Rare gas isotopic compositions in natural gases of Japan     

Keisuke Nagao  Nobuo Takaoka  Osamu Matsubayashi 《Earth and Planetary Science Letters》1981,53(2):175-188

Isotopic and elemental compositions of rare gases in various types of gas samples collected in the Japanese Islands were investigated. Excess³He was found in most samples. Many samples showed a regionally uniform high³He/⁴He ratio of about 7 times the atmospheric ratio. The He concentrations varied from 0.6 to 1800 ppm, and they were low in CO₂-rich gases and high in N₂-rich gases. Ne isotopic deviations from the atmospheric Ne were detected in most volcanic gases. The deviations and the elemental abundance patterns in volcanic gases can be explained by a mixing between two components, one is mass fractionated rare gases and the other is isotopically atmospheric and is enriched in heavy rare gas elements. Ar was a mixture of mass fractionated Ar, atmospheric Ar and radiogenic Ar, and the contribution of radiogenic⁴⁰Ar was small in all samples. Except for He, elemental abundance patterns were progressively enriched in the heavier rare gases relative to the atmosphere. Several samples were highly enriched in Kr and Xe relative to the abundance pattern of dissolution equilibrium of atmospheric rare gases in water. The component which is highly enriched in heavy rare gases may be released from sedimentary materials in the crust.  相似文献   

Partition of magnesium and iron between Olivine and spinel,and between pyroxene and spinel     

Osamu Nishizawa  Syun-iti Akimoto 《Contributions to Mineralogy and Petrology》1973,41(3):217-230

Partition of Fe²⁺ and Mg between coexisting (Mg, Fe)₂SiO₄ spinel and (Mg, Fe)SiO₃ pyroxene was investigated at pressures 80 and 90 kbar and at temperatures 840 and 1050° C, using tetrahedral-anvil type of high pressure apparatus. Olivine-spinel solid solution equilibria in the system Mg₂SiO₄-Fe₂SiO₄ were discussed in the light of the partition reaction. Partition of Fe²⁺ and Mg in both olivine-spinel and pyroxene-spinel systems can not be regarded as that between ideal solid solutions. By applying the simple solution model for the partition of Fe²⁺ and Mg, sign of the heat of mixing was estimated to be positive for all olivine, spinel and pyroxene. Relative concentration of Fe²⁺ in spinel in the pyroxene-spinel system is likely to cause some change in the chemical composition of modified spinel () or spinel () in the transition zone of the mantle. A considerable change is also expected in the transition pressure of to ( + ) and ( + ) to .Presented at the symposium Recent Advances in the Studies of Rocks and Minerals at High Pressures and Temperatures held in Montreal, 1972. Jointly sponsored by the International Mineralogical Association and the Commission on Experimental Petrology.  相似文献   

In situ X-ray observations of the decomposition of brucite and the graphite–diamond conversion in aqueous fluid at high pressure and temperature     

T. Okada  W. Utsumi  H. Kaneko  M. Yamakata  O. Shimomura 《Physics and Chemistry of Minerals》2002,29(7):439-445

 An experimental technique to make real-time observations at high pressure and temperature of the diamond-forming process in candidate material of mantle fluids as a catalyst has been established for the first time. In situ X-ray diffraction experiments using synchrotron radiation have been performed upon a mixture of brucite [Mg(OH)₂] and graphite as starting material. Brucite decomposes into periclase (MgO) and H₂O at 3.6 GPa and 1050 °C while no periclase is formed after the decomposition of brucite at 6.2 GPa and 1150 °C, indicating that the solubility of the MgO component in H₂O greatly increases with increasing pressure. The conversion of graphite to diamond in aqueous fluid has been observed at 7.7 GPa and 1835 °C. Time-dependent X-ray diffraction profiles for this transformation have been successfully obtained. Received: 17 July 2001 / Accepted: 18 February 2002  相似文献   

Step-like temperature fluctuations associated with inverted ramps in a stable surface layer   总被引：1，自引：0，他引：1  

Tokio Kikuchi  Osamu Chiba 《Boundary-Layer Meteorology》1985,31(1):51-63

Ensemble averages of temperature before and after step-like temperature fluctuations reveal the presence of inverted ramps in a stable surface layer. Normalized frequency of upward steps increases with increasing stability, whereas normalized magnitude of the temperature step decreases with stability and becomes constant at about R _i = 1. These results suggest that the significance of temperature steps increases as stability increases. In moderate stability, the temperature pattern shows a gradual decrease after an upward step, which can be called a time-inverted ramp. Descending air and large downward heat flux are observed in a time-inverted ramp, suggesting a contribution from an ordered motion in wind. On the other hand, the temperature steps are related to gravity waves in strong stability.  相似文献   

