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1.
Five spinel lherzolite xenoliths hosted in Neogene alkali basalts from the marginal parts of the Pannonian Basin (Styrian Basin in Austria and Persani Mts. in the Eastern Transylvanian Basin, Romania) contain orthopyroxene–clinopyroxene–spinel clusters, which are believed to represent former garnet in lherzolitic mantle material. 'Palaeo' equilibrium pressure of this former garnet lherzolite was estimated to be equivalent to depths of 90–120 km using calculated garnet compositions and measured orthopyroxene compositions from the clusters. 'Neo' equilibrium pressures of the xenoliths indicate depths of 55–65 km, suggesting c. 50–60 km uprise of the mantle section represented by these xenoliths. This petrological result confirms the observations from previous geophysical studies that significant mantle uplift has occurred beneath the Pannonian Basin. 相似文献
2.
Hydrogeochemistry and strontium isotopes in the Arno River Basin (Tuscany, Italy): Constraints on natural controls by statistical modeling 总被引：2，自引：0，他引：2
B. Nisi A. Buccianti O. Vaselli G. Perini F. Tassi A. Minissale G. Montegrossi 《Journal of Hydrology》2008,360(1-4):166-183
In this paper the chemistry of major and trace elements and, for the first time, strontium isotopic ratios measured in running waters from the Arno River Basin (Tuscany, central-northern Italy) and thermal springs discharging in the same hydrographic system are presented and discussed. Classical graphical methods (e.g. mixing diagrams) have here been improved to identify, in a correct statistical sample space, extreme chemical compositions attributable to the action of geochemical processes and/or inherited from specific lithologies (namely contributions or components 1, 2 and 3) to be used in inverse modeling procedures, due to the absence of clear end-members. A linear least squares problem, with non-negativity constraints and distances, as required for compositional data (convex linear mixing) was solved by considering the contribution of the most discriminant variables given by the 87Sr/86Sr isotopic ratios and the concentration of Ca2+, Mg2+, Sr and Rb. Following such approach, it can be assumed (p < 0.05) that component 1, characterized by a Ca2+(Mg2+)– radiogenic-rich (87Sr/86Sr = 0.71274; Rb/Sr = 0.039), represents a dominant feature at basin scale, with a weight ranging from 69% to 100%. Much lower percentages are related to component 2, represented by a Ca2+(Mg2+)– facies with intermediate 87Sr/86Sr (0.70874) and low Rb/Sr (2.8 × 10−4) ratios and component 3, identified by Ca2+– facies with less radiogenic 87Sr/86Sr (0.70827) and low Mg2+/Ca2+ (0.011) ratios. These components are mainly dominated by the dissolution of evaporitic rocks and/or mixing with thermal waters in the southern part of the Arno River Basin and by dissolution of the carbonatic fraction, kinetically favored with respect to that of the silicatic minerals, in the upper reaches of the main course and its tributaries, respectively. 相似文献
3.
K. Garofalo F. Tassi O. Vaselli A. Delgado-Huertas D. Tedesco M. Frische T. H. Hansteen R. J. Poreda W. Strauch 《Bulletin of Volcanology》2007,69(7):785-795
Mombacho is a deeply dissected volcano belonging to the Quaternary volcanic chain of Nicaragua. The southern, historic collapse
crater (El Crater) currently hosts a fumarolic field with a maximum temperature of 121°C. Chemical and isotopic data from
five gas-sampling field campaigns carried out in 2002, 2003 and 2005 highlight the presence of high-temperature gas components
(e.g. SO2, HCl and HF), which indicate a significant contribution of juvenile magmatic fluids to the hydrothermal system feeding the
gas discharges. This is strongly supported by the mantle-derived helium and carbon isotopic signatures, although the latter
is partly masked by either a sedimentary subduction-related or a shallow carbonate component. The observed chemical and isotopic
composition of the Mombacho fluids seems to indicate that this volcanic system, although it has not experienced eruptive events
during the last centuries, can be considered active and possibly dangerous, in agreement with the geophysical data recorded
in the region. Systematic geochemical monitoring of the fumarolic gas discharges, coupled with a seismic and ground deformation
network, is highly recommended in order to monitor a possible new eruptive phase. 相似文献
4.
