Satellite records show that the extent and thickness of sea ice in the Arctic Ocean have significantly decreased since the early 1970s. The prediction of sea ice is highly important, but accurate simulation of sea ice variations remains highly challenging. For improving model performance, sensitivity experiments were conducted using the coupled ocean and sea ice model (NEMO-LIM), and the simulation results were compared against satellite observations. Moreover, the contribution ratios of dynamic and thermodynamic processes to sea ice variations were analyzed. The results show that the performance of the model in reconstructing the spatial distribution of Arctic sea ice is highly sensitive to ice strength decay constant (Crhg). By reducing the Crhg constant, the sea ice compressive strength increases, leading to improved simulated sea ice states. The contribution of thermodynamic processes to sea ice melting was reduced due to less deformation and fracture of sea ice with increased compressive strength. Meanwhile, dynamic processes constrained more sea ice to the central Arctic Ocean and contributed to the increases in ice concentration, reducing the simulation bias in the central Arctic Ocean in summer. The root mean square error (RMSE) between modeled and the CryoSat-2/SMOS satellite observed ice thickness was reduced in the compressive strength-enhanced model solution. The ice thickness, especially of multiyear thick ice, was also reduced and matched with the satellite observation better in the freezing season. These provide an essential foundation on exploring the response of the marine ecosystem and biogeochemical cycling to sea ice changes.
Based on the digital waveforms of the Xinjiang Digital Seismic Network,the Jinghe M_S6.6 earthquake sequence( M_L≥1. 0) were relocated by HypoDD,The characteristics of the spatial distribution and the seismogenic structure of this earthquake sequence were analyzed. The results show that the main shock is relocated at 44. 2639° N,82. 8294° E,and the initial rupture depth is 17. 6 km. The earthquake sequence clearly demonstrates a unilateral extension of about 20 km in the EW direction,and is mainly located at a depth of 7km-17 km. The depth profile along the aftershock direction shows that the focal depth of aftershocks tend to be shallower within 10 km to the west of the main shock,the focal depth of the aftershock sequence with the tail direction deflecting SW is deeper. The depth profile perpendicular to the earthquake sequence shows a gradual deepening of the seismic sequence from north to south,which indicates that the fault plane is dipping south.According to the focal mechanism solution,given by the Institute of Geophysics,China Earthquake Administration,and the geological structure of the seismic source region,it is inferred that the seismogenic structure of the Jinghe M_S 6.6 earthquake may be the eastern segment of the Kusongmuxieke fault. 相似文献
The control of soil pollution in China has become an issue, and in this study, a compound contaminated site was selected and focus on the site and its nearby environment, organochlorine pesticides (OCPs) were investigated in both soil (top and deep soil) and air samples. The main pollutants in top soils at site are dichlorodiphenyltrichloroethane (DDTs, 0.05–104 mg/kg d.w., avg: 14.5 mg/kg d.w.) and hexachlorobenzene (HCB, 0.02–4.85 mg/kg d.w., avg: 0.72 mg/kg d.w.) which is in accordance with its production history. As for the deep soils, ΣOCPs at site were found concentrated at workshops especially the technical pesticide workshop (5.29–22.1 mg/kg d.w., avg: 9.15 mg/kg d.w.) and the history DDTs’ workshop (4.00–64.8 mg/kg d.w., avg: 20.4 mg/kg d.w). Around site, OCPs were mainly concentrated at layers of −20 cm and the −40 cm and decreased with distance being far away, at 5000 m, the ΣOCPs was comparable with normal agriculture soil (22.1−91.4 ng/g d.w., avg: 55.4 ng/g d.w.). ΣOCPs in the air samples ranged 64.6–823 ng/m3 (avg: 459 ng/m3) at site and 9.93–176 ng/m3 (avg: 50.8 ng/m3) around site which are all dominated with DDTs and HCHs. Soil–air exchange fugacity was calculated to judge the transportation of the OCPs and the results showed soils at the site and its nearby areas (within 5000 m) are releasing most of the OCPs into air, and accordingly through evaluation, inhalation was found to be the major source for human health risk, which is a great threat to the workers at site and the nearby residents.
Adsorption by nanoporous media is critically involved in many fundamental geological and geochemical processes including chemical weathering,element migration and enrichment,environmental pollution,etc.Yet,the adsorption behavior of metal ions on nanoporous materials has not been systematically investigated.In this study,MCM-41 material with a monodisperse pore size(4.4 nm)and a large BET specific surface area(839 m^2/g)was hydrothermally prepared and used as a model silica adsorbent to study the adsorption characteristics of Cu^2+as a representative metal ion.The Cu^2+adsorption capacity was found to increase with increasing suspension pH in the range from 3 to 5 and to decrease in the presence of NaNO3.At 25℃,pH=5,and a solid-to-liquid ratio of 5 g/L,the adsorption capacity was determined to be 0.29 mg/g,which can be converted to a dimensionless partition coefficient of 45,indicating a strong enriching effect of nanoporous silica.The adsorption isotherm and kinetic data were fitted to several commonly used thermodynamic,kinetic,and diffusion models.The adsorption mechanism was also studied by Fourier transform infrared spectroscopy,X-ray photoelectron spectroscopy and synchrotron-based X-ray absorption spectroscopy.The results suggest that Cu2+ion adsorption is an entropy-driven endothermal process,possibly involving both outer-sphere and inner-sphere complexes. 相似文献
