Biogeochemical processes in a clay formation in situ experiment: Part E - Equilibrium controls on chemistry of pore water from the Opalinus Clay, Mont Terri Underground Research Laboratory, Switzerland     

F.J. Pearson  Christophe TournassatEric C. Gaucher 《Applied Geochemistry》2011,26(6):990-1008

The chemistry of pore water (particularly pH and ionic strength) is an important property of clay rocks being considered as host rocks for long-term storage of radioactive waste. Pore waters in clay-rich rocks generally cannot be sampled directly. Instead, their chemistry must be found using laboratory-measured properties of core samples and geochemical modelling. Many such measurements have been made on samples from the Opalinus Clay from the Mont Terri Underground Research Laboratory (URL). Several boreholes in that URL yielded water samples against which pore water models have been calibrated. Following a first synthesis report published in 2003, this paper presents the evolution of the modelling approaches developed within Mont Terri URL scientific programs through the last decade (1997-2009). Models are compared to the composition of waters sampled during dedicated borehole experiments. Reanalysis of the models, parameters and database enabled the principal shortcomings of the previous modelling efforts to be overcome. The inability to model the K concentrations correctly with the measured cation exchange properties was found to be due to the use of an inappropriate selectivity coefficient for Na-K exchange; the inability to reproduce the measured carbonate chemistry and pH of the pore waters using mineral-water reactions alone was corrected by considering clay mineral equilibria. Re-examination of the measured Ca/Mg activity ratios and consideration of the mineralogical composition of the Opalinus Clay suggested that Ca/Mg cation exchange rather than dolomite saturation may control the ratio of these ions in solution. This re-examination also suggests that the Ca/Mg ratio decreases with increasing pore-water salinity. Several possible reasons for this are proposed. Moreover, it is demonstrated that feldspar equilibria must not be included in Opalinus Clay modelling because feldspars are present only in very small quantities in the formation and because Na/K ratios measured in pore water samples are inconsistent with feldspar saturation. The principal need to improve future modelling is additional or better data on rock properties, in particular: (i) a more detailed identification of phases in the Opalinus Clay that include redox-sensitive elements together with evaluation of their thermodynamic properties; (ii) an improved understanding of the distribution of celestite throughout the Opalinus Clay for Sr/SO₄ concentrations control; (iii) improvements in analytic and thermodynamic data for Ca-Mg rock cation exchange and mineral chemical properties and (iv) the measurement of composition and stability constants of clay minerals actually present in the formation.  相似文献   

Biogeochemical processes in a clay formation in situ experiment: Part G - Key interpretations and conclusions. Implications for repository safety     

P. Wersin  S. Stroes-GascoyneF.J. Pearson  C. TournassatO.X. Leupin  B. Schwyn 《Applied Geochemistry》2011,26(6):1023-1034

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Granitic magmatism,basement ages,and provenance indicators in the Malay Peninsula: Insights from detrital zircon U–Pb and Hf-isotope data     

Inga Sevastjanova  Benjamin Clements  Robert Hall  Elena A. Belousova  William L. Griffin  Norman Pearson 《Gondwana Research》2011,19(4):1024-1039

The Malay Peninsula lies on two continental blocks, Sibumasu and East Malaya, which are intruded by granitoids in two provinces: the Main Range and Eastern. Previous models propose that Permian–Triassic granitoids are subduction-related and syn-to post-collisional. We present 752 U–Pb analyses that were carried out on zircons from river sands in the Malay Peninsula; of these, 243 grains were selected for Hf-isotope analyses. Our data suggest a more complex Sibumasu–East Malaya collision history. ¹⁷⁶Hf/¹⁷⁷Hf_i ratios reveal that Permian–Triassic zircons were sourced from three magmatic suites: (a) Permian crustally-derived granitoids, (b) Early-Middle Triassic granitoids with mixed mantle–crust sources, and (c) Late Triassic crustally-derived granitoids. This suggests three Permian–Triassic episodes of magmatism in the Malay Peninsula, two of which occurred in the Eastern Province. Although the exact timing of the Sibumasu–East Malaya collision remains unresolved, current data suggest that it occurred before the Late Triassic, probably in Late Permian–Early Triassic. Our data also indicate that Sibumasu and East Malaya basements are chronologically heterogeneous, but predominantly of Proterozoic age. Some basement may be Neoarchaean but there is no evidence for basement older than 2.8 Ga. Finally, we show that Hf-isotope signatures of Triassic zircons can be used as provenance indicators.  相似文献   