Pinarelli Laura Gioncada Anna Capaccioni Bruno Vaselli Orlando Downes Hilary 《Mineralogy and Petrology》2019,113(1):39-60
Mineralogy and Petrology - Vulcano is part of the Aeolian volcanic arc in the southern Tyrrhenian Sea. Its products were emplaced through multiple episodes of edifice building and collapse since... 相似文献
5.
In the present study, two sampling and analytical methods for VOC determination in fumarolic exhalations related to hydrothermal-magmatic reservoirs in volcanic and geothermal areas and biogas released from waste landfills were compared: (a) Solid Traps (STs), consisting of three phase (Carboxen B, Carboxen C and Carbosieve S111) absorbent stainless steel tubes and (b) Solid Phase Micro Extraction (SPME) fibers, composed of DiVinylBenzene (DVB), Carboxen and PolyDimethylSiloxane. These techniques were applied to pre-concentrate VOCs discharged from: (i) low-to-high temperature fumaroles collected at Vulcano Island, Phlegrean Fields (Italy), and Nisyros Island (Greece), (ii) recovery wells in a solid waste disposal site located near Florence (Italy). A glass condensing system cooled with water was used to collect the dry fraction of the fumarolic gases, in order to allow more efficient VOC absorption avoiding any interference by water vapor and acidic gases, such as SO2, H2S, HF and HCl, typically present at relatively high concentrations in these fluids. Up to 37 organic species, in the range of 40–400 m/z, were determined by coupling gas chromatography to mass spectrometry (GC–MS). This study shows that the VOC compositions of fumaroles and biogas determined via SPME and ST are largely consistent and can be applied to the analysis of VOCs in gases released from different natural and anthropogenic environments. The SPME method is rapid and simple and more appropriate for volcanic and geothermal emissions, where VOCs are present at relatively high concentrations and prolonged gas sampling may be hazardous for the operator. The ST method, allowing the collection of large quantities of sample, is to be preferred to analyze the VOC composition of fluids from diffuse emissions and air, where these compounds are present at relatively low concentrations. 相似文献
6.
Franco Tassi Bruno Capaccioni Giorgio Caramanna Daniele Cinti Giordano Montegrossi Luca Pizzino Fedora Quattrocchi Orlando Vaselli 《Applied Geochemistry》2009
A geochemical survey of thermal waters collected from submarine vents at Panarea Island (Aeolian Islands, southern Italy) was carried out from December 2002 to March 2007, in order to investigate (i) the geochemical processes controlling the chemical composition of the hydrothermal fluids and (ii) the possible relations between the chemical features of the hydrothermal reservoir and the activity of the magmatic system. Compositional data of the thermal water samples were integrated in a hydrological conceptual model, which describes the formation of the vent fluid by mixing of seawater, seawater concentrated by boiling, and a deep, highly-saline end-member, whose composition is regulated by water-rock interactions at relatively high temperature and shows clear clues of magmatic-related inputs. The chemical composition of concentrated seawater was assumed to be represented by that of the water sample having the highest Mg content. The composition of the deep end-member was instead calculated by extrapolation assuming a zero-Mg end-member. The Na–K–Ca geothermometer, when applied to the thermal end-member composition, indicated an equilibrium temperature of approximately 300 °C, a temperature in agreement with the results obtained by gas-geothermometry. 相似文献
7.
