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91.
92.
Pinarelli Laura Gioncada Anna Capaccioni Bruno Vaselli Orlando Downes Hilary 《Mineralogy and Petrology》2019,113(1):39-60
Mineralogy and Petrology - Vulcano is part of the Aeolian volcanic arc in the southern Tyrrhenian Sea. Its products were emplaced through multiple episodes of edifice building and collapse since... 相似文献
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Travertine deposits are important records of past fluid flow in the Earth's crust, and document fluid migration through both tectonic activity and changes in climate. While many studies hint at possible relationships between travertine formation and global climate, none have investigated these connections on a global scale. Here we compile 1649 published travertine ages from six continents to test the hypothesis that global and/or regional changes in climate regulate travertine deposition. Peaks in bedded travertine ages occur with main frequencies that correspond to 100‐kyr changes in global climate, where most peaks occur during glacial terminations or interglacial periods, including a large peak that coincides with the Early Holocene climatic optimum. Time–series analysis also suggests a possible connection with 41‐kyr obliquity cycles. At regional scales, many peaks also correspond with local times of high precipitation or wet conditions. This can be attributed to higher groundwater recharge rates, providing the necessary water to form travertine. Many bedded travertine‐depositing systems may therefore be water‐limiting and sufficient CO2 may be present even during times of no travertine deposition. Exceptions to this conclusion are banded vein travertine deposits, which typically form during times of dry climate when water tables are low. Copyright © 2019 John Wiley & Sons, Ltd. 相似文献
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Mariano Garcia Sassan Saatchi Antonio Ferraz Carlos Alberto Silva Susan Ustin Alexander Koltunov Heiko Balzter 《Carbon balance and management》2017,12(1):4
Background
Accurate estimation of aboveground forest biomass (AGB) and its dynamics is of paramount importance in understanding the role of forest in the carbon cycle and the effective implementation of climate change mitigation policies. LiDAR is currently the most accurate technology for AGB estimation. LiDAR metrics can be derived from the 3D point cloud (echo-based) or from the canopy height model (CHM). Different sensors and survey configurations can affect the metrics derived from the LiDAR data. We evaluate the ability of the metrics derived from the echo-based and CHM data models to estimate AGB in three different biomes, as well as the impact of point density on the metrics derived from them.Results
Our results show that differences among metrics derived at different point densities were significantly different from zero, with a larger impact on CHM-based than echo-based metrics, particularly when the point density was reduced to 1 point m?2. Both data models-echo-based and CHM-performed similarly well in estimating AGB at the three study sites. For the temperate forest in the Sierra Nevada Mountains, California, USA, R2 ranged from 0.79 to 0.8 and RMSE (relRMSE) from 69.69 (35.59%) to 70.71 (36.12%) Mg ha?1 for the echo-based model and from 0.76 to 0.78 and 73.84 (37.72%) to 128.20 (65.49%) Mg ha?1 for the CHM-based model. For the moist tropical forest on Barro Colorado Island, Panama, the models gave R2 ranging between 0.70 and 0.71 and RMSE between 30.08 (12.36%) and 30.32 (12.46) Mg ha?1 [between 0.69–0.70 and 30.42 (12.50%) and 61.30 (25.19%) Mg ha?1] for the echo-based [CHM-based] models. Finally, for the Atlantic forest in the Sierra do Mar, Brazil, R2 was between 0.58–0.69 and RMSE between 37.73 (8.67%) and 39.77 (9.14%) Mg ha?1 for the echo-based model, whereas for the CHM R2 was between 0.37–0.45 and RMSE between 45.43 (10.44%) and 67.23 (15.45%) Mg ha?1.Conclusions
Metrics derived from the CHM show a higher dependence on point density than metrics derived from the echo-based data model. Despite the median of the differences between metrics derived at different point densities differing significantly from zero, the mean change was close to zero and smaller than the standard deviation except for very low point densities (1 point m?2). The application of calibrated models to estimate AGB on metrics derived from thinned datasets resulted in less than 5% error when metrics were derived from the echo-based model. For CHM-based metrics, the same level of error was obtained for point densities higher than 5 points m?2. The fact that reducing point density does not introduce significant errors in AGB estimates is important for biomass monitoring and for an effective implementation of climate change mitigation policies such as REDD + due to its implications for the costs of data acquisition. Both data models showed similar capability to estimate AGB when point density was greater than or equal to 5 point m?2.97.