Uranium and Thorium Concentration and Isotopic Composition in Five Glass (BHVO‐2G,BCR‐2G,NKT‐1G,T1‐G,ATHO‐G) and Two Powder (BHVO‐2, BCR‐2) Reference Materials     

Kathryn A. Matthews  Michael T. Murrell  Steven J. Goldstein  Andrew J. Nunn  Deborah E. Norman 《Geostandards and Geoanalytical Research》2011,35(2):227-234

Here we report uranium and thorium isotopic ratios and elemental concentrations measured in solid reference materials from the USGS (BHVO‐2G, BCR‐2G, NKT‐1G), as well as those from the MPI‐DING series (T1‐G, ATHO‐G). Specifically created for microanalysis, these naturally‐sourced glasses were fused from rock powders. They cover a range of compositions, elemental concentrations and expected isotopic ratios. The U‐Th isotopic ratios of two powdered source materials (BCR‐2, BHVO‐2) were also characterised. These new measurements via multi‐collector thermal ionisation mass spectrometry and multi‐collector inductively coupled plasma‐mass spectrometry can now be used to assess the relative performance of techniques and facilitate comparison of U‐Th data amongst laboratories in the geoscience community for in situ and bulk analyses.  相似文献   

Was Himalayan normal faulting triggered by initiation of the Ramgarh–Munsiari thrust and development of the Lesser Himalayan duplex?     

Delores M. Robinson  Ofori N. Pearson 《International Journal of Earth Sciences》2013,102(7):1773-1790

The Ramgarh–Munsiari thrust is a major orogen-scale fault that extends for more than 1,500 km along strike in the Himalayan fold-thrust belt. The fault can be traced along the Himalayan arc from Himachal Pradesh, India, in the west to eastern Bhutan. The fault is located within the Lesser Himalayan tectonostratigraphic zone, and it translated Paleoproterozoic Lesser Himalayan rocks more than 100 km toward the foreland. The Ramgarh–Munsiari thrust is always located in the proximal footwall of the Main Central thrust. Northern exposures (toward the hinterland) of the thrust sheet occur in the footwall of the Main Central thrust at the base of the high Himalaya, and southern exposures (toward the foreland) occur between the Main Boundary thrust and Greater Himalayan klippen. Although the metamorphic grade of rocks within the Ramgarh–Munsiari thrust sheet is not significantly different from that of Greater Himalayan rock in the hanging wall of the overlying Main Central thrust sheet, the tectonostratigraphic origin of the two different thrust sheets is markedly different. The Ramgarh–Munsiari thrust became active in early Miocene time and acted as the roof thrust for a duplex system within Lesser Himalayan rocks. The process of slip transfer from the Main Central thrust to the Ramgarh–Munsiari thrust in early Miocene time and subsequent development of the Lesser Himalayan duplex may have played a role in triggering normal faulting along the South Tibetan Detachment system.  相似文献   

A Comparative Study of Five Reference Materials and the Lombard Meteorite for the Determination of the Platinum‐Group Elements and Gold by LA‐ICP‐MS     

Sarah Gilbert  Leonid Danyushevsky  Philip Robinson  Cora Wohlgemuth‐Ueberwasser  Norman Pearson  Dany Savard  Marc Norman  Jacob Hanley 《Geostandards and Geoanalytical Research》2013,37(1):51-64