Lastarria volcano (25°10′ S, 68°31′ W; 5,697 m above sea level), located in the Central Andes Volcanic Zone (northern Chile),
is characterized by four distinct fumarolic fields with outlet temperatures ranging between 80°C and 408°C as measured between
May 2006–March 2008 and April–June 2009. Fumarolic gasses contain significant concentrations of high temperature gas compounds
(i.e., SO2, HCl, HF, H2, and CO), and isotopic ratios (3He/4He, δ13C–CO2, δ18O–H2O, and δD–H2O) diagnostic of magmatic gas sources. Gas equilibria systematics, in both the H2O-H2-CO2-CO-CH4 and alkane–alkene C3 system, suggest that Lastarria fumarolic gasses emanate from a superheated vapor that is later cooled and condensed at relatively
shallow depths. This two-stage process inhibits the formation of a continuous aquifer (e.g., horizontal liquid layer) at relatively
shallow depth. Recent developments in the magmatic gas system may have enhanced the transfer and release of heat causing shallow
aquifer vaporization. The consequent pressure increase and aquifer vaporization likely triggered the inflation events beginning
in 2003 at the Lastarria volcano. 相似文献
8.
Jacopo Cabassi Franco Tassi Orlando Vaselli Jens Fiebig Matteo Nocentini Francesco Capecchiacci Dmitri Rouwet Gabriele Bicocchi 《Bulletin of Volcanology》2013,75(1):1-19
This paper focuses on the chemical and isotopic features of dissolved gases (CH4 and CO2) from four meromictic lakes hosted in volcanic systems of Central–Southern Italy: Lake Albano (Alban Hills), Lake Averno (Phlegrean Fields), and Monticchio Grande and Piccolo lakes (Mt. Vulture). Deep waters in these lakes are characterized by the presence of a significant reservoir of extra-atmospheric dissolved gases mainly consisting of CH4 and CO2. The δ13C-CH4 and δD-CH4 values of dissolved gas samples from the maximum depths of the investigated lakes (from ?66.8 to ?55.6?‰ V-PDB and from ?279 to ?195?‰ V-SMOW, respectively) suggest that CH4 is mainly produced by microbial activity. The δ13C-CO2 values of Lake Grande, Lake Piccolo, and Lake Albano (ranging from ?5.8 to ?0.4?‰ V-PDB) indicate a significant CO2 contribution from sublacustrine vents originating from (1) mantle degassing and (2) thermometamorphic reactions involving limestone, i.e., the same CO2 source feeding the regional thermal and cold CO2-rich fluid emissions. In contrast, the relatively low δ13C-CO2 values (from ?13.4 to ?8.2?‰ V-PDB) of Lake Averno indicate a prevalent organic CO2. Chemical and isotopic compositions of dissolved CO2 and CH4 at different depths are mainly depending on (1) CO2 inputs from external sources (hydrothermal and/or anthropogenic); (2) CO2–CH4 isotopic exchange; and (3) methanogenic and methanotrophic activity. In the epilimnion, vertical water mixing, free oxygen availability, and photosynthesis cause the dramatic decrease of both CO2 and CH4 concentrations. In the hypolimnion, where the δ13C-CO2 values progressively increase with depth and the δ13C-CH4 values show an opposite trend, biogenic CO2 production from CH4 using different electron donor species, such as sulfate, tend to counteract the methanogenesis process whose efficiency achieves its climax at the water–bottom sediment interface. Theoretical values, calculated on the basis of δ13C-CO2 values, and measured δ13CTDIC values are not consistent, indicating that CO2 and the main carbon-bearing ion species (HCO3 ?) are not in isotopic equilibrium, likely due to the fast kinetics of biochemical processes involving both CO2 and CH4. This study demonstrates that the vertical patterns of the CO2/CH4 ratio and of δ13C-CO2 and δ13C-CH4 are to be regarded as promising tools to detect perturbations, related to different causes, such as changes in the CO2 input from sublacustrine springs, that may affect aerobic and anaerobic layers of meromictic volcanic lakes. 相似文献
9.