Photosynthesis-irradiance relationship of phytoplankton and primary production in the vicinity of Kuroshio warm core ring in spring     

Ken Furuya  Osamu Hasegawa  Takashi Yoshikawa  Satoru Taguchi 《Journal of Oceanography》1998,54(5):545-552

The light-saturated maximum value (P ^B _max) and initial slope (α) of the photosynthesis-irradiance (P-E) curve were examined in a warm streamer, a cold streamer and a warm core ring off the Sanriku area in the subarctic western North Pacific Ocean during an ADEOS/OCTS Sanriku field campaign in early May 1997. BothP ^B _max and α were within the ranges of temperate populations. A regional difference was apparent inP ^B _max: populations in the warm streamer tended to show higher value ranging between 1.92 and 4.74 mgC (mgChla)⁻¹h⁻¹ than those in the cold streamer and the warm core ring (1.35–2.87 mgC (mgChla)⁻¹h⁻¹). A depth variation was also observed in α in both the warm streamer and the warm core ring: shallow populations tended to have lower α than deep populations. The depth variations in bothP ^B _max and α resulted in a lower light intensity of the light saturation in a deeper population than that of a shallower one. These depth-related variations in the P-E parameters were likely a manifestation of “shade-adaptation” of photosynthesis. Photoinhibition was not observed over in situ surface light intensity varying below ca 1600 μmol photon m⁻²s⁻¹. Water-column primary productivity was biooptically estimated to be 233 to 949 mgC m⁻²d⁻¹ using vertical distributions of the P-E parameters, chlorophylla, phytoplankton light absorption and underwater irradiance. Applicability of surface data sets for estimation of water-column productivity is discussed.  相似文献   

Phytoremediation of shallow organically enriched marine sediments using benthic microalgae     

Yamamoto T  Goto I  Kawaguchi O  Minagawa K  Ariyoshi E  Matsuda O 《Marine pollution bulletin》2008,57(1-5):108-115

We examined whether replantation of benthic microalgae (BMA) can remediate shallow organically enriched sediment. Nitzschia sp., the dominant species in the tested area (Hiroshima Bay, Japan), was isolated and mass cultured, then replanted in the same area. Changes in the condition of the sediment were monitored for five months. During the study period, we observed an increase in redox potential (ORP) and a decrease in acid-volatile sulfide (AVS) in the experimental area, indicating that the sediment condition changed from reduced to oxic. Organic matter in the sediment, represented by chemical oxygen demand (COD), ignition loss (IL) and organic nitrogen (ON) decreased significantly, while inorganic nutrients (ammonia and phosphate) increased in the interstitial water. These changes imply that oxygen produced by the replanted BMA may have enhanced aerobic bacterial activity, accelerating the decomposition of organic matter. Thus, replantation of BMA shows potential as a novel and promising "phytoremediation" method for organically enriched sediment.  相似文献   

Process of the Tsushima Current formation revealed by ADCP measurements in summer   总被引：1，自引：0，他引：1  

Osamu Katoh  Kazuyuki Teshima  Osamu Abe  Hitoshi Fujita  Kuniaki Miyaji  Kenji Morinaga  Norihisa Nakagawa 《Journal of Oceanography》1996,52(4):491-507

In order to clarify detailed current structures over the continental shelf margin in the East China Sea, ADCP measurements were carried out in summers in 1991 and 1994 by the quadrireciprocal method (Katoh, 1988) for removing diurnal and semidiurnal tidal flows from observed flows, together with CTD measurements. We discussed the process of the Tsushima Current formation in the East China Sea. The Tsushima Current with a volume transport of 2 Sv (1 Sv=10⁶ m³s^–1) was found north of 31°N. A current with a volume transport of 0.4 Sv was clearly found along the 100 m isobath. Between the Kuroshio and the current along the 100 m isobath, southeastward component of velocity was dominant compared to northwestward one. Four eastward to southeastward currents were found over the sea bed shallower than 90 m depth. Total volume transport of these four currents was 1 Sv, and they seemed to be originated from the Taiwan Strait. Intrusion of offshore water into the inner shelf northwest of Amami Oshima was estimated to have a volume transport of 0.6 Sv. It is concluded that the Tsushima Current is the confluence of these currents over the continental shelf margin with the offshore water intruding northwest of Amami Oshima.  相似文献   