A range of independently characterised reference materials (RMs) for LA‐ICP‐MS, used for the determination of the platinum‐group elements (PGE) and Au in a sulfide matrix, were analysed and compared: 8b, PGE‐A, NiS‐3, Po727‐T1, Po724‐T and the Lombard meteorite. The newly developed RM NiS‐3 was used as the RM for the calibration of all LA‐ICP‐MS analyses and the measured concentrations of the other RMs compared against their published concentrations. This data were also used to assess the consistency of concentrations calibrated against the different RMs. It was found that Po727‐T1 and 8b produced results that were comparable, within uncertainty, for all elements. Po727‐T1 also produced consistent results with NiS‐3 for all elements. All other RMs showed differences for some elements, especially Ru in Po724‐T, and Os, Ir and Au in PGE‐A. The homogeneity of the PGE and Au in each RM was assessed, by comparing the precision of multiple LA‐ICP‐MS spot analyses with the average uncertainty of the signal. Po724‐T, Po727‐T1 and the Lombard meteorite were found to be homogeneous for all elements, but 8b, PGE‐A and NiS‐3 were heterogeneous for some elements. This is the first direct comparison between a range of independently characterised PGE and Au LA‐ICP‐MS RMs.  相似文献   

Source depletion and extent of melting in the Tongan sub-arc mantle   总被引：3，自引：0，他引：3  

J.T. Caulfield  S.P. Turner  A. Dosseto  N.J. Pearson  C. Beier 《Earth and Planetary Science Letters》2008,273(3-4):279-288

The fluid immobile High Field Strength Elements (HFSE) Nb and Ta can be used to distinguish between the effects of variable extents of melting and prior source depletion of the Tongan sub-arc mantle. Melting of spinel lherzolite beneath the Lau Basin back-arc spreading centres has the ability to fractionate Nb from Ta due to the greater compatibility of the latter in clinopyroxene. The identified spatial variation in plate velocities and separation of melt extraction zones, combined with extremely depleted lavas make Tonga an ideal setting in which to test models for arc melt generation and the role of back-arc magmatism.We present new data acquired by laser ablation-ICPMS of fused sample glasses produced without the use of a melt fluxing agent. The results show an arc trend towards strongly sub-chondritic Nb/Ta (< 17) with values as low as 7.2. Melting models show that large degree melts of depleted MORB mantle fail to reproduce the observed Nb/Ta. Alternatively, incorporation of residual back-arc mantle that has undergone less than 1% melting into the sub-arc melting regime reproduces arc values. However, the extent of partial melting required to produce the composition of the Lau Basin back-arc basalts averages 7%. This apparent discrepancy can be explained if only the lowermost 4 km of the residua from the mantle melt column beneath the back-arc is added to the source of arc magmas. We have identified that the degree of arc/back-arc coupling displayed in the rock record provides an index of the depth of hydrous melting beneath the arc. In this case, this would imply a depth of ~ 75 km for generation of arc magmas, indicating that hydrous melting in the mantle wedge is triggered by the breakdown of hydrous phases in the subducting slab.  相似文献   

Elevation adjustments of paired natural levees during flooding of the Saskatchewan River     

Norman D. Smith  Marta Pérez‐Arlucea  Douglas A. Edmonds  Rudy L. Slingerland 《地球表面变化过程与地形》2009,34(8):1060-1068