Evolution of fluid geochemistry at the Turrialba volcano (Costa Rica) from 1998 to 2008 总被引：3，自引：1，他引：2
O. Vaselli Franco Tassi E. Duarte E. Fernandez R. J. Poreda A. Delgado Huertas 《Bulletin of Volcanology》2010,72(4):397-410
Turrialba (10°02′N, 83°45′W) is a 3,349-m high stratovolcano belonging to the Holocene “Cordillera Central” volcanic belt
of Costa Rica. The summit consists of three EW-oriented craters (East, Central, and West). Since its last eruptive phase (1864–1866),
the Central and West craters have displayed modest fumarolic activity, with outlet temperatures clustering around 90°C. In
2001, seismic swarms, ground deformation, and increasing fumarolic activity occurred. From 2005 to 2008, new fumarolic vents
opened between and within the Central and West craters, and along the western and southwestern outer flanks of the volcanic
edifice. These physical changes were accompanied by a drastic modification in the gas chemistry that can be divided in three
stages: (1) hydrothermal (from 1998 to autumn 2001), characterized by the presence of H2O, CO2, H2S, and, to a very minor extent, HCl and HF; (2) hydrothermal/magmatic (autumn 2001–2007), with the appearance of SO2 and a significant increase of HCl and HF; and (3) magmatic-dominated (2007–2008), characterized by increased SO2 content, SO2/H2S > 100, and temperatures up to 282°C. Accordingly, gas equilibrium in the CO2-CH4-H2 system suggests a progressive evolution of the deep fluid reservoir toward higher temperatures and more oxidizing conditions.
The chemical–physical modifications of Turrialba in the last decade can be interpreted as part of a cyclic mechanism controlling
the balance between the hydrothermal and the magmatic systems. Nevertheless, the risk of rejuvenation of the volcanic activity
cannot be excluded, and an appropriate seismic, ground deformation, and geochemical monitoring program is highly recommended.
Turrialba lies at a distance of 35 and 15 km from San José and Cartago, respectively, the two largest cities in Costa Rica. 相似文献
10.
Benedetti-Cecchi L Bertocci I Micheli F Maggi E Fosella T Vaselli S 《Marine environmental research》2003,55(5):95-458
Marine protected areas (MPAs) are increasingly used as a management tool to preserve species and habitats. Testing hypotheses about the effectiveness of MPAs is important for their implementation and to identify informative criteria to support management decisions. This study tested the general proposition that MPAs affected assemblages of algae and invertebrates between 0.0 and 0.5 m above the mean low water level of rocky coasts on two islands in the Tuscan Archipelago (northwest Mediterranean). Protection was concentrated mainly on the west coasts of the islands, raising the possibility that neither the full range of assemblages nor the relevant scales of variation were properly represented within MPAs. This motivated the comparison of assemblages on opposite sides of islands (habitats). The effects of MPAs and habitat were assessed with a multifactorial sampling design; hypotheses were tested about differences in structure of assemblages, in mean abundance of common taxa and in univariate and multivariate measures of spatial variation. The design consisted of three replicate shores for each condition of protected and reference areas on the west side of each island and three unprotected shores on the eastern side. Assemblages were sampled independently four times on each island between June 1999 and January 2001. At each time of sampling two sites were selected randomly at each of two tidal heights to represent midshore and lowshore assemblages on each shore. Estimates of abundance were obtained using non-destructive sampling methods from five replicate 20x20 cm quadrats at each site. Results indicated differences among habitats in structure of assemblages, in mean abundance of common taxa and in univariate and multivariate measures of spatial variation at the scale of shores. Most of these patterns were inconsistent with the predicted effect of management through MPAs. The data suggest that designation of MPAs in the Tuscan Archipelago should proceed through management of multiple shores and types of habitat selected to guarantee protection to a representative sample of assemblages and to the processes responsible for maintenance of spatial patchiness at different scales. This study also shows that considerations of spatial heterogeneity are important to underpin management decisions about the number, size and location of MPAs. 相似文献