Middle Layer Intrusion as an Important Factor Supporting Phytoplankton Productivity at a Tidal Front in Iyo Nada, the Seto Inland Sea, Japan     

Tamiji Yamamoto  Toshiya Hashimoto  Hidetaka Takeoka  Tenji Sugiyama  Osamu Matsuda 《Journal of Oceanography》2000,56(2):131-139

Field observations were conducted to examine the processes governing the phytoplankton distribution and photosynthetic activity in and around a tidal front formed in Iyo Nada, the Seto Inland Sea, Japan. The existence of a middle layer intrusion, which, it has been suggested, moves from the mixed region to the stratified region of the tidal front, was ascertained by the phytoplankton distribution in addition to a T-S diagram. Skeletonema costatum, which originally inhabited the mixed region, was used as the indicator to reveal the intrusion. However, the tip of water containing the S. costatum population did not extend deeply into the stratified region. The velocity of the intrusion seemed to be slow enough to make biological processes, such as nutrient uptake by phytoplankton and subsequent growth, as well as the decrease in cell density due to zooplankton grazing, dominate during the transportation. The patchy distribution of copepod nauplii implied that grazing has an influence on the distribution pattern of phytoplankton. The location of high photosynthetic activity did not coincide spatially with the center of high phytoplankton biomass, suggesting the importance of these biological processes. Therefore, it is considered that the middle layer intrusion plays a role as an inducer of subsequent biological processes at the tidal front by not only supplying nutrients from the mixed region but also by increasing the vertical diffusivity.  相似文献   

The Role of Suspended Oyster Culture on Nitrogen Cycle in Hiroshima Bay   总被引：1，自引：0，他引：1  

Putth Songsangjinda  Osamu Matsuda  Tamiji Yamamoto  Narasimmalu Rajendran  Hajime Maeda 《Journal of Oceanography》2000,56(2):223-231

The predominance of bivalves affects the cycle of materials in the coastal ecosystem. In the present study, the role of suspended oyster culture on the nitrogen cycle was demonstrated for the northern Hiroshima Bay. The nitrogen cycle was considered as two systems, (1) the primary production (PP) system and (2) the oyster culture (OC) system. The results show that about 26% of N productivity was supplied to process by cultured oysters in the OC system. This process varies seasonally due to the seasonal variations of PON, physiological activities and biomass of oysters. The N processing rates were found to be high in summer and low in winter. The biodeposition and excretion of N in the OC system are 3.0 and 2.1 ton N d^–1, while the natural sedimentation rate and N regeneration in the PP system are 8.3 and 18.0 ton N d^–1, which indicates that the PP system is a major system regenerating N in the water column. The release of total dissolved N from the bottom to the water column is about 8.3 ton N d^–1. The amount of N harvested as oyster product was about 1.3 ton N d^–1, which is about 10% of daily N loading in north Hiroshima Bay. According to the N cycle developed in the present study, the results suggest the significant role of suspended oyster culture on the nitrogen cycle in Hiroshima Bay. In addition, our results indicate that oyster production was efficiently harvested, suggesting that oyster culture could probably be used as a tool to remove N from Hiroshima Bay.  相似文献   

Surface current structure of the Tsushima Warm Current region in the Japan Sea derived by satellite-tracked surface drifters     

Tatsuro Watanabe  Daisuke Simizu  Kou Nishiuchi  Toru Hasegawa  Osamu Katoh 《Journal of Oceanography》2009,65(6):791-801

We examined the surface current structure in the Tsushima Warm Current (TWC) region of the Japan Sea based on a dataset from satellite-tracked surface drifters, including our new deployments during 2004–2008. The gridded mean current velocity and mean kinetic energy (KE) fields calculated from all available drifter data revealed the structure and seasonality of the three branches of the TWC. By comparing the eddy kinetic energy (EKE) field to the KE field, we found four regions where the ratio of EKE to KE was high. In particular, this ratio became extremely high east of the Oki Islands located between the first branch of the TWC (FBTWC) and the second branch of the TWC (SBTWC). Our analysis suggests that the generation of alternate warm and cold eddies east of the Oki Island induced this high ratio. The occurrence of a warm or cold eddy was related to the route—either nearshore or offshore—of the SBTWC. When the offshore route of the SBTWC became dominant, a warm eddy was frequently generated east of the Oki Islands. In contrast, when the nearshore route of the SBTWC became dominant, a cold eddy was more likely to be generated.  相似文献