Natural levees control the exchange of water between an alluvial channel and its floodplain, but little is known about the spatial distribution and evolution of levee heights. The summer 2005 flood of the Saskatchewan River (Cumberland Marshes, east‐central Saskatchewan) inundated large areas of floodplain for up to seven weeks, forming prominent new deposits on natural levees along main‐stem channels. Measurements of flood‐deposit thickness and crest heights of 61 levee pairs show that the thickest deposits occur on the lower pre‐flood levee in 80% of the sites, though no clear relationship exists between deposit thickness and magnitude of height difference. Only 16% of the pairs displayed thicker deposits on the higher levee, half of which occurred at sites where relatively clear floodbasin waters re‐entered turbid channels during general flooding. Difference in crest elevation (ΔE) between paired levees is approximately log‐normally distributed, both before and after the flood, though with different mean values. Supplemental observations from tank experiments indicate that during near‐bankfull flows, temporally and spatially variable deposition and erosion occur on levees due to backwater effects associated with nearby channel bars and irregular rises of the channel bed forced by channel extension. During floods, preferential deposition in lows tends to even out crest heights. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Truncation of the distribution of ground-motion residuals   总被引：4，自引：3，他引：1  

Fleur O. Strasser  Julian J. Bommer  Norman A. Abrahamson 《Journal of Seismology》2008,12(1):79-105

Recent studies to assess very long-term seismic hazard in the USA and in Europe have highlighted the importance of the upper tail of the ground-motion distribution at the very low annual frequencies of exceedance required by these projects. In particular, the use of an unbounded lognormal distribution to represent the aleatory variability of ground motions leads to very high and potentially unphysical estimates of the expected level of shaking. Current practice in seismic hazard analysis consists of truncating the ground-motion distribution at a fixed number (ε _max) of standard deviations (σ). However, there is a general lack of consensus regarding the truncation level to adopt. This paper investigates whether a physical basis for choosing ε _max can be found, by examining records with large positive residuals from the dataset used to derive one of the ground-motion models of the Next Generation Attenuation (NGA) project. In particular, interpretations of the selected records in terms of causative physical mechanisms are reviewed. This leads to the conclusion that even in well-documented cases, it is not possible to establish a robust correlation between specific physical mechanisms and large values of the residuals, and thus obtain direct physical constraints on ε _max. Alternative approaches based on absolute levels of ground motion and numerical simulations are discussed. However, the choice of ε _max is likely to remain a matter of judgment for the foreseeable future, in view of the large epistemic uncertainties associated with these alternatives. Additional issues arise from the coupling between ε _max and σ, which causes the truncation level in terms of absolute ground motion to be dependent on the predictive equation used. Furthermore, the absolute truncation level implied by ε _max will also be affected if σ is reduced significantly. These factors contribute to rendering a truncation scheme based on a single ε _max value impractical.  相似文献   

New views of Betelgeuse: multi-wavelength surface imaging and implications for models of hotspot generation     

J. S. Young  J. E. Baldwin  R. C. Boysen  C. A. Haniff  P. R. Lawson  †  C. D. Mackay  D. Pearson  J. Rogers  D. St.-Jacques  ‡  P. J. Warner  D. M. A. Wilson  R. W. Wilson § 《Monthly notices of the Royal Astronomical Society》2000,315(3):635-645

We report contemporaneous multi-wavelength interferometric imaging of the red supergiant star Betelgeuse ( α Orionis), using the Cambridge Optical Aperture Synthesis Telescope (COAST) and the William Herschel Telescope (WHT), at wavelengths of 700, 905 and 1290 nm. We find a strong variation in the apparent symmetry of the stellar brightness distribution as a function of wavelength. At 700 nm the star is highly asymmetric, and can be modelled as the superposition of three bright spots on a strongly limb-darkened disc. However, at 905 nm only a single low-contrast feature is visible and at 1290 nm the star presents a featureless symmetric disc. The change in spot contrast with wavelength is consistent with a model in which the bright spots represent unobscured areas of elevated temperature, owing perhaps to convection, on a stellar disc that itself has a different appearance, i.e. geometrical extent and limb-darkening profile, at different wavelengths. The featureless centre-to-limb brightness profile seen at 1290 nm is consistent with this model and suggests that future interferometric monitoring of the star to quantify the size changes associated with radial velocity variations should be performed at similar wavelengths in the near-infrared.  相似文献