The scope for generating bio-oils with relatively low oxygen contents via hydropyrolysis 总被引：3，自引：0，他引：3
The primary oils obtained in high yields from fast (fluidised-bed) pyrolysis of biomass generally have high oxygen contents (ca. 40% w/w). The scope for using pyrolysis under hydrogen pressure (hydropyrolysis), to give oils with much lower oxygen contents compared to normal pyrolysis has been investigated. Fixed-bed hydropyrolysis tests have been conducted on cellulose, sugar cane bagasse and eucalyptus wood using hydrogen pressures up to 10 MPa, with heating rates of 5 and 300°C min−1. A colloidal FeS catalyst was used in some tests (Fe loading of 5%, w/w) to increase overall conversions. Further, the attractive option of using a two-stage reactor in which the primary oil vapors are passed though a bed of hydrotreating catalyst is also described. Raising the hydrogen pressure from atmospheric to 10 MPa reduced the oxygen content of the primary oil by over 10% to below 20% w/w. The addition of a dispersed iron sulphide catalyst gave conversions close to 100% for all three biomass samples investigated at 10 MPa under conditions in the fixed-bed reactor where significant diffusional resistances existed and reduced the oxygen content of the bio-oil by a further 10%. Although NMR indicated that the oils became increasingly aromatic as more oxygen was removed, the increase in hydrogen pressure decreased the extent of overall aromatisation that occurs primarily due to the lower char yields obtained. In two-stage tests for cellulose, using a commercial sulphided Ni/Mo γ-Al2O3 catalyst at 400°C, increasing the hydrogen pressure from 2.5 to 10 MPa decreased the oxygen content of the oil by over 20% to 10% w/w. The H/C ratios were higher and O/C ratios smaller for the two-stage bio-oils compared to their single stage counterparts. However, the differences in the O/C ratios between the single and two-stage bio-oils increase with pressure. 相似文献
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We discuss a strategy capable of a quantitative long-term monitoring of water saturation and volume variation of light non-aqueous phase liquids in the soil. The goal was reached monitoring a controlled sand cell contaminated with classical gasoline over 124 days, using geophysical methods such as electrical resistivity tomography, induced polarization and ground penetrating radar. We show that empirical relations, linking the water saturation to the physical parameters measured as resistivity from electrical resistivity tomography and travel time from georadar with advanced processing, are good tools for this purpose. The consistence of the proposed process is validated by both good overlap of results carried out from electrical resistivity tomography and georadar and theoretical models simulating the actual experiment. 相似文献
99.
Aaron T. Fricke Charles A. Nittrouer Andrea S. Ogston Daniel J. Nowacki Nils E. Asp Pedro W. M. Souza Filho 《地球表面变化过程与地形》2019,44(1):204-218
Depositional environments along the tidal river downstream of Óbidos have been proposed as important sinks for up to one third of the sediment discharge from the Amazon River. However, the morphology of the intertidal floodplain and the dynamics of sediment exchange along this reach have yet to be described. River-bank surveys in five regions along the Amazon tidal river reveal a distinct transition in bank morphology between the upper, central and lower reaches of the tidal river. The upper tidal-river floodplain is defined by prominent natural levees that control the transfer of water and sediment between the mainstem Amazon River and its floodplain. Greater tidal influence in the central tidal river suppresses levee development, and tidal currents increase sediment transport into the distal parts of the floodplain. In the lower tidal river, the floodplain morphology closely resembles marine intertidal environments (e.g. mud flats, salt marshes), with dendritic tidal channels incising elevated vegetated flats. Theory, morphology and geochronology suggest that the dynamics of sediment delivery to the intertidal floodplain of the Amazon tidal river vary along its length due to the relative influence and coupling of fluvial and tidal dynamics. © 2018 John Wiley & Sons, Ltd. 相似文献
100.
Two sedimentary cores with pollen, charcoal and radiocarbon data are presented. These records document the Late‐glacial and Holocene dry forest vegetation, fire and environmental history of the southern Cauca Valley in Colombia (1020 m). Core Quilichao‐1 (640 cm; 3° 6′N, 76° 31′W) represents the periods of 13 150–7720 14C yr BP and, following a hiatus, from 2880 14C yr BP to modern. Core La Teta‐2 (250 cm; 3° 5′N, 76° 32′W) provides a continuous record from 8700 14C yr BP to modern. Around 13 150 14C yr BP core Quilichao‐1 shows an active Late‐glacial drainage system and presence of dry forest. From 11 465 to 10 520 14C yr BP dry forest consists mainly of Crotalaria, Moraceae/Urticaceae, Melastomataceae/Combretaceae, Piper and low stature trees, such as Acalypha, Alchornea, Cecropia and Celtis. At higher elevation Andean forest comprising Alnus, Hedyosmum, Quercus and Myrica was common. After 10 520 14C yr BP the floral composition of dry forest changed, with extensive open grass vegetation indicative of dry climatic conditions. This event may coincide with the change to cool and dry conditions in the second part of the El Abra stadial, an equivalent to the Younger Dryas. From 8850 14C yr BP the record from La Teta indicates dry climatic conditions relative to the present, these prevailing up to 2880 14C yr BP at Quilichao and to 2720 14C yr BP at La Teta. Severe dryness reached maxima at 7500 14C yr BP and 4300 14C yr BP, when dry forest reached maximum expansion. Dry forest was gradually replaced by grassy vegetation, reaching maximum expansion around 2300 14C yr BP. After 2300 14C yr BP grassy vegetation remains abundant. Presence of crop taxa (a.o. Zea mays), disturbance indicators (Cecropia) and an increase in charcoal point to the presence of pre‐Columbian people since 2300 14C yr BP. After 950 14C yr BP, expansion of secondary forest taxa may indicate depopulation and abandonment of previously cultivated land. After 400 14C yr BP, possibly related to the Spanish conquest, secondary forest expanded and charcoal concentrations increased, possibly indicating further reduction of cultivated land. During the past century, Heliotropium and Didymopanax became abundant in an increasingly degraded landscape. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献