry which attains a state of equilibrium, unlike models which are based on the initial transport field only.  相似文献   
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Natural Hazards - Hurricanes and tropical storms are natural hazards with the capacity to devastate coastal regions. Understanding this catastrophic potential is critical to support informed...  相似文献   
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This paper presents the sediment, landform and dynamic context of four avalanche-fed valley glaciers (Khumbu, Imja, Lhotse and Chukhung) in the Mount Everest (Sagarmatha) region of Nepal. All four glaciers have a mantle of debris dominated by sandy boulder-gravel that suppresses melting to an increasing degree towards the snout, leading to a progressive reduction in the overall slope of their longitudinal profile. Prominent lateral–terminal moraine complexes, also comprising sandy bouldergravel, enclose the glaciers. These terminal moraines originally grew by accretion of multiple sedimentary facies of basal glacial and supraglacial origin, probably by folding and thrusting when the glaciers were more dynamic during the Little Ice Age. The four glaciers are in various stages of recession, and demonstrate a range of scenarios from down-wasting of the glacier tongue, through morainedammed lake development, to post-moraine-dam breaching. Khumbu Glacier is at the earliest stage of supraglacial pond formation and shows no sign yet of developing a major lake, although one is likely to develop behind its >250 m high composite terminal moraine. Imja Glacier terminates in a substantial body of water behind a partially ice-cored moraine dam (as determined from geophysical surveys), but morphologically appears unlikely to be an immediate threat. Chukhung Glacier already has a breached moraine and a connected debris fan, and therefore no longer poses a threat. Lhotse Glacier has an inclined, free-draining tongue that precludes hazardous lake development. From the data assembled, a conceptual model, applicable to other Himalayan glaciers, is proposed to explain the development of large, lateral-terminal moraine complexes and associated potentially hazardous moraine dams. – 2008 Elsevier Ltd. All rights reserved.  相似文献   
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We describe a powerful signal processing method, the continuous wavelet transform, and use it to analyze radial structure in Cassini ISS images of Saturn's rings. Wavelet analysis locally separates signal components in frequency space, causing many structures to become evident that are difficult to observe with the naked eye. Density waves, generated at resonances with saturnian satellites orbiting outside (or within) the rings, are particularly amenable to such analysis. We identify a number of previously unobserved weak waves, and demonstrate the wavelet transform's ability to isolate multiple waves superimposed on top of one another. We also present two wave-like structures that we are unable to conclusively identify. In a multi-step semi-automated process, we recover four parameters from clearly observed weak spiral density waves: the local ring surface density, the local ring viscosity, the precise resonance location (useful for pointing images, and potentially for refining saturnian astrometry), and the wave amplitude (potentially providing new constraints upon the masses of the perturbing moons). Our derived surface densities have less scatter than previous measurements that were derived from stronger non-linear waves, and suggest a gentle linear increase in surface density from the inner to the mid-A Ring. We show that ring viscosity consistently increases from the Cassini Division outward to the Encke Gap. Meaningful upper limits on ring thickness can be placed on the Cassini Division (3.0 m at r∼118,800 km, 4.5 m at r∼120,700 km) and the inner A Ring (10-15 m for r<127,000 km).  相似文献   
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Novel machine-learning and feature-selection algorithms have been developed to study: i) the flare-prediction-capability of magnetic feature (MF) properties generated by the recently developed Solar Monitor Active Region Tracker (SMART); iiSMART’s MF properties that are most significantly related to flare occurrence. Spatiotemporal association algorithms are developed to associate MFs with flares from April 1996 to December 2010 in order to differentiate flaring and non-flaring MFs and enable the application of machine-learning and feature-selection algorithms. A machine-learning algorithm is applied to the associated datasets to determine the flare-prediction-capability of all 21 SMART MF properties. The prediction performance is assessed using standard forecast-verification measures and compared with the prediction measures of one of the standard technologies for flare-prediction that is also based on machine-learning: Automated Solar Activity Prediction (ASAP). The comparison shows that the combination of SMART MFs with machine-learning has the potential to achieve more accurate flare-prediction than ASAP. Feature-selection algorithms are then applied to determine the MF properties that are most related to flare occurrence. It is found that a reduced set of six MF properties can achieve a similar degree of prediction accuracy as the full set of 21 SMART MF properties.  相似文献